TWI687636B - Sinter ore manufacturing method - Google Patents
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- TWI687636B TWI687636B TW107136625A TW107136625A TWI687636B TW I687636 B TWI687636 B TW I687636B TW 107136625 A TW107136625 A TW 107136625A TW 107136625 A TW107136625 A TW 107136625A TW I687636 B TWI687636 B TW I687636B
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C1/00—Refining of pig-iron; Cast iron
- C21C1/02—Dephosphorising or desulfurising
- C21C1/025—Agents used for dephosphorising or desulfurising
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B1/00—Preliminary treatment of ores or scrap
- C22B1/14—Agglomerating; Briquetting; Binding; Granulating
- C22B1/16—Sintering; Agglomerating
- C22B1/22—Sintering; Agglomerating in other sintering apparatus
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B5/00—Making pig-iron in the blast furnace
- C21B5/008—Composition or distribution of the charge
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B1/00—Preliminary treatment of ores or scrap
- C22B1/14—Agglomerating; Briquetting; Binding; Granulating
- C22B1/16—Sintering; Agglomerating
- C22B1/20—Sintering; Agglomerating in sintering machines with movable grates
- C22B1/205—Sintering; Agglomerating in sintering machines with movable grates regulation of the sintering process
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B1/00—Preliminary treatment of ores or scrap
- C22B1/14—Agglomerating; Briquetting; Binding; Granulating
- C22B1/24—Binding; Briquetting ; Granulating
- C22B1/242—Binding; Briquetting ; Granulating with binders
- C22B1/244—Binding; Briquetting ; Granulating with binders organic
- C22B1/245—Binding; Briquetting ; Granulating with binders organic with carbonaceous material for the production of coked agglomerates
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B1/00—Preliminary treatment of ores or scrap
- C22B1/26—Cooling of roasted, sintered, or agglomerated ores
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Abstract
本發明提供一種即便燒結的反應溫度變動,亦可儘早把握該變動而抑制設備障礙的燒結礦的製造方法。 本發明的燒結礦的製造方法於調配有含鐵原料、含CaO原料及凝結材料的燒結原料中添加水進行造粒,並利用燒結機進行燒結而製造燒結礦,且所述燒結礦的製造方法包括:測定步驟,連續測定燒結礦的成分濃度;以及托板台車速度的調整步驟,使用測定步驟中測定的燒結礦的成分濃度來調整托板台車的行進速度。The present invention provides a method for producing a sintered ore that can grasp the change as soon as possible even if the reaction temperature of the sintering changes and suppress equipment troubles. The method for producing sintered ore of the present invention adds water to the sintered raw material blended with iron-containing raw material, CaO-containing raw material and coagulation material for granulation, and sintering with a sintering machine to produce sintered ore, and the method for producing the sintered ore It includes: a measurement step, which continuously measures the component concentration of the sintered ore; and an adjustment step of the speed of the pallet trolley, which uses the component concentration of the sintered ore measured in the measurement step to adjust the traveling speed of the pallet trolley.
Description
本發明是有關於一種燒結礦的製造方法,具體而言,本發明是有關於一種測定燒結礦的成分濃度,並使用該成分濃度來調整托板台車的行進速度的燒結礦的製造方法。The present invention relates to a method of manufacturing sintered ore. Specifically, the present invention relates to a method of manufacturing sintered ore which measures the component concentration of the sintered ore and uses the component concentration to adjust the traveling speed of the pallet trolley.
於高爐製鐵法中,作為鐵源,主要使用燒結礦或塊鐵礦石、球團礦(pellet)等含鐵原料作為高爐原料。此處,燒結礦是利用圓筒混合機(drum mixer)對燒結原料一面添加水一面進行混合、造粒,並煅燒而成的團塊礦的一種,所述燒結原料是於粒徑為10 mm以下的鐵礦石及製鐵所內產生的各種鐵粉(dust)等雜鐵源中,調配石灰石或生石灰、製鋼爐渣等含CaO原料,焦炭粉或無煙炭等凝結材料,作為任意調配原料的包含精煉鎳爐渣、白雲石(dolomite)、蛇紋岩等的含MgO原料,以及包含精煉鎳爐渣、矽石(矽砂)等的含SiO2 原料而成。In the blast furnace ironmaking method, as the iron source, iron-containing raw materials such as sintered ore lump iron ore, pellets, etc. are mainly used as blast furnace raw materials. Here, the sintered ore is a kind of agglomerate ore obtained by mixing, granulating, and calcining the sintering raw material using a drum mixer to add water while adding water. The particle size of the sintering raw material is 10 mm. CaO-containing raw materials such as limestone or quicklime, steel-making slag, etc., and condensing materials such as coke powder or smokeless charcoal are included in the following iron ore and various iron powder (dust) generated in iron making, as arbitrarily prepared raw materials. Refined nickel slag, dolomite (dolomite), serpentine and other MgO-containing raw materials, and refined nickel slag, silica (silica) and other SiO 2 containing raw materials.
近年來,燒結礦的原料即燒結原料所含的鐵礦石的鐵成分濃度降低,取而代之,SiO2 或Al2 O3 等脈石成分濃度增加,即便於同種鐵礦石內,有時成分濃度亦於進口時的每條船中不同,所產出的鐵礦石的成分濃度變得不穩定。In recent years, the iron component concentration of the iron ore contained in the raw material of the sintered ore has decreased. Instead, the concentration of gangue components such as SiO 2 or Al 2 O 3 has increased. Even in the same type of iron ore, the component concentration may sometimes be It is also different in each ship at the time of import, and the component concentration of the produced iron ore becomes unstable.
對於製鐵所內產生的各種鐵粉而言,產生量的偏差或所含碳的變動量大。若燒結原料所含的碳量的變動增大,則燒結的反應溫度變動。For the various iron powders produced in iron making, there is a large variation in the amount of production or a variation in the amount of carbon contained. When the variation in the amount of carbon contained in the sintering raw material increases, the reaction temperature for sintering varies.
燒結的反應溫度的變動導致作為成品的成品燒結礦(以下,亦簡單記載為「燒結礦」)的品質變動,大幅度地影響燒結礦的品質。例如,於熱量過剩的情形時,燒結的反應溫度上升,於燒結礦中形成玻璃質的低強度組織,磁鐵礦(magnetite)組織增加而被還原性降低等,導致燒結礦的品質降低。另一方面,於熱量不足的情形時,燒結的反應溫度降低,可能原本不引起燒結反應,於該情形時無法獲得燒結礦自身。因此,管理燒結的反應溫度對於維持穩定的燒結礦品質而言不可或缺。Variations in the reaction temperature of sintering cause variations in the quality of the finished sintered ore (hereinafter also simply referred to as "sintered ore"), which greatly affects the quality of the sintered ore. For example, in the case of excess heat, the reaction temperature of sintering rises, a glassy low-strength structure is formed in the sintered ore, the magnetite (magnetite) structure increases and the reducibility is reduced, and the quality of the sintered ore decreases. On the other hand, in the case of insufficient heat, the reaction temperature of sintering decreases, which may not cause the sintering reaction originally, and in this case, the sintered ore itself cannot be obtained. Therefore, managing the reaction temperature of sintering is indispensable for maintaining stable sintered ore quality.
但是,連續地測定燒結的反應溫度非常困難。因此,通常藉由對燒結礦的成分進行分析而推定燒結的反應溫度,進行熱量管理。具體而言,測定燒結礦的FeO濃度或殘留的C濃度。於燒結反應中,燒結礦的赤鐵礦(hematite)隨著溫度上升而熱解離成磁鐵礦。隨著反應後的溫度降低,再次由磁鐵礦轉變成赤鐵礦,但並非經熱解離的磁鐵礦的總量恢復成赤鐵礦,故而若燒結的反應溫度高,則燒結礦中大量殘留磁鐵礦。磁鐵礦包含二價Fe,故而燒結礦的FeO濃度成為表示燒結的反應溫度的指標。燒結礦中殘留的C表示於燒結反應中未被用作熱源,故而於燒結礦中殘留的C濃度高的情形時,懷疑燒結反應時的熱量不足。However, it is very difficult to continuously measure the reaction temperature of sintering. Therefore, it is common to estimate the reaction temperature of sintering by analyzing the composition of sintered ore, and perform heat management. Specifically, the FeO concentration or the residual C concentration of the sintered ore is measured. In the sintering reaction, the hematite of the sinter ore (hematite) thermally dissociates into magnetite as the temperature rises. As the temperature after the reaction decreases, the magnetite is transformed into hematite again, but the total amount of magnetite not thermally dissociated is restored to hematite, so if the reaction temperature of sintering is high, a large amount of sintered ore Magnetite remains. Magnetite contains divalent Fe, so the FeO concentration of the sintered ore becomes an index indicating the reaction temperature of sintering. The C remaining in the sintered ore indicates that it is not used as a heat source in the sintering reaction. Therefore, when the concentration of C remaining in the sintered ore is high, it is suspected that the amount of heat during the sintering reaction is insufficient.
先前以來一直進行燒結礦的成分測定、及燒結反應的熱量調整。例如,於專利文獻1中揭示有下述技術:測定燒結礦的FeO濃度,並使用燒結礦的FeO濃度來調整燒結原料的凝結材料或造粒水分、排風量。另外,於專利文獻2中揭示有下述技術:測定燒結礦的FeO濃度,並使用燒結礦的FeO濃度來調整燒結機中吹入的城市燃氣(city gas)量。In the past, the composition of sintered ore and the heat adjustment of the sintering reaction have been adjusted. For example,
另外,於專利文獻3中揭示有下述技術:於燒結機上設置雷射式成分測量機,利用使用該成分測量機所測定的裝入至托板內的原料裝入層表層的成分濃度來推測燒結礦的成分濃度,並使用其來調整燒結原料的調配量。
[現有技術文獻]
[專利文獻]In addition,
專利文獻1:日本專利第1464203號公報 專利文獻2:日本專利第5544784號公報 專利文獻3:日本專利特開昭60-262926號公報Patent Document 1: Japanese Patent No. 1464203 Patent Document 2: Japanese Patent No. 5544784 Patent Document 3: Japanese Patent Laid-Open No. 60-262926
[發明所欲解決之課題]
專利文獻1及專利文獻2所揭示的技術為測定燒結礦的FeO濃度,並以成為目標值的方式調整凝結材料量、造粒水分、排風量、城市燃氣吹入量的技術。然而,於使燒結礦的成分反映出該些的調整結果為止需要時間,於燒結的反應溫度變高的情形時,可能導致冷卻機的異常停止或較冷卻機更靠下游側的設備的故障等設備障礙(trouble)。[Problems to be solved by the invention]
The technology disclosed in
專利文獻3所揭示的技術根據原料裝入層表層的成分濃度來推測燒結礦的成分濃度,但裝入層表層的成分濃度視燒結原料的裝入裝置或伴隨燒結原料的粒度的偏析而變動。因此,裝入層表層的成分濃度與燒結礦的成分濃度之關係不一致,難以根據裝入層表層的成分濃度來實際推測燒結礦的成分濃度。The technique disclosed in
本發明是鑒於此種先前技術的問題點而成,其目的在於提供一種即便燒結的反應溫度變動,亦可檢測出該變動而抑制燒結礦製造裝置的設備障礙的燒結礦的製造方法。 [解決課題之手段]The present invention is made in view of such problems of the prior art, and an object of the present invention is to provide a method for producing sintered ore that can detect the change in the reaction temperature of the sintering and detect the change and suppress the equipment malfunction of the sintered ore manufacturing apparatus. [Means to solve the problem]
解決此種課題的本發明的特徵如以下所述。 (1)一種燒結礦的製造方法,於調配有含鐵原料、含CaO原料及凝結材料的燒結原料中添加水進行造粒,並利用燒結機進行燒結而製造燒結礦,且所述燒結礦的製造方法包括:測定步驟,連續測定所述燒結礦的成分濃度;以及托板台車速度的調整步驟,使用所述測定步驟中測定的所述燒結礦的成分濃度來調整托板台車的行進速度。 (2)如(1)所記載的燒結礦的製造方法,其中於所述燒結原料中更調配有含MgO原料及含SiO2 原料的至少一者。 (3)如(1)或(2)所記載的燒結礦的製造方法,其中於所述測定步驟中,連續測定所述燒結礦的FeO及C的至少一種以上的成分濃度。 (4)如(1)至(3)中任一項所記載的燒結礦的製造方法,更包括:調配量的調整步驟,使用所述燒結礦的成分濃度來調整燒結原料的凝結材料的調配量。 (5)如(1)至(4)中任一項所記載的燒結礦的製造方法,其中於所述燒結機中,吹入氣體燃料及氧的至少一者而對燒結原料進行燒結,且所述燒結礦的製造方法更包括:吹入量的調整步驟,使用所述燒結礦的成分濃度來調整所述氣體燃料及所述氧的至少一者的吹入量。 [發明的效果]The features of the present invention that solve such a problem are as follows. (1) A method for manufacturing sintered ore, adding water to the sintered raw material mixed with iron-containing raw material, CaO-containing raw material and coagulation material for granulation, and sintering with a sintering machine to produce sintered ore, and the sintered ore The manufacturing method includes: a measuring step, which continuously measures the component concentration of the sintered ore; and an adjustment step of the speed of the pallet trolley, which uses the component concentration of the sintered ore measured in the measurement step to adjust the traveling speed of the pallet trolley. (2) The method for producing sintered ore as described in (1), wherein at least one of the MgO-containing raw material and the SiO 2 -containing raw material is further added to the sintered raw material. (3) The method for producing sintered ore described in (1) or (2), wherein in the measurement step, at least one or more component concentrations of FeO and C of the sintered ore are continuously measured. (4) The method for producing sintered ore as described in any one of (1) to (3), further comprising: a step of adjusting the blending amount, and using the component concentration of the sintered ore to adjust the blending of the sintered raw material coagulation material the amount. (5) The method for producing sintered ore described in any one of (1) to (4), wherein at least one of gas fuel and oxygen is blown into the sintering machine to sinter the sintered raw material, and The method for manufacturing the sintered ore further includes the step of adjusting the blowing amount, and adjusting the blowing amount of at least one of the gas fuel and the oxygen using the component concentration of the sintered ore. [Effect of invention]
藉由實施本發明的燒結礦的製造方法,而連續測定燒結礦的成分濃度,變更燒結機托板台車的行進速度。藉此,可抑制冷卻機出側的燒結礦的溫度上升,從而可抑制燒結機的設備故障等設備障礙。By implementing the method for producing sintered ore of the present invention, the component concentration of the sintered ore is continuously measured to change the traveling speed of the sintering machine pallet truck. As a result, the temperature rise of the sintered ore on the outlet side of the cooler can be suppressed, thereby suppressing equipment malfunctions such as equipment failure of the sintering machine.
以下,根據發明的實施形態對本發明進行說明。圖1為表示可實施本實施形態的燒結礦的製造方法的燒結礦製造裝置10的一例的示意圖。保管於堆場(yard)11的含鐵原料12是由搬送輸送機14搬送至調配槽22。含鐵原料12包含各種品種的鐵礦石及製鐵所內產生鐵粉。Hereinafter, the present invention will be described based on the embodiments of the invention. FIG. 1 is a schematic diagram showing an example of a sintered
原料供給部20具備多個調配槽22、24、25、26、28。調配槽22中蓄積有含鐵原料12。調配槽24中蓄積有包含石灰石或生石灰等的含CaO原料16。調配槽25中蓄積有包含白雲石或精煉鎳爐渣等的含MgO原料17。調配槽26中蓄積有凝結材料18,該凝結材料18包含使用棒磨機(rod mill)破碎至粒徑1 mm以下的焦炭粉或無煙炭。調配槽28中蓄積有燒結礦篩下的粒徑5 mm以下的返礦74(燒結礦篩下粉)。自原料供給部20的調配槽22、24、25、26、28切出既定量的各原料進行調配,於搬送輸送機30中製成燒結原料。燒結原料是由搬送輸送機30搬送至圓筒混合機36。燒結原料中亦可調配有含SiO2
原料。於該情形時,含SiO2
原料可於保管於堆場11中的含鐵原料12中調配既定量,亦可另設置蓄積含SiO2
原料的調配槽,並自該調配槽切出既定量進行調配。
搬送至圓筒混合機36的燒結原料被投入至圓筒混合機36中,添加適量的水34,例如製造成平均粒徑3.0 mm~6.0 mm的準粒子。經造粒的燒結原料是由搬送輸送機38搬送至燒結機40的燒結原料供給裝置42。圓筒混合機36為對燒結原料進行造粒的造粒裝置的一例,亦可使用多個圓筒混合機36,亦可代替圓筒混合機36而使用製粒機(pelletizer)。亦可使用圓筒混合機36與製粒機兩者,亦可於圓筒混合機36的上游設置高速攪拌機,於投入至圓筒混合機36之前對燒結原料進行攪拌。本實施形態中,平均粒徑為算術平均粒徑,且為Σ(Vi×di)(其中,Vi為存在於第i號粒度範圍中的粒子的存在比率,di為第i號粒度範圍的代表粒徑)所定義的粒徑。燒結機40中,對經圓筒混合機36造粒的燒結原料進行燒結。燒結機40例如為下方抽吸式的型帶式(dwight lioyd)燒結機。燒結機40具有燒結原料供給裝置42、循環移動的環形移動式的托板台車44、點火爐46以及風箱(wind box)48。自燒結原料供給裝置42將經造粒的燒結原料裝入至托板台車44的托板中,形成燒結原料的裝入層。裝入層是由點火爐46點火,並且通過風箱48向下方抽吸裝入層內的空氣,由此使裝入層內的燃燒、熔融帶向裝入層的下方移動。藉此,將裝入層燒結而形成燒結餅。通過風箱48向下方抽吸裝入層內的空氣時,亦可自裝入層的上方吹入氣體燃料及氧的至少一者。氣體燃料為選自高爐煤氣、焦爐煤氣、轉爐煤氣、城市燃氣、天然氣、甲烷氣、乙烷氣、丙烷氣、頁岩氣(shale gas)及該些的混合氣體中的任一種可燃性氣體。The raw
燒結餅是由破碎機50破碎而製成燒結礦。經破碎機50破碎的燒結礦是由冷卻機60進行冷卻。經冷卻機60冷卻的燒結礦是由具有多個篩的篩分裝置70進行篩分,被篩分成粒徑超過5 mm的成品燒結礦72與粒徑5 mm以下的返礦74。The sinter cake is crushed by the
成品燒結礦72是由搬送輸送機76搬送至高爐82。搬送成品燒結礦72的搬送輸送機76中設有紅外線分析計80。利用紅外線分析計80來實施測定步驟。測定步驟中,使用紅外線分析計80連續測定成品燒結礦72的FeO及C的至少一種以上的成分濃度。The finished sintered
紅外線分析計80將0.5 μm~50.0 μm的範圍內的波長的紅外線照射於成品燒結礦72,並接收來自成品燒結礦72的反射光。成品燒結礦72所含的FeO的分子振動吸收所照射的紅外線的固有波長成分,故而FeO對反射紅外線賦予固有的波長成分。C般的單原子分子的結晶結構亦因紅外線的照射而開始振動,對反射紅外線賦予固有的波長成分。因此,藉由分析照射紅外線及反射紅外線,可測定成品燒結礦72中的FeO及C的成分濃度。The
紅外線分析計80例如以一分鐘128次的頻率照射20以上的波長的紅外線,並接收經成品燒結礦72反射的反射光。如此般可於短時間內照射、接收紅外線,故而紅外線分析計80可在線(on-line)連續測定藉由搬送輸送機76所搬送的成品燒結礦72的成分濃度。紅外線分析計80為測定燒結原料的成分濃度的分析裝置的一例,亦可代替紅外線分析計80而使用將雷射照射於測定對象的雷射分析計、將中子照射於測定對象的中子分析計、或將微波照射於測定對象的微波分析計。The
粒徑超過5 mm的成品燒結礦72是由搬送輸送機76搬送至高爐82,作為高爐原料而裝入至高爐中。另一方面,粒徑5 mm以下的返礦74是由搬送輸送機78搬送至原料供給部20的調配槽28。The finished sintered
成品燒結礦72是將經破碎機50破碎的燒結礦冷卻並篩分而成,故而成品燒結礦72與經破碎機50破碎的燒結礦及返礦74為相同成分濃度的燒結礦。因此,亦可將紅外線分析計80設於冷卻機60與篩分裝置70之間,亦可設於搬送輸送機78中。於在冷卻機60與篩分裝置70之間設有紅外線分析計80的情形時,於測定步驟中測定冷卻後的燒結礦的成分濃度。於在搬送輸送機78中設有紅外線分析計80的情形時,於測定步驟中測定返礦74的成分濃度。The finished sintered
本實施形態中,成品燒結礦72的粒徑及返礦74的粒徑是指利用篩進行篩分的粒徑,例如所謂粒徑超過5 mm,是指使用網眼5 mm的篩而篩分至篩上的粒徑,所謂粒徑5 mm以下,是指使用網眼5 mm的篩而篩分至篩下的粒徑。成品燒結礦72及返礦74的粒徑的各值僅為一例,不限定於該值。In this embodiment, the particle size of the finished sintered
本實施形態的燒結礦的製造方法包括托板台車速度的調整步驟,調整托板台車的行進速度。於托板台車速度的調整步驟中,例如使用測定步驟中所測定的成品燒結礦72的FeO濃度來調整托板台車的行進速度。The manufacturing method of the sintered ore of this embodiment includes the step of adjusting the speed of the pallet trolley to adjust the traveling speed of the pallet trolley. In the pallet trolley speed adjustment step, for example, the FeO concentration of the finished sintered
成品燒結礦72的FeO濃度高表示成品燒結礦72中大量殘留磁鐵礦,由此預測燒結的反應溫度高,燒結餅成為高溫。因此,即便將該燒結餅粉碎並利用冷卻機60進行冷卻,亦無法將燒結礦冷卻至冷卻機60出側的上限溫度以下,由此可能導致冷卻機60的異常停止、或較冷卻機60更靠下游側的設備的故障等設備障礙。The high FeO concentration of the finished sintered
因此,針對托板台車的每個行進速度而預先把握燒結礦的FeO濃度與冷卻機60出側的燒結礦溫度之對應關係,預先設定超過冷卻機60的出側的上限溫度的FeO濃度的管理值。於托板台車的調整步驟中,於成品燒結礦72的FeO濃度較管理值而進一步上升,預測根據所述對應關係所算出的冷卻機60出側的燒結礦溫度超過上限溫度的情形時,調整托板台車的行進速度,將托板台車的行進速度減慢。若減慢托板台車的行進速度,則利用冷卻機60進行冷卻的時間變長,故而冷卻機60出側的燒結礦的溫度變低。如此,可降低冷卻機60出側的燒結礦的溫度,故而可抑制冷卻機60的異常停止、或較冷卻機60更靠下游側的設備的故障等設備障礙的產生。Therefore, the relationship between the FeO concentration of the sintered ore and the temperature of the sintered ore of the sintered ore at the exit side of the cooler 60 is grasped in advance for each traveling speed of the pallet truck, and the management of the FeO concentration that exceeds the upper limit temperature of the exit of the cooler 60 is set in advance value. In the adjustment step of the pallet trolley, when the FeO concentration of the finished
所述例中,表示了於測定步驟中連續測定成品燒結礦72的FeO濃度,於成品燒結礦72的FeO濃度較管理值而進一步上升,根據所述對應關係所算出的冷卻機60出側的燒結礦溫度超過上限溫度的情形時,調整托板台車的行進速度的例子,但於測定步驟中,亦可代替FeO濃度而測定成品燒結礦72的C濃度。預先把握燒結礦的C濃度與冷卻機60出側的燒結礦溫度之對應關係,預先設定超過冷卻機60的出側的上限溫度的C濃度的管理值,於C濃度較管理值進一步上升的情形時,將托板台車的行進速度減慢。這表示燒結機寬度方向的溫度變得不均勻而C未燃燒,由此C濃度變高,排出未經煅燒的燒結礦。因此,將托板台車的行進速度減慢而於燒結機上使C完全燃燒,可抑制冷卻機60內的C燃燒所致的冷卻機60的異常停止、或較冷卻機60更靠下游側的設備內的C燃燒等所致的設備障礙的產生。In the above example, it is shown that the FeO concentration of the finished sintered
本實施形態的燒結礦的製造方法亦可更包括:調配量的調整步驟,使用測定步驟中測定的成品燒結礦72的FeO及C的至少一種以上的成分濃度,來調整燒結原料的凝結材料的調配量。例如,即便於成品燒結礦72的FeO濃度較管理值而進一步上升,預測燒結反應溫度高的情形時,亦可藉由調配量的調整步驟而減少凝結材料的調配量,由此降低燒結的反應溫度。降低燒結的反應溫度後,可使於托板台車速度的調整步驟中經減慢的托板台車的行進速度恢復,故而可抑制由減慢托板台車的行進速度所致的燒結礦的生產性的降低。只要可藉由調整凝結材料的調配量而抑制燒結的反應溫度的變動,則燒結礦的FeO濃度的變動得到抑制,燒結礦的品質變高。The method for producing sintered ore of this embodiment may further include an adjustment step of the blending amount, and the concentration of at least one or more components of FeO and C of the finished sintered
本實施形態的燒結礦的製造方法亦可包括:吹入量的調整步驟,使用測定步驟中測定的燒結礦的FeO及C的至少一種以上的成分濃度,來調整氣體燃料及氧的至少一者的吹入量。例如,即便於燒結礦的FeO濃度較管理值而進一步上升,預測燒結反應溫度高的情形時,亦可藉由吹入量的調整步驟而減少氣體燃料及氧的至少一者的吹入量,由此縮短燒結的反應溫度的高溫保持時間。於縮短燒結的反應溫度的高溫保持時間後,可使托板台車速度的調整步驟中經減慢的托板台車的行進速度恢復,故而可抑制由減慢托板台車的行進速度所致的生產性的降低。只要可藉由調整氣體燃及氧的至少一者的吹入量而抑制燒結的反應溫度變動,則燒結礦的FeO濃度的變動亦得到抑制,燒結礦的品質亦變高。The method for producing a sintered ore of this embodiment may include a step of adjusting the blowing amount, and adjust at least one of gaseous fuel and oxygen using at least one or more component concentrations of FeO and C of the sintered ore measured in the measurement step. The blowing volume. For example, even if the FeO concentration of the sintered ore is further increased than the management value and it is predicted that the sintering reaction temperature is high, the injection amount of at least one of gaseous fuel and oxygen can be reduced by the adjustment step of the injection amount, This shortens the high-temperature retention time of the sintering reaction temperature. After shortening the high-temperature holding time of the reaction temperature of the sintering, the traveling speed of the pallet trolley, which was slowed down in the adjustment step of the pallet trolley speed, can be recovered, so that the production caused by slowing down the traveling speed of the pallet trolley can be suppressed Sexual decline. As long as the reaction temperature fluctuation of sintering can be suppressed by adjusting the injection amount of at least one of gas combustion and oxygen, the fluctuation of the FeO concentration of the sintered ore is also suppressed, and the quality of the sintered ore also becomes higher.
本實施形態中,表示了自原料供給部20的調配槽22、24、25、26、28切出各原料進行調配,於搬送輸送機30中製成燒結原料,於圓筒混合機36中製成經造粒的燒結原料的例子,但不限於此。例如,亦可將調配有含鐵原料12、含CaO原料16、含MgO原料17及返礦74的燒結原料投入至圓筒混合機36中,於燒結原料中添加水進行造粒,於造粒時的後半投入凝結材料18,由此將使凝結材料18存在於表層的炭材外飾粒子用作經造粒的燒結原料。In this embodiment, each raw material is cut out from the mixing
亦可將調配有含鐵原料12、含CaO原料16、含MgO原料17及返礦74、以及凝結材料18的一部分的燒結原料投入至圓筒混合機36中,於該燒結原料中添加水進行造粒,於造粒時的後半投入凝結材料18的剩餘部分,由此將使凝結材料18存在於所造粒的燒結原料的表層的炭材外飾粒子用作經造粒的燒結原料。作為在燒結原料中添加水並於造粒時的後半調配的凝結材料,使用焦炭粉或無煙炭。A part of the sintered raw material mixed with the iron-containing
於設有多個圓筒混合機36,且利用使凝結材料18存在於表層的炭材外飾粒子的情形時,亦可將一部分或全部的凝結材料18投入至最後的圓筒混合機36的後半,並利用上文所述的方法將燒結原料投入至圓筒混合機36中,由此製造使凝結材料18存在於表層的炭材外飾粒子。進而,關於使用多個圓筒混合機36的情形時添加至燒結原料中的水,可於第1台圓筒混合機36中添加所有的水,亦可於第1台圓筒混合機36中添加一部分水,將剩餘部分添加至其他圓筒混合機36中。When a plurality of
本實施形態中,表示了自原料供給部20的調配槽22、24、25、26、28切出各原料進行調配,於搬送輸送機30中製成燒結原料,並於圓筒混合機36中製成經造粒的燒結原料的例子,但不限於此。例如,亦可將調配有含鐵原料12、含MgO原料17及返礦74的燒結原料投入至圓筒混合機36中,於燒結原料中添加水進行造粒,於造粒時的後半投入含CaO原料16及凝結材料18,由此將使含CaO原料16及凝結材料18存在於表層的造粒粒子用作經造粒的燒結原料。In the present embodiment, each raw material is cut out from the
亦可將調配有含鐵原料12的一部分、含MgO原料17及返礦74、以及凝結材料18的燒結原料投入至圓筒混合機36中,於燒結原料中添加水進行造粒,於造粒時的後半投入含鐵原料12的剩餘部分及含CaO原料16,由此將使含鐵原料12及含CaO原料16存在於表層的造粒粒子用作經造粒的燒結原料。It is also possible to put a part of the sintered raw material mixed with the iron-containing
亦可將調配有含鐵原料12、返礦74及含MgO原料17、以及含CaO原料16的一部分的燒結原料投入至圓筒混合機36中,於燒結原料中添加水進行造粒,於造粒時的後半調配含CaO原料16的剩餘部分及凝結材料18,由此將使含CaO原料16及凝結材料18存在於表層的造粒粒子用作經造粒的燒結原料。A part of the sintered raw materials mixed with the iron-containing
亦可將調配有含鐵原料12、返礦74及含MgO原料17、含CaO原料16的一部分、以及凝結材料18的一部分的燒結原料投入至圓筒混合機36中,於燒結原料中添加水進行造粒,於造粒時的後半調配含CaO原料16的剩餘部分及凝結材料18的剩餘部分,由此將使含CaO原料16及凝結材料18存在於表層的造粒粒子用作經造粒的燒結原料。The sintered raw material mixed with the iron-containing
於使用多個圓筒混合機36,且製造使含CaO原料16或含CaO原料16及凝結材料18存在於表層的造粒粒子的情形時,亦可將一部分或全部的含CaO原料16及凝結材料18投入至最後的圓筒混合機36的後半,並利用上文所述的方法將燒結原料投入至圓筒混合機36中,由此製造使含CaO原料16及凝結材料18存在於表層的造粒粒子。In the case of using a plurality of
本實施形態中,表示了自原料供給部20的調配槽22、24、25、26、28切出各原料進行調配,並於搬送輸送機30中製成燒結原料的例子,但不限於此。例如,亦可直接利用搬送輸送機30將自原料供給部20的調配槽22、24、25、26、28切出的各原料的一部分搬送至圓筒混合機36,並利用與搬送輸送機30不同的搬送輸送機將剩餘部分搬送至高速攪拌裝置進行攪拌處理後,利用圓筒混合機36或製粒機等造粒機進行造粒,視需要利用乾燥機進行乾燥後,投入至搬送輸送機30或搬送輸送機38中。也可於經攪拌處理後不利用圓筒混合機36或製粒機等造粒機進行造粒,而直接投入至搬送輸送機30中。進而,亦可於利用高速攪拌裝置進行攪拌處理之前設置破碎步驟及篩步驟的至少一者。於使用多個圓筒混合機36的情形時,亦可投入至任一圓筒混合機間的搬送輸送機。In the present embodiment, an example is shown in which each raw material is cut out from the
進而,測定步驟中的紅外線分析計80不限於一個,亦可設置多個。亦可使用多個紅外線分析計80,測定燒結礦的FeO及C的至少一種以上的成分濃度。
[實施例]Furthermore, the
實施例、比較例均使用圖1所示的燒結礦製造裝置10製造燒結礦。實施例、比較例均於搬送輸送機76中設置紅外線分析計80,以每小時18次的頻率連續測定FeO濃度作為燒結礦的成分濃度,並使用所測定的FeO濃度,以燒結礦的FeO濃度成為FeO管理值的方式調整作為凝結材料的焦炭粉的調配率而製造燒結礦5小時。實施例、比較例均於經過1小時後,變更為包含C濃度高的鐵粉的原料堆。In the examples and comparative examples, the sintered
實施例為包括調整燒結機托板台車的行進速度的托板台車速度的調整步驟的例子,比較例為不包括托板台車速度的調整步驟的例子。因此,於燒結礦的FeO濃度變高的情形時,於實施例中減慢托板台車的行進速度並且調整焦炭粉的調配率來應對,於比較例中不調整托板台車的行進速度,而調整焦炭粉的調配率。The embodiment is an example that includes an adjustment step of the pallet speed that adjusts the traveling speed of the sintering machine pallet, and the comparative example is an example that does not include the adjustment step of the pallet speed. Therefore, when the FeO concentration of the sintered ore becomes high, the traveling speed of the pallet trolley is slowed down in the examples and the ratio of coke powder is adjusted to cope with it. In the comparative example, the traveling speed of the pallet trolley is not adjusted. Adjust the ratio of coke powder.
圖2為表示實施例中的燒結礦的FeO濃度(質量%)、托板台車的行進速度(m/min)、焦炭粉的調配率(質量%)及冷卻機出側的燒結礦溫度(℃)的時間變化的圖表。圖3為表示比較例中的燒結礦的FeO濃度(質量%)、托板台車的行進速度(m/min)、焦炭粉的調配率(質量%)及冷卻機出側的燒結礦溫度(℃)的時間變化的圖表。2 is a graph showing the FeO concentration (mass %) of the sintered ore, the traveling speed of the pallet trolley (m/min), the ratio of coke powder (mass %) and the temperature of the sintered ore on the outlet side of the cooler (°C) ) A graph of time changes. Fig. 3 shows the FeO concentration (mass %) of the sintered ore in the comparative example, the traveling speed of the pallet trolley (m/min), the blending rate of coke powder (mass %), and the temperature of the sintered ore on the outlet side of the cooler (°C ) A graph of time changes.
因具有藉由紅外線分析計80連續測定燒結礦的FeO濃度的測定步驟,故而於原料堆變更後,可儘早檢測出燒結礦的FeO濃度較FeO管理值而進一步上升。由於檢測出因FeO濃度的上升而燒結的反應溫度變高,冷卻機出側的燒結礦的溫度超過上限溫度,故而實施例中,於托板台車速度的調整步驟中減慢燒結機托板台車的行進速度並且調整焦炭粉調配率。其結果,冷卻機出側的燒結礦溫度的上升得到抑制,可於不超過冷卻機出側上限溫度的情況下進行作業。藉由調整焦炭粉的調配率而FeO濃度恢復至管理值後,將托板台車的行進速度恢復至原本的速度。由此,亦可抑制燒結礦的生產性的降低。Since the
如此,本實施形態的燒結礦的製造方法中,連續測定燒結礦的FeO濃度,於檢測出燒結礦的FeO濃度的上升的時間點,調整燒結機托板台車的行進速度。藉此確認到,可抑制冷卻機出側的燒結礦溫度的上升,減輕冷卻機或其後的設備負荷,可避免設備故障等裝置障礙。In this way, in the method for producing sintered ore of the present embodiment, the FeO concentration of the sintered ore is continuously measured, and the traveling speed of the sintering machine pallet truck is adjusted at the time when the rise of the FeO concentration of the sintered ore is detected. From this, it was confirmed that the increase in the temperature of the sintered ore on the outlet side of the cooler can be suppressed, the load on the cooler or the equipment behind it can be reduced, and device failures such as equipment failure can be avoided.
比較例中,亦檢測出因燒結礦的FeO濃度的上升而冷卻機出側的燒結礦的溫度超過上限溫度,故而進行焦炭粉的調配率的調整。然而,冷卻機出側的燒結礦溫度降低是在調整焦炭粉的調配率後,已裝入至燒結機中的原料被替換所需要的約30分鐘經過之後,在此之前,燒結礦的溫度超過冷卻機出側的上限溫度而上升,其結果導致冷卻機異常停止。停止冷卻機及托板台車後,燒結機的溫度降低,因此提高燒結原料的焦炭粉的調配率,於減慢托板台車的行進速度的狀態下再次開始燒結礦的生產。In the comparative example, it was also detected that the temperature of the sintered ore on the cooler outlet side exceeded the upper limit temperature due to the increase in the FeO concentration of the sintered ore, so the adjustment of the ratio of coke powder was adjusted. However, the temperature reduction of the sinter ore on the outlet side of the cooler is after adjusting the blending rate of the coke powder, and after the raw materials charged into the sinterer are replaced for about 30 minutes, before the temperature of the sinter ore exceeds The upper limit temperature on the outlet side of the cooler rises, and as a result, the cooler stops abnormally. After the cooling machine and the pallet trolley are stopped, the temperature of the sintering machine is lowered, so the sintering raw material coke powder blending rate is increased, and the production of sintered ore is restarted while the traveling speed of the pallet trolley is slowed down.
實施例、比較例中均檢測燒結礦的FeO濃度的上升,並於檢測出冷卻機出側的燒結礦的溫度超過上限溫度的時間點,將源自包含使燒結的反應溫度上升的C濃度高的鐵粉的原料堆的燒結原料裝入至燒結機托板台車的托板中。比較例中調整焦炭粉的調配率,但反映出該調配率的調整是從由此開始從原料供給部切出並調配的燒結原料開始,且並非反映在已裝入至托板中的燒結原料中。因此,比較例中,因燒結的反應溫度上升而燒結礦的溫度上升,燒結礦的溫度超過冷卻機出側的上限溫度。其結果產生冷卻機的異常停止這一設備障礙。In both the examples and the comparative examples, the increase in the FeO concentration of the sintered ore was detected, and at the time when the temperature of the sintered ore on the outlet side of the cooler was detected to exceed the upper limit temperature, the concentration of C derived from the increase in the reaction temperature of the sintering was increased. The sintered raw materials of the raw material pile of iron powder are loaded into the pallet of the pallet trolley of the sintering machine. In the comparative example, the blending rate of the coke powder was adjusted, but the adjustment reflecting the blending rate was started from the sintered raw material cut and prepared from the raw material supply section, and it was not reflected in the sintered raw material already loaded into the pallet in. Therefore, in the comparative example, the temperature of the sintered ore increases due to the increase in the reaction temperature of sintering, and the temperature of the sintered ore exceeds the upper limit temperature on the outlet side of the cooler. As a result, the equipment malfunctions such as abnormal stopping of the cooling machine.
實施例中,檢測燒結礦的FeO濃度的上升,並於檢測出冷卻機出側的燒結礦的溫度超過上限溫度的時間點,於托板台車速度的調整步驟中減慢托板台車的行進速度。由此,可從已裝入至托板中的燒結原料開始延長利用冷卻機進行冷卻的時間,故而即便該燒結原料的燒結的反應溫度上升,亦可抑制冷卻機出側的燒結礦的溫度上升,藉此可抑制冷卻機的異常停止或設備故障等障礙。本實施例中,表示了將設置於搬送輸送機76的紅外線分析計80的測定頻率設定為每小時18次的例子,但即便為較此更低的測定頻率,亦可獲得由調整托板台車速度所得的效果。測定頻率只要於裝入至燒結機中的原料被替換所需要的約30分鐘內設為一次以上即可。In the embodiment, the increase in the FeO concentration of the sintered ore is detected, and when the temperature of the sintered ore on the outlet side of the cooler is detected to exceed the upper limit temperature, the traveling speed of the pallet trolley is slowed down in the adjustment step of the pallet trolley speed . As a result, the time for cooling by the cooler can be extended from the sintered raw material loaded into the pallet. Therefore, even if the reaction temperature of sintering of the sintered raw material increases, the temperature increase of the sintered ore on the outlet side of the cooler can be suppressed In this way, it is possible to suppress obstacles such as abnormal stop of the cooler or equipment failure. In this embodiment, the example in which the measurement frequency of the
如此,本實施形態的燒結礦的製造方法中,藉由利用測定步驟連續測定燒結礦的FeO濃度而儘早檢測出燒結的反應溫度的上升,於托板台車速度的調整步驟中減慢托板台車的行進速度。藉此確認到,例如即便於因變更為包含C濃度高的鐵粉的原料堆而燒結的反應溫度上升的情形時,亦可抑制冷卻機出側的燒結礦的溫度上升,從而可抑制冷卻機的異常停止或燒結機的設備故障等設備障礙。In this way, in the method for producing sintered ore of the present embodiment, by continuously measuring the FeO concentration of the sintered ore in the measurement step, an increase in the sintering reaction temperature is detected as early as possible, and the pallet trolley is slowed down in the adjustment step of the pallet trolley speed Speed of travel. From this, it was confirmed that, for example, even when the reaction temperature of sintering is changed due to the change to a raw material pile containing iron powder with a high C concentration, the temperature increase of the sintered ore on the outlet side of the cooler can be suppressed, thereby suppressing the cooler Equipment failures such as abnormal stopping or equipment failure of the sintering machine.
10‧‧‧燒結礦製造裝置
11‧‧‧堆場
12‧‧‧含鐵原料
14、30、38、76、78‧‧‧搬送輸送機
16‧‧‧含CaO原料
17‧‧‧含MgO原料
18‧‧‧凝結材料
20‧‧‧原料供給部
22、24、25、26、28‧‧‧調配槽
34‧‧‧水
36‧‧‧圓筒混合機
40‧‧‧燒結機
42‧‧‧燒結原料供給裝置
44‧‧‧托板台車
46‧‧‧點火爐
48‧‧‧風箱
50‧‧‧破碎機
60‧‧‧冷卻機
70‧‧‧篩分裝置
72‧‧‧成品燒結礦
74‧‧‧返礦
80‧‧‧紅外線分析計
82‧‧‧高爐10‧‧‧Sinter ore manufacturing equipment
11‧‧‧
圖1為表示可實施本實施形態的燒結礦的製造方法的燒結礦製造裝置10的一例的示意圖。
圖2為表示實施例的燒結礦的FeO濃度、托板台車的行進速度、焦炭粉的調配率及冷卻機出側的燒結礦溫度的時間變化的圖表。
圖3為表示比較例的燒結礦的FeO濃度、托板台車的行進速度、焦炭粉的調配率及冷卻機出側的燒結礦溫度的時間變化的圖表。FIG. 1 is a schematic diagram showing an example of a sintered
10‧‧‧燒結礦製造裝置 10‧‧‧Sinter ore manufacturing equipment
11‧‧‧堆場 11‧‧‧ Yard
12‧‧‧含鐵原料 12‧‧‧ Iron-containing raw materials
14、30、38、76、78‧‧‧搬送輸送機 14, 30, 38, 76, 78‧‧‧‧ conveyor
16‧‧‧含CaO原料 16‧‧‧CaO-containing raw materials
17‧‧‧含MgO原料 17‧‧‧MgO-containing raw materials
18‧‧‧凝結材料 18‧‧‧Condensation material
20‧‧‧原料供給部 20‧‧‧ Raw Material Supply Department
22、24、25、26、28‧‧‧調配槽 22, 24, 25, 26, 28
34‧‧‧水 34‧‧‧Water
36‧‧‧圓筒混合機 36‧‧‧Cylinder mixer
40‧‧‧燒結機 40‧‧‧sintering machine
42‧‧‧燒結原料供給裝置 42‧‧‧Sintering raw material supply device
44‧‧‧托板台車 44‧‧‧pallet trolley
46‧‧‧點火爐 46‧‧‧Ignition furnace
48‧‧‧風箱 48‧‧‧bellows
50‧‧‧破碎機 50‧‧‧Crusher
60‧‧‧冷卻機 60‧‧‧cooler
70‧‧‧篩分裝置 70‧‧‧ Screening device
72‧‧‧成品燒結礦 72‧‧‧Finished Sinter
74‧‧‧返礦 74‧‧‧return to mine
80‧‧‧紅外線分析計 80‧‧‧Infrared Analyzer
82‧‧‧高爐 82‧‧‧blast furnace
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