EP3670685B1 - Method for manufacturing sintered ore - Google Patents
Method for manufacturing sintered ore Download PDFInfo
- Publication number
- EP3670685B1 EP3670685B1 EP18869498.8A EP18869498A EP3670685B1 EP 3670685 B1 EP3670685 B1 EP 3670685B1 EP 18869498 A EP18869498 A EP 18869498A EP 3670685 B1 EP3670685 B1 EP 3670685B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- raw material
- sintered ore
- sintering
- cooler
- feo
- Prior art date
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- 238000000034 method Methods 0.000 title claims description 64
- 238000004519 manufacturing process Methods 0.000 title claims description 26
- 239000002994 raw material Substances 0.000 claims description 153
- 238000005245 sintering Methods 0.000 claims description 131
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 54
- 238000002156 mixing Methods 0.000 claims description 38
- 239000007767 bonding agent Substances 0.000 claims description 32
- 229910052742 iron Inorganic materials 0.000 claims description 27
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
- 239000007789 gas Substances 0.000 claims description 17
- 239000000377 silicon dioxide Substances 0.000 claims description 9
- 229910052681 coesite Inorganic materials 0.000 claims description 7
- 229910052906 cristobalite Inorganic materials 0.000 claims description 7
- 239000000446 fuel Substances 0.000 claims description 7
- 229910052682 stishovite Inorganic materials 0.000 claims description 7
- 229910052905 tridymite Inorganic materials 0.000 claims description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 6
- 239000001301 oxygen Substances 0.000 claims description 6
- 229910052760 oxygen Inorganic materials 0.000 claims description 6
- 238000007664 blowing Methods 0.000 claims description 3
- 238000005259 measurement Methods 0.000 claims description 3
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 47
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 44
- 238000006243 chemical reaction Methods 0.000 description 33
- 239000002245 particle Substances 0.000 description 29
- 239000000292 calcium oxide Substances 0.000 description 22
- 235000012255 calcium oxide Nutrition 0.000 description 22
- 239000000571 coke Substances 0.000 description 17
- 239000010410 layer Substances 0.000 description 13
- 230000003247 decreasing effect Effects 0.000 description 12
- 239000002344 surface layer Substances 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 11
- 230000002159 abnormal effect Effects 0.000 description 8
- 239000011361 granulated particle Substances 0.000 description 8
- 230000015556 catabolic process Effects 0.000 description 7
- 239000000428 dust Substances 0.000 description 7
- 239000008187 granular material Substances 0.000 description 7
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- 230000000717 retained effect Effects 0.000 description 5
- 238000007873 sieving Methods 0.000 description 5
- 239000003575 carbonaceous material Substances 0.000 description 4
- 238000005469 granulation Methods 0.000 description 4
- 230000003179 granulation Effects 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000002893 slag Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 3
- RHZUVFJBSILHOK-UHFFFAOYSA-N anthracen-1-ylmethanolate Chemical compound C1=CC=C2C=C3C(C[O-])=CC=CC3=CC2=C1 RHZUVFJBSILHOK-UHFFFAOYSA-N 0.000 description 3
- 239000003830 anthracite Substances 0.000 description 3
- 229910052595 hematite Inorganic materials 0.000 description 3
- 239000011019 hematite Substances 0.000 description 3
- 238000009775 high-speed stirring Methods 0.000 description 3
- LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 238000007670 refining Methods 0.000 description 3
- 238000012216 screening Methods 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 230000007704 transition Effects 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 235000019738 Limestone Nutrition 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 238000010494 dissociation reaction Methods 0.000 description 2
- 230000005593 dissociations Effects 0.000 description 2
- 239000010459 dolomite Substances 0.000 description 2
- 229910000514 dolomite Inorganic materials 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000002401 inhibitory effect Effects 0.000 description 2
- 239000006028 limestone Substances 0.000 description 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- -1 and serpentinite Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 238000009628 steelmaking Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B1/00—Preliminary treatment of ores or scrap
- C22B1/14—Agglomerating; Briquetting; Binding; Granulating
- C22B1/16—Sintering; Agglomerating
- C22B1/22—Sintering; Agglomerating in other sintering apparatus
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C1/00—Refining of pig-iron; Cast iron
- C21C1/02—Dephosphorising or desulfurising
- C21C1/025—Agents used for dephosphorising or desulfurising
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B5/00—Making pig-iron in the blast furnace
- C21B5/008—Composition or distribution of the charge
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B1/00—Preliminary treatment of ores or scrap
- C22B1/14—Agglomerating; Briquetting; Binding; Granulating
- C22B1/16—Sintering; Agglomerating
- C22B1/20—Sintering; Agglomerating in sintering machines with movable grates
- C22B1/205—Sintering; Agglomerating in sintering machines with movable grates regulation of the sintering process
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B1/00—Preliminary treatment of ores or scrap
- C22B1/14—Agglomerating; Briquetting; Binding; Granulating
- C22B1/24—Binding; Briquetting ; Granulating
- C22B1/242—Binding; Briquetting ; Granulating with binders
- C22B1/244—Binding; Briquetting ; Granulating with binders organic
- C22B1/245—Binding; Briquetting ; Granulating with binders organic with carbonaceous material for the production of coked agglomerates
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B1/00—Preliminary treatment of ores or scrap
- C22B1/26—Cooling of roasted, sintered, or agglomerated ores
Definitions
- the present invention relates to a method for manufacturing sintered ore, and in particular, to a method for manufacturing sintered ore including measuring component concentrations in the sintered ore and adjusting the pallet speed in accordance with the measured component concentrations.
- iron-containing raw materials such as sintered ore, lump iron ore, and pellets are mainly used as iron sources for blast furnace feed materials.
- sintered ore is a kind of agglomerated ore manufactured in such a manner that a sintering raw material, which is prepared by gathering iron ore having a particle size of 10 mm or less, miscellaneous iron sources, such as various kinds of dust generated in a steel plant, CaO-containing raw materials, such as limestone, quick lime, and steel-making slag, and bonding agents, such as coke breeze and anthracite, and by adding, as an optional blending material, MgO-containing raw materials, such as nickel refining slag, dolomite, and serpentinite, and SiO 2 -containing raw materials, such as nickel refining slag and silica stone (silica sand), is stirred, mixed and granulated in a drum mixer with adding water, and then burned.
- MgO-containing raw materials such as nickel refining
- the concentration of iron in iron ore contained in a sintering raw material which is a raw material for sintered ore
- concentrations of gangue components such as SiO 2 and Al 2 O 3
- the component concentrations in produced iron ore have become variable to such an extent that, even in the case of the same kind of iron ore, the component concentrations may vary from one shipment to another when the iron ore is imported.
- a variation in the sintering reaction temperature causes a variation in the quality of product sintered ore (hereinafter, also referred to as "sintered ore"), which is produced by performing sintering
- the variation in the sintering reaction temperature has a significant influence on the quality of the sintered ore.
- the quality of sintered ore for example, due to a low-strength vitreous structure being formed in the sintered ore or due to a deterioration in reducibility as a result of an increase in the amount of magnetite structure.
- the amount of heat is adjusted in accordance with the sintering reaction temperature which is estimated on the basis of analysis results. Specifically, the FeO concentration and the retained C concentration in sintered ore are determined.
- thermal dissociation in which hematite in sintered ore transitions into magnetite, progresses with an increase in temperature.
- magnetite transitions back into hematite with a decrease in temperature after the reaction
- the magnetite which has been formed by thermal dissociation, does not always transition back into hematite
- a large amount of magnetite is retained in sintered ore in the case where the sintering reaction temperature is high.
- magnetite contains divalent iron
- the FeO concentration in sintered ore provides an indication of the sintering reaction temperature. Since C retained in sintered ore indicates that such C has not been used as a heat resource for a sintering reaction, it is supposed that there is an insufficient amount of heat at the time of the sintering reaction in the case where the C concentration retained in sintered ore is high.
- Patent Literature 1 discloses a technique in which the FeO concentration in sintered ore is determined and in which the amounts of a bonding agent and granulation water and an air-discharging rate of the sintering raw material are adjusted in accordance with the FeO concentration of the sintered ore.
- Patent Literature 2 discloses a technique in which the FeO concentration in sintered ore is determined and in which the amount of city gas blown into a sintering machine is adjusted in accordance with the FeO concentration of the sintered ore.
- Patent Literature 3 discloses a technique in which the component concentrations in sintered ore are estimated on the basis of the component concentrations in a surface layer of the burden layer of a sintering raw material, which has been charged onto a pallet, the component concentrations in the surface layer being determined by using a laser-type component measuring device disposed above a sintering machine, and in which the composition of a sintering raw material is adjusted in accordance with the estimation results.
- Patent Literature 4 and 5 disclose a method for manufacturing sintered ore, in which a sintering raw material containing an iron-containing raw material, a CaO-containing raw material, and a bonding agent is mixed with water and granulated, and the granulated sintering raw material is sintered in a sintering machine to manufacture sintered ore, the method comprising a pallet speed-adjusting process.
- the present invention has been completed in view of the problems of the conventional techniques, and an object of the present invention is to provide a method for manufacturing sintered ore with which it is possible to inhibit equipment problems from occurring in equipment for manufacturing sintered ore, even when there is a variation in the sintering reaction temperature, by detecting such a variation.
- the component concentrations in sintered ore are continuously measured, and the pallet speed of a sintering machine is adjusted. With this, since it is possible to inhibit an increase in sintered ore temperature at the discharge part of a cooler, it is possible to inhibit equipment problems such as the equipment breakdown of the sintering machine.
- FIG. 1 is a schematic diagram illustrating an example of sintered ore manufacturing equipment 10 with which the method for manufacturing sintered ore according to the present embodiment is implemented.
- An iron-containing raw material 12 which is stored in a yard 11 is transported to a blending bin 22 via a transporting conveyer 14.
- the iron-containing raw material 12 contains various brands of iron ore and dust generated in a steel plant.
- a raw material feeding section 20 has plural blending bins 22, 24, 25, 26, and 28.
- the blending bin 22 contains the iron-containing raw material 12.
- the blending bin 24 contains a CaO-containing raw material 16 including limestone, quicklime, and so forth.
- the blending bin 25 contains a MgO-containing raw material 17 including dolomite, nickel refining slag, and so forth.
- the blending bin 26 contains a bonding agent 18 including coke breeze, which is prepared by performing crushing in a rod mill so that the particle diameter is 1 mm or less, and anthracite.
- the blending bin 28 contains return fine 74 having a particle diameter of 5 mm or less, which is the portion of sintered ore passing through sieves for sintered ore (powder under the sieves for sintered ore).
- Predetermined amounts of the raw materials are discharged from each of the blending bins 22, 24, 25, 26, and 28 of the raw material feeding section 20 so as to be added, and a blend of the discharged raw materials is made into a sintering raw material on a transporting conveyer 30.
- the sintering raw material is transported to a drum mixer 36 via the transporting conveyer 30.
- a SiO 2 -containing raw material may be blended in the sintering raw material.
- a predetermined amount of the SiO 2 -containing raw material may be blended to the iron-containing raw material 12 stored in the yard 11, or another blending bin containing the SiO 2 -containing raw material may be installed and a predetermined amount of the SiO 2 -containing raw material may be discharged from the blending bin so as to be blended.
- the sintering raw material which has been transported to the drum mixer 36, is charged into the drum mixer 36 with an appropriate amount of water 34 being added and granulated to form quasiparticles having an average particle diameter of, for example, 3.0 mm to 6.0 mm.
- the granulated sintering raw material is transported to a sintering raw material charging device 42 of a sintering machine 40 via a transporting conveyer 38. Since the drum mixer 36 is an example of a granulating apparatus which is used to granulate the sintering raw material, plural drum mixers 36 may be used, and a pelletizer may be used as a granulating apparatus instead of the drum mixer 36.
- Both the drum mixer 36 and the pelletizer may be used, and a high-speed stirring apparatus may be placed upstream of the drum mixer 36 to stir the sintering raw material before the sintering raw material is charged into the drum mixer 36.
- the term "average particle diameter” denotes an arithmetic average particle diameter defined by the formula ⁇ (Vi ⁇ di), where Vi denotes the abundance ratio of particles having a particle diameter within the i-th range defined in terms of particle diameter and di denotes the representative particle diameter of the i-th range.
- the sintering raw material which has been granulated in the drum mixer 36, is sintered.
- the sintering machine 40 is, for example, a downward suction-type Dwight-Lloyd sintering machine.
- the sintering machine 40 has the sintering raw material charging device 42, an endless mobile pallet 44 that circulates and moves, an ignition furnace 46, and wind boxes 48.
- the sintering raw material which has been granulated, is charged into the pallet 44 through the sintering raw material charging device 42 to form a burden layer of the sintering raw material.
- the burden layer is ignited by using the ignition furnace 46, and air in the burden layer is suctioned downward through the wind boxes 48 so that a combustion-melting zone in the burden layer moves toward the lower portion of the burden layer. With this, the burden layer is sintered to form a sintered cake.
- a gas fuel and oxygen may be blown down from above the burden layer.
- the gas fuel is a combustible gas selected from among blast furnace gas, coke oven gas, converter gas, city gas, natural gas, methane gas, ethane gas, propane gas, and shale gas, and a mixture thereof.
- the sintered cake is crushed by using a crushing machine 50 to form sintered ore.
- the sintered ore, which has been crushed by using the crushing machine 50 is cooled by using a cooler 60.
- the sintered ore, which has been cooled by using the cooler 60 is subjected to screening utilizing a sieving apparatus 70 having plural sieves to separate the sintered ore into product sintered ore 72 having a particle diameter of more than 5 mm and the return fine 74 having a particle diameter of 5 mm or less.
- the product sintered ore 72 is transported to a blast furnace 82 via a transporting conveyer 76.
- an infrared analyzer 80 is installed in the transporting conveyer 76.
- a measuring process is performed.
- the component concentration of at least one or more of FeO and C in the product sintered ore 72 is continuously measured by using the infrared analyzer 80.
- the infrared analyzer 80 radiates infrared light having a wavelength of 0.5 ⁇ m to 50.0 ⁇ m and receives reflected light from the product sintered ore 72. Since the molecular vibration of FeO contained in the product sintered ore 72 absorbs specific-wavelength components of the radiated infrared light, FeO imparts specific-wavelength components to the reflected infrared light. Also, the crystal structure of a single-atom molecule, such as C, starts vibrating at the time of radiating the infrared light and thereby imparts the specific-wavelength components to the reflected infrared light. Therefore, it is possible to determine the component concentrations of FeO and C in the product sintered ore 72 by analyzing the radiated infrared light and the reflected infrared light.
- the infrared analyzer 80 radiates infrared light having 20 or more wavelengths and receives reflected light reflected from the product sintered ore 72 at a frequency of, for example, 128 times per minute. Since it is possible to radiate and receive infrared light in such a short time by using the infrared analyzer 80, it is possible to continuously measure the component concentrations in the product sintered ore 72, which is transported on the transporting conveyer 76, online by using the infrared analyzer 80.
- the infrared analyzer 80 is an example of an analyzing device which is used to measure the component concentrations in the sintering raw material, a laser analyzer which radiates laser beams onto an object to be measured, a neutron analyzer which radiates neutrons onto an object to be measured, or a microwave analyzer which radiates microwaves onto an object to be measured may be used instead of the infrared analyzer 80.
- the product sintered ore 72 having a particle diameter of more than 5 mm is transported to the blast furnace 82 via the transporting conveyer 76 and charged into a blast furnace as a blast furnace feed material.
- the return fine 74 having a particle diameter of 5 mm or less is transported to the blending bin 28 in the raw material feeding section 20 via a transporting conveyer 78.
- the infrared analyzer 80 may be installed between the cooler 60 and the sieving apparatus 70 or on the transporting conveyer 78. In the case where the infrared analyzer 80 is installed between the cooler 60 and the sieving apparatus 70, the component concentrations in the sintered ore, which has been cooled, are measured in the measuring process. In the case where the infrared analyzer 80 is installed in the transporting conveyer 78, the component concentrations in the return fine 74 are measured in the measuring process.
- the term "particle diameter of the product sintered ore 72 or the return fine 74" denotes a particle diameter determined by performing screening utilizing a sieve, and, for example, the expression “a particle diameter of more than 5 mm” denotes the particle diameter of particles which remain on a sieve having a sieve mesh of 5 mm, and the expression “a particle diameter of 5 mm or less” denotes the particle diameter of particles which pass through a sieve having a sieve mesh of 5 mm.
- the value expressing the particle diameter of the product sintered ore 72 or the return fine 74 is definitely used as an example, and the particle diameter of the product sintered ore 72 or the return fine 74 is not limited to this example.
- the method for manufacturing sintered ore according to the present embodiment includes a pallet speed-adjusting process of adjusting the pallet speed.
- the pallet speed is adjusted in accordance with, for example, the FeO concentration in the product sintered ore 72 which is measured in the measuring process.
- the control value of the FeO concentration which indicates that the sintered ore temperature at the discharge part of the cooler 60 exceeds the upper-temperature limit at the discharge part of the cooler 60, is determined in advance.
- the pallet speed-adjusting process in the case where the FeO concentration in the product sintered ore 72 is higher than the control value, that is, in the case where it is predicted that the sintered ore temperature at the discharge part of the cooler 60, which is calculated by using the relationship described above, will exceed the upper-temperature limit, the pallet speed is adjusted lower.
- the FeO concentration in the product sintered ore 72 is continuously measured in the measuring process, and the pallet speed is adjusted in the case where the FeO concentration in the product sintered ore 72 is higher than the control value, that is, in the case where it is predicted that the sintered ore temperature at the discharge part of the cooler 60, which is calculated by using the relationship described above, will exceed the upper-temperature limit.
- the C concentration in the product sintered ore 72 may be measured instead of the FeO concentration.
- the control value of the C concentration with which the sintered ore temperature at the discharge part of the cooler 60 exceeds the upper-temperature limit at the discharge part of the cooler 60 is determined in advance. Then, in the case where the C concentration is higher than the control value, the pallet speed is adjusted lower. In this case, an increase in C concentration indicates that there is an increase in C concentration due to C remaining uncombusted because of inhomogeneous temperature distribution in the width direction of the sintering machine, that is, unburned sintered ore is discharged.
- the method for manufacturing sintered ore according to the present embodiment may further include a blending amount-adjusting process of adjusting the amount of the bonding agent, of the sintering raw material, in accordance with the component concentration of at least one or more of FeO and C in the product sintered ore 72 that is measured in the measuring process. For example, even in the case where the FeO concentration in the product sintered ore 72 is higher than the control value, that is, even in the case where it is predicted that the sintering reaction temperature will be high, by decreasing the amount of the bonding agent in the blending amount-adjusting process, it is possible to decrease the sintering reaction temperature.
- the method for manufacturing sintered ore according to the present embodiment may further include a blowing amount-adjusting process of adjusting the amount of at least one of a gas fuel and oxygen blown in accordance with the concentration of at least one or more of FeO and C in the sintered ore that is measured in the measuring process. For example, even in the case where the FeO concentration in the sintered ore is higher than the control value, that is, even in the case where it is predicted that the sintering reaction temperature will be high, by decreasing the amount of at least one of the gas fuel and the oxygen blown in the blowing amount-adjusting process, it is possible to decrease the time for which the sintering reaction temperature is held at a higher level.
- carbonaceous material-coated particles which are manufactured by charging a sintering raw material containing the iron-containing raw material 12, the CaO-containing raw material 16, the MgO-containing raw material 17, and the return fine 74 to the drum mixer 36, by adding water to the sintering raw material to granulate the sintering raw material, and by charging the bonding agent 18 in the posterior part of the granulating time to coat the granulated particles with the bonding agent 18, may be used as a granulated sintering raw material.
- Carbonaceous material-coated particles which are manufactured by charging a sintering raw material containing the iron-containing raw material 12, the CaO-containing raw material 16, the MgO-containing raw material 17, the return fine 74, and part of the bonding agent 18 to the drum mixer 36, by adding water to the sintering raw material to granulate the sintering raw material, and by charging the remaining bonding agent 18 in the posterior part of the granulating time to coat the surface layer of the granulated sintering raw material with the bonding agent 18, may be used as a granulated sintering raw material.
- the bonding agent which is added in the posterior part of the granulating time after water has been added to the sintering raw material include coke breeze and anthracite.
- the carbonaceous material-coated particles, which are coated with the bonding agent 18 may be manufactured by charging all or part of the bonding agent 18 into the posterior part of the last drum mixer 36 and by charging the sintering raw material into the drum mixers 36 by using the method described above.
- the sintering raw material in the case where plural drum mixers 36 are used, all of the water may be added in the first drum mixer 36, or part of the water may be added in the first drum mixer 36 with the remaining water being added in the other drum mixers 36.
- granulated particles which are manufactured by charging a sintering raw material containing the iron-containing raw material 12, the MgO-containing raw material 17, and the return fine 74 to the drum mixer 36, by adding water to the sintering raw material to granulate the sintering raw material, and by charging the CaO-containing raw material 16 and the bonding agent 18 in the posterior part of the granulating time to coat the surface layer of the granulated particles with the CaO-containing raw material 16 and the bonding agent 18, may be used as a granulated sintering raw material.
- Granulated particles which are manufactured by charging a sintering raw material containing part of the iron-containing raw material 12, MgO-containing raw material 17, the return fine 74, and the bonding agent 18 to the drum mixer 36, by adding water to the sintering raw material to granulate the sintering raw material, and by adding the remaining iron-containing raw material 12 and the CaO-containing raw material 16 in the posterior part of the granulating time to coat the surface layer of the granulated sintering raw material with the iron-containing raw material 12 and the CaO-containing raw material 16, may be used as a granulated sintering raw material.
- Granulated particles which are manufactured by charging a sintering raw material containing the iron-containing raw material 12, the return fine 74, MgO-containing raw material 17, and part of the CaO-containing raw material 16 to the drum mixer 36, by adding water to the sintering raw material to granulate the sintering raw material, and by adding the remaining CaO-containing raw material 16 and the bonding agent 18 in the posterior part of the granulating time to coat the surface layer of the granulated sintering raw material with the CaO-containing raw material 16 and the bonding agent 18, may be used as a granulated sintering raw material.
- Granulated particles which are manufactured by charging a sintering raw material containing the iron-containing raw material 12, the return fine 74, MgO-containing raw material 17, and part of the CaO-containing raw material 16 and part of the bonding agent 18 to the drum mixer 36, by adding water to the sintering raw material to granulate the sintering raw material, and by adding the remaining CaO-containing raw material 16 and the remaining bonding agent 18 in the posterior part of the granulating time to coat the surface layer of the granulated sintering raw material with the CaO-containing raw material 16 and the bonding agent 18, may be used as a granulated sintering raw material.
- the granulated particles, which are coated with the CaO-containing raw material 16 and the bonding agent 18 may be manufactured by charging all or part of the CaO-containing raw material 16 and the bonding agent 18 into the posterior part of the last drum mixer 36 and by charging the sintering raw material into the drum mixers 36 by using the method described above.
- the embodiment of the present invention is not limited to this example.
- parts of the respective raw materials discharged from each of the blending bins 22, 24, 25, 26, and 28 in the raw material feeding section 20 are directly transported to the drum mixer 36 via the transporting conveyer 30, and the remaining parts of the respective raw materials are transported to a high-speed stirring apparatus via a transporting conveyer, which is different from the transporting conveyer 30, so as to be subjected to a stirring treatment.
- such remaining parts may be charged into the transporting conveyer 30 or the transporting conveyer 38 after having been subjected to granulation utilizing a granulating machine, such as a drum mixer 36 or a pelletizer, optionally followed by drying utilizing a drying machine as needed.
- a granulating machine such as a drum mixer 36 or a pelletizer
- such remaining parts may be directly charged into the transporting conveyer 30 after having been subjected to a stirring treatment without being subjected to granulation utilizing the granulating machine, such as a drum mixer 36 or a pelletizer.
- a crushing process and/or a sieving process may be performed before a stirring treatment is performed by using the high-speed stirring apparatus.
- such remaining parts may be charged into any one of the transporting conveyers placed between the drum mixers.
- plural infrared analyzers 80 may be installed.
- the component concentration of at least one or more of FeO and C in the sintered ore may be measured by using the plural infrared analyzers 80.
- sintered ore was manufactured by using the sintered ore manufacturing equipment 10 illustrated in Fig. 1 .
- the sintered ore was manufactured for 5 hours while the FeO concentration, as the component concentration in the sintered ore, was continuously measured at a frequency of 18 times per hour by using the infrared analyzer 80 installed in the transporting conveyer 76, and the blending ratio of the coke breeze, that is a bonding agent, was adjusted in accordance with the measured FeO concentrations so that the FeO concentration in the sintered ore was equal to the FeO control value.
- the raw material pile was changed to one containing dust having a high C concentration.
- the example of the present invention was an example including the pallet speed-adjusting process of adjusting the pallet speed in the sintering machine, and the comparative example was an example not including the pallet speed-adjusting process. Therefore, when there was an increase in the FeO concentration in the sintered ore, while the pallet speed was decreased and the blending ratio of coke breeze was adjusted in the example of the present invention, the blending ratio of coke breeze was adjusted without adjusting the pallet speed in the comparative example.
- Fig. 2 includes graphs illustrating the variations of the FeO concentration (mass%) in sintered ore, the pallet speed (m/min), the blending ratio (mass%) of coke breeze, and a sintered ore temperature (°C) at the discharge part of a cooler with respect to time in the case of the example of the present invention.
- Fig. 3 includes graphs illustrating the variations of the FeO concentration (mass%) in sintered ore, the pallet speed (m/min), the blending ratio (mass%) of coke breeze, and a sintered ore temperature (°C) at the discharge part of a cooler with respect to time in the case of the comparative example.
- the measuring process of continuously measuring the FeO concentration in the sintered ore by using the infrared analyzer 80 was included, it was possible to promptly detect that the FeO concentration in the sintered ore was higher than the FeO control value after the raw material pile had been changed. Since it was possible to detect, on the basis of an increase in the FeO concentration, that the temperature of the sintered ore at the discharge part of the cooler would exceed the upper-temperature limit due to an increase in the sintering reaction temperature, the pallet speed in the sintering machine was decreased in the pallet speed-adjusting process and the blending ratio of coke breeze was adjusted in the example of the present invention.
- the FeO concentration in the sintered ore is continuously measured, and the pallet speed in the sintering machine is adjusted when an increase in the FeO concentration in the sintered ore is detected.
- the blending ratio of coke breeze was adjusted. However, it was only after an elapsed time of about 30 minutes, which was the period of time from when the blending ratio of coke breeze was adjusted until the raw material already charged in the sintering machine was replaced by the adjusted raw material, that there was a decrease in sintered ore temperature at the discharge part of the cooler.
- the measurement utilizing the infrared analyzer 80 installed in the transporting conveyer 76 was performed at a measuring frequency of 18 times per hour in this example of the present invention, it is possible to realize the effects of the present invention caused by adjusting the pallet speed with a measuring frequency lower than this. It is sufficient that the measurement be performed once or more in a period of about 30 minutes, which is the time taken to replace the raw material already charged in the sintering machine.
- an increase in the sintering reaction temperature is promptly detected by continuously measuring the FeO concentration in the sintered ore in the measuring process, and the pallet speed is decreased in the pallet speed-adjusting process. It is clarified that, with this, for example, even in the case where there is an increase in the sintering reaction temperature due to the raw material pile being changed to one containing dust having a high C concentration, since it is possible to inhibit an increase in the sintered ore temperature at the discharge part of the cooler, it is possible to inhibit equipment problems such as abnormal stoppage of the cooler and the equipment breakdown of the sintering machine.
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Description
- The present invention relates to a method for manufacturing sintered ore, and in particular, to a method for manufacturing sintered ore including measuring component concentrations in the sintered ore and adjusting the pallet speed in accordance with the measured component concentrations.
- In blast furnace ironmaking methods, iron-containing raw materials such as sintered ore, lump iron ore, and pellets are mainly used as iron sources for blast furnace feed materials. Here, sintered ore is a kind of agglomerated ore manufactured in such a manner that a sintering raw material, which is prepared by gathering iron ore having a particle size of 10 mm or less, miscellaneous iron sources, such as various kinds of dust generated in a steel plant, CaO-containing raw materials, such as limestone, quick lime, and steel-making slag, and bonding agents, such as coke breeze and anthracite, and by adding, as an optional blending material, MgO-containing raw materials, such as nickel refining slag, dolomite, and serpentinite, and SiO2-containing raw materials, such as nickel refining slag and silica stone (silica sand), is stirred, mixed and granulated in a drum mixer with adding water, and then burned.
- In recent years, the concentration of iron in iron ore contained in a sintering raw material, which is a raw material for sintered ore, has been decreasing, and, in contrast, the concentrations of gangue components, such as SiO2 and Al2O3, have been increasing. In addition, the component concentrations in produced iron ore have become variable to such an extent that, even in the case of the same kind of iron ore, the component concentrations may vary from one shipment to another when the iron ore is imported.
- There is a large variation in the amounts of the various kinds of dust generated in a steel plant and in the carbon concentration in the dust. In the case where there is a large variation in the amount of carbon contained in a sintering raw material, there is a variation in the sintering reaction temperature.
- Since a variation in the sintering reaction temperature causes a variation in the quality of product sintered ore (hereinafter, also referred to as "sintered ore"), which is produced by performing sintering, the variation in the sintering reaction temperature has a significant influence on the quality of the sintered ore. For example, in the case where there is an excessive amount of heat, since there is an increase in the sintering reaction temperature, there is a deterioration in the quality of sintered ore, for example, due to a low-strength vitreous structure being formed in the sintered ore or due to a deterioration in reducibility as a result of an increase in the amount of magnetite structure. On the other hand, in the case where there is an insufficient amount of heat, since there is a decrease in the sintering reaction temperature, there may be a case where a sintering reaction does not occur, which results in sintered ore not being obtained. Therefore, adjusting the sintering reaction temperature is indispensable for achieving stable quality of sintered ore.
- However, it is very difficult to continuously determine the sintering reaction temperature. Therefore, generally, by analyzing the composition of sintered ore, the amount of heat is adjusted in accordance with the sintering reaction temperature which is estimated on the basis of analysis results. Specifically, the FeO concentration and the retained C concentration in sintered ore are determined. In a sintering reaction, thermal dissociation, in which hematite in sintered ore transitions into magnetite, progresses with an increase in temperature. Although magnetite transitions back into hematite with a decrease in temperature after the reaction, since the magnetite, which has been formed by thermal dissociation, does not always transition back into hematite, a large amount of magnetite is retained in sintered ore in the case where the sintering reaction temperature is high. Since magnetite contains divalent iron, the FeO concentration in sintered ore provides an indication of the sintering reaction temperature. Since C retained in sintered ore indicates that such C has not been used as a heat resource for a sintering reaction, it is supposed that there is an insufficient amount of heat at the time of the sintering reaction in the case where the C concentration retained in sintered ore is high.
- To date, determination of the components of sintered ore and adjustment of the amount of heat of the sintering reaction have been implemented. For example,
Patent Literature 1 discloses a technique in which the FeO concentration in sintered ore is determined and in which the amounts of a bonding agent and granulation water and an air-discharging rate of the sintering raw material are adjusted in accordance with the FeO concentration of the sintered ore. In addition,Patent Literature 2 discloses a technique in which the FeO concentration in sintered ore is determined and in which the amount of city gas blown into a sintering machine is adjusted in accordance with the FeO concentration of the sintered ore. - In addition,
Patent Literature 3 discloses a technique in which the component concentrations in sintered ore are estimated on the basis of the component concentrations in a surface layer of the burden layer of a sintering raw material, which has been charged onto a pallet, the component concentrations in the surface layer being determined by using a laser-type component measuring device disposed above a sintering machine, and in which the composition of a sintering raw material is adjusted in accordance with the estimation results. Futhermore,Patent Literature -
- PTL 1:
Japanese Unexamined Patent No. 1464203 - PTL 2:
Japanese Unexamined Patent No. 5544784 - PTL 3:
Japanese Unexamined Patent Application Publication No. 60-262926 - PTL 4:
US 2012/103136 A1 - PTL 5:
US 2005/050995 A1 - In the case of the techniques disclosed in
Patent Literature 1 andPatent Literature 2, the FeO concentration in sintered ore is determined, and the amounts of bonding agents and granulation water, the air-discharging rate, and the amount of city gas blown are adjusted to achieve the target concentration of FeO. However, since it takes a long time to reflect the adjustment results in the component of the sintered ore, there may be equipment problems such as abnormal stoppage of a cooler and the breakdown of equipment located downstream of the cooler when there is an increase in the sintering reaction temperature. - In the case of the technique disclosed in
Patent Literature 3, although the component concentrations in sintered ore are estimated on the basis of the component concentrations in the surface layer of a burden layer of a sintering raw material, there is a variation in the component concentrations in the surface layer of the burden layer of the sintering raw material due to segregation caused by a charging apparatus for the sintering raw material and the particle diameter of the sintering raw material. Therefore, there is no definite relationship between the component concentrations in the surface layer of the burden layer and the component concentrations in the sintered ore, which makes it difficult to practically estimate the component concentrations in the sintered ore on the basis of the component concentrations in the surface layer of the burden layer. - The present invention has been completed in view of the problems of the conventional techniques, and an object of the present invention is to provide a method for manufacturing sintered ore with which it is possible to inhibit equipment problems from occurring in equipment for manufacturing sintered ore, even when there is a variation in the sintering reaction temperature, by detecting such a variation.
- The features of the present invention for solving the issues described above are as disclosed in appended claims 1-4.
- By implementing the method for manufacturing sintered ore according to the present invention, the component concentrations in sintered ore are continuously measured, and the pallet speed of a sintering machine is adjusted. With this, since it is possible to inhibit an increase in sintered ore temperature at the discharge part of a cooler, it is possible to inhibit equipment problems such as the equipment breakdown of the sintering machine.
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Fig. 1] Fig. 1 is a schematic diagram illustrating an example of sinteredore manufacturing equipment 10 with which the method for manufacturing sintered ore according to the present embodiment is implemented. - [
Fig. 2] Fig. 2 includes graphs illustrating the variations of the FeO concentration in sintered ore, the pallet speed, the blending ratio of coke breeze, and a sintered ore temperature at the discharge part of a cooler with respect to time in the case of the example of the present invention. - [
Fig. 3] Fig. 3 includes graphs illustrating the variations of the FeO concentration in sintered ore, the pallet speed, the blending ratio of coke breeze, and a sintered ore temperature at the discharge part of a cooler with respect to time in the case of the comparative example. - Hereafter, the present invention will be described in accordance with the embodiments of the present invention.
Fig. 1 is a schematic diagram illustrating an example of sinteredore manufacturing equipment 10 with which the method for manufacturing sintered ore according to the present embodiment is implemented. An iron-containingraw material 12 which is stored in ayard 11 is transported to ablending bin 22 via a transportingconveyer 14. The iron-containingraw material 12 contains various brands of iron ore and dust generated in a steel plant. - A raw
material feeding section 20 hasplural blending bins blending bin 22 contains the iron-containingraw material 12. Theblending bin 24 contains a CaO-containingraw material 16 including limestone, quicklime, and so forth. Theblending bin 25 contains a MgO-containingraw material 17 including dolomite, nickel refining slag, and so forth. Theblending bin 26 contains abonding agent 18 including coke breeze, which is prepared by performing crushing in a rod mill so that the particle diameter is 1 mm or less, and anthracite. Theblending bin 28 contains return fine 74 having a particle diameter of 5 mm or less, which is the portion of sintered ore passing through sieves for sintered ore (powder under the sieves for sintered ore). Predetermined amounts of the raw materials are discharged from each of theblending bins material feeding section 20 so as to be added, and a blend of the discharged raw materials is made into a sintering raw material on a transportingconveyer 30. The sintering raw material is transported to adrum mixer 36 via the transportingconveyer 30. A SiO2-containing raw material may be blended in the sintering raw material. In this case, a predetermined amount of the SiO2-containing raw material may be blended to the iron-containingraw material 12 stored in theyard 11, or another blending bin containing the SiO2-containing raw material may be installed and a predetermined amount of the SiO2-containing raw material may be discharged from the blending bin so as to be blended. - The sintering raw material, which has been transported to the
drum mixer 36, is charged into thedrum mixer 36 with an appropriate amount ofwater 34 being added and granulated to form quasiparticles having an average particle diameter of, for example, 3.0 mm to 6.0 mm. The granulated sintering raw material is transported to a sintering rawmaterial charging device 42 of asintering machine 40 via a transportingconveyer 38. Since thedrum mixer 36 is an example of a granulating apparatus which is used to granulate the sintering raw material,plural drum mixers 36 may be used, and a pelletizer may be used as a granulating apparatus instead of thedrum mixer 36. Both thedrum mixer 36 and the pelletizer may be used, and a high-speed stirring apparatus may be placed upstream of thedrum mixer 36 to stir the sintering raw material before the sintering raw material is charged into thedrum mixer 36. In the present embodiment, the term "average particle diameter" denotes an arithmetic average particle diameter defined by the formula ∑(Vi × di), where Vi denotes the abundance ratio of particles having a particle diameter within the i-th range defined in terms of particle diameter and di denotes the representative particle diameter of the i-th range. In thesintering machine 40, the sintering raw material, which has been granulated in thedrum mixer 36, is sintered. The sinteringmachine 40 is, for example, a downward suction-type Dwight-Lloyd sintering machine. The sinteringmachine 40 has the sintering rawmaterial charging device 42, an endlessmobile pallet 44 that circulates and moves, anignition furnace 46, andwind boxes 48. The sintering raw material, which has been granulated, is charged into thepallet 44 through the sintering rawmaterial charging device 42 to form a burden layer of the sintering raw material. - The burden layer is ignited by using the
ignition furnace 46, and air in the burden layer is suctioned downward through thewind boxes 48 so that a combustion-melting zone in the burden layer moves toward the lower portion of the burden layer. With this, the burden layer is sintered to form a sintered cake. When air in the burden layer is suctioned downward through thewind boxes 48, at least one of a gas fuel and oxygen may be blown down from above the burden layer. The gas fuel is a combustible gas selected from among blast furnace gas, coke oven gas, converter gas, city gas, natural gas, methane gas, ethane gas, propane gas, and shale gas, and a mixture thereof. - The sintered cake is crushed by using a crushing
machine 50 to form sintered ore. The sintered ore, which has been crushed by using the crushingmachine 50, is cooled by using a cooler 60. The sintered ore, which has been cooled by using the cooler 60, is subjected to screening utilizing asieving apparatus 70 having plural sieves to separate the sintered ore into product sinteredore 72 having a particle diameter of more than 5 mm and the return fine 74 having a particle diameter of 5 mm or less. - The product sintered
ore 72 is transported to ablast furnace 82 via a transportingconveyer 76. In the transportingconveyer 76, via which the product sinteredore 72 is transported, aninfrared analyzer 80 is installed. By using theinfrared analyzer 80, a measuring process is performed. In the measuring process, the component concentration of at least one or more of FeO and C in the product sinteredore 72 is continuously measured by using theinfrared analyzer 80. - The
infrared analyzer 80 radiates infrared light having a wavelength of 0.5 µm to 50.0 µm and receives reflected light from the product sinteredore 72. Since the molecular vibration of FeO contained in the product sinteredore 72 absorbs specific-wavelength components of the radiated infrared light, FeO imparts specific-wavelength components to the reflected infrared light. Also, the crystal structure of a single-atom molecule, such as C, starts vibrating at the time of radiating the infrared light and thereby imparts the specific-wavelength components to the reflected infrared light. Therefore, it is possible to determine the component concentrations of FeO and C in the product sinteredore 72 by analyzing the radiated infrared light and the reflected infrared light. - The
infrared analyzer 80 radiates infrared light having 20 or more wavelengths and receives reflected light reflected from the product sinteredore 72 at a frequency of, for example, 128 times per minute. Since it is possible to radiate and receive infrared light in such a short time by using theinfrared analyzer 80, it is possible to continuously measure the component concentrations in the product sinteredore 72, which is transported on the transportingconveyer 76, online by using theinfrared analyzer 80. Since theinfrared analyzer 80 is an example of an analyzing device which is used to measure the component concentrations in the sintering raw material, a laser analyzer which radiates laser beams onto an object to be measured, a neutron analyzer which radiates neutrons onto an object to be measured, or a microwave analyzer which radiates microwaves onto an object to be measured may be used instead of theinfrared analyzer 80. - The product sintered
ore 72 having a particle diameter of more than 5 mm is transported to theblast furnace 82 via the transportingconveyer 76 and charged into a blast furnace as a blast furnace feed material. On the other hand, the return fine 74 having a particle diameter of 5 mm or less is transported to theblending bin 28 in the rawmaterial feeding section 20 via a transportingconveyer 78. - Since the product sintered
ore 72 is sintered ore which has been subjected to crushing by using the crushingmachine 50 followed by cooling and screening, the product sinteredore 72, the sintered ore which has been crushed by using the crushingmachine 50 and thereturn fine 74 have the same component concentrations. Therefore, theinfrared analyzer 80 may be installed between the cooler 60 and the sievingapparatus 70 or on the transportingconveyer 78. In the case where theinfrared analyzer 80 is installed between the cooler 60 and the sievingapparatus 70, the component concentrations in the sintered ore, which has been cooled, are measured in the measuring process. In the case where theinfrared analyzer 80 is installed in the transportingconveyer 78, the component concentrations in thereturn fine 74 are measured in the measuring process. - In the present embodiment, the term "particle diameter of the product sintered
ore 72 or the return fine 74" denotes a particle diameter determined by performing screening utilizing a sieve, and, for example, the expression "a particle diameter of more than 5 mm" denotes the particle diameter of particles which remain on a sieve having a sieve mesh of 5 mm, and the expression "a particle diameter of 5 mm or less" denotes the particle diameter of particles which pass through a sieve having a sieve mesh of 5 mm. The value expressing the particle diameter of the product sinteredore 72 or thereturn fine 74 is definitely used as an example, and the particle diameter of the product sinteredore 72 or thereturn fine 74 is not limited to this example. - The method for manufacturing sintered ore according to the present embodiment includes a pallet speed-adjusting process of adjusting the pallet speed. In the pallet speed-adjusting process, the pallet speed is adjusted in accordance with, for example, the FeO concentration in the product sintered
ore 72 which is measured in the measuring process. - Since the fact that the FeO concentration in the product sintered
ore 72 is high indicates that a large amount of magnetite is retained in the product sinteredore 72, it is inferred that there is an increase in the temperature of a sintered cake due to an increase in the sintering reaction temperature. Therefore, even if such a sintered cake is crushed and cooled by using the cooler 60, since it is not possible to cool the sintered ore to a temperature equal to or lower than the upper-temperature limit at the discharge part of the cooler 60, there may be equipment problems such as abnormal stoppage of the cooler 60 and the breakdown of equipment located downstream of the cooler 60. - Therefore, by checking the relationship between the FeO concentration in the sintered ore and a sintered ore temperature at the discharge part of the cooler 60 in accordance with the pallet speed in advance, the control value of the FeO concentration, which indicates that the sintered ore temperature at the discharge part of the cooler 60 exceeds the upper-temperature limit at the discharge part of the cooler 60, is determined in advance. In the pallet speed-adjusting process, in the case where the FeO concentration in the product sintered
ore 72 is higher than the control value, that is, in the case where it is predicted that the sintered ore temperature at the discharge part of the cooler 60, which is calculated by using the relationship described above, will exceed the upper-temperature limit, the pallet speed is adjusted lower. In the case where there is a decrease in the pallet speed, since there is an increase in the time for which the sintered ore is cooled in the cooler 60, there is a decrease in sintered ore temperature at the discharge part of the cooler 60, which makes it possible to inhibit equipment problems such as abnormal stoppage of the cooler 60 and the breakdown of equipment located downstream of the cooler 60. - In the example described above, the FeO concentration in the product sintered
ore 72 is continuously measured in the measuring process, and the pallet speed is adjusted in the case where the FeO concentration in the product sinteredore 72 is higher than the control value, that is, in the case where it is predicted that the sintered ore temperature at the discharge part of the cooler 60, which is calculated by using the relationship described above, will exceed the upper-temperature limit. However, in the measuring process, the C concentration in the product sinteredore 72 may be measured instead of the FeO concentration. By checking the relationship between the C concentration in the sintered ore and a sintered ore temperature at the discharge part of the cooler 60 in advance, the control value of the C concentration with which the sintered ore temperature at the discharge part of the cooler 60 exceeds the upper-temperature limit at the discharge part of the cooler 60 is determined in advance. Then, in the case where the C concentration is higher than the control value, the pallet speed is adjusted lower. In this case, an increase in C concentration indicates that there is an increase in C concentration due to C remaining uncombusted because of inhomogeneous temperature distribution in the width direction of the sintering machine, that is, unburned sintered ore is discharged. Therefore, by adjusting the pallet speed lower to completely combust C in the sintering machine, it is possible to inhibit abnormal stoppage of the cooler 60 due to C being combusted in the cooler 60 and equipment problems, for example, due to C being combusted in equipment located downstream of the cooler 60. - The method for manufacturing sintered ore according to the present embodiment may further include a blending amount-adjusting process of adjusting the amount of the bonding agent, of the sintering raw material, in accordance with the component concentration of at least one or more of FeO and C in the product sintered
ore 72 that is measured in the measuring process. For example, even in the case where the FeO concentration in the product sinteredore 72 is higher than the control value, that is, even in the case where it is predicted that the sintering reaction temperature will be high, by decreasing the amount of the bonding agent in the blending amount-adjusting process, it is possible to decrease the sintering reaction temperature. After the sintering reaction temperature has been decreased, since it is possible to return the pallet speed, which has been decreased in the pallet speed-adjusting process, to the original value, it is possible to inhibit a decrease in the productivity of sintered ore due to a decrease in the pallet speed. By inhibiting a variation in the sintering reaction temperature by adjusting the amount of the bonding agent added, since it is possible to inhibit a variation in the FeO concentration in the sintered ore, there is an improvement in the quality of sintered ore. - The method for manufacturing sintered ore according to the present embodiment may further include a blowing amount-adjusting process of adjusting the amount of at least one of a gas fuel and oxygen blown in accordance with the concentration of at least one or more of FeO and C in the sintered ore that is measured in the measuring process. For example, even in the case where the FeO concentration in the sintered ore is higher than the control value, that is, even in the case where it is predicted that the sintering reaction temperature will be high, by decreasing the amount of at least one of the gas fuel and the oxygen blown in the blowing amount-adjusting process, it is possible to decrease the time for which the sintering reaction temperature is held at a higher level. After the time for which the sintering reaction temperature is held at a higher level has been decreased, since it is possible to return the pallet speed, which has been decreased in the pallet speed-adjusting process, to the original value, it is possible to inhibit a decrease in the productivity of sintered ore due to a decrease in the pallet speed. By inhibiting a variation in the sintering reaction temperature by adjusting the amount of at least one of the gas fuel and oxygen blown, since it is possible to inhibit a variation in the FeO concentration in the sintered ore, there is an improvement in the quality of sintered ore.
- Although an example, in which raw materials are discharged from each of the blending
bins material feeding section 20 to be blended, made into the sintering raw material in the transportingconveyer 30, and granulated in thedrum mixer 36, is described in the present embodiment, the embodiment of the present invention is not limited to this example. For example, carbonaceous material-coated particles, which are manufactured by charging a sintering raw material containing the iron-containingraw material 12, the CaO-containingraw material 16, the MgO-containingraw material 17, and the return fine 74 to thedrum mixer 36, by adding water to the sintering raw material to granulate the sintering raw material, and by charging thebonding agent 18 in the posterior part of the granulating time to coat the granulated particles with thebonding agent 18, may be used as a granulated sintering raw material. - Carbonaceous material-coated particles, which are manufactured by charging a sintering raw material containing the iron-containing
raw material 12, the CaO-containingraw material 16, the MgO-containingraw material 17, thereturn fine 74, and part of thebonding agent 18 to thedrum mixer 36, by adding water to the sintering raw material to granulate the sintering raw material, and by charging the remainingbonding agent 18 in the posterior part of the granulating time to coat the surface layer of the granulated sintering raw material with thebonding agent 18, may be used as a granulated sintering raw material. Examples of the bonding agent which is added in the posterior part of the granulating time after water has been added to the sintering raw material include coke breeze and anthracite. - In the case where
plural drum mixers 36 are used and the surface layer of the carbonaceous material-coated particles which is coated with thebonding agent 18 are used, the carbonaceous material-coated particles, which are coated with thebonding agent 18, may be manufactured by charging all or part of thebonding agent 18 into the posterior part of thelast drum mixer 36 and by charging the sintering raw material into thedrum mixers 36 by using the method described above. Moreover, regarding water which is added to the sintering raw material in the case whereplural drum mixers 36 are used, all of the water may be added in thefirst drum mixer 36, or part of the water may be added in thefirst drum mixer 36 with the remaining water being added in theother drum mixers 36. - Although an example, in which raw materials are discharged from each of the blending
bins material feeding section 20 to be blended, made into the sintering raw material in the transportingconveyer 30, and granulated in thedrum mixer 36, is described in the present embodiment, the embodiment of the present invention is not limited to this example. For example, granulated particles, which are manufactured by charging a sintering raw material containing the iron-containingraw material 12, the MgO-containingraw material 17, and the return fine 74 to thedrum mixer 36, by adding water to the sintering raw material to granulate the sintering raw material, and by charging the CaO-containingraw material 16 and thebonding agent 18 in the posterior part of the granulating time to coat the surface layer of the granulated particles with the CaO-containingraw material 16 and thebonding agent 18, may be used as a granulated sintering raw material. - Granulated particles, which are manufactured by charging a sintering raw material containing part of the iron-containing
raw material 12, MgO-containingraw material 17, thereturn fine 74, and thebonding agent 18 to thedrum mixer 36, by adding water to the sintering raw material to granulate the sintering raw material, and by adding the remaining iron-containingraw material 12 and the CaO-containingraw material 16 in the posterior part of the granulating time to coat the surface layer of the granulated sintering raw material with the iron-containingraw material 12 and the CaO-containingraw material 16, may be used as a granulated sintering raw material. - Granulated particles, which are manufactured by charging a sintering raw material containing the iron-containing
raw material 12, thereturn fine 74, MgO-containingraw material 17, and part of the CaO-containingraw material 16 to thedrum mixer 36, by adding water to the sintering raw material to granulate the sintering raw material, and by adding the remaining CaO-containingraw material 16 and thebonding agent 18 in the posterior part of the granulating time to coat the surface layer of the granulated sintering raw material with the CaO-containingraw material 16 and thebonding agent 18, may be used as a granulated sintering raw material. - Granulated particles, which are manufactured by charging a sintering raw material containing the iron-containing
raw material 12, thereturn fine 74, MgO-containingraw material 17, and part of the CaO-containingraw material 16 and part of thebonding agent 18 to thedrum mixer 36, by adding water to the sintering raw material to granulate the sintering raw material, and by adding the remaining CaO-containingraw material 16 and the remainingbonding agent 18 in the posterior part of the granulating time to coat the surface layer of the granulated sintering raw material with the CaO-containingraw material 16 and thebonding agent 18, may be used as a granulated sintering raw material. - In the case where
plural drum mixers 36 are used and the granulated particles which are coated with the CaO-containingraw material 16 or the CaO-containingraw material 16 and thebonding agent 18 are manufactured, the granulated particles, which are coated with the CaO-containingraw material 16 and thebonding agent 18, may be manufactured by charging all or part of the CaO-containingraw material 16 and thebonding agent 18 into the posterior part of thelast drum mixer 36 and by charging the sintering raw material into thedrum mixers 36 by using the method described above. - Although an example, in which raw materials are discharged from each of the blending
bins material feeding section 20 to be blended and made into the sintering raw material in the transportingconveyer 30, is described in the present embodiment, the embodiment of the present invention is not limited to this example. For example, parts of the respective raw materials discharged from each of the blendingbins material feeding section 20 are directly transported to thedrum mixer 36 via the transportingconveyer 30, and the remaining parts of the respective raw materials are transported to a high-speed stirring apparatus via a transporting conveyer, which is different from the transportingconveyer 30, so as to be subjected to a stirring treatment. Subsequently, such remaining parts may be charged into the transportingconveyer 30 or the transportingconveyer 38 after having been subjected to granulation utilizing a granulating machine, such as adrum mixer 36 or a pelletizer, optionally followed by drying utilizing a drying machine as needed. Also, such remaining parts may be directly charged into the transportingconveyer 30 after having been subjected to a stirring treatment without being subjected to granulation utilizing the granulating machine, such as adrum mixer 36 or a pelletizer. Moreover, a crushing process and/or a sieving process may be performed before a stirring treatment is performed by using the high-speed stirring apparatus. In the case whereplural drum mixers 36 are used, such remaining parts may be charged into any one of the transporting conveyers placed between the drum mixers. - Moreover, in the measuring process, not only one but plural
infrared analyzers 80 may be installed. The component concentration of at least one or more of FeO and C in the sintered ore may be measured by using the pluralinfrared analyzers 80. - In the case of both the example of the present invention and the comparative example, sintered ore was manufactured by using the sintered
ore manufacturing equipment 10 illustrated inFig. 1 . In the case of example of the present invention and the comparative example, the sintered ore was manufactured for 5 hours while the FeO concentration, as the component concentration in the sintered ore, was continuously measured at a frequency of 18 times per hour by using theinfrared analyzer 80 installed in the transportingconveyer 76, and the blending ratio of the coke breeze, that is a bonding agent, was adjusted in accordance with the measured FeO concentrations so that the FeO concentration in the sintered ore was equal to the FeO control value. In the case of both the example of the present invention and the comparative example, after one hour had elapsed since the start of manufacturing, the raw material pile was changed to one containing dust having a high C concentration. - The example of the present invention was an example including the pallet speed-adjusting process of adjusting the pallet speed in the sintering machine, and the comparative example was an example not including the pallet speed-adjusting process. Therefore, when there was an increase in the FeO concentration in the sintered ore, while the pallet speed was decreased and the blending ratio of coke breeze was adjusted in the example of the present invention, the blending ratio of coke breeze was adjusted without adjusting the pallet speed in the comparative example.
-
Fig. 2 includes graphs illustrating the variations of the FeO concentration (mass%) in sintered ore, the pallet speed (m/min), the blending ratio (mass%) of coke breeze, and a sintered ore temperature (°C) at the discharge part of a cooler with respect to time in the case of the example of the present invention.Fig. 3 includes graphs illustrating the variations of the FeO concentration (mass%) in sintered ore, the pallet speed (m/min), the blending ratio (mass%) of coke breeze, and a sintered ore temperature (°C) at the discharge part of a cooler with respect to time in the case of the comparative example. - Since the measuring process of continuously measuring the FeO concentration in the sintered ore by using the
infrared analyzer 80 was included, it was possible to promptly detect that the FeO concentration in the sintered ore was higher than the FeO control value after the raw material pile had been changed. Since it was possible to detect, on the basis of an increase in the FeO concentration, that the temperature of the sintered ore at the discharge part of the cooler would exceed the upper-temperature limit due to an increase in the sintering reaction temperature, the pallet speed in the sintering machine was decreased in the pallet speed-adjusting process and the blending ratio of coke breeze was adjusted in the example of the present invention. As a result, since it was possible to inhibit an increase in sintered ore temperature at the discharge part of the cooler, it was possible to perform the operation without the upper-temperature limit at the discharge part of the cooler being exceeded. After the FeO concentration had been returned to the control value by adjusting the blending ratio of coke breeze, the pallet speed was returned to the original value. With this, it was also possible to inhibit a decrease in the productivity of the sintered ore. - As described above, in the case of the method for manufacturing sintered ore according to the present embodiment, the FeO concentration in the sintered ore is continuously measured, and the pallet speed in the sintering machine is adjusted when an increase in the FeO concentration in the sintered ore is detected. With this, it is clarified that, since it is possible to inhibit an increase in sintered ore temperature at the discharge part of the cooler, it is possible to decrease a load on the cooler and equipment located downstream of the cooler, which makes it possible to avoid equipment problems such as equipment breakdown.
- Also in the case of the comparative example, since it was possible to detect, on the basis of an increase in the FeO concentration in the sintered ore, that the temperature of the sintered ore at the discharge part of the cooler would exceed the upper-temperature limit, the blending ratio of coke breeze was adjusted. However, it was only after an elapsed time of about 30 minutes, which was the period of time from when the blending ratio of coke breeze was adjusted until the raw material already charged in the sintering machine was replaced by the adjusted raw material, that there was a decrease in sintered ore temperature at the discharge part of the cooler. During such an elapsed time, there was an increase in sintered ore temperature at the discharge part of the cooler to a level exceeding the upper-temperature limit at the discharge part of the cooler, which resulted in abnormal stoppage of the cooler. After the stoppage of the cooler and the pallet, since there was a decrease in the temperature of the sintering machine, the manufacture of sintered ore was restarted with the blending ratio of coke breeze in the sintering raw material being increased and with the pallet speed being decreased.
- In the case of both the example of the present invention and the comparative example, when an increase in the FeO concentration in the sintered ore was detected and it was thereby possible to detect that the temperature of the sintered ore at the discharge part of the cooler would exceed the upper-temperature limit, the sintering raw material taken from the raw material pile containing dust having a high C concentration causing the sintering reaction temperature to increase had already been charged onto a pallet in the sintering machine. In the case of the comparative example, although the blending ratio of coke breeze was adjusted, such adjustment of the blending ratio was reflected in the sintering raw material which was prepared by using the raw materials discharged from the raw material feeding section to be added after such adjustment had been performed and not in the sintering raw material which had already been charged on the pallet. Therefore, in the case of the comparative example, since there was an increase in sintered ore temperature due to an increase in the sintering reaction temperature, the sintered ore temperature exceeded the upper-temperature limit at the discharge part of the cooler. As a result, an equipment problem, that is, abnormal stoppage of the cooler occurred.
- In the case of the example of the present invention, when an increase in the FeO concentration in the sintered ore was detected and it was thereby possible to detect that the temperature of the sintered ore at the discharge part of the cooler would exceed the upper-temperature limit, the pallet speed was decreased in the pallet speed-adjusting process. With this, since it was possible to increase the time for which the sintering raw material which had already been charged onto a pallet was cooled in the cooler, it was possible to inhibit an increase in sintered ore temperature at the discharge part of the cooler, even if there was an increase in the sintering reaction temperature of such a sintering raw material, which made it possible to inhibit problems such as abnormal stoppage of the cooler and the equipment breakdown. Although the measurement utilizing the
infrared analyzer 80 installed in the transportingconveyer 76 was performed at a measuring frequency of 18 times per hour in this example of the present invention, it is possible to realize the effects of the present invention caused by adjusting the pallet speed with a measuring frequency lower than this. It is sufficient that the measurement be performed once or more in a period of about 30 minutes, which is the time taken to replace the raw material already charged in the sintering machine. - As described above, in the case of the method for manufacturing sintered ore according to the present embodiment, an increase in the sintering reaction temperature is promptly detected by continuously measuring the FeO concentration in the sintered ore in the measuring process, and the pallet speed is decreased in the pallet speed-adjusting process. It is clarified that, with this, for example, even in the case where there is an increase in the sintering reaction temperature due to the raw material pile being changed to one containing dust having a high C concentration, since it is possible to inhibit an increase in the sintered ore temperature at the discharge part of the cooler, it is possible to inhibit equipment problems such as abnormal stoppage of the cooler and the equipment breakdown of the sintering machine.
-
- 10
- sintered ore manufacturing equipment
- 11
- yard
- 12
- iron-containing raw material
- 14
- transporting conveyer
- 16
- CaO-containing raw material
- 17
- MgO-containing raw material
- 18
- bonding agent
- 20
- raw material feeding section
- 22
- blending bin
- 24
- blending bin
- 25
- blending bin
- 26
- blending bin
- 28
- blending bin
- 30
- transporting conveyer
- 34
- water
- 36
- drum mixer
- 38
- transporting conveyer
- 40
- sintering machine
- 42
- sintering raw material charging device
- 44
- pallet
- 46
- ignition furnace
- 48
- wind box
- 50
- crushing machine
- 60
- cooler
- 70
- sieving apparatus
- 72
- product sintered ore
- 74
- return fine
- 76
- transporting conveyer
- 78
- transporting conveyer
- 80
- infrared analyzer
- 82
- blast furnace
Claims (4)
- A method for manufacturing sintered ore, in which a sintering raw material containing an iron-containing raw material, a CaO-containing raw material, and a bonding agent is mixed with water and granulated, and the granulated sintering raw material is sintered in a sintering machine to manufacture sintered ore, the method comprising:a measuring process of continuously measuring component concentration (mass%) of at least one or more of FeO and C in the sintered ore, wherein the measurement is performed by use of any of an infrared analyzer, a laser analyzer, a neutron analyzer or a microwave analyzer; anda pallet speed-adjusting process of adjusting a pallet speed in accordance with the component concentration of at least one or more of FeO and C in the sintered ore measured in the measuring process,wherein, in the case that the component concentration is higher than a control value, the pallet speed is adjusted to be lower in the pallet speed-adjusting process.
- The method for manufacturing sintered ore according to Claim 1, wherein the sintering raw material further contains at least one of a MgO-containing raw material and a SiO2-containing raw material.
- The method for manufacturing sintered ore according to Claim 1 or 2, the method further comprising
a blending amount-adjusting process of adjusting an amount of the bonding agent, of the sintering raw material, in accordance with the component concentration of at least one or more of FeO and C in the sintered ore. - The method for manufacturing sintered ore according to any one of Claims 1 to 3,wherein at least one of a gas fuel and oxygen is blown into the sintering machine to sinter the sintering raw material, the method further comprisinga blowing amount-adjusting process of adjusting an amount of at least one of the gas fuel and the oxygen blown in accordance with the component concentration of at least one or more of FeO and C in the sintered ore.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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JP2017206136 | 2017-10-25 | ||
PCT/JP2018/038576 WO2019082749A1 (en) | 2017-10-25 | 2018-10-17 | Sintered ore manufacturing method |
Publications (3)
Publication Number | Publication Date |
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EP3670685A1 EP3670685A1 (en) | 2020-06-24 |
EP3670685A4 EP3670685A4 (en) | 2020-07-15 |
EP3670685B1 true EP3670685B1 (en) | 2022-03-09 |
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EP18869498.8A Active EP3670685B1 (en) | 2017-10-25 | 2018-10-17 | Method for manufacturing sintered ore |
Country Status (8)
Country | Link |
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EP (1) | EP3670685B1 (en) |
JP (1) | JP6665972B2 (en) |
KR (1) | KR102434776B1 (en) |
CN (1) | CN111263822A (en) |
BR (1) | BR112020007400B1 (en) |
PH (1) | PH12020550475A1 (en) |
TW (1) | TWI687636B (en) |
WO (1) | WO2019082749A1 (en) |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
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JPS5114193A (en) | 1974-07-26 | 1976-02-04 | Denki Kagaku Kogyo Kk | KAABONBURATSUKUPURESUHO |
JPS52109416A (en) * | 1976-03-10 | 1977-09-13 | Sumitomo Metal Ind Ltd | Control method for cooling temperature of sintered ore |
JPS569336A (en) * | 1979-07-05 | 1981-01-30 | Sumitomo Metal Ind Ltd | Operation of sintering machine |
JPS5616628A (en) * | 1979-07-17 | 1981-02-17 | Kawasaki Steel Corp | Controlling method for sintering of ore or the like |
JPS5848609A (en) * | 1981-09-16 | 1983-03-22 | Sumitomo Metal Ind Ltd | Monitoring method for progressing condition of sintering |
JPS60262926A (en) | 1984-06-08 | 1985-12-26 | Kawasaki Steel Corp | Method for controlling concentration of component in product sintered ore |
WO2004055224A1 (en) * | 2002-12-17 | 2004-07-01 | Jfe Steel Corporation | Process for producing sintering feedstock and apparatus therefor |
EP1847536A1 (en) | 2006-04-20 | 2007-10-24 | Prodimed, S.A. | Synthesis and uses of pyroglutamic acid derivatives |
KR100833008B1 (en) * | 2006-12-18 | 2008-05-27 | 주식회사 포스코 | Producing apparatus for sintered ore having easily seaching surface complexing of raw material |
JP5298634B2 (en) * | 2008-05-19 | 2013-09-25 | 新日鐵住金株式会社 | Quality control method for sintered ore |
JP2011042870A (en) * | 2009-07-21 | 2011-03-03 | Kobe Steel Ltd | Apparatus and method for producing reduced iron using alkali-containing iron-making dust as raw material |
JP5544784B2 (en) * | 2009-08-17 | 2014-07-09 | Jfeスチール株式会社 | Sintering machine |
JP5947277B2 (en) * | 2013-12-11 | 2016-07-06 | Primetals Technologies Japan株式会社 | Partially reduced iron production equipment |
CN103697699B (en) * | 2013-12-26 | 2015-03-11 | 中冶长天国际工程有限责任公司 | Method and system for controlling sintering end point |
CN104977316A (en) * | 2014-04-03 | 2015-10-14 | 宝钢不锈钢有限公司 | Method for distinguishing trend of content of FeO in sinter |
CN110325654A (en) * | 2017-02-16 | 2019-10-11 | 杰富意钢铁株式会社 | The manufacturing method of sinter |
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2018
- 2018-10-17 BR BR112020007400-4A patent/BR112020007400B1/en active IP Right Grant
- 2018-10-17 KR KR1020207011596A patent/KR102434776B1/en active IP Right Grant
- 2018-10-17 EP EP18869498.8A patent/EP3670685B1/en active Active
- 2018-10-17 CN CN201880069110.XA patent/CN111263822A/en active Pending
- 2018-10-17 JP JP2019551040A patent/JP6665972B2/en active Active
- 2018-10-17 WO PCT/JP2018/038576 patent/WO2019082749A1/en unknown
- 2018-10-18 TW TW107136625A patent/TWI687636B/en active
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PH12020550475A1 (en) | 2021-03-08 |
EP3670685A1 (en) | 2020-06-24 |
BR112020007400A2 (en) | 2020-09-29 |
WO2019082749A1 (en) | 2019-05-02 |
TWI687636B (en) | 2020-03-11 |
EP3670685A4 (en) | 2020-07-15 |
KR20200057745A (en) | 2020-05-26 |
KR102434776B1 (en) | 2022-08-19 |
TW201923299A (en) | 2019-06-16 |
CN111263822A (en) | 2020-06-09 |
JPWO2019082749A1 (en) | 2019-12-12 |
BR112020007400B1 (en) | 2023-03-21 |
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