TWI490040B - 製備低分子量氫化腈橡膠之方法 - Google Patents

製備低分子量氫化腈橡膠之方法 Download PDF

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Publication number
TWI490040B
TWI490040B TW099129017A TW99129017A TWI490040B TW I490040 B TWI490040 B TW I490040B TW 099129017 A TW099129017 A TW 099129017A TW 99129017 A TW99129017 A TW 99129017A TW I490040 B TWI490040 B TW I490040B
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TW
Taiwan
Prior art keywords
group
alkyl
aryl
formula
hydrogen
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TW099129017A
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English (en)
Chinese (zh)
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TW201124201A (en
Inventor
克利斯托弗 翁格
朱莉亞瑪麗亞 米勒
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朗盛德意志有限公司
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Publication of TW201124201A publication Critical patent/TW201124201A/zh
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/02—Hydrogenation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2265—Carbenes or carbynes, i.e.(image)
    • B01J31/2278—Complexes comprising two carbene ligands differing from each other, e.g. Grubbs second generation catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/08—Depolymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/04—Reduction, e.g. hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L15/00—Compositions of rubber derivatives
    • C08L15/005—Hydrogenated nitrile rubber
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/02—Copolymers with acrylonitrile
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/54—Metathesis reactions, e.g. olefin metathesis
    • B01J2231/543—Metathesis reactions, e.g. olefin metathesis alkene metathesis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/643—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of R2C=O or R2C=NR (R= C, H)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/825—Osmium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
TW099129017A 2009-08-31 2010-08-30 製備低分子量氫化腈橡膠之方法 TWI490040B (zh)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP09169064A EP2289621A1 (en) 2009-08-31 2009-08-31 Process for the preparation of low molecular weight hydrogenated nitrile rubber

Publications (2)

Publication Number Publication Date
TW201124201A TW201124201A (en) 2011-07-16
TWI490040B true TWI490040B (zh) 2015-07-01

Family

ID=41694683

Family Applications (1)

Application Number Title Priority Date Filing Date
TW099129017A TWI490040B (zh) 2009-08-31 2010-08-30 製備低分子量氫化腈橡膠之方法

Country Status (13)

Country Link
US (1) US9150669B2 (OSRAM)
EP (2) EP2289621A1 (OSRAM)
JP (1) JP5544424B2 (OSRAM)
KR (1) KR101426623B1 (OSRAM)
CN (1) CN102711993B (OSRAM)
BR (1) BR112012004413A2 (OSRAM)
CA (1) CA2771246A1 (OSRAM)
IN (1) IN2012DN01532A (OSRAM)
MX (1) MX2012002404A (OSRAM)
RU (1) RU2548681C9 (OSRAM)
SG (1) SG178434A1 (OSRAM)
TW (1) TWI490040B (OSRAM)
WO (1) WO2011029732A1 (OSRAM)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2289622A1 (en) * 2009-08-31 2011-03-02 LANXESS Deutschland GmbH Ruthenium based catalysts for the metathesis of nitrile rubbers
WO2013056459A1 (en) 2011-10-21 2013-04-25 Lanxess Deutschland Gmbh Catalyst compositions and their use for hydrogenation of nitrile rubber
WO2013056461A1 (en) 2011-10-21 2013-04-25 Lanxess Deutschland Gmbh Catalyst compositions and their use for hydrogenation of nitrile rubber
WO2013056400A1 (en) 2011-10-21 2013-04-25 Lanxess Deutschland Gmbh Catalyst compositions and their use for hydrogenation of nitrile rubber
WO2013056463A1 (en) * 2011-10-21 2013-04-25 Lanxess Deutschland Gmbh Catalyst compositions and their use for hydrogenation of nitrile rubber
WO2013159365A1 (en) 2012-04-28 2013-10-31 Lanxess Deutschland Gmbh Hydrogenation of nitrile rubber
EP2676969B1 (en) * 2012-06-22 2016-06-01 University Of Waterloo Tandem metathesis and hydrogenation of diene-based polymers in latex
EP2676971B1 (en) * 2012-06-22 2015-04-08 University Of Waterloo Hydrogenation of a diene-based polymer latex
EP2725030A1 (en) * 2012-10-29 2014-04-30 Umicore AG & Co. KG Ruthenium-based metathesis catalysts, precursors for their preparation and their use
CN105246905B (zh) * 2013-05-24 2018-09-25 阿朗新科德国有限责任公司 新型过渡金属配合物、它们的制备和用途
CN106068290B (zh) * 2014-03-27 2020-05-22 日本瑞翁株式会社 含腈基共聚物橡胶、交联性橡胶组合物及橡胶交联物
TWI566835B (zh) 2014-12-25 2017-01-21 財團法人工業技術研究院 烯烴複分解觸媒及低分子量丁腈橡膠之製備方法
JP7282776B2 (ja) * 2017-12-18 2023-05-29 アランセオ・ドイチュランド・ゲーエムベーハー ニトリルブタジエンゴムラテックスの水素化
EP3827029A1 (en) 2018-07-23 2021-06-02 ARLANXEO Deutschland GmbH Method for producing hydrogenated nitrile rubber and hnbr compositions thereof
KR20210104663A (ko) * 2018-12-17 2021-08-25 아란세오 도이치란드 게엠베하 Peg 아크릴레이트-hnbr 공중합체의 생성 공정
CN113227153B (zh) * 2018-12-17 2023-11-14 阿朗新科德国有限责任公司 用替代性溶剂制备hnbr溶液的方法

Citations (2)

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Publication number Priority date Publication date Assignee Title
CN1922224A (zh) * 2004-02-23 2007-02-28 兰塞克斯公司 制备低分子量氢化丁腈橡胶的方法
CN101371992A (zh) * 2007-08-21 2009-02-25 朗盛德国有限责任公司 催化剂体系及其在复分解反应中的应用

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US5258647A (en) 1989-07-03 1993-11-02 General Electric Company Electronic systems disposed in a high force environment
US5210151A (en) 1992-09-02 1993-05-11 Polysar Rubber Corporation Hydrogenation of nitrile rubber
US5208296A (en) 1992-09-02 1993-05-04 Polysar Rubber Corporation Nitrile rubber hydrogenation
JP2000119328A (ja) * 1998-10-16 2000-04-25 Teijin Ltd 触媒残渣の少ない環状オレフィン系重合体、その用途並びにその製造法
AU2001284773B2 (en) 2000-08-10 2004-08-05 Trustees Of Boston College Recyclable metathesis catalysts
CA2350280A1 (en) * 2001-06-12 2002-12-12 Bayer Inc. Low molecular weight hydrogenated nitrile rubber
PL199412B1 (pl) 2002-10-15 2008-09-30 Boehringer Ingelheim Int Nowe kompleksy rutenu jako (pre)katalizatory reakcji metatezy, pochodne 2-alkoksy-5-nitrostyrenu jako związki pośrednie i sposób ich wytwarzania
CA2413607A1 (en) * 2002-12-05 2004-06-05 Bayer Inc. Process for the preparation of low molecular weight hydrogenated nitrile rubber
US7241898B2 (en) * 2003-08-02 2007-07-10 Boehringer Ingelheim International Gmbh Metathesis catalysts
DE10335416A1 (de) * 2003-08-02 2005-02-17 Boehringer Ingelheim Pharma Gmbh & Co. Kg Neue Metathesekatalysatoren
US8058351B2 (en) 2005-05-20 2011-11-15 Bridgestone Corporation Method for preparing low molecular weight polymers
DE102006008521A1 (de) * 2006-02-22 2007-08-23 Lanxess Deutschland Gmbh Verwendung von Katalysatoren mit erhöhter Aktivität für die NBR-Metathese
DE102006040569A1 (de) * 2006-08-30 2008-03-06 Lanxess Deutschland Gmbh Verfahren zum Metathese-Abbau von Nitrilkautschuken
DE102006043704A1 (de) * 2006-09-18 2008-03-27 Umicore Ag & Co. Kg Neue Metathesekatalysatoren
DE102007039525A1 (de) 2007-08-21 2009-02-26 Lanxess Deutschland Gmbh Verfahren zum Metathese-Abbau von Nitrilkautschuk

Patent Citations (2)

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Publication number Priority date Publication date Assignee Title
CN1922224A (zh) * 2004-02-23 2007-02-28 兰塞克斯公司 制备低分子量氢化丁腈橡胶的方法
CN101371992A (zh) * 2007-08-21 2009-02-25 朗盛德国有限责任公司 催化剂体系及其在复分解反应中的应用

Also Published As

Publication number Publication date
RU2548681C9 (ru) 2016-06-20
WO2011029732A1 (en) 2011-03-17
RU2548681C2 (ru) 2015-04-20
RU2012112351A (ru) 2013-10-10
KR20120049898A (ko) 2012-05-17
US9150669B2 (en) 2015-10-06
CN102711993B (zh) 2015-04-08
US20130005916A1 (en) 2013-01-03
CA2771246A1 (en) 2011-03-17
JP5544424B2 (ja) 2014-07-09
CN102711993A (zh) 2012-10-03
TW201124201A (en) 2011-07-16
EP2473281B1 (en) 2014-04-02
JP2013503227A (ja) 2013-01-31
EP2473281A1 (en) 2012-07-11
EP2289621A1 (en) 2011-03-02
MX2012002404A (es) 2012-04-02
IN2012DN01532A (OSRAM) 2015-06-05
KR101426623B1 (ko) 2014-08-05
SG178434A1 (en) 2012-04-27
BR112012004413A2 (pt) 2019-09-24

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