MX2012002404A - Procedimiento para la preparacion de caucho de nitrilo hidrogenado de bajo peso molecular. - Google Patents

Procedimiento para la preparacion de caucho de nitrilo hidrogenado de bajo peso molecular.

Info

Publication number
MX2012002404A
MX2012002404A MX2012002404A MX2012002404A MX2012002404A MX 2012002404 A MX2012002404 A MX 2012002404A MX 2012002404 A MX2012002404 A MX 2012002404A MX 2012002404 A MX2012002404 A MX 2012002404A MX 2012002404 A MX2012002404 A MX 2012002404A
Authority
MX
Mexico
Prior art keywords
nitrile rubber
hydrogenated nitrile
molecular weight
preparation
low molecular
Prior art date
Application number
MX2012002404A
Other languages
English (en)
Inventor
Christopher Ong
Julia Maria Mueller
Original Assignee
Lanxess Deutschland Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lanxess Deutschland Gmbh filed Critical Lanxess Deutschland Gmbh
Publication of MX2012002404A publication Critical patent/MX2012002404A/es

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08CTREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00Chemical modification of rubber
    • C08C19/02Hydrogenation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22Organic complexes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22Organic complexes
    • B01J31/2265Carbenes or carbynes, i.e.(image)
    • B01J31/2278Complexes comprising two carbene ligands differing from each other, e.g. Grubbs second generation catalysts
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08CTREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00Chemical modification of rubber
    • C08C19/08Depolymerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/04Reduction, e.g. hydrogenation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L15/00Compositions of rubber derivatives
    • C08L15/005Hydrogenated nitrile rubber
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/02Copolymers with acrylonitrile
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/54Metathesis reactions, e.g. olefin metathesis
    • B01J2231/543Metathesis reactions, e.g. olefin metathesis alkene metathesis
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60Reduction reactions, e.g. hydrogenation
    • B01J2231/64Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/643Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of R2C=O or R2C=NR (R= C, H)
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/821Ruthenium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/825Osmium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08CTREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00Chemical modification of rubber
    • C08C2019/09Metathese

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

Conforme a la invención, se proporciona un procedimiento para la producción de polímeros de caucho de nitrilo hidrogenado que tienen pesos moleculares más bajos y distribuciones de peso molecular más estrechas que los conocidos en la técnica, en el que el procedimiento se lleva a cabo en presencia de hidrógeno y, de manera opcional, al menos una co-(olefina). La presente invención además se refiere al uso de compuestos de metal específicos en un procedimiento para la producción de caucho de nitrilo hidrogenado por medio de hidrogenación y metátesis simultáneas de un caucho de nitrilo.
MX2012002404A 2009-08-31 2010-08-26 Procedimiento para la preparacion de caucho de nitrilo hidrogenado de bajo peso molecular. MX2012002404A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP09169064A EP2289621A1 (en) 2009-08-31 2009-08-31 Process for the preparation of low molecular weight hydrogenated nitrile rubber
PCT/EP2010/062500 WO2011029732A1 (en) 2009-08-31 2010-08-26 Process for the preparation of low molecular weight hydrogenated nitrile rubber

Publications (1)

Publication Number Publication Date
MX2012002404A true MX2012002404A (es) 2012-04-02

Family

ID=41694683

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2012002404A MX2012002404A (es) 2009-08-31 2010-08-26 Procedimiento para la preparacion de caucho de nitrilo hidrogenado de bajo peso molecular.

Country Status (13)

Country Link
US (1) US9150669B2 (es)
EP (2) EP2289621A1 (es)
JP (1) JP5544424B2 (es)
KR (1) KR101426623B1 (es)
CN (1) CN102711993B (es)
BR (1) BR112012004413A2 (es)
CA (1) CA2771246A1 (es)
IN (1) IN2012DN01532A (es)
MX (1) MX2012002404A (es)
RU (1) RU2548681C9 (es)
SG (1) SG178434A1 (es)
TW (1) TWI490040B (es)
WO (1) WO2011029732A1 (es)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2289622A1 (en) * 2009-08-31 2011-03-02 LANXESS Deutschland GmbH Ruthenium based catalysts for the metathesis of nitrile rubbers
WO2013056459A1 (en) 2011-10-21 2013-04-25 Lanxess Deutschland Gmbh Catalyst compositions and their use for hydrogenation of nitrile rubber
WO2013056400A1 (en) * 2011-10-21 2013-04-25 Lanxess Deutschland Gmbh Catalyst compositions and their use for hydrogenation of nitrile rubber
WO2013056463A1 (en) * 2011-10-21 2013-04-25 Lanxess Deutschland Gmbh Catalyst compositions and their use for hydrogenation of nitrile rubber
WO2013056461A1 (en) 2011-10-21 2013-04-25 Lanxess Deutschland Gmbh Catalyst compositions and their use for hydrogenation of nitrile rubber
WO2013159365A1 (en) 2012-04-28 2013-10-31 Lanxess Deutschland Gmbh Hydrogenation of nitrile rubber
EP2676969B1 (en) * 2012-06-22 2016-06-01 University Of Waterloo Tandem metathesis and hydrogenation of diene-based polymers in latex
EP2676971B1 (en) * 2012-06-22 2015-04-08 University Of Waterloo Hydrogenation of a diene-based polymer latex
EP2725030A1 (en) 2012-10-29 2014-04-30 Umicore AG & Co. KG Ruthenium-based metathesis catalysts, precursors for their preparation and their use
EP3004124B1 (en) * 2013-05-24 2018-12-26 ARLANXEO Deutschland GmbH Novel transition metal complexes, their preparation and use
EP3124511A4 (en) * 2014-03-27 2017-11-15 Zeon Corporation Nitrile group-containing copolymer rubber, crosslinkable rubber composition and crosslinked rubber product
TWI566835B (zh) 2014-12-25 2017-01-21 財團法人工業技術研究院 烯烴複分解觸媒及低分子量丁腈橡膠之製備方法
WO2019121153A1 (en) * 2017-12-18 2019-06-27 Arlanxeo Deutschland Gmbh Hydrogenation of nitrile butadiene rubber latex
KR20210035088A (ko) 2018-07-23 2021-03-31 아란세오 도이치란드 게엠베하 수소화된 니트릴 고무의 제조 방법 및 그의 hnbr 조성물
JP2022510814A (ja) * 2018-12-17 2022-01-28 アランセオ・ドイチュランド・ゲーエムベーハー Pegアクリレート-hnbrコポリマーを製造するためのプロセス
KR20210104664A (ko) * 2018-12-17 2021-08-25 아란세오 도이치란드 게엠베하 대체 용매를 이용하여 hnbr 용액을 제조하기 위한 공정

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US5258647A (en) 1989-07-03 1993-11-02 General Electric Company Electronic systems disposed in a high force environment
US5208296A (en) 1992-09-02 1993-05-04 Polysar Rubber Corporation Nitrile rubber hydrogenation
US5210151A (en) 1992-09-02 1993-05-11 Polysar Rubber Corporation Hydrogenation of nitrile rubber
JP2000119328A (ja) * 1998-10-16 2000-04-25 Teijin Ltd 触媒残渣の少ない環状オレフィン系重合体、その用途並びにその製造法
WO2002014376A2 (en) 2000-08-10 2002-02-21 Trustees Of Boston College Recyclable metathesis catalysts
CA2350280A1 (en) * 2001-06-12 2002-12-12 Bayer Inc. Low molecular weight hydrogenated nitrile rubber
PL199412B1 (pl) 2002-10-15 2008-09-30 Boehringer Ingelheim Int Nowe kompleksy rutenu jako (pre)katalizatory reakcji metatezy, pochodne 2-alkoksy-5-nitrostyrenu jako związki pośrednie i sposób ich wytwarzania
CA2413607A1 (en) * 2002-12-05 2004-06-05 Bayer Inc. Process for the preparation of low molecular weight hydrogenated nitrile rubber
DE10335416A1 (de) * 2003-08-02 2005-02-17 Boehringer Ingelheim Pharma Gmbh & Co. Kg Neue Metathesekatalysatoren
US7241898B2 (en) * 2003-08-02 2007-07-10 Boehringer Ingelheim International Gmbh Metathesis catalysts
CA2462005A1 (en) * 2004-02-23 2005-08-23 Bayer Inc. Process for the preparation of low molecular weight hydrogenated nitrile rubber
WO2006127483A1 (en) * 2005-05-20 2006-11-30 Bridgestone Corporation Method for preparing low molecular weight polymers
DE102006008521A1 (de) * 2006-02-22 2007-08-23 Lanxess Deutschland Gmbh Verwendung von Katalysatoren mit erhöhter Aktivität für die NBR-Metathese
DE102006040569A1 (de) * 2006-08-30 2008-03-06 Lanxess Deutschland Gmbh Verfahren zum Metathese-Abbau von Nitrilkautschuken
DE102006043704A1 (de) * 2006-09-18 2008-03-27 Umicore Ag & Co. Kg Neue Metathesekatalysatoren
DE102007039525A1 (de) 2007-08-21 2009-02-26 Lanxess Deutschland Gmbh Verfahren zum Metathese-Abbau von Nitrilkautschuk
DE102007039526A1 (de) * 2007-08-21 2009-02-26 Lanxess Deutschland Gmbh Katalysator-Systeme und deren Verwendung für Metathese-Reaktionen

Also Published As

Publication number Publication date
JP2013503227A (ja) 2013-01-31
EP2473281B1 (en) 2014-04-02
KR20120049898A (ko) 2012-05-17
US20130005916A1 (en) 2013-01-03
CA2771246A1 (en) 2011-03-17
SG178434A1 (en) 2012-04-27
US9150669B2 (en) 2015-10-06
EP2473281A1 (en) 2012-07-11
CN102711993B (zh) 2015-04-08
JP5544424B2 (ja) 2014-07-09
RU2548681C9 (ru) 2016-06-20
IN2012DN01532A (es) 2015-06-05
EP2289621A1 (en) 2011-03-02
RU2548681C2 (ru) 2015-04-20
TWI490040B (zh) 2015-07-01
WO2011029732A1 (en) 2011-03-17
BR112012004413A2 (pt) 2019-09-24
RU2012112351A (ru) 2013-10-10
TW201124201A (en) 2011-07-16
KR101426623B1 (ko) 2014-08-05
CN102711993A (zh) 2012-10-03

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