TWI564327B - 發泡性樹脂粒子，以及顆粒發泡成形體之製造方法 - Google Patents
發泡性樹脂粒子，以及顆粒發泡成形體之製造方法 Download PDFInfo
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- TWI564327B TWI564327B TW104132056A TW104132056A TWI564327B TW I564327 B TWI564327 B TW I564327B TW 104132056 A TW104132056 A TW 104132056A TW 104132056 A TW104132056 A TW 104132056A TW I564327 B TWI564327 B TW I564327B
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- resin
- foaming agent
- particles
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- foamed
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- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 1
- 229910052939 potassium sulfate Inorganic materials 0.000 description 1
- 235000011151 potassium sulphates Nutrition 0.000 description 1
- 238000009417 prefabrication Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 235000014102 seafood Nutrition 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 238000002076 thermal analysis method Methods 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 1
- 229940029284 trichlorofluoromethane Drugs 0.000 description 1
- JNXDCMUUZNIWPQ-UHFFFAOYSA-N trioctyl benzene-1,2,4-tricarboxylate Chemical compound CCCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCC)C(C(=O)OCCCCCCCC)=C1 JNXDCMUUZNIWPQ-UHFFFAOYSA-N 0.000 description 1
- QJAVUVZBMMXBRO-UHFFFAOYSA-N tripentyl phosphate Chemical compound CCCCCOP(=O)(OCCCCC)OCCCCC QJAVUVZBMMXBRO-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/16—Making expandable particles
- C08J9/18—Making expandable particles by impregnating polymer particles with the blowing agent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B11/00—Making preforms
- B29B11/06—Making preforms by moulding the material
- B29B11/10—Extrusion moulding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/12—Making granules characterised by structure or composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/142—Compounds containing oxygen but no halogen atom
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/16—Making expandable particles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/22—After-treatment of expandable particles; Forming foamed products
- C08J9/228—Forming foamed products
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/22—After-treatment of expandable particles; Forming foamed products
- C08J9/228—Forming foamed products
- C08J9/232—Forming foamed products by sintering expandable particles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L79/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen or carbon only, not provided for in groups C08L61/00 - C08L77/00
- C08L79/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
- C08L79/08—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L81/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
- C08L81/06—Polysulfones; Polyethersulfones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2201/00—Foams characterised by the foaming process
- C08J2201/02—Foams characterised by the foaming process characterised by mechanical pre- or post-treatments
- C08J2201/03—Extrusion of the foamable blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/12—Organic compounds only containing carbon, hydrogen and oxygen atoms, e.g. ketone or alcohol
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2205/00—Foams characterised by their properties
- C08J2205/04—Foams characterised by their properties characterised by the foam pores
- C08J2205/052—Closed cells, i.e. more than 50% of the pores are closed
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2379/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen, or carbon only, not provided for in groups C08J2361/00 - C08J2377/00
- C08J2379/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
- C08J2379/08—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2381/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen, or carbon only; Polysulfones; Derivatives of such polymers
- C08J2381/06—Polysulfones; Polyethersulfones
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Molding Of Porous Articles (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2014200892 | 2014-09-30 | ||
| JP2014255231 | 2014-12-17 |
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| TW201619257A TW201619257A (zh) | 2016-06-01 |
| TWI564327B true TWI564327B (zh) | 2017-01-01 |
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| TW104132056A TWI564327B (zh) | 2014-09-30 | 2015-09-30 | 發泡性樹脂粒子，以及顆粒發泡成形體之製造方法 |
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Country Status (7)
| Country | Link |
|---|---|
| US (2) | US10815354B2 (enExample) |
| EP (2) | EP3527614B1 (enExample) |
| JP (2) | JP6064096B2 (enExample) |
| KR (2) | KR101954116B1 (enExample) |
| CN (2) | CN106795313B (enExample) |
| TW (2) | TWI600688B (enExample) |
| WO (1) | WO2016052604A1 (enExample) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6660862B2 (ja) * | 2016-09-27 | 2020-03-11 | 積水化成品工業株式会社 | ビーズ発泡体の製造方法および樹脂複合品の製造方法 |
| JP7117829B2 (ja) * | 2017-07-03 | 2022-08-15 | 株式会社ジェイエスピー | オレフィン系熱可塑性エラストマー発泡粒子 |
| CN111032756B (zh) * | 2017-08-04 | 2023-01-24 | 巴斯夫欧洲公司 | 基于高温热塑性塑料的、可膨胀的含有发泡剂的颗粒 |
| KR102628067B1 (ko) * | 2017-08-24 | 2024-01-23 | 에보닉 오퍼레이션스 게엠베하 | 항공기 내부에서의 적용을 위한 pei 입자 발포체 |
| MX2020005297A (es) * | 2017-11-27 | 2020-08-13 | Evonik Operations Gmbh | Espumas de particulas de polietersulfona (pesu) para aplicaciones en interiores de aeronaves. |
| IL274860B2 (en) * | 2017-11-27 | 2025-01-01 | Evonik Operations Gmbh | High-temperature foams with reduced resin absorption for the production of sandwich materials |
| US11780981B2 (en) | 2018-12-06 | 2023-10-10 | Exxonmobil Chemical Patents Inc. | Foam beads and method of making the same |
| US20200247012A1 (en) * | 2019-02-05 | 2020-08-06 | Scott DeFelice | Method for Grinding Materials for Additive Manufacturing |
| EP3889212A1 (de) * | 2020-04-03 | 2021-10-06 | Evonik Operations GmbH | Polyetherimid-polyetheretherketon-partikelschäume für anwendungen im leichtbau |
| CN113416341B (zh) * | 2021-06-01 | 2022-05-24 | 中山大学 | 一种聚酯发泡珠粒和聚酯发泡珠粒成型体及其制备方法 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW200530297A (en) * | 2004-01-13 | 2005-09-16 | Jsp Corp | Thermoplastic resin pellet, process for preparing thermoplastic resin pellets and expanded thermoplastic resin bead |
| CN103764738A (zh) * | 2011-08-29 | 2014-04-30 | 积水化成品工业株式会社 | 模内发泡成型用芳香族聚酯系树脂发泡颗粒及其制造方法、模内发泡成型体、复合结构构件、以及汽车用构件 |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5936139A (ja) * | 1982-08-24 | 1984-02-28 | Toyobo Co Ltd | 耐熱性発泡体 |
| GB8303111D0 (en) | 1983-02-04 | 1983-03-09 | Smith Tech Dev | Foam production |
| US4532263A (en) * | 1983-12-12 | 1985-07-30 | Mobil Oil Corporation | Expansible polymer molding process and the resultant product |
| DE3585318D1 (de) * | 1984-11-22 | 1992-03-12 | Asahi Chemical Ind | Expandierbare polyetherimidzusammensetzungen und davon abgeleitete geschaeumte materialien. |
| JPS63500457A (ja) * | 1985-07-24 | 1988-02-18 | モ−ビル・オイル・コ−ポレ−シヨン | ポリマ−発泡体、その熱成形体及びその成形方法 |
| US4727093A (en) * | 1986-10-27 | 1988-02-23 | General Electric Company | Low density particles of polyphenylene ether resins |
| EP0373402A3 (en) * | 1988-12-15 | 1991-01-23 | General Electric Company | Expandable polyetherimide resins |
| DE3925740A1 (de) | 1989-08-03 | 1991-02-07 | Basf Ag | Verfahren zur herstellung von expandierbarem granulat und schaumstoffen daraus |
| US5128073A (en) * | 1989-10-26 | 1992-07-07 | General Electric Company | Expanding thermoplastic resin beads with very high frequency energy |
| US5095041A (en) * | 1989-12-27 | 1992-03-10 | General Electric Company | Simple process for imbibing blowing agents in thermoplastic resin granules |
| US5670102A (en) * | 1993-02-11 | 1997-09-23 | Minnesota Mining And Manufacturing Company | Method of making thermoplastic foamed articles using supercritical fluid |
| CN1060998C (zh) | 1994-09-28 | 2001-01-24 | 松下电器产业株式会社 | 中空结构件的制造方法及中空结构件 |
| DE19605359A1 (de) | 1996-02-14 | 1997-08-21 | Hoechst Ag | Kunststoff-Schäume und Verfahren zu deren Herstellung |
| ATE299789T1 (de) | 1998-12-11 | 2005-08-15 | Sekisui Plastics | Herstellungsmethode für im werkzeug geschäumtes formteil auf basis von aromatischem polyester |
| DE10162602A1 (de) | 2001-12-20 | 2003-07-10 | Basf Ag | Verfahren zur Herstellung von Schaumstoffbahnen aus hochtemperaturbeständigen Polysulfonen oder Polyethersulfonen |
| DE10307736A1 (de) | 2003-02-24 | 2004-09-02 | Basf Ag | Offenzelliger Schaumstoff aus hochschmelzenden Kunststoffen |
| DE10358801A1 (de) * | 2003-12-12 | 2005-07-14 | Basf Ag | Partikelschaumformteile aus expandierbaren Styrolpolymeren und Mischungen mit thermoplastischen Polymeren |
| US20070149629A1 (en) | 2005-12-22 | 2007-06-28 | Michael Stephen Donovan | Expanded and expandable high glass transition temperature polymers |
| JP5545988B2 (ja) | 2010-06-23 | 2014-07-09 | 積水化成品工業株式会社 | 発泡性樹脂粒子及びその製造方法、予備発泡粒子ならびに発泡成形体 |
| DE102011110216A1 (de) | 2010-08-18 | 2012-02-23 | Basf Se | Partikelschaumstoffe mit verbesserter Steifigkeit |
| EP2766412A1 (en) | 2011-10-12 | 2014-08-20 | Solvay Specialty Polymers USA, LLC. | Polyetherimide/ poly(biphenyl ether sulfone) foam materials |
| CA2934429A1 (en) | 2013-12-23 | 2015-07-02 | Solvay Specialty Polymers Usa, Llc | New foam materials from aromatic poly(aryl ether sulfone) foamable compositions |
-
2015
- 2015-09-30 CN CN201580045799.9A patent/CN106795313B/zh active Active
- 2015-09-30 US US15/323,787 patent/US10815354B2/en active Active
- 2015-09-30 KR KR1020177004985A patent/KR101954116B1/ko active Active
- 2015-09-30 TW TW105123735A patent/TWI600688B/zh active
- 2015-09-30 CN CN201911154405.XA patent/CN110922630A/zh active Pending
- 2015-09-30 EP EP19163447.6A patent/EP3527614B1/en active Active
- 2015-09-30 KR KR1020187023374A patent/KR101967142B1/ko active Active
- 2015-09-30 TW TW104132056A patent/TWI564327B/zh active
- 2015-09-30 EP EP15846822.3A patent/EP3202837B1/en active Active
- 2015-09-30 JP JP2016543238A patent/JP6064096B2/ja active Active
- 2015-09-30 WO PCT/JP2015/077704 patent/WO2016052604A1/ja not_active Ceased
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2016
- 2016-10-18 JP JP2016204412A patent/JP6473119B2/ja active Active
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW200530297A (en) * | 2004-01-13 | 2005-09-16 | Jsp Corp | Thermoplastic resin pellet, process for preparing thermoplastic resin pellets and expanded thermoplastic resin bead |
| CN103764738A (zh) * | 2011-08-29 | 2014-04-30 | 积水化成品工业株式会社 | 模内发泡成型用芳香族聚酯系树脂发泡颗粒及其制造方法、模内发泡成型体、复合结构构件、以及汽车用构件 |
Also Published As
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| CN106795313B (zh) | 2019-12-06 |
| US20200102439A1 (en) | 2020-04-02 |
| WO2016052604A1 (ja) | 2016-04-07 |
| JP6473119B2 (ja) | 2019-02-20 |
| JP2017025337A (ja) | 2017-02-02 |
| JP6064096B2 (ja) | 2017-01-18 |
| TWI600688B (zh) | 2017-10-01 |
| EP3527614B1 (en) | 2020-11-18 |
| KR20180094139A (ko) | 2018-08-22 |
| KR20170038007A (ko) | 2017-04-05 |
| CN110922630A (zh) | 2020-03-27 |
| EP3202837A1 (en) | 2017-08-09 |
| US10947359B2 (en) | 2021-03-16 |
| EP3202837B1 (en) | 2019-12-11 |
| KR101954116B1 (ko) | 2019-03-05 |
| JPWO2016052604A1 (ja) | 2017-04-27 |
| US20180186958A1 (en) | 2018-07-05 |
| TW201639907A (zh) | 2016-11-16 |
| EP3202837A4 (en) | 2018-05-02 |
| US10815354B2 (en) | 2020-10-27 |
| TW201619257A (zh) | 2016-06-01 |
| KR101967142B1 (ko) | 2019-04-09 |
| CN106795313A (zh) | 2017-05-31 |
| EP3527614A1 (en) | 2019-08-21 |
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