TWI433273B - 形成雙金屬閘極結構之方法 - Google Patents
形成雙金屬閘極結構之方法 Download PDFInfo
- Publication number
- TWI433273B TWI433273B TW097118679A TW97118679A TWI433273B TW I433273 B TWI433273 B TW I433273B TW 097118679 A TW097118679 A TW 097118679A TW 97118679 A TW97118679 A TW 97118679A TW I433273 B TWI433273 B TW I433273B
- Authority
- TW
- Taiwan
- Prior art keywords
- layer
- forming
- gate
- gate electrode
- channel region
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 39
- 239000010410 layer Substances 0.000 claims description 534
- 239000004065 semiconductor Substances 0.000 claims description 125
- 229910052751 metal Inorganic materials 0.000 claims description 81
- 239000002184 metal Substances 0.000 claims description 81
- 239000011241 protective layer Substances 0.000 claims description 47
- 239000000463 material Substances 0.000 claims description 27
- 230000008719 thickening Effects 0.000 claims description 24
- 238000005530 etching Methods 0.000 claims description 8
- 238000000151 deposition Methods 0.000 claims description 7
- 150000004767 nitrides Chemical class 0.000 claims description 7
- 239000003989 dielectric material Substances 0.000 claims 1
- 239000000758 substrate Substances 0.000 description 8
- 229910052732 germanium Inorganic materials 0.000 description 7
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 7
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 7
- 229920005591 polysilicon Polymers 0.000 description 7
- 238000003672 processing method Methods 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 4
- 230000010354 integration Effects 0.000 description 4
- 229920002120 photoresistant polymer Polymers 0.000 description 4
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 3
- 230000009977 dual effect Effects 0.000 description 3
- 210000000988 bone and bone Anatomy 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- YBMRDBCBODYGJE-UHFFFAOYSA-N germanium dioxide Chemical compound O=[Ge]=O YBMRDBCBODYGJE-UHFFFAOYSA-N 0.000 description 2
- 229910000449 hafnium oxide Inorganic materials 0.000 description 2
- KQHQLIAOAVMAOW-UHFFFAOYSA-N hafnium(4+) oxygen(2-) zirconium(4+) Chemical compound [O--].[O--].[O--].[O--].[Zr+4].[Hf+4] KQHQLIAOAVMAOW-UHFFFAOYSA-N 0.000 description 2
- WIHZLLGSGQNAGK-UHFFFAOYSA-N hafnium(4+);oxygen(2-) Chemical compound [O-2].[O-2].[Hf+4] WIHZLLGSGQNAGK-UHFFFAOYSA-N 0.000 description 2
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 description 1
- GPBUGPUPKAGMDK-UHFFFAOYSA-N azanylidynemolybdenum Chemical compound [Mo]#N GPBUGPUPKAGMDK-UHFFFAOYSA-N 0.000 description 1
- 229910000420 cerium oxide Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 229940119177 germanium dioxide Drugs 0.000 description 1
- 238000002513 implantation Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- NFFIWVVINABMKP-UHFFFAOYSA-N methylidynetantalum Chemical compound [Ta]#C NFFIWVVINABMKP-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- QPJSUIGXIBEQAC-UHFFFAOYSA-N n-(2,4-dichloro-5-propan-2-yloxyphenyl)acetamide Chemical compound CC(C)OC1=CC(NC(C)=O)=C(Cl)C=C1Cl QPJSUIGXIBEQAC-UHFFFAOYSA-N 0.000 description 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910003468 tantalcarbide Inorganic materials 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- MZLGASXMSKOWSE-UHFFFAOYSA-N tantalum nitride Chemical compound [Ta]#N MZLGASXMSKOWSE-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D84/00—Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers
- H10D84/01—Manufacture or treatment
- H10D84/0123—Integrating together multiple components covered by H10D12/00 or H10D30/00, e.g. integrating multiple IGBTs
- H10D84/0126—Integrating together multiple components covered by H10D12/00 or H10D30/00, e.g. integrating multiple IGBTs the components including insulated gates, e.g. IGFETs
- H10D84/0165—Integrating together multiple components covered by H10D12/00 or H10D30/00, e.g. integrating multiple IGBTs the components including insulated gates, e.g. IGFETs the components including complementary IGFETs, e.g. CMOS devices
- H10D84/0167—Manufacturing their channels
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D84/00—Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers
- H10D84/01—Manufacture or treatment
- H10D84/0123—Integrating together multiple components covered by H10D12/00 or H10D30/00, e.g. integrating multiple IGBTs
- H10D84/0126—Integrating together multiple components covered by H10D12/00 or H10D30/00, e.g. integrating multiple IGBTs the components including insulated gates, e.g. IGFETs
- H10D84/0165—Integrating together multiple components covered by H10D12/00 or H10D30/00, e.g. integrating multiple IGBTs the components including insulated gates, e.g. IGFETs the components including complementary IGFETs, e.g. CMOS devices
- H10D84/017—Manufacturing their source or drain regions, e.g. silicided source or drain regions
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D84/00—Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers
- H10D84/01—Manufacture or treatment
- H10D84/0123—Integrating together multiple components covered by H10D12/00 or H10D30/00, e.g. integrating multiple IGBTs
- H10D84/0126—Integrating together multiple components covered by H10D12/00 or H10D30/00, e.g. integrating multiple IGBTs the components including insulated gates, e.g. IGFETs
- H10D84/0165—Integrating together multiple components covered by H10D12/00 or H10D30/00, e.g. integrating multiple IGBTs the components including insulated gates, e.g. IGFETs the components including complementary IGFETs, e.g. CMOS devices
- H10D84/0172—Manufacturing their gate conductors
- H10D84/0177—Manufacturing their gate conductors the gate conductors having different materials or different implants
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D84/00—Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers
- H10D84/01—Manufacture or treatment
- H10D84/0123—Integrating together multiple components covered by H10D12/00 or H10D30/00, e.g. integrating multiple IGBTs
- H10D84/0126—Integrating together multiple components covered by H10D12/00 or H10D30/00, e.g. integrating multiple IGBTs the components including insulated gates, e.g. IGFETs
- H10D84/0165—Integrating together multiple components covered by H10D12/00 or H10D30/00, e.g. integrating multiple IGBTs the components including insulated gates, e.g. IGFETs the components including complementary IGFETs, e.g. CMOS devices
- H10D84/0181—Manufacturing their gate insulating layers
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D84/00—Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers
- H10D84/01—Manufacture or treatment
- H10D84/02—Manufacture or treatment characterised by using material-based technologies
- H10D84/03—Manufacture or treatment characterised by using material-based technologies using Group IV technology, e.g. silicon technology or silicon-carbide [SiC] technology
- H10D84/038—Manufacture or treatment characterised by using material-based technologies using Group IV technology, e.g. silicon technology or silicon-carbide [SiC] technology using silicon technology, e.g. SiGe
Landscapes
- Metal-Oxide And Bipolar Metal-Oxide Semiconductor Integrated Circuits (AREA)
- Electrodes Of Semiconductors (AREA)
- Thin Film Transistor (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/771,721 US7666730B2 (en) | 2007-06-29 | 2007-06-29 | Method for forming a dual metal gate structure |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW200903722A TW200903722A (en) | 2009-01-16 |
| TWI433273B true TWI433273B (zh) | 2014-04-01 |
Family
ID=40161071
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW097118679A TWI433273B (zh) | 2007-06-29 | 2008-05-21 | 形成雙金屬閘極結構之方法 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US7666730B2 (enExample) |
| JP (1) | JP2010532578A (enExample) |
| CN (1) | CN101689509B (enExample) |
| TW (1) | TWI433273B (enExample) |
| WO (1) | WO2009005903A1 (enExample) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8298882B2 (en) * | 2009-09-18 | 2012-10-30 | International Business Machines Corporation | Metal gate and high-K dielectric devices with PFET channel SiGe |
| KR101926336B1 (ko) * | 2010-02-05 | 2019-03-07 | 가부시키가이샤 한도오따이 에네루기 켄큐쇼 | 반도체 장치 |
| US9041116B2 (en) * | 2012-05-23 | 2015-05-26 | International Business Machines Corporation | Structure and method to modulate threshold voltage for high-K metal gate field effect transistors (FETs) |
| US9373501B2 (en) * | 2013-04-16 | 2016-06-21 | International Business Machines Corporation | Hydroxyl group termination for nucleation of a dielectric metallic oxide |
| US9887297B2 (en) | 2013-09-17 | 2018-02-06 | Semiconductor Energy Laboratory Co., Ltd. | Semiconductor device comprising oxide semiconductor layer in which thickness of the oxide semiconductor layer is greater than or equal to width of the oxide semiconductor layer |
Family Cites Families (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH1145885A (ja) * | 1997-07-25 | 1999-02-16 | Nec Corp | 半導体装置の製造方法 |
| US6444512B1 (en) * | 2000-06-12 | 2002-09-03 | Motorola, Inc. | Dual metal gate transistors for CMOS process |
| KR100399356B1 (ko) * | 2001-04-11 | 2003-09-26 | 삼성전자주식회사 | 듀얼 게이트를 가지는 씨모스형 반도체 장치 형성 방법 |
| JP4034627B2 (ja) * | 2001-09-28 | 2008-01-16 | テキサス インスツルメンツ インコーポレイテツド | 集積回路及びその製造方法 |
| US6794252B2 (en) | 2001-09-28 | 2004-09-21 | Texas Instruments Incorporated | Method and system for forming dual work function gate electrodes in a semiconductor device |
| JP2003318166A (ja) * | 2002-04-26 | 2003-11-07 | Promos Technologies Inc | ハードマスク除去方法、トレンチ形成方法、コンタクト形成方法 |
| US6645818B1 (en) | 2002-11-13 | 2003-11-11 | Chartered Semiconductor Manufacturing Ltd. | Method to fabricate dual-metal gate for N- and P-FETs |
| JP2004165555A (ja) * | 2002-11-15 | 2004-06-10 | Matsushita Electric Ind Co Ltd | 半導体装置の製造方法 |
| US6972224B2 (en) | 2003-03-27 | 2005-12-06 | Freescale Semiconductor, Inc. | Method for fabricating dual-metal gate device |
| US6790719B1 (en) * | 2003-04-09 | 2004-09-14 | Freescale Semiconductor, Inc. | Process for forming dual metal gate structures |
| US6872613B1 (en) * | 2003-09-04 | 2005-03-29 | Advanced Micro Devices, Inc. | Method for integrating metals having different work functions to form CMOS gates having a high-k gate dielectric and related structure |
| JP2005093530A (ja) * | 2003-09-12 | 2005-04-07 | Semiconductor Leading Edge Technologies Inc | 半導体装置の製造方法 |
| US6897095B1 (en) * | 2004-05-12 | 2005-05-24 | Freescale Semiconductor, Inc. | Semiconductor process and integrated circuit having dual metal oxide gate dielectric with single metal gate electrode |
| US8178902B2 (en) * | 2004-06-17 | 2012-05-15 | Infineon Technologies Ag | CMOS transistor with dual high-k gate dielectric and method of manufacture thereof |
| US20060011949A1 (en) * | 2004-07-18 | 2006-01-19 | Chih-Wei Yang | Metal-gate cmos device and fabrication method of making same |
| US7344934B2 (en) * | 2004-12-06 | 2008-03-18 | Infineon Technologies Ag | CMOS transistor and method of manufacture thereof |
| KR100719340B1 (ko) | 2005-01-14 | 2007-05-17 | 삼성전자주식회사 | 듀얼 게이트 전극을 갖는 반도체 소자 및 그 형성 방법 |
| KR100697694B1 (ko) | 2005-08-02 | 2007-03-20 | 삼성전자주식회사 | 듀얼 게이트를 갖는 반도체 장치 및 그 제조 방법 |
| TWI267926B (en) * | 2005-09-23 | 2006-12-01 | Ind Tech Res Inst | A new method for high mobility enhancement strained channel CMOS with single workfunction metal-gate |
| US20070152276A1 (en) * | 2005-12-30 | 2007-07-05 | International Business Machines Corporation | High performance CMOS circuits, and methods for fabricating the same |
| US7504696B2 (en) * | 2006-01-10 | 2009-03-17 | International Business Machines Corporation | CMOS with dual metal gate |
| JP2008210874A (ja) * | 2007-02-23 | 2008-09-11 | Toshiba Corp | 半導体装置の製造方法 |
| US7863124B2 (en) * | 2007-05-10 | 2011-01-04 | International Business Machines Corporation | Residue free patterned layer formation method applicable to CMOS structures |
| US7445981B1 (en) * | 2007-06-29 | 2008-11-04 | Freescale Semiconductor, Inc. | Method for forming a dual metal gate structure |
| US8211786B2 (en) * | 2008-02-28 | 2012-07-03 | International Business Machines Corporation | CMOS structure including non-planar hybrid orientation substrate with planar gate electrodes and method for fabrication |
-
2007
- 2007-06-29 US US11/771,721 patent/US7666730B2/en active Active
-
2008
- 2008-05-20 WO PCT/US2008/064192 patent/WO2009005903A1/en not_active Ceased
- 2008-05-20 JP JP2010514909A patent/JP2010532578A/ja active Pending
- 2008-05-20 CN CN2008800228330A patent/CN101689509B/zh active Active
- 2008-05-21 TW TW097118679A patent/TWI433273B/zh active
Also Published As
| Publication number | Publication date |
|---|---|
| WO2009005903A1 (en) | 2009-01-08 |
| CN101689509A (zh) | 2010-03-31 |
| US7666730B2 (en) | 2010-02-23 |
| TW200903722A (en) | 2009-01-16 |
| CN101689509B (zh) | 2011-05-25 |
| US20090004792A1 (en) | 2009-01-01 |
| JP2010532578A (ja) | 2010-10-07 |
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