TWI702317B - 用於高速紡絲應用之雙重終端聚醯胺 - Google Patents
用於高速紡絲應用之雙重終端聚醯胺 Download PDFInfo
- Publication number
- TWI702317B TWI702317B TW105142834A TW105142834A TWI702317B TW I702317 B TWI702317 B TW I702317B TW 105142834 A TW105142834 A TW 105142834A TW 105142834 A TW105142834 A TW 105142834A TW I702317 B TWI702317 B TW I702317B
- Authority
- TW
- Taiwan
- Prior art keywords
- dual
- polyamide
- terminal
- fibers
- mmol
- Prior art date
Links
- 238000009987 spinning Methods 0.000 title claims abstract description 45
- 239000004952 Polyamide Substances 0.000 title claims abstract description 37
- 229920002647 polyamide Polymers 0.000 title claims abstract description 37
- 239000000835 fiber Substances 0.000 claims abstract description 100
- 238000000034 method Methods 0.000 claims abstract description 29
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims abstract description 21
- 229920002292 Nylon 6 Polymers 0.000 claims description 104
- 230000009977 dual effect Effects 0.000 claims description 27
- 238000004519 manufacturing process Methods 0.000 claims description 9
- 125000003277 amino group Chemical group 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 abstract description 15
- 239000011347 resin Substances 0.000 description 54
- 229920005989 resin Polymers 0.000 description 54
- 239000000463 material Substances 0.000 description 49
- 239000004744 fabric Substances 0.000 description 15
- 238000004043 dyeing Methods 0.000 description 11
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 10
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 10
- 229920002302 Nylon 6,6 Polymers 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 7
- 239000004753 textile Substances 0.000 description 7
- 229920003189 Nylon 4,6 Polymers 0.000 description 6
- 229920000305 Nylon 6,10 Polymers 0.000 description 6
- 239000002253 acid Substances 0.000 description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 4
- 238000009941 weaving Methods 0.000 description 4
- 238000004804 winding Methods 0.000 description 4
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- -1 and in particular Substances 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 238000004020 luminiscence type Methods 0.000 description 3
- 239000002932 luster Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000002411 thermogravimetry Methods 0.000 description 3
- 230000004580 weight loss Effects 0.000 description 3
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000002657 fibrous material Substances 0.000 description 2
- 235000019253 formic acid Nutrition 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- CNPURSDMOWDNOQ-UHFFFAOYSA-N 4-methoxy-7h-pyrrolo[2,3-d]pyrimidin-2-amine Chemical group COC1=NC(N)=NC2=C1C=CN2 CNPURSDMOWDNOQ-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000000980 acid dye Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 235000019445 benzyl alcohol Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/253—Formation of filaments, threads, or the like with a non-circular cross section; Spinnerette packs therefor
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
- D01F6/60—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyamides
- D01F6/605—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyamides from aromatic polyamides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
- C08G69/14—Lactams
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
- C08G69/14—Lactams
- C08G69/22—Beta-lactams
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/48—Polymers modified by chemical after-treatment
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/08—Melt spinning methods
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/12—Stretch-spinning methods
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
- D01F6/60—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyamides
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mechanical Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Artificial Filaments (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201562387441P | 2015-12-23 | 2015-12-23 | |
| US62/387,441 | 2015-12-23 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW201736654A TW201736654A (zh) | 2017-10-16 |
| TWI702317B true TWI702317B (zh) | 2020-08-21 |
Family
ID=59088194
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW105142834A TWI702317B (zh) | 2015-12-23 | 2016-12-22 | 用於高速紡絲應用之雙重終端聚醯胺 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US10494740B2 (enExample) |
| EP (1) | EP3394330B1 (enExample) |
| JP (1) | JP6927979B2 (enExample) |
| KR (1) | KR102615689B1 (enExample) |
| CN (1) | CN108368645B (enExample) |
| ES (1) | ES2878070T3 (enExample) |
| MY (1) | MY183674A (enExample) |
| TW (1) | TWI702317B (enExample) |
| WO (1) | WO2017112890A1 (enExample) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA3118466C (en) * | 2018-11-09 | 2023-05-16 | Advansix Resins & Chemicals Llc | Stain resistant polyamide polymers obtained via high end group termination |
| CN115427481B (zh) * | 2020-02-18 | 2024-05-31 | 艾德凡斯化学公司 | 基于聚酰胺的母料制剂 |
| CN117337313A (zh) * | 2021-03-03 | 2024-01-02 | 艾德凡斯化学公司 | 高流动性双封端聚酰胺聚合物 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5176926A (en) * | 1991-08-27 | 1993-01-05 | E. I. Du Pont De Nemours And Company | Spinnerets for producing trilobal and tetralobal filaments exhibiting low glitter and high bulk |
| KR100264615B1 (ko) * | 1992-06-06 | 2000-09-01 | 스타르크 카르크 | 폴리카프로락탐을 기재로 한 고속 방적 필라멘트사 및 이들의 제조 방법 |
| JP2001200055A (ja) * | 2000-01-19 | 2001-07-24 | Toray Ind Inc | ポリアミド樹脂の製造法およびポリアミド繊維 |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ATE67799T1 (de) | 1985-04-22 | 1991-10-15 | Basf Corp | Verfahren zum schnellspinnen von polyamidfasern. |
| US5462802A (en) * | 1991-12-02 | 1995-10-31 | Teijin Limited | Polyamide hollow and/or non-circular fiber and process for making same |
| US6051312A (en) * | 1996-06-06 | 2000-04-18 | Dsm Nv | Fibers of strongly branched polyamide |
| US5851238A (en) * | 1996-07-31 | 1998-12-22 | Basf Corporation | Photochemically stabilized polyamide compositions |
| DE19854421B4 (de) * | 1998-11-25 | 2006-11-02 | Ems-Inventa Ag | Verfahren zur Herstellung von Polyamid-6 für Spinnzwecke |
| US6268468B1 (en) | 2000-07-10 | 2001-07-31 | Basf Corporation | Treatment of polyamide with gas phase of acid anhydride or amine |
| WO2007128715A1 (en) * | 2006-05-04 | 2007-11-15 | Clariant International Ltd | Process for improved and controlled dyeability of polyamide-6 fibers |
| US8663524B2 (en) | 2009-05-12 | 2014-03-04 | Miller Waste Mills | Controlled geometry composite micro pellets for use in compression molding |
| KR101755054B1 (ko) | 2009-09-14 | 2017-07-06 | 미츠비시 가스 가가쿠 가부시키가이샤 | 폴리아미드 수지 조성물 |
| TW201307436A (zh) * | 2011-08-08 | 2013-02-16 | Chain Yarn Co Ltd | 可深染且高速紡絲之聚醯胺－６纖維及其製造與控制其染色性之方法 |
| KR20140101045A (ko) * | 2013-02-07 | 2014-08-19 | 주식회사 효성 | 용융 안정성과 조업성이 개선된 폴리아미드의 제조방법 |
| FR3010093B1 (fr) | 2013-09-04 | 2015-08-14 | Arkema France | Monofilament a base d'une composition de polyamide |
| CN104130404B (zh) * | 2014-07-23 | 2016-11-02 | 苏州大学 | 一种链端修饰的聚酰胺6、制备方法及应用 |
| CN104480561B (zh) * | 2014-12-12 | 2016-08-24 | 东华大学 | 一种己内酰胺水解聚合物纤维及其纺丝方法 |
-
2016
- 2016-12-22 KR KR1020187020668A patent/KR102615689B1/ko active Active
- 2016-12-22 MY MYPI2018702175A patent/MY183674A/en unknown
- 2016-12-22 WO PCT/US2016/068390 patent/WO2017112890A1/en not_active Ceased
- 2016-12-22 EP EP16880109.0A patent/EP3394330B1/en active Active
- 2016-12-22 US US15/388,999 patent/US10494740B2/en active Active
- 2016-12-22 JP JP2018532785A patent/JP6927979B2/ja active Active
- 2016-12-22 CN CN201680075597.3A patent/CN108368645B/zh active Active
- 2016-12-22 TW TW105142834A patent/TWI702317B/zh active
- 2016-12-22 ES ES16880109T patent/ES2878070T3/es active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5176926A (en) * | 1991-08-27 | 1993-01-05 | E. I. Du Pont De Nemours And Company | Spinnerets for producing trilobal and tetralobal filaments exhibiting low glitter and high bulk |
| KR100264615B1 (ko) * | 1992-06-06 | 2000-09-01 | 스타르크 카르크 | 폴리카프로락탐을 기재로 한 고속 방적 필라멘트사 및 이들의 제조 방법 |
| JP2001200055A (ja) * | 2000-01-19 | 2001-07-24 | Toray Ind Inc | ポリアミド樹脂の製造法およびポリアミド繊維 |
Also Published As
| Publication number | Publication date |
|---|---|
| TW201736654A (zh) | 2017-10-16 |
| EP3394330A1 (en) | 2018-10-31 |
| JP6927979B2 (ja) | 2021-09-01 |
| CN108368645A (zh) | 2018-08-03 |
| KR20180087445A (ko) | 2018-08-01 |
| KR102615689B1 (ko) | 2023-12-18 |
| EP3394330B1 (en) | 2021-03-31 |
| US20170183796A1 (en) | 2017-06-29 |
| WO2017112890A1 (en) | 2017-06-29 |
| US10494740B2 (en) | 2019-12-03 |
| JP2018538460A (ja) | 2018-12-27 |
| EP3394330A4 (en) | 2019-07-24 |
| MY183674A (en) | 2021-03-08 |
| ES2878070T3 (es) | 2021-11-18 |
| CN108368645B (zh) | 2021-02-09 |
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