TWI654224B - 製備固體顆粒乙烯基芳香族聚合物組合物之方法 - Google Patents
製備固體顆粒乙烯基芳香族聚合物組合物之方法Info
- Publication number
- TWI654224B TWI654224B TW103146357A TW103146357A TWI654224B TW I654224 B TWI654224 B TW I654224B TW 103146357 A TW103146357 A TW 103146357A TW 103146357 A TW103146357 A TW 103146357A TW I654224 B TWI654224 B TW I654224B
- Authority
- TW
- Taiwan
- Prior art keywords
- styrene
- suspension
- polymerization
- weight
- vinyl aromatic
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 153
- 229920000642 polymer Polymers 0.000 title claims abstract description 89
- 239000002245 particle Substances 0.000 title claims abstract description 74
- 229920002554 vinyl polymer Polymers 0.000 title claims abstract description 44
- 239000000203 mixture Substances 0.000 title claims description 53
- 239000007787 solid Substances 0.000 title claims description 19
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 235
- 239000011324 bead Substances 0.000 claims abstract description 64
- 239000000725 suspension Substances 0.000 claims description 75
- 150000003440 styrenes Chemical class 0.000 claims description 58
- 238000006116 polymerization reaction Methods 0.000 claims description 53
- 239000003795 chemical substances by application Substances 0.000 claims description 38
- 239000003999 initiator Substances 0.000 claims description 35
- 239000000178 monomer Substances 0.000 claims description 32
- 239000004604 Blowing Agent Substances 0.000 claims description 26
- 239000003063 flame retardant Substances 0.000 claims description 20
- 238000010557 suspension polymerization reaction Methods 0.000 claims description 20
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 15
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 14
- 238000004519 manufacturing process Methods 0.000 claims description 14
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims description 12
- 239000007900 aqueous suspension Substances 0.000 claims description 9
- 239000006233 lamp black Substances 0.000 claims description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 8
- 239000012074 organic phase Substances 0.000 claims description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 7
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- 239000003381 stabilizer Substances 0.000 claims description 6
- 229920000058 polyacrylate Polymers 0.000 claims description 5
- 230000009477 glass transition Effects 0.000 claims description 4
- 238000010521 absorption reaction Methods 0.000 claims description 3
- 125000003118 aryl group Chemical group 0.000 claims description 3
- 238000005187 foaming Methods 0.000 claims description 3
- 238000005227 gel permeation chromatography Methods 0.000 claims description 3
- 239000011164 primary particle Substances 0.000 claims description 3
- 238000012545 processing Methods 0.000 abstract description 17
- 238000009413 insulation Methods 0.000 abstract description 13
- 238000009826 distribution Methods 0.000 description 37
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical group CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 22
- 239000000047 product Substances 0.000 description 18
- 238000006243 chemical reaction Methods 0.000 description 17
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 15
- 230000000052 comparative effect Effects 0.000 description 13
- 230000008901 benefit Effects 0.000 description 12
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 12
- 230000008569 process Effects 0.000 description 12
- 239000004793 Polystyrene Substances 0.000 description 11
- 239000011810 insulating material Substances 0.000 description 11
- 239000012774 insulation material Substances 0.000 description 11
- 239000000654 additive Substances 0.000 description 10
- 239000004094 surface-active agent Substances 0.000 description 10
- 238000012546 transfer Methods 0.000 description 10
- MGIDEDVBLNEGDG-UHFFFAOYSA-N 1-methoxy-1-(2-methylbutan-2-ylperoxy)cyclohexane Chemical compound CCC(C)(C)OOC1(OC)CCCCC1 MGIDEDVBLNEGDG-UHFFFAOYSA-N 0.000 description 9
- 239000001506 calcium phosphate Substances 0.000 description 8
- 238000001816 cooling Methods 0.000 description 8
- 229920002223 polystyrene Polymers 0.000 description 8
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 8
- 229940078499 tricalcium phosphate Drugs 0.000 description 8
- 229910000391 tricalcium phosphate Inorganic materials 0.000 description 8
- 235000019731 tricalcium phosphate Nutrition 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 7
- 241000579895 Chlorostilbon Species 0.000 description 6
- 239000006229 carbon black Substances 0.000 description 6
- 229920001577 copolymer Polymers 0.000 description 6
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 6
- 229910052876 emerald Inorganic materials 0.000 description 6
- 239000010976 emerald Substances 0.000 description 6
- 229920006248 expandable polystyrene Polymers 0.000 description 6
- -1 polyethylene Polymers 0.000 description 6
- 238000010558 suspension polymerization method Methods 0.000 description 6
- 239000004698 Polyethylene Substances 0.000 description 5
- 238000004458 analytical method Methods 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 239000006185 dispersion Substances 0.000 description 5
- 230000002349 favourable effect Effects 0.000 description 5
- 239000000693 micelle Substances 0.000 description 5
- 238000000465 moulding Methods 0.000 description 5
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 5
- 229920000573 polyethylene Polymers 0.000 description 5
- 239000004926 polymethyl methacrylate Substances 0.000 description 5
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- BRQMAAFGEXNUOL-LLVKDONJSA-N [(2R)-2-ethylhexyl] (2-methylpropan-2-yl)oxy carbonate Chemical compound CCCC[C@@H](CC)COC(=O)OOC(C)(C)C BRQMAAFGEXNUOL-LLVKDONJSA-N 0.000 description 4
- 230000000996 additive effect Effects 0.000 description 4
- 230000002411 adverse Effects 0.000 description 4
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 4
- 229910000397 disodium phosphate Inorganic materials 0.000 description 4
- 235000019800 disodium phosphate Nutrition 0.000 description 4
- 239000004088 foaming agent Substances 0.000 description 4
- 239000012212 insulator Substances 0.000 description 4
- WRUGWIBCXHJTDG-UHFFFAOYSA-L magnesium sulfate heptahydrate Chemical compound O.O.O.O.O.O.O.[Mg+2].[O-]S([O-])(=O)=O WRUGWIBCXHJTDG-UHFFFAOYSA-L 0.000 description 4
- 229940061634 magnesium sulfate heptahydrate Drugs 0.000 description 4
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 4
- 239000001488 sodium phosphate Substances 0.000 description 4
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 4
- 229920001169 thermoplastic Polymers 0.000 description 4
- 230000008859 change Effects 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- 239000012809 cooling fluid Substances 0.000 description 3
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 3
- 238000010348 incorporation Methods 0.000 description 3
- 230000000379 polymerizing effect Effects 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 3
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 3
- 239000000375 suspending agent Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 239000001692 EU approved anti-caking agent Substances 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- 229920002319 Poly(methyl acrylate) Polymers 0.000 description 2
- 239000002216 antistatic agent Substances 0.000 description 2
- 239000007822 coupling agent Substances 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000007720 emulsion polymerization reaction Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000012757 flame retardant agent Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 229920005669 high impact polystyrene Polymers 0.000 description 2
- 239000004797 high-impact polystyrene Substances 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000002667 nucleating agent Substances 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 238000005029 sieve analysis Methods 0.000 description 2
- 239000002344 surface layer Substances 0.000 description 2
- 125000001973 tert-pentyl group Chemical group [H]C([H])([H])C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 2
- QFQZKISCBJKVHI-UHFFFAOYSA-N 1,2,3,4,5,6-hexabromocyclohexane Chemical compound BrC1C(Br)C(Br)C(Br)C(Br)C1Br QFQZKISCBJKVHI-UHFFFAOYSA-N 0.000 description 1
- DEIGXXQKDWULML-UHFFFAOYSA-N 1,2,5,6,9,10-hexabromocyclododecane Chemical compound BrC1CCC(Br)C(Br)CCC(Br)C(Br)CCC1Br DEIGXXQKDWULML-UHFFFAOYSA-N 0.000 description 1
- CTPDTSUPMNFWHS-UHFFFAOYSA-N 1-methoxy-1-(1-methoxycyclohexyl)peroxycyclohexane Chemical compound C1CCCCC1(OC)OOC1(OC)CCCCC1 CTPDTSUPMNFWHS-UHFFFAOYSA-N 0.000 description 1
- NPSJHQMIVNJLNN-UHFFFAOYSA-N 2-ethylhexyl 4-nitrobenzoate Chemical compound CCCCC(CC)COC(=O)C1=CC=C([N+]([O-])=O)C=C1 NPSJHQMIVNJLNN-UHFFFAOYSA-N 0.000 description 1
- LXUJDFITFWBMQT-UHFFFAOYSA-M 2-ethylhexyl carbonate Chemical compound CCCCC(CC)COC([O-])=O LXUJDFITFWBMQT-UHFFFAOYSA-M 0.000 description 1
- 239000004808 2-ethylhexylester Substances 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- SVERKYZMGGXICT-UHFFFAOYSA-N C(OCC(CCCC)CC)(O)=O.C(OC(C)(C)C)(=O)OO Chemical compound C(OCC(CCCC)CC)(O)=O.C(OC(C)(C)C)(=O)OO SVERKYZMGGXICT-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 230000006399 behavior Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- SYWDWCWQXBUCOP-UHFFFAOYSA-N benzene;ethene Chemical group C=C.C1=CC=CC=C1 SYWDWCWQXBUCOP-UHFFFAOYSA-N 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 230000010485 coping Effects 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000000368 destabilizing effect Effects 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- XZTWHWHGBBCSMX-UHFFFAOYSA-J dimagnesium;phosphonato phosphate Chemical group [Mg+2].[Mg+2].[O-]P([O-])(=O)OP([O-])([O-])=O XZTWHWHGBBCSMX-UHFFFAOYSA-J 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000010556 emulsion polymerization method Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 230000017525 heat dissipation Effects 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000000399 optical microscopy Methods 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 150000003018 phosphorus compounds Chemical class 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 229920006389 polyphenyl polymer Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 238000004886 process control Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- YOEYNURYLFDCEV-UHFFFAOYSA-N tert-butyl hydroxy carbonate Chemical compound CC(C)(C)OC(=O)OO YOEYNURYLFDCEV-UHFFFAOYSA-N 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- DXZMANYCMVCPIM-UHFFFAOYSA-L zinc;diethylphosphinate Chemical compound [Zn+2].CCP([O-])(=O)CC.CCP([O-])(=O)CC DXZMANYCMVCPIM-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/12—Powdering or granulating
- C08J3/126—Polymer particles coated by polymer, e.g. core shell structures
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/16—Making expandable particles
- C08J9/20—Making expandable particles by suspension polymerisation in the presence of the blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F112/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F112/02—Monomers containing only one unsaturated aliphatic radical
- C08F112/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F112/06—Hydrocarbons
- C08F112/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F12/02—Monomers containing only one unsaturated aliphatic radical
- C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F12/06—Hydrocarbons
- C08F12/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/18—Suspension polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F257/00—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00
- C08F257/02—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00 on to polymers of styrene or alkyl-substituted styrenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0066—Use of inorganic compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/141—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0066—Flame-proofing or flame-retarding additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/18—Binary blends of expanding agents
- C08J2203/182—Binary blends of expanding agents of physical blowing agents, e.g. acetone and butane
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
- C08J2325/02—Homopolymers or copolymers of hydrocarbons
- C08J2325/04—Homopolymers or copolymers of styrene
- C08J2325/06—Polystyrene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP13199815 | 2013-12-30 | ||
| ??13199815.5 | 2013-12-30 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW201533100A TW201533100A (zh) | 2015-09-01 |
| TWI654224B true TWI654224B (zh) | 2019-03-21 |
Family
ID=49916935
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW103146357A TWI654224B (zh) | 2013-12-30 | 2014-12-30 | 製備固體顆粒乙烯基芳香族聚合物組合物之方法 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US9976006B2 (cg-RX-API-DMAC7.html) |
| EP (1) | EP3090004B1 (cg-RX-API-DMAC7.html) |
| JP (1) | JP6672166B2 (cg-RX-API-DMAC7.html) |
| KR (1) | KR102397588B1 (cg-RX-API-DMAC7.html) |
| CN (1) | CN105873961B (cg-RX-API-DMAC7.html) |
| PL (1) | PL3090004T3 (cg-RX-API-DMAC7.html) |
| TW (1) | TWI654224B (cg-RX-API-DMAC7.html) |
| WO (1) | WO2015101621A1 (cg-RX-API-DMAC7.html) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2017196512A1 (en) * | 2016-05-11 | 2017-11-16 | Owens Corning Intellectual Capital, Llc | Polymeric foam comprising low levels of brominated flame retardant and method of making same |
| CN109180881A (zh) * | 2018-09-07 | 2019-01-11 | 山东日兴新材料股份有限公司 | 一种高效阻燃聚苯乙烯的制备方法 |
| FR3105228B1 (fr) * | 2019-12-18 | 2021-11-26 | Arkema France | Composition comprenant un hemiperoxyacetal, son procédé de polymérisation, son utilisation et matériau de composition obtenu après polymérisation de la composition |
| CN114940719B (zh) * | 2022-05-12 | 2023-11-24 | 洪湖市一泰科技有限公司 | 阻燃性聚苯乙烯及其制备方法 |
Family Cites Families (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE602203C (de) | 1933-05-16 | 1934-09-03 | Gustaf Bernhard Nygren | Vorrichtung zum Umstimmen von Saiteninstrumenten, insbesondere von Akkordzithern |
| DE2264224C3 (de) | 1972-12-30 | 1981-11-19 | Röhm GmbH, 6100 Darmstadt | Herstellung eines vernetzten Polystyrol-Emulsionspolymerisats und seine Verwendung zum Trüben von Kunststoffen auf Methacrylatbasis |
| US4173688A (en) | 1973-07-23 | 1979-11-06 | Sekisui Kagaku Kogyo Kabushiki Kaisha | Process for preparing styrenic polymer foams |
| DE2734607A1 (de) | 1977-08-01 | 1979-02-15 | Basf Ag | Verfahren zur herstellung von kugelfoermigen, expandierbaren styrolpolymerisaten |
| US4271281A (en) | 1980-05-29 | 1981-06-02 | American Hoechst Corporation | Process for preparing styrenic polymer particles |
| FR2540126A1 (fr) * | 1983-01-28 | 1984-08-03 | Rhone Poulenc Spec Chim | Latex stables et amphoteres de copolymeres a base de dienes conjugues |
| DE4029298A1 (de) * | 1990-09-15 | 1992-03-19 | Huels Chemische Werke Ag | Verfahren zur koernungssteuerung bei der herstellung von expandierbaren styrolpolymerisaten durch suspensionspolymerisation |
| US5126120A (en) | 1990-10-02 | 1992-06-30 | Uop | Crystalline microporous zinc phosphate compositions |
| DE4220225A1 (de) | 1992-06-20 | 1993-12-23 | Basf Ag | Verfahren zur Herstellung von perlförmigen expandierbaren Styrolpolymerisaten |
| JPH08109279A (ja) * | 1994-10-12 | 1996-04-30 | Hitachi Chem Co Ltd | 発泡性スチレン系重合体粒子、その製造法及び発泡成形品 |
| DE19640793A1 (de) | 1996-10-02 | 1998-04-16 | Basf Ag | Verfahren und Vorrichtung zur Herstellung von Homo- und Copolymeren in Emulsionspolymerisationstechnik |
| AU748704B2 (en) * | 1997-05-14 | 2002-06-13 | Basf Aktiengesellschaft | Method for producing expandable styrene polymers containing graphite particles |
| DE19742910A1 (de) | 1997-09-29 | 1999-04-01 | Basf Ag | Verfahren zur Herstellung von expandierbaren Styrolpolymerisaten |
| EP1041108B1 (en) | 1999-03-29 | 2004-10-27 | Young Bae Chang | Process for producing foamed styrene resin bead |
| DE60225203T2 (de) | 2001-03-29 | 2009-02-19 | Agfa Graphics N.V. | Verfahren zur Herstellung von Polymerpartikeln mit enger Teilchengrössen-Verteilung |
| EP1247820B1 (en) | 2001-03-29 | 2008-02-27 | Agfa Graphics N.V. | Method of preparing polymer particles having narrow particle size distribution |
| US6455219B1 (en) | 2001-06-22 | 2002-09-24 | Xerox Corporation | Semicontinuous emulsion polymerization process for making silica-containing latex for toners |
| DE10150405A1 (de) | 2001-10-11 | 2003-04-17 | Basf Ag | Verfahren zur Herstellung von expandierbaren Styrolpolymerisaten |
| DE102004028768A1 (de) | 2004-06-16 | 2005-12-29 | Basf Ag | Styrolpolymer-Partikelschaumstoffe mit verringerter Wärmeleitfähigkeit |
| WO2010066331A1 (en) | 2008-12-12 | 2010-06-17 | Jackon Gmbh | Process for the preparation of an expandable polymer composition in the form of beads |
| EP2364329B1 (en) * | 2008-12-12 | 2018-09-26 | Jackon GmbH | Process for the preparation of an expandable polymer composition in the form of beads |
| JP5840355B2 (ja) * | 2009-10-22 | 2016-01-06 | 旭化成ケミカルズ株式会社 | アクリル系樹脂、及び成形体 |
| CA2779995A1 (en) * | 2009-12-10 | 2011-06-16 | Akzo Nobel Chemicals International B.V. | Process for the polymerization of styrene |
| WO2013005683A1 (ja) | 2011-07-01 | 2013-01-10 | 日本ゼオン株式会社 | 二次電池用多孔膜、製造方法、及び用途 |
| BR112014015258A8 (pt) | 2011-12-21 | 2017-07-04 | Basf Se | material de grânulo de polímero de estireno, e, processo patra produzir material de grânulo de polímero de estireno |
-
2014
- 2014-12-30 PL PL14827240T patent/PL3090004T3/pl unknown
- 2014-12-30 TW TW103146357A patent/TWI654224B/zh active
- 2014-12-30 JP JP2016561081A patent/JP6672166B2/ja not_active Expired - Fee Related
- 2014-12-30 WO PCT/EP2014/079438 patent/WO2015101621A1/en not_active Ceased
- 2014-12-30 KR KR1020167020686A patent/KR102397588B1/ko active Active
- 2014-12-30 CN CN201480071618.5A patent/CN105873961B/zh active Active
- 2014-12-30 EP EP14827240.4A patent/EP3090004B1/en active Active
- 2014-12-30 US US15/108,464 patent/US9976006B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| EP3090004A1 (en) | 2016-11-09 |
| JP6672166B2 (ja) | 2020-03-25 |
| JP2017501294A (ja) | 2017-01-12 |
| EP3090004B1 (en) | 2018-11-28 |
| US20160326333A1 (en) | 2016-11-10 |
| KR102397588B1 (ko) | 2022-05-12 |
| CN105873961B (zh) | 2018-10-19 |
| WO2015101621A1 (en) | 2015-07-09 |
| US9976006B2 (en) | 2018-05-22 |
| PL3090004T3 (pl) | 2019-04-30 |
| CN105873961A (zh) | 2016-08-17 |
| KR20160105973A (ko) | 2016-09-08 |
| TW201533100A (zh) | 2015-09-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP5570501B2 (ja) | 改善された断熱性能を備えた発泡性ビニル芳香族ポリマー組成物、その調製方法及びその組成物から得られる発泡物品 | |
| US6387968B1 (en) | Method for producing water expandable styrene polymers | |
| JP5080226B2 (ja) | 発泡性樹脂粒子及びこの製造方法並びに発泡成形体 | |
| HU223596B1 (hu) | Eljárás polimerszemcsék előállítására, valamint habosítható polimerszemcsék | |
| MX2011006635A (es) | Composiciones de polimeros aromaticos de vinilo expandibles con una capacidad de aislamiento termico mejorada, proceso para su produccion y articulos expandidos obtenidos de las mismas. | |
| JP6735281B2 (ja) | ペロブスカイト構造を有する鉱物のビニル芳香族ポリマーフォームでの使用 | |
| TWI654224B (zh) | 製備固體顆粒乙烯基芳香族聚合物組合物之方法 | |
| CN104011119B (zh) | 制备包含石墨和阻燃剂的可膨胀苯乙烯聚合物的方法 | |
| US6342540B1 (en) | Method for producing water expandable styrene polymers | |
| US9453083B2 (en) | Vinyl polymers prepared via suspension polymerization and methods thereof | |
| WO2014111628A2 (en) | Method of producing polystyrene beads having low moisture content | |
| KR20180019361A (ko) | 친환경 난연제를 사용한 흑연을 포함한 발포성 폴리스티렌 입자의 제조 방법 | |
| US20180258248A1 (en) | Large-diameter heat-expanding microspheres and method for producing same | |
| JP6697862B2 (ja) | 難燃性を付与した発泡性スチレン系樹脂粒子の製造方法 | |
| JP2012153826A (ja) | ポリスチレン系樹脂発泡体、発泡性ポリスチレン系樹脂粒子及びその製造方法 | |
| JP6539436B2 (ja) | 発泡性ポリスチレン系樹脂粒子 | |
| KR100843444B1 (ko) | 발포성 폴리스티렌의 제조 방법 | |
| US6545062B2 (en) | Production of water-expandable styrene polymers | |
| JP3265246B2 (ja) | スチレン系樹脂粒子の製造方法 | |
| JP5377917B2 (ja) | 難燃性発泡性ポリスチレン系樹脂粒子 | |
| JP5552399B2 (ja) | 発泡性ポリスチレン系樹脂粒子、その製造方法、予備発泡粒子及び発泡成形体 | |
| JP2907068B2 (ja) | 発泡性スチレン系重合体粒子の製造方法 | |
| JP2024007832A (ja) | 発泡性スチレン系樹脂粒子の製造方法 | |
| JP2002507638A (ja) | 水発泡性スチレン重合体の製造法 | |
| US20150005402A1 (en) | Method for producing expandable styrene polymers containing particulate additives |