TWI530518B - 包含氧化鋯奈米粒子之非晶形全氟聚合物 - Google Patents
包含氧化鋯奈米粒子之非晶形全氟聚合物 Download PDFInfo
- Publication number
- TWI530518B TWI530518B TW101103571A TW101103571A TWI530518B TW I530518 B TWI530518 B TW I530518B TW 101103571 A TW101103571 A TW 101103571A TW 101103571 A TW101103571 A TW 101103571A TW I530518 B TWI530518 B TW I530518B
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- Taiwan
- Prior art keywords
- fluoropolymer composition
- curable fluoropolymer
- zirconia
- curable
- composition
- Prior art date
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- 239000002105 nanoparticle Substances 0.000 title claims description 51
- 229920005548 perfluoropolymer Polymers 0.000 title claims description 19
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 title 1
- 229910001928 zirconium oxide Inorganic materials 0.000 title 1
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 74
- 239000000203 mixture Substances 0.000 claims description 48
- 229920002313 fluoropolymer Polymers 0.000 claims description 30
- 239000004811 fluoropolymer Substances 0.000 claims description 30
- 238000000034 method Methods 0.000 claims description 29
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 24
- 229910052740 iodine Inorganic materials 0.000 claims description 18
- 239000011787 zinc oxide Substances 0.000 claims description 12
- 229920006169 Perfluoroelastomer Polymers 0.000 claims description 10
- 229910052794 bromium Inorganic materials 0.000 claims description 10
- 239000003795 chemical substances by application Substances 0.000 claims description 10
- -1 amine oxime Chemical class 0.000 claims description 7
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 6
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 5
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 5
- 230000002378 acidificating effect Effects 0.000 claims description 5
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 5
- 239000011630 iodine Substances 0.000 claims description 5
- 239000000178 monomer Substances 0.000 claims description 5
- 150000007513 acids Chemical class 0.000 claims description 4
- 150000002978 peroxides Chemical class 0.000 claims description 4
- 150000004714 phosphonium salts Chemical class 0.000 claims description 4
- 125000000524 functional group Chemical group 0.000 claims description 3
- BLTXWCKMNMYXEA-UHFFFAOYSA-N 1,1,2-trifluoro-2-(trifluoromethoxy)ethene Chemical compound FC(F)=C(F)OC(F)(F)F BLTXWCKMNMYXEA-UHFFFAOYSA-N 0.000 claims description 2
- 150000001336 alkenes Chemical class 0.000 claims description 2
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 claims description 2
- 150000002825 nitriles Chemical class 0.000 claims description 2
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims description 2
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 claims 1
- LDQKDAUATAVUHZ-UHFFFAOYSA-N 1-ethenoxy-1,1,2,2,3,3-hexafluoro-3-methoxypropane Chemical compound COC(F)(F)C(F)(F)C(F)(F)OC=C LDQKDAUATAVUHZ-UHFFFAOYSA-N 0.000 claims 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 claims 1
- CEIPQQODRKXDSB-UHFFFAOYSA-N ethyl 3-(6-hydroxynaphthalen-2-yl)-1H-indazole-5-carboximidate dihydrochloride Chemical compound Cl.Cl.C1=C(O)C=CC2=CC(C3=NNC4=CC=C(C=C43)C(=N)OCC)=CC=C21 CEIPQQODRKXDSB-UHFFFAOYSA-N 0.000 claims 1
- 150000004715 keto acids Chemical class 0.000 claims 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 1
- 239000007787 solid Substances 0.000 description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 16
- 229910000420 cerium oxide Inorganic materials 0.000 description 12
- 239000000463 material Substances 0.000 description 12
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 11
- 239000002245 particle Substances 0.000 description 11
- 239000004816 latex Substances 0.000 description 10
- 229920000126 latex Polymers 0.000 description 10
- 239000008367 deionised water Substances 0.000 description 9
- 229910021641 deionized water Inorganic materials 0.000 description 9
- 230000004580 weight loss Effects 0.000 description 9
- 239000002131 composite material Substances 0.000 description 8
- 229920001971 elastomer Polymers 0.000 description 8
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 description 7
- 150000001451 organic peroxides Chemical class 0.000 description 7
- 239000004971 Cross linker Substances 0.000 description 6
- 238000001914 filtration Methods 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- 239000004065 semiconductor Substances 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 5
- 229920001973 fluoroelastomer Polymers 0.000 description 5
- 150000002894 organic compounds Chemical class 0.000 description 5
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 150000001735 carboxylic acids Chemical class 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 238000001020 plasma etching Methods 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- GVNVAWHJIKLAGL-UHFFFAOYSA-N 2-(cyclohexen-1-yl)cyclohexan-1-one Chemical compound O=C1CCCCC1C1=CCCCC1 GVNVAWHJIKLAGL-UHFFFAOYSA-N 0.000 description 2
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical compound NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 101150065749 Churc1 gene Proteins 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 102100038239 Protein Churchill Human genes 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 229910052796 boron Inorganic materials 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 150000007942 carboxylates Chemical class 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000000806 elastomer Substances 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 238000009616 inductively coupled plasma Methods 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- LYIPDZSLYLDLCU-UHFFFAOYSA-N 2,2,3,3-tetrafluoro-3-[1,1,1,2,3,3-hexafluoro-3-(1,2,2-trifluoroethenoxy)propan-2-yl]oxypropanenitrile Chemical compound FC(F)=C(F)OC(F)(F)C(F)(C(F)(F)F)OC(F)(F)C(F)(F)C#N LYIPDZSLYLDLCU-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical class [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 1
- 239000012963 UV stabilizer Substances 0.000 description 1
- 238000005411 Van der Waals force Methods 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 description 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical class OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 1
- 229910001413 alkali metal ion Inorganic materials 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- HFEHLDPGIKPNKL-UHFFFAOYSA-N allyl iodide Chemical compound ICC=C HFEHLDPGIKPNKL-UHFFFAOYSA-N 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 238000001636 atomic emission spectroscopy Methods 0.000 description 1
- 150000007514 bases Chemical class 0.000 description 1
- UUEDINPOVKWVAZ-UHFFFAOYSA-N bis(2-ethylhexyl) 3,4,5,6-tetrabromobenzene-1,2-dicarboxylate Chemical compound CCCCC(CC)COC(=O)C1=C(Br)C(Br)=C(Br)C(Br)=C1C(=O)OCC(CC)CCCC UUEDINPOVKWVAZ-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- FYHXNYLLNIKZMR-UHFFFAOYSA-N calcium;carbonic acid Chemical compound [Ca].OC(O)=O FYHXNYLLNIKZMR-UHFFFAOYSA-N 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 150000001722 carbon compounds Chemical class 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- UUAGAQFQZIEFAH-UHFFFAOYSA-N chlorotrifluoroethylene Chemical group FC(F)=C(F)Cl UUAGAQFQZIEFAH-UHFFFAOYSA-N 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 238000001246 colloidal dispersion Methods 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000000502 dialysis Methods 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000002296 dynamic light scattering Methods 0.000 description 1
- 239000008393 encapsulating agent Substances 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- PGFXOWRDDHCDTE-UHFFFAOYSA-N hexafluoropropylene oxide Chemical compound FC(F)(F)C1(F)OC1(F)F PGFXOWRDDHCDTE-UHFFFAOYSA-N 0.000 description 1
- 150000002429 hydrazines Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 150000003949 imides Chemical class 0.000 description 1
- GHXZPUGJZVBLGC-UHFFFAOYSA-N iodoethene Chemical compound IC=C GHXZPUGJZVBLGC-UHFFFAOYSA-N 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000002114 nanocomposite Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000003129 oil well Substances 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- UJMWVICAENGCRF-UHFFFAOYSA-N oxygen difluoride Chemical group FOF UJMWVICAENGCRF-UHFFFAOYSA-N 0.000 description 1
- 239000008177 pharmaceutical agent Substances 0.000 description 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-N phosphine group Chemical group P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 1
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 1
- 150000003009 phosphonic acids Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000011164 primary particle Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000008281 solid sol Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- 125000003011 styrenyl group Chemical class [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- VDZOOKBUILJEDG-UHFFFAOYSA-M tetrabutylammonium hydroxide Chemical compound [OH-].CCCC[N+](CCCC)(CCCC)CCCC VDZOOKBUILJEDG-UHFFFAOYSA-M 0.000 description 1
- 150000003527 tetrahydropyrans Chemical class 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/18—Monomers containing fluorine
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/18—Monomers containing fluorine
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/18—Monomers containing fluorine
- C08F214/184—Monomers containing fluorine with fluorinated vinyl ethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161439421P | 2011-02-04 | 2011-02-04 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW201237079A TW201237079A (en) | 2012-09-16 |
| TWI530518B true TWI530518B (zh) | 2016-04-21 |
Family
ID=46603240
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW101103571A TWI530518B (zh) | 2011-02-04 | 2012-02-03 | 包含氧化鋯奈米粒子之非晶形全氟聚合物 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US9309370B2 (enExample) |
| EP (1) | EP2670802B1 (enExample) |
| JP (1) | JP5837619B2 (enExample) |
| KR (1) | KR101862899B1 (enExample) |
| CN (1) | CN103443195B (enExample) |
| TW (1) | TWI530518B (enExample) |
| WO (1) | WO2012106172A2 (enExample) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5837619B2 (ja) * | 2011-02-04 | 2015-12-24 | スリーエム イノベイティブ プロパティズ カンパニー | ジルコニウム酸化物ナノ粒子を含む非晶質ペルフルオロポリマー |
| US10404360B2 (en) * | 2017-02-14 | 2019-09-03 | Qualcomm Incorporated | Narrowband time-division duplex frame structure for narrowband communications |
| EP3807369B1 (en) | 2018-06-12 | 2024-07-24 | 3M Innovative Properties Company | Fluoropolymer compositions comprising fluorinated additives, coated substrates and methods |
| EP3807344B1 (en) | 2018-06-12 | 2023-12-27 | 3M Innovative Properties Company | Fluoropolymer coating compositions comprising aminosilane curing agents, coated substrates and related methods |
| TW202033573A (zh) * | 2018-12-17 | 2020-09-16 | 美商3M新設資產公司 | 包括可固化氟聚合物及固化劑之組成物及製造及使用其之方法 |
| WO2020261089A1 (en) * | 2019-06-28 | 2020-12-30 | 3M Innovative Properties Company | Functionalized triazine compounds, compositions comprising such compounds and cured fluoropolymer articles |
| JP7698633B2 (ja) * | 2019-08-27 | 2025-06-25 | スリーエム イノベイティブ プロパティズ カンパニー | 金属フッ化物粒子を含む硬化性フルオロポリマー組成物及びそれからの物品 |
| WO2021088198A1 (en) * | 2019-11-04 | 2021-05-14 | 3M Innovative Properties Company | Electronic telecommunications articles comprising crosslinked fluoropolymers and methods |
| CN114630874B (zh) * | 2019-11-04 | 2023-12-05 | 3M创新有限公司 | 包含具有烯键式不饱和基团和电子供体基团的固化剂的含氟聚合物组合物及用其涂覆的基底 |
| EP4563645A1 (en) * | 2022-07-25 | 2025-06-04 | Daikin Industries, Ltd. | Crosslinkable composition and molded article |
| KR102700169B1 (ko) | 2022-09-08 | 2024-08-27 | 강원대학교산학협력단 | 락토바실러스 람노서스에 의해 합성되며 테트라사이클린 클로라이드로 로드된 산화지르코늄 나노입자 및 그 제조방법 |
Family Cites Families (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5037579A (en) | 1990-02-12 | 1991-08-06 | Nalco Chemical Company | Hydrothermal process for producing zirconia sol |
| WO1997001599A1 (en) | 1995-06-28 | 1997-01-16 | E.I. Du Pont De Nemours And Company | Fluoropolymer nanocomposites |
| DE19544912A1 (de) | 1995-12-01 | 1997-06-05 | Gore W L & Ass Gmbh | PTFE-Körper aus mikroporösem Polytetrafluorethylen mit Füllstoff und Verfahren zu dessen Herstellung |
| AU5484499A (en) * | 1998-08-18 | 2000-03-14 | Ppg Industries Ohio, Inc. | Process for producing durable antireflective surfaces and antireflective articles |
| JP2000119468A (ja) | 1998-10-16 | 2000-04-25 | Nippon Valqua Ind Ltd | 含フッ素エラストマー組成物、その架橋体、並びにその用途 |
| US6376590B2 (en) | 1999-10-28 | 2002-04-23 | 3M Innovative Properties Company | Zirconia sol, process of making and composite material |
| KR100646151B1 (ko) | 1999-11-04 | 2006-11-14 | 다이낑 고오교 가부시키가이샤 | 반도체 제조장치용 엘라스토머 성형품 및 가교성 불소계엘라스토머 조성물 |
| JP2002037666A (ja) | 2000-07-24 | 2002-02-06 | Toshiba Ceramics Co Ltd | 耐プラズマ性部材およびその製造方法 |
| US7351471B2 (en) * | 2000-12-06 | 2008-04-01 | 3M Innovative Properties Company | Fluoropolymer coating compositions with multifunctional fluoroalkyl crosslinkers for anti-reflective polymer films |
| JP3979845B2 (ja) | 2001-12-28 | 2007-09-19 | 日本バルカー工業株式会社 | 表面改質フッ素ゴムの製造方法、得られた表面改質フッ素ゴムおよびその用途 |
| ITMI20021202A1 (it) * | 2002-06-04 | 2003-12-04 | Ausimont Spa | Composizioni di fluoropolimeri e particelle inorganiche nanometriche |
| US20050107544A1 (en) | 2003-11-13 | 2005-05-19 | Shuhong Wang | Plasma resistant curable fluoroelastomer composition |
| EP1699829A1 (en) | 2003-12-30 | 2006-09-13 | 3M Innovative Properties Company | Fluoropolymer coagulation method and composition |
| US7323514B2 (en) * | 2004-12-30 | 2008-01-29 | 3M Innovative Properties Company | Low refractive index fluoropolymer coating compositions for use in antireflective polymer films |
| US7495049B2 (en) * | 2005-02-04 | 2009-02-24 | Du Pont - Mitsoi Fluorochemicals Co, Ltd. | Melt processible fluoropolymer composition containing nano particles |
| JP4628814B2 (ja) | 2005-02-15 | 2011-02-09 | 日本バルカー工業株式会社 | 半導体製造装置用シール材 |
| US7790658B2 (en) | 2005-05-27 | 2010-09-07 | University of Florida Research Foundaction, Inc. | Inert wear resistant PTFE-based solid lubricant nanocomposite |
| ATE501212T1 (de) | 2005-09-26 | 2011-03-15 | Asahi Glass Co Ltd | Perfluoroelastomerzusammensetzung und formteil aus einem perfluorkautschuk |
| JP5044999B2 (ja) | 2005-09-26 | 2012-10-10 | 旭硝子株式会社 | パーフルオロエラストマー組成物およびパーフルオロゴム成形品 |
| KR20130118995A (ko) | 2005-09-30 | 2013-10-30 | 듀폰-미쯔이 플루오로케미칼 가부시끼가이샤 | 균일하게 분포된 나노-크기의 무기 입자를 갖는 중합체 조성물 |
| WO2007120122A1 (en) | 2006-01-31 | 2007-10-25 | Dupont-Mitsui Fluorochemicals Co Ltd. | Melt processible fluoropolymer composition containing nano particles |
| KR20090024805A (ko) | 2006-06-22 | 2009-03-09 | 다이킨 고교 가부시키가이샤 | 밀봉재, 상기 밀봉재를 갖는 플라즈마 처리 장치용 부품 및상기 밀봉재의 제조 방법 |
| JP2008115336A (ja) | 2006-11-07 | 2008-05-22 | Du Pont Mitsui Fluorochem Co Ltd | 接着性フッ素樹脂複合体組成物 |
| EP2223170A1 (en) | 2007-12-19 | 2010-09-01 | E. I. du Pont de Nemours and Company | Bilayer anti-reflective films containing nanoparticles |
| US8647510B2 (en) | 2007-12-28 | 2014-02-11 | 3M Innovative Properties Company | Method of making zirconia-containing nanoparticles |
| WO2009096342A1 (ja) | 2008-01-28 | 2009-08-06 | Asahi Glass Company, Limited | 硬化性組成物、含フッ素硬化物、それらを用いた光学材料および発光素子 |
| EP2311047A4 (en) | 2008-07-22 | 2014-01-22 | Du Pont | AQUEOUS DISPERSIONS OF ELECTRICALLY CONDUCTIVE POLYMERS CONTAINING INORGANIC NANOPARTICLES |
| JP5744016B2 (ja) | 2009-06-15 | 2015-07-01 | アーケマ・インコーポレイテッド | ナノ粒子を含む高分子電解質ブレンド物の有機／無機複合ブレンド物膜組成物 |
| EP2585521B1 (en) | 2010-06-24 | 2018-04-11 | 3M Innovative Properties Company | Polymerizable compositions free of organic emulsifier and polymers and methods of making thereof |
| WO2012067937A2 (en) | 2010-11-18 | 2012-05-24 | 3M Innovative Properties Company | Method of coagulating an amorphous fluoropolymer using modified inorganic nanoparticles |
| CN103221479B (zh) * | 2010-11-18 | 2016-06-22 | 3M创新有限公司 | 凝聚无定形含氟聚合物胶乳的方法 |
| JP5837619B2 (ja) * | 2011-02-04 | 2015-12-24 | スリーエム イノベイティブ プロパティズ カンパニー | ジルコニウム酸化物ナノ粒子を含む非晶質ペルフルオロポリマー |
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2012
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- 2012-01-26 CN CN201280015155.1A patent/CN103443195B/zh not_active Expired - Fee Related
- 2012-01-26 KR KR1020137022981A patent/KR101862899B1/ko not_active Expired - Fee Related
- 2012-01-26 EP EP12741594.1A patent/EP2670802B1/en not_active Not-in-force
- 2012-01-26 US US13/983,321 patent/US9309370B2/en active Active
- 2012-01-26 WO PCT/US2012/022663 patent/WO2012106172A2/en not_active Ceased
- 2012-02-03 TW TW101103571A patent/TWI530518B/zh not_active IP Right Cessation
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|---|---|
| CN103443195B (zh) | 2017-10-10 |
| KR101862899B1 (ko) | 2018-05-30 |
| CN103443195A (zh) | 2013-12-11 |
| TW201237079A (en) | 2012-09-16 |
| JP5837619B2 (ja) | 2015-12-24 |
| WO2012106172A2 (en) | 2012-08-09 |
| EP2670802A4 (en) | 2015-02-11 |
| EP2670802B1 (en) | 2018-04-25 |
| US20140011933A1 (en) | 2014-01-09 |
| JP2014504674A (ja) | 2014-02-24 |
| EP2670802A2 (en) | 2013-12-11 |
| KR20140008365A (ko) | 2014-01-21 |
| WO2012106172A3 (en) | 2013-01-17 |
| US9309370B2 (en) | 2016-04-12 |
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