TWI680798B - 結晶微孔材料介導之ｃ-含氧化合物至ｃ-含氧化合物的轉換 - Google Patents

結晶微孔材料介導之ｃ-含氧化合物至ｃ-含氧化合物的轉換 Download PDF

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TWI680798B
TWI680798B TW104119956A TW104119956A TWI680798B TW I680798 B TWI680798 B TW I680798B TW 104119956 A TW104119956 A TW 104119956A TW 104119956 A TW104119956 A TW 104119956A TW I680798 B TWI680798 B TW I680798B
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oxygen
oxygenates
compounds
crystalline microporous
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TW201634117A (zh
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撒拉凡南慕魯剛 舒慕賈菲爾
蘇比瑞 伊朗斯 撒達巴
艾斯班 塔爾寧
馬丁 史班斯伯格 荷爾姆
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丹麥商托普索公司
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    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/405—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
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    • B01J29/7049—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
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TW104119956A 2014-06-19 2015-06-22 結晶微孔材料介導之ｃ-含氧化合物至ｃ-含氧化合物的轉換 TWI680798B (zh)

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EP14173148.9 2014-06-19
EP14173148 2014-06-19

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US (1) US11034713B2 (OSRAM)
EP (1) EP3157939B8 (OSRAM)
JP (1) JP6882895B2 (OSRAM)
KR (1) KR20170018308A (OSRAM)
CN (1) CN106457230B (OSRAM)
BR (1) BR112016024659B8 (OSRAM)
CA (1) CA2949596A1 (OSRAM)
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Families Citing this family (6)

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Publication number Priority date Publication date Assignee Title
BR112019009884B1 (pt) * 2016-11-24 2022-08-02 Haldor Topsøe A/S Método para produção catalítica de ácido glicólico e/ou glicolato
ES2732747B2 (es) 2018-05-25 2020-07-02 Consejo Superior Investigacion Proceso catalitico para la produccion de hidrocarburos y compuestos aromaticos a partir de compuestos oxigenados presentes en mezclas acuosas
US11292806B2 (en) * 2019-02-11 2022-04-05 Purdue Research Foundation Processes for preparing sorbose from glucose
RU2741007C1 (ru) * 2020-04-16 2021-01-22 Федеральное государственное бюджетное учреждение науки "Федеральный исследовательский центр "Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук" (ИК СО РАН, Институт катализа СО РАН) Способ получения эритрулозы из дигидроксиацетона и формальдегида
JP7674390B2 (ja) * 2020-05-12 2025-05-09 アーチャー－ダニエルズ－ミッドランド カンパニー Ｃ－４糖及びケト糖の調製方法
JP7695053B1 (ja) * 2023-11-21 2025-06-18 東ソー株式会社 ゼオライト

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0773190B1 (en) * 1995-05-24 1999-06-30 Kubota Corporation Process for producing crystalline microporous body
ZA973972B (en) 1996-05-14 1998-03-23 Kvaerner Process Tech Ltd A process for the production of at least one C4 compound selected from butane-1,4-diol, gamma-butyrolactone and tetrahydrofuran.
FR2753451B1 (fr) * 1996-09-16 1998-11-27 Roquette Freres Procede de fabrication de d-erythrose
PL205620B1 (pl) * 2001-04-27 2010-05-31 Pepsico Inc Napój dietetyczny i sposób jego wytwarzania, dietetyczny produkt spożywczy i sposób jego wytwarzania, napój o zmniejszonej wartości kalorycznej i sposób jego wytwarzania, oraz produkt spożywczy o zmniejszonej wartości kalorycznej i sposób jego wytwarzania
US8227006B2 (en) 2001-04-27 2012-07-24 Pepsico, Inc. Use of erythritol and D-tagatose in diet or reduced-calorie beverages and food products
US7019155B2 (en) * 2001-11-13 2006-03-28 Invista North America S.A.R.L. Hydrogenation of tetrahydroxybutane to tetrahydrofuran
US7518026B2 (en) * 2004-10-01 2009-04-14 Exxonmobil Chemical Patents Inc. Catalyst and process for the conversion of oxygenates to olefins
CN101040051B (zh) * 2004-10-14 2012-02-01 住友化学株式会社 生产2-羟基-4-(甲硫基)丁酸的方法
CN1810753A (zh) 2006-02-28 2006-08-02 上海华谊丙烯酸有限公司 一种酸性沸石催化合成缩醛（酮）的方法
CN101024195A (zh) 2007-03-23 2007-08-29 福建师范大学 一种以hzsm－5为载体的分子筛复合氧化物催化剂的制备方法及其应用
CA2983397C (en) * 2015-04-30 2023-04-04 Haldor Topsoe A/S A process for the preparation of methionine alpha-hydroxy analogues from sugars and derivatives thereof.

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
DUMITRIU, E. HULEA, V. FECHETE, I. AUROUX, A. LACAZE, J.-F. GUIMON, C.: "The aldol condensation of lower aldehydes over MFI zeolites with different acidic properties", MICROPOROUS AND MESOPOROUS MATERIALS, ELSEVIER, AMSTERDAM, NL, vol. 43, no. 3, 1 May 2001 (2001-05-01), AMSTERDAM, NL, pages 341 - 359, XP004235234, ISSN: 1387-1811, DOI: 10.1016/S1387-1811(01)00265-7 *
Emil Dumitriu et al, "The aldol condensation of lower aldehydes over MFI zeolites with different acidic properties", MICROPOROUS AND MESOPOROUS MATERIALS, ELSEVIER SCIENCE PUBLISHING, NEW YORK, US, Volume 43, Issue 3, May 2001, Pages 341-359, doi:10.1016/S1387-1811(01)00265-7, ISSN 1387-1811, *
Emil Dumitriu et al, "The aldol condensation of lower aldehydes over MFI zeolites with different acidic properties", MICROPOROUS AND MESOPOROUS MATERIALS, ELSEVIER SCIENCE PUBLISHING, NEW YORK, US, Volume 43, Issue 3, May 2001, Pages 341-359, doi:10.1016/S1387-1811(01)00265-7, ISSN 1387-1811, XP004235234。

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JP6882895B2 (ja) 2021-06-02
WO2015193461A2 (en) 2015-12-23
SG11201610525PA (en) 2017-01-27
TW201634117A (zh) 2016-10-01
US11034713B2 (en) 2021-06-15
WO2015193461A3 (en) 2016-08-11
MX2016016238A (es) 2017-03-31
JP2017525662A (ja) 2017-09-07
CA2949596A1 (en) 2015-12-23
RU2017101582A (ru) 2018-07-20
EP3157939A2 (en) 2017-04-26
BR112016024659A2 (pt) 2018-05-15
US20170129913A1 (en) 2017-05-11
MY181768A (en) 2021-01-06
BR112016024659B8 (pt) 2022-07-12
RU2017101582A3 (OSRAM) 2018-12-19
EP3157939B8 (en) 2022-09-07
BR112016024659B1 (pt) 2022-05-17
CN106457230B (zh) 2020-12-11
CN106457230A (zh) 2017-02-22
EP3157939B1 (en) 2022-08-03
KR20170018308A (ko) 2017-02-17
RU2710598C2 (ru) 2019-12-30
MX380488B (es) 2025-03-12
ZA201606992B (en) 2019-02-27

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