TWI481594B - 可再生資源中異戊二烯之純化 - Google Patents
可再生資源中異戊二烯之純化 Download PDFInfo
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- TWI481594B TWI481594B TW099144617A TW99144617A TWI481594B TW I481594 B TWI481594 B TW I481594B TW 099144617 A TW099144617 A TW 099144617A TW 99144617 A TW99144617 A TW 99144617A TW I481594 B TWI481594 B TW I481594B
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- Prior art keywords
- isoprene
- solvent
- methyl
- column
- gas
- Prior art date
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- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 title claims description 988
- 238000000746 purification Methods 0.000 title description 26
- 239000002904 solvent Substances 0.000 claims description 195
- 239000007789 gas Substances 0.000 claims description 188
- 238000000034 method Methods 0.000 claims description 178
- 239000012535 impurity Substances 0.000 claims description 175
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- 239000006227 byproduct Substances 0.000 claims description 114
- 238000001179 sorption measurement Methods 0.000 claims description 59
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 55
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 48
- 150000001875 compounds Chemical class 0.000 claims description 47
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 25
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 24
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- 238000009835 boiling Methods 0.000 claims description 19
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- 150000002739 metals Chemical class 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
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- CBIDRCWHNCKSTO-UHFFFAOYSA-N prenyl diphosphate Chemical compound CC(C)=CCO[P@](O)(=O)OP(O)(O)=O CBIDRCWHNCKSTO-UHFFFAOYSA-N 0.000 description 1
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- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C11/00—Aliphatic unsaturated hydrocarbons
- C07C11/12—Alkadienes
- C07C11/173—Alkadienes with five carbon atoms
- C07C11/18—Isoprene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D11/00—Solvent extraction
- B01D11/04—Solvent extraction of solutions which are liquid
- B01D11/0426—Counter-current multistage extraction towers in a vertical or sloping position
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D11/00—Solvent extraction
- B01D11/04—Solvent extraction of solutions which are liquid
- B01D11/0492—Applications, solvents used
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/04—Purification; Separation; Use of additives by distillation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/10—Purification; Separation; Use of additives by extraction, i.e. purification or separation of liquid hydrocarbons with the aid of liquids
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Water Supply & Treatment (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
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| MX318543B (es) | 2008-07-02 | 2014-03-18 | Danisco Us Inc | Composiciones y metodos para producir isopreno libre de hidrocarburos de c5 bajo condicion de desacoplamiento y/o intervalos de operacion seguros. |
| US8324442B2 (en) | 2009-03-03 | 2012-12-04 | Amyris, Inc. | Microbial derived isoprene and methods for making the same |
| TWI434921B (zh) * | 2009-06-17 | 2014-04-21 | Danisco Us Inc | 從生物異戊二烯組合物製造燃料成分之方法及系統 |
| TW201412988A (zh) * | 2009-06-17 | 2014-04-01 | Danisco Us Inc | 使用ｄｘｐ及ｍｖａ途徑之改良之異戊二烯製造 |
| WO2011075534A2 (en) * | 2009-12-18 | 2011-06-23 | Danisco Us Inc. | Purification of isoprene from renewable resources |
| WO2011075748A1 (en) * | 2009-12-22 | 2011-06-23 | Danisco Us Inc. | Membrane bioreactor for increased production of isoprene gas |
| CN103025688A (zh) | 2010-06-17 | 2013-04-03 | 丹尼斯科美国公司 | 包含异戊二烯衍生物的燃料组合物 |
| EP2601300A1 (en) | 2010-08-06 | 2013-06-12 | Danisco US Inc. | Production of isoprene under neutral ph conditions |
| SG190043A1 (en) | 2010-10-27 | 2013-06-28 | Danisco Us Inc | Isoprene synthase variants for improved production of isoprene |
| CN103403145A (zh) | 2010-12-22 | 2013-11-20 | 丹尼斯科美国公司 | 使用重组细胞进行戊糖的生物制备 |
| CN103476926A (zh) | 2010-12-22 | 2013-12-25 | 丹尼斯科美国公司 | 使用两种类型的ispg酶改善异戊二烯产量的组合物和方法 |
| AU2012249320A1 (en) | 2011-04-29 | 2013-11-14 | Danisco Us Inc. | Recombinant microorganisms for enhanced production of mevalonate, isoprene, and isoprenoids |
| SG194691A1 (en) | 2011-04-29 | 2013-12-30 | Danisco Us Inc | Production of mevalonate, isoprene, and isoprenoids using genes encodingpolypeptides having thiolase, hmg-coa synthase and hmg-coa reductase enzymatic activities |
| HK1198837A1 (en) | 2011-08-05 | 2015-06-12 | Danisco Us Inc. | Production of isoprenoids under neutral ph conditions |
| WO2013066568A1 (en) | 2011-10-07 | 2013-05-10 | Danisco Us Inc. | Utilization of phosphoketolase in the production of mevalonate, isoprenoid precursors, and isoprene |
| DK2771460T3 (en) | 2011-10-27 | 2017-06-06 | Danisco Us Inc | ISOPRENE SYNTHASE VARIETIES WITH IMPROVED SOLUBILITY FOR THE PREPARATION OF ISOPRENE |
| SG11201403163QA (en) | 2011-12-23 | 2014-09-26 | Danisco Us Inc | Enhanced production of isoprene using host cells having decreased ispa activity |
| US9315831B2 (en) | 2012-03-30 | 2016-04-19 | Danisco Us Inc. | Direct starch to fermentable sugar as feedstock for the production of isoprene, isoprenoid precursor molecules, and/or isoprenoids |
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| US8895277B2 (en) | 2012-05-02 | 2014-11-25 | Danisco Us Inc. | Legume isoprene synthase for production of isoprene |
| US9163263B2 (en) | 2012-05-02 | 2015-10-20 | The Goodyear Tire & Rubber Company | Identification of isoprene synthase variants with improved properties for the production of isoprene |
| JP6010342B2 (ja) * | 2012-05-21 | 2016-10-19 | 株式会社ブリヂストン | イソプレン−ブタジエン共重合体、イソプレン−ブタジエン共重合体の製造方法、ゴム組成物及びタイヤ |
| JP6010343B2 (ja) * | 2012-05-21 | 2016-10-19 | 株式会社ブリヂストン | イソプレン−ブタジエン共重合体、イソプレン−ブタジエン共重合体の製造方法、ゴム組成物及びタイヤ |
| JP6074160B2 (ja) * | 2012-05-22 | 2017-02-01 | 株式会社ブリヂストン | ゴム組成物およびタイヤの製造方法 |
| JP6074161B2 (ja) * | 2012-05-22 | 2017-02-01 | 株式会社ブリヂストン | ゴム組成物およびタイヤの製造方法 |
| WO2013181647A2 (en) | 2012-06-01 | 2013-12-05 | Danisco Us Inc. | Compositions and methods of producing isoprene and/or industrrial bio-products using anaerobic microorganisms |
| EP2935364A2 (en) | 2012-12-21 | 2015-10-28 | Danisco US Inc. | Production of isoprene, isoprenoid, and isoprenoid precursors using an alternative lower mevalonate pathway |
| BR112015018807B1 (pt) * | 2013-02-07 | 2021-07-27 | Braskem S.A. | Método para separação e purificação de uma diolefina conjugada produzida por fermentação sob condições anaeróbicas |
| US9850512B2 (en) | 2013-03-15 | 2017-12-26 | The Research Foundation For The State University Of New York | Hydrolysis of cellulosic fines in primary clarified sludge of paper mills and the addition of a surfactant to increase the yield |
| WO2014156997A1 (ja) | 2013-03-29 | 2014-10-02 | 味の素株式会社 | 発酵ガス中のイソプレンの回収方法および精製イソプレンの製造方法 |
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| ES2728307T3 (es) | 2013-06-21 | 2019-10-23 | Danisco Us Inc | Composiciones y métodos para la transformación clostridial |
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| EP3107993B1 (en) | 2014-02-20 | 2020-08-26 | Danisco US Inc. | Recombinant microorganisms for the enhanced production of mevalonate, isoprene, isoprenoid precursors, isoprenoids, and acetyl-coa-derived products |
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| CN110354644A (zh) * | 2018-04-10 | 2019-10-22 | 天津科技大学 | 一种高效的醋酸丁酯废气吸收与解吸装置 |
| CN111454114B (zh) * | 2020-05-11 | 2023-07-14 | 长沙贝塔医药科技有限公司 | 一种用13c2-香叶醇合成高纯度13c2-月桂烯的方法 |
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2010
- 2010-12-15 WO PCT/US2010/060552 patent/WO2011075534A2/en not_active Ceased
- 2010-12-15 CN CN201080064167.4A patent/CN102884028B/zh not_active Expired - Fee Related
- 2010-12-15 SG SG2012042511A patent/SG181605A1/en unknown
- 2010-12-15 BR BR112012014736A patent/BR112012014736B1/pt not_active IP Right Cessation
- 2010-12-15 EP EP10799184A patent/EP2513021A2/en not_active Withdrawn
- 2010-12-15 IN IN5187DEN2012 patent/IN2012DN05187A/en unknown
- 2010-12-15 JP JP2012544763A patent/JP5643838B2/ja not_active Expired - Fee Related
- 2010-12-15 AU AU2010331946A patent/AU2010331946A1/en not_active Abandoned
- 2010-12-15 US US12/969,440 patent/US8569562B2/en active Active
- 2010-12-15 CA CA2783976A patent/CA2783976A1/en not_active Abandoned
- 2010-12-17 TW TW099144617A patent/TWI481594B/zh active
- 2010-12-20 AR ARP100104783A patent/AR079560A1/es unknown
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2013
- 2013-09-24 US US14/035,746 patent/US20140187839A1/en not_active Abandoned
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2014
- 2014-09-10 JP JP2014184058A patent/JP6378013B2/ja not_active Expired - Fee Related
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2015
- 2015-04-09 US US14/682,930 patent/US9751820B2/en active Active
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2016
- 2016-11-18 JP JP2016225310A patent/JP2017081924A/ja active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3510405A (en) * | 1967-11-11 | 1970-05-05 | Nippon Zeon Co | Isoprene purification process |
| US20090203102A1 (en) * | 2007-12-13 | 2009-08-13 | Cervin Marguerite A | Compositions and methods for producing isoprene |
Also Published As
| Publication number | Publication date |
|---|---|
| BR112012014736A2 (pt) | 2016-04-19 |
| AR079560A1 (es) | 2012-02-01 |
| WO2011075534A3 (en) | 2012-04-12 |
| EP2513021A2 (en) | 2012-10-24 |
| US20110178261A1 (en) | 2011-07-21 |
| US8569562B2 (en) | 2013-10-29 |
| CN102884028A (zh) | 2013-01-16 |
| AU2010331946A2 (en) | 2012-07-19 |
| JP2017081924A (ja) | 2017-05-18 |
| BR112012014736B1 (pt) | 2018-09-18 |
| JP5643838B2 (ja) | 2014-12-17 |
| US20150274615A1 (en) | 2015-10-01 |
| WO2011075534A2 (en) | 2011-06-23 |
| JP2013514375A (ja) | 2013-04-25 |
| US20140187839A1 (en) | 2014-07-03 |
| CA2783976A1 (en) | 2011-06-23 |
| JP2015007119A (ja) | 2015-01-15 |
| IN2012DN05187A (cg-RX-API-DMAC10.html) | 2015-10-23 |
| CN102884028B (zh) | 2015-08-19 |
| JP6378013B2 (ja) | 2018-08-22 |
| AU2010331946A1 (en) | 2012-06-28 |
| TW201139367A (en) | 2011-11-16 |
| US9751820B2 (en) | 2017-09-05 |
| SG181605A1 (en) | 2012-07-30 |
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