TWI414553B - 駐極體材料 - Google Patents
駐極體材料 Download PDFInfo
- Publication number
- TWI414553B TWI414553B TW96112227A TW96112227A TWI414553B TW I414553 B TWI414553 B TW I414553B TW 96112227 A TW96112227 A TW 96112227A TW 96112227 A TW96112227 A TW 96112227A TW I414553 B TWI414553 B TW I414553B
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- Taiwan
- Prior art keywords
- group
- acid
- alkyl
- aromatic
- aliphatic
- Prior art date
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- 239000000463 material Substances 0.000 title abstract description 11
- -1 hydroxylamine ester compounds Chemical class 0.000 claims abstract description 156
- 125000003118 aryl group Chemical group 0.000 claims abstract description 39
- 239000000203 mixture Substances 0.000 claims abstract description 39
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 31
- 239000001257 hydrogen Substances 0.000 claims abstract description 30
- 239000000654 additive Substances 0.000 claims abstract description 14
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 12
- 150000001412 amines Chemical class 0.000 claims abstract description 11
- 230000000996 additive effect Effects 0.000 claims abstract description 7
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims abstract description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 5
- 238000003851 corona treatment Methods 0.000 claims abstract description 5
- 239000002667 nucleating agent Substances 0.000 claims abstract description 5
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 5
- 239000001301 oxygen Substances 0.000 claims abstract description 5
- 239000004611 light stabiliser Substances 0.000 claims abstract description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 63
- 239000002253 acid Substances 0.000 claims description 28
- 125000004432 carbon atom Chemical group C* 0.000 claims description 28
- 150000001875 compounds Chemical class 0.000 claims description 26
- 238000000034 method Methods 0.000 claims description 23
- 125000001931 aliphatic group Chemical group 0.000 claims description 22
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 21
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 21
- 150000002431 hydrogen Chemical class 0.000 claims description 20
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 19
- 125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 claims description 19
- 125000001424 substituent group Chemical group 0.000 claims description 17
- 239000004743 Polypropylene Substances 0.000 claims description 15
- 229920001155 polypropylene Polymers 0.000 claims description 15
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 12
- 125000002947 alkylene group Chemical group 0.000 claims description 11
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 11
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 10
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 9
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 6
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 6
- 229910052698 phosphorus Inorganic materials 0.000 claims description 6
- 239000011574 phosphorus Substances 0.000 claims description 6
- 125000002853 C1-C4 hydroxyalkyl group Chemical group 0.000 claims description 5
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 150000001336 alkenes Chemical class 0.000 claims description 4
- IVHKZGYFKJRXBD-UHFFFAOYSA-N amino carbamate Chemical compound NOC(N)=O IVHKZGYFKJRXBD-UHFFFAOYSA-N 0.000 claims description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 4
- 239000004416 thermosoftening plastic Substances 0.000 claims description 4
- 125000001731 2-cyanoethyl group Chemical group [H]C([H])(*)C([H])([H])C#N 0.000 claims description 3
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 claims description 3
- 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 claims description 3
- 230000000087 stabilizing effect Effects 0.000 claims description 3
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 2
- 239000004135 Bone phosphate Substances 0.000 claims description 2
- 235000019253 formic acid Nutrition 0.000 claims description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 2
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 2
- 150000007934 α,β-unsaturated carboxylic acids Chemical class 0.000 claims description 2
- 150000001735 carboxylic acids Chemical class 0.000 claims 3
- VZXTWGWHSMCWGA-UHFFFAOYSA-N 1,3,5-triazine-2,4-diamine Chemical compound NC1=NC=NC(N)=N1 VZXTWGWHSMCWGA-UHFFFAOYSA-N 0.000 claims 1
- 241000208340 Araliaceae Species 0.000 claims 1
- 235000005035 Panax pseudoginseng ssp. pseudoginseng Nutrition 0.000 claims 1
- 235000003140 Panax quinquefolius Nutrition 0.000 claims 1
- 235000008434 ginseng Nutrition 0.000 claims 1
- 229920000098 polyolefin Polymers 0.000 abstract description 6
- 150000002148 esters Chemical class 0.000 abstract description 5
- 239000000155 melt Substances 0.000 abstract description 5
- 239000002250 absorbent Substances 0.000 abstract description 2
- 230000002745 absorbent Effects 0.000 abstract description 2
- 239000000758 substrate Substances 0.000 abstract description 2
- 239000012814 acoustic material Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 description 22
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 12
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 11
- 125000003837 (C1-C20) alkyl group Chemical group 0.000 description 8
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 8
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 7
- 125000006309 butyl amino group Chemical group 0.000 description 7
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 7
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 6
- 125000001624 naphthyl group Chemical group 0.000 description 6
- 229920000728 polyester Polymers 0.000 description 6
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 5
- 125000003342 alkenyl group Chemical group 0.000 description 5
- 239000004744 fabric Substances 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 125000003396 thiol group Chemical group [H]S* 0.000 description 5
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 4
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 4
- RXFCIXRFAJRBSG-UHFFFAOYSA-N 3,2,3-tetramine Chemical compound NCCCNCCNCCCN RXFCIXRFAJRBSG-UHFFFAOYSA-N 0.000 description 4
- POJWUDADGALRAB-PVQJCKRUSA-N Allantoin Natural products NC(=O)N[C@@H]1NC(=O)NC1=O POJWUDADGALRAB-PVQJCKRUSA-N 0.000 description 4
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 4
- 125000002252 acyl group Chemical group 0.000 description 4
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 4
- POJWUDADGALRAB-UHFFFAOYSA-N allantion Natural products NC(=O)NC1NC(=O)NC1=O POJWUDADGALRAB-UHFFFAOYSA-N 0.000 description 4
- 229960000458 allantoin Drugs 0.000 description 4
- 125000003710 aryl alkyl group Chemical group 0.000 description 4
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 4
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 4
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 4
- 239000007859 condensation product Substances 0.000 description 4
- 125000004122 cyclic group Chemical group 0.000 description 4
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 4
- 125000004915 dibutylamino group Chemical group C(CCC)N(CCCC)* 0.000 description 4
- 150000001991 dicarboxylic acids Chemical class 0.000 description 4
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
- 229910052736 halogen Inorganic materials 0.000 description 4
- 150000002367 halogens Chemical group 0.000 description 4
- 229920001903 high density polyethylene Polymers 0.000 description 4
- 239000004700 high-density polyethylene Substances 0.000 description 4
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 4
- 150000002443 hydroxylamines Chemical class 0.000 description 4
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 4
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 4
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 4
- WLJVNTCWHIRURA-UHFFFAOYSA-N pimelic acid Chemical compound OC(=O)CCCCCC(O)=O WLJVNTCWHIRURA-UHFFFAOYSA-N 0.000 description 4
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 4
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 4
- 125000000027 (C1-C10) alkoxy group Chemical group 0.000 description 3
- 125000004974 2-butenyl group Chemical group C(C=CC)* 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 125000003860 C1-C20 alkoxy group Chemical group 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000007983 Tris buffer Substances 0.000 description 3
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 description 3
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 150000002009 diols Chemical class 0.000 description 3
- 125000000219 ethylidene group Chemical group [H]C(=[*])C([H])([H])[H] 0.000 description 3
- 125000000524 functional group Chemical group 0.000 description 3
- 150000002334 glycols Chemical class 0.000 description 3
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 3
- 238000010348 incorporation Methods 0.000 description 3
- 229920001684 low density polyethylene Polymers 0.000 description 3
- 239000004702 low-density polyethylene Substances 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- UKJARPDLRWBRAX-UHFFFAOYSA-N n,n'-bis(2,2,6,6-tetramethylpiperidin-4-yl)hexane-1,6-diamine Chemical compound C1C(C)(C)NC(C)(C)CC1NCCCCCCNC1CC(C)(C)NC(C)(C)C1 UKJARPDLRWBRAX-UHFFFAOYSA-N 0.000 description 3
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 3
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 3
- 229960003742 phenol Drugs 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 3
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 description 2
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 description 2
- 125000006702 (C1-C18) alkyl group Chemical group 0.000 description 2
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 2
- 125000002030 1,2-phenylene group Chemical group [H]C1=C([H])C([*:1])=C([*:2])C([H])=C1[H] 0.000 description 2
- AUHZEENZYGFFBQ-UHFFFAOYSA-N 1,3,5-trimethylbenzene Chemical compound CC1=CC(C)=CC(C)=C1 AUHZEENZYGFFBQ-UHFFFAOYSA-N 0.000 description 2
- 125000001989 1,3-phenylene group Chemical group [H]C1=C([H])C([*:1])=C([H])C([*:2])=C1[H] 0.000 description 2
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 2
- 125000001140 1,4-phenylene group Chemical group [H]C1=C([H])C([*:2])=C([H])C([H])=C1[*:1] 0.000 description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 2
- KFBXUKHERGLHLG-UHFFFAOYSA-N 2,4-Nonanedione Chemical compound CCCCCC(=O)CC(C)=O KFBXUKHERGLHLG-UHFFFAOYSA-N 0.000 description 2
- UIAFKZKHHVMJGS-UHFFFAOYSA-N 2,4-dihydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1O UIAFKZKHHVMJGS-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- RLHGFJMGWQXPBW-UHFFFAOYSA-N 2-hydroxy-3-(1h-imidazol-5-ylmethyl)benzamide Chemical compound NC(=O)C1=CC=CC(CC=2NC=NC=2)=C1O RLHGFJMGWQXPBW-UHFFFAOYSA-N 0.000 description 2
- 125000006024 2-pentenyl group Chemical group 0.000 description 2
- XCZKKZXWDBOGPA-UHFFFAOYSA-N 2-phenylbenzene-1,4-diol Chemical compound OC1=CC=C(O)C(C=2C=CC=CC=2)=C1 XCZKKZXWDBOGPA-UHFFFAOYSA-N 0.000 description 2
- QOXOZONBQWIKDA-UHFFFAOYSA-N 3-hydroxypropyl Chemical group [CH2]CCO QOXOZONBQWIKDA-UHFFFAOYSA-N 0.000 description 2
- CYYZDBDROVLTJU-UHFFFAOYSA-N 4-n-Butylphenol Chemical compound CCCCC1=CC=C(O)C=C1 CYYZDBDROVLTJU-UHFFFAOYSA-N 0.000 description 2
- 239000005711 Benzoic acid Substances 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 2
- 229920002943 EPDM rubber Polymers 0.000 description 2
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical group CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- 239000004594 Masterbatch (MB) Substances 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 2
- 239000001361 adipic acid Substances 0.000 description 2
- 235000011037 adipic acid Nutrition 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 125000003282 alkyl amino group Chemical group 0.000 description 2
- PXXJHWLDUBFPOL-UHFFFAOYSA-N benzamidine Chemical group NC(=N)C1=CC=CC=C1 PXXJHWLDUBFPOL-UHFFFAOYSA-N 0.000 description 2
- 239000004305 biphenyl Substances 0.000 description 2
- 235000010290 biphenyl Nutrition 0.000 description 2
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 2
- 125000001589 carboacyl group Chemical group 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 2
- 125000000392 cycloalkenyl group Chemical group 0.000 description 2
- 125000001316 cycloalkyl alkyl group Chemical group 0.000 description 2
- VKONPUDBRVKQLM-UHFFFAOYSA-N cyclohexane-1,4-diol Chemical compound OC1CCC(O)CC1 VKONPUDBRVKQLM-UHFFFAOYSA-N 0.000 description 2
- HGCIXCUEYOPUTN-UHFFFAOYSA-N cyclohexene Chemical compound C1CCC=CC1 HGCIXCUEYOPUTN-UHFFFAOYSA-N 0.000 description 2
- 125000004210 cyclohexylmethyl group Chemical group [H]C([H])(*)C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C1([H])[H] 0.000 description 2
- WJTCGQSWYFHTAC-UHFFFAOYSA-N cyclooctane Chemical compound C1CCCCCCC1 WJTCGQSWYFHTAC-UHFFFAOYSA-N 0.000 description 2
- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 2
- LPIQUOYDBNQMRZ-UHFFFAOYSA-N cyclopentene Chemical compound C1CC=CC1 LPIQUOYDBNQMRZ-UHFFFAOYSA-N 0.000 description 2
- 150000001993 dienes Chemical class 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- GHLKSLMMWAKNBM-UHFFFAOYSA-N dodecane-1,12-diol Chemical compound OCCCCCCCCCCCCO GHLKSLMMWAKNBM-UHFFFAOYSA-N 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
- 229920006178 high molecular weight high density polyethylene Polymers 0.000 description 2
- 150000002430 hydrocarbons Chemical group 0.000 description 2
- 229920001179 medium density polyethylene Polymers 0.000 description 2
- 239000004701 medium-density polyethylene Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
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- 125000001204 arachidyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 1
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- 125000006267 biphenyl group Chemical group 0.000 description 1
- RSOILICUEWXSLA-UHFFFAOYSA-N bis(1,2,2,6,6-pentamethylpiperidin-4-yl) decanedioate Chemical compound C1C(C)(C)N(C)C(C)(C)CC1OC(=O)CCCCCCCCC(=O)OC1CC(C)(C)N(C)C(C)(C)C1 RSOILICUEWXSLA-UHFFFAOYSA-N 0.000 description 1
- PVIFXIBJQWPGNU-UHFFFAOYSA-N bis(1-acetyloxy-2,2,6,6-tetramethylpiperidin-4-yl) decanedioate Chemical compound C1C(C)(C)N(OC(=O)C)C(C)(C)CC1OC(=O)CCCCCCCCC(=O)OC1CC(C)(C)N(OC(C)=O)C(C)(C)C1 PVIFXIBJQWPGNU-UHFFFAOYSA-N 0.000 description 1
- XITRBUPOXXBIJN-UHFFFAOYSA-N bis(2,2,6,6-tetramethylpiperidin-4-yl) decanedioate Chemical compound C1C(C)(C)NC(C)(C)CC1OC(=O)CCCCCCCCC(=O)OC1CC(C)(C)NC(C)(C)C1 XITRBUPOXXBIJN-UHFFFAOYSA-N 0.000 description 1
- WUXGYZUOHKJTEY-UHFFFAOYSA-N bis[1-(2-hydroxy-2-methylpropoxy)-2,2,6,6-tetramethylpiperidin-4-yl] hexanedioate Chemical compound C1C(C)(C)N(OCC(C)(O)C)C(C)(C)CC1OC(=O)CCCCC(=O)OC1CC(C)(C)N(OCC(C)(C)O)C(C)(C)C1 WUXGYZUOHKJTEY-UHFFFAOYSA-N 0.000 description 1
- ZFVMWEVVKGLCIJ-UHFFFAOYSA-N bisphenol AF Chemical compound C1=CC(O)=CC=C1C(C(F)(F)F)(C(F)(F)F)C1=CC=C(O)C=C1 ZFVMWEVVKGLCIJ-UHFFFAOYSA-N 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- GGAUUQHSCNMCAU-UHFFFAOYSA-N butane-1,2,3,4-tetracarboxylic acid Chemical compound OC(=O)CC(C(O)=O)C(C(O)=O)CC(O)=O GGAUUQHSCNMCAU-UHFFFAOYSA-N 0.000 description 1
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- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
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- 125000004181 carboxyalkyl group Chemical group 0.000 description 1
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- 238000009833 condensation Methods 0.000 description 1
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- 229920001940 conductive polymer Polymers 0.000 description 1
- 125000004093 cyano group Chemical group *C#N 0.000 description 1
- MGNCLNQXLYJVJD-UHFFFAOYSA-N cyanuric chloride Chemical compound ClC1=NC(Cl)=NC(Cl)=N1 MGNCLNQXLYJVJD-UHFFFAOYSA-N 0.000 description 1
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- 125000004978 cyclooctylene group Chemical group 0.000 description 1
- LNGJOYPCXLOTKL-UHFFFAOYSA-N cyclopentane-1,3-dicarboxylic acid Chemical compound OC(=O)C1CCC(C(O)=O)C1 LNGJOYPCXLOTKL-UHFFFAOYSA-N 0.000 description 1
- 125000004979 cyclopentylene group Chemical group 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
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- 239000000539 dimer Chemical class 0.000 description 1
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- 238000009826 distribution Methods 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
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- 230000002708 enhancing effect Effects 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 125000005745 ethoxymethyl group Chemical group [H]C([H])([H])C([H])([H])OC([H])([H])* 0.000 description 1
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- 239000000835 fiber Substances 0.000 description 1
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- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
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- 239000008187 granular material Substances 0.000 description 1
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- 125000006038 hexenyl group Chemical group 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
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- 238000004519 manufacturing process Methods 0.000 description 1
- 125000002960 margaryl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000004750 melt-blown nonwoven Substances 0.000 description 1
- 125000004184 methoxymethyl group Chemical group [H]C([H])([H])OC([H])([H])* 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 125000004573 morpholin-4-yl group Chemical group N1(CCOCC1)* 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- GXFQBBOZTNQHMW-UHFFFAOYSA-N n'-(2,2,6,6-tetramethylpiperidin-4-yl)hexane-1,6-diamine Chemical compound CC1(C)CC(NCCCCCCN)CC(C)(C)N1 GXFQBBOZTNQHMW-UHFFFAOYSA-N 0.000 description 1
- COFLEVLXIIWATL-UHFFFAOYSA-N n,n'-bis(1,2,2,6,6-pentamethylpiperidin-4-yl)hexane-1,6-diamine Chemical compound C1C(C)(C)N(C)C(C)(C)CC1NCCCCCCNC1CC(C)(C)N(C)C(C)(C)C1 COFLEVLXIIWATL-UHFFFAOYSA-N 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 125000003136 n-heptyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical compound C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 description 1
- WPUMVKJOWWJPRK-UHFFFAOYSA-N naphthalene-2,7-dicarboxylic acid Chemical compound C1=CC(C(O)=O)=CC2=CC(C(=O)O)=CC=C21 WPUMVKJOWWJPRK-UHFFFAOYSA-N 0.000 description 1
- DFQICHCWIIJABH-UHFFFAOYSA-N naphthalene-2,7-diol Chemical compound C1=CC(O)=CC2=CC(O)=CC=C21 DFQICHCWIIJABH-UHFFFAOYSA-N 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- ZCYXXKJEDCHMGH-UHFFFAOYSA-N nonane Chemical compound CCCC[CH]CCCC ZCYXXKJEDCHMGH-UHFFFAOYSA-N 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- SJYNFBVQFBRSIB-UHFFFAOYSA-N norbornadiene Chemical compound C1=CC2C=CC1C2 SJYNFBVQFBRSIB-UHFFFAOYSA-N 0.000 description 1
- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 description 1
- BKIMMITUMNQMOS-UHFFFAOYSA-N normal nonane Natural products CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 description 1
- IOQPZZOEVPZRBK-UHFFFAOYSA-N octan-1-amine Chemical compound CCCCCCCCN IOQPZZOEVPZRBK-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 125000001820 oxy group Chemical group [*:1]O[*:2] 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- AZQWKYJCGOJGHM-UHFFFAOYSA-N para-benzoquinone Natural products O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 1
- 125000002958 pentadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000004817 pentamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- UWJJYHHHVWZFEP-UHFFFAOYSA-N pentane-1,1-diol Chemical compound CCCCC(O)O UWJJYHHHVWZFEP-UHFFFAOYSA-N 0.000 description 1
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 238000012667 polymer degradation Methods 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920000306 polymethylpentene Polymers 0.000 description 1
- 239000011116 polymethylpentene Substances 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- 125000005767 propoxymethyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])[#8]C([H])([H])* 0.000 description 1
- 229920001384 propylene homopolymer Polymers 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 229940116351 sebacate Drugs 0.000 description 1
- CXMXRPHRNRROMY-UHFFFAOYSA-L sebacate(2-) Chemical compound [O-]C(=O)CCCCCCCCC([O-])=O CXMXRPHRNRROMY-UHFFFAOYSA-L 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- SNOOUWRIMMFWNE-UHFFFAOYSA-M sodium;6-[(3,4,5-trimethoxybenzoyl)amino]hexanoate Chemical compound [Na+].COC1=CC(C(=O)NCCCCCC([O-])=O)=CC(OC)=C1OC SNOOUWRIMMFWNE-UHFFFAOYSA-M 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 150000000000 tetracarboxylic acids Chemical class 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 150000003628 tricarboxylic acids Chemical class 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 125000004953 trihalomethyl group Chemical group 0.000 description 1
- 229920000785 ultra high molecular weight polyethylene Polymers 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G7/00—Capacitors in which the capacitance is varied by non-mechanical means; Processes of their manufacture
- H01G7/02—Electrets, i.e. having a permanently-polarised dielectric
- H01G7/021—Electrets, i.e. having a permanently-polarised dielectric having an organic dielectric
- H01G7/023—Electrets, i.e. having a permanently-polarised dielectric having an organic dielectric of macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/12—Chemical modification
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G7/00—Capacitors in which the capacitance is varied by non-mechanical means; Processes of their manufacture
- H01G7/02—Electrets, i.e. having a permanently-polarised dielectric
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- General Chemical & Material Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Filtering Materials (AREA)
- Nonwoven Fabrics (AREA)
- Electrostatic, Electromagnetic, Magneto- Strictive, And Variable-Resistance Transducers (AREA)
- Inorganic Insulating Materials (AREA)
- Artificial Filaments (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Description
本發明的目標為具有極佳的熱穩定性及電荷穩定性之駐極體組成物。駐極體組成物為例如聚烯烴纖維或膜,且適合用作過濾材料、擦拭布、吸收材料、過濾遮罩、隔音材料、印刷基板、測量裝置或無觸點開關。
駐極體(由來自〝電〞之elektr-及來自〝磁鐵〞之-et所構成)為具有准永久電荷或電偶極化之介電材料。駐極體產生內及外電場,並為永久磁鐵的靜電相應物(Wikipedia Definition,Entry Electret:Last modified 22th Feb.2007)。
美國專利申請案第5,057,710號揭示含有受阻胺、含氮之受阻酚或含金屬之受阻酚的駐極體材料。
美國專利申請案第5,556,618號揭示抗細菌性駐極體材料。
美國專利申請案第6,123,752號揭示含有性能增強性添加劑之高效率過濾介質。
美國專利申請案第6,743,464號揭示經由蒸氣冷凝製造駐極體的方法。
美國發表之申請案第2003/0216494號揭示受阻羥胺酯化合物。
本發明的主題為具有增強的熱及電荷穩定性之駐極體組成物,已使該組成物接受駐極體處理,其包含熱塑性合物及併入其中的有效穩定量之至少一種受阻羥胺酯化合物,該化合物包括至少一部分的式I
其中Ra
’為單醯基或二醯基;R1
-R4
各自為C1
-C6
烷基;及R5
及R6
彼此各自獨立為氫、C1
-C6
烷基或C6
-C10
芳基;或R5
與R6
一起為氧。
在化合物(I)中,虛線代表連接至基團及取代基之鍵。
本發明也揭示一種製備具有增強熱及電荷穩定性之駐極體組成物的方法,該方法包含熔融摻合熱塑性聚合物與有效穩定量之至少一種受阻羥胺酯化合物,該化合物包括至少一部分如上所定義之式I,並使摻合物接受駐極體處理。
熱塑性聚合物為具有非暫時性或長久性阻陷電荷的能力之非導電性聚合物。聚合物為例如聚烯烴、鹵化乙烯基聚合物(例如,聚氯乙烯)、聚苯乙烯、聚碳酸酯、聚酯(例如,聚對苯二甲酸乙烯酯)、聚醯胺或氟基-聚合物(例如聚四氟乙烯)。
熱塑性聚合物為例如丙烯均聚物、丙烯共聚物及聚丙烯摻合物。丙烯共聚物可包括至多90.0%,較佳為至多50.0%的各種比例之共單體。共單體的實例為:烯烴類,如1-烯烴類(例如,乙烯、1-丁烯、1-戊烯、1-己烯、1-庚烯或1-辛烯)、異丁烯、環烯烴類(例如,環戊烯、環己烯、降莰烯或亞乙基降莰烯)、二烯類(如丁二烯、異戊二烯、1,4-己二烯、環戊二烯、二環戊二烯或降莰二烯);也為丙烯酸衍生物及不飽和羧酸酐,如馬來酸酐。
可使用的聚丙烯摻合物為聚丙烯與聚烯烴類之混合物。實例為聚丙烯與選自由高密度聚乙烯(HDPE)、高分子量高密度聚乙烯(HMW HDPE)、超高分子量高密度聚乙烯(UHMW HDPE)、中密度聚乙烯(MDPE)、低密度聚乙烯(LDPE)、線性低密度聚乙烯(LLDPE)、支鏈低密度聚乙烯(BLDPE)及含有少量二烯比例之乙烯-丙烯-二烯三聚物(EPDM)所組成的群組之聚乙烯的摻合物。
聚合物尤其為聚烯烴,例如,聚丙烯、聚(4-甲基-1-戊烯)或線性低密度聚乙烯,或其摻合物或共聚物。聚合物可為聚烯烴與包括極性基團之聚合物(例如聚酯或聚醯胺)的摻合物。
含有熱塑性組成物之駐極體組成物具有不織網、膜、或編織物形式。駐極體組成物特別為不織纖維網。
駐極體處理可為任何已知的處理。駐極體處理被講述於例如美國專利申請案第5,057,710號、第5,556,618號、第6,123,752號、第6,743,464號、第6,969,484號、第6,284,339號、第5,256,176號及第6,926,961號中。駐極體處理為任何暴露於電的處理,例如,水力充電、磨擦充電或電暈處理。駐極體處理尤其為電暈處理。
根據本發明的駐極體組成物為已接受駐極體處理之熱塑性組成物。
受阻羥胺酯化合物被揭示於例如美國發表申請案第2003/0216494號中。
本發明的羥胺酯化合物包括至少一部分的式I
其中Ra
’為單醯基或二醯基;R1
-R4
各自為C1
-C6
烷基;及R5
及R6
彼此各自獨立為氫、C1
-C6
烷基或C6
-C10
芳基;或R5
與R6
一起為氧。
優先選擇為含有一部分的式I之化合物,其中Ra
’為C2
-C18
烷醯基或C3
-C6
烯醯基。
在化合物(I)中,虛線代表連接至基團及取代基之鍵。
單醯基Ra
’可為例如自含有C基及酸官能基之一元有機酸所衍生之醯基,例如,上述定義之部分化學式-C(=O)-H、-C(=O)-C1
-C19
烷基、-C(=O)-C2
-C19
烯基、-C(=O)-C2
-C4
烯基-C6
-C10
芳基、-C(=O)-C6
-C10
芳基、-C(=O)-O-C1
-C6
烷基、-C(=O)-O-C6
-C10
芳基、-C(=O)-NH-C1
-C6
烷基、-C(=O)-NH-C6
-C10
芳基及-C(=O)-N(C1
-C6
烷基)2
的醯基中之一。
當Ra
’為單醯基時,則含有基團(I)之羥胺酯為單體或二單體結構。因此,二單體結構在4-位置上具有適合的二價取代基及這些取代基在末端位置上被化合物(I)經由彼之4-位置依次被取代(α,ω-取代)。
羥胺酯術語包含單體及寡聚合化合物二者,並也為式I化合物所形成的聚合物。
二醯基Ra
’可為例如自具有C基及兩個酸官能基之一元有機酸所衍生之二醯基,例如,自脂肪族、芳香族或環脂肪族二羧酸所衍生之二醯基。
適合的脂肪族二羧酸具有從2至40個C-原子,例如,乙二酸、丙二酸、二甲基丙二酸、丁二酸、庚二酸、己二酸、三甲基己二酸、癸二酸、壬二酸及二聚物酸(不飽和脂肪族羧酸,如油酸之二聚合產物)、烷基化丙二酸與丁二酸,例如,十八烷基丁二酸。
適合的環脂肪族二羧酸為例如1,3-環丁烷二羧酸、1,3-環戊烷二羧酸、1,3-與1,4-環己烷二羧酸、1,3-與1,4-(二羧甲基)環己烷或4,4’-二環己基二羧酸。
適合的芳香族二羧酸為例如對苯二甲酸、異苯二甲酸、鄰苯二甲酸,並也為1,3-、1,4-、2,6-或2,7-萘二羧酸、4,4’-聯苯二羧酸、雙(4-羧苯基)碸、4,4’-二苯甲酮二羧酸、1,1,3-三甲基-5-羧基-3-(對-羧苯基)-二氫茚、雙(4-羧苯基)醚、雙(對-羧苯基)甲烷或雙(對-羧苯基)乙烷。
優先選擇為芳香族二羧酸,特別為對苯二甲酸、異苯二甲酸及2,6-萘二羧酸。
更適合的二羧酸為含有-CO-NH-基團者。這些被敘述在美國專利申請案第4,002,600號中。也適合的是含有N-雜環型環之二羧酸,例如,那些自羧烷基化、羧苯基化或羧苯甲基化單胺-s-三二羧酸所衍生者,參見美國專利申請案第3,697,520號及美國專利申請案第4,034,019號,自單-尿囊素或雙-尿囊素、鹵化或未鹵化苯并咪唑或對苯甲酸所衍生者。羧烷基可包括從3至20個C-原子。
當Ra
’為二醯基且適合的官能基,例如,羥基或胺基係存在於4-位置上時,則含有式I基團之化合物為聚合物結構,例如,聚酯、聚酯醯胺、聚胺基甲酸乙酯、聚碳酸酯或聚醯亞胺酯。
例如,受阻羥胺酯具有式IA
其中n為從1至4之整數,Ra
為醯基,且R1
’、R2
’及R3
’彼此各自獨立為氫或甲基;及G具有下列意義:當n=1時,則G為氫、C1
-C18
烷基(其可被至少一個氧原子間斷)、2-氰乙基、苯甲基、環氧丙基、脂肪族-、環脂肪族-、芳脂肪族-、不飽和-或芳香族-羧酸、胺基甲酸或含磷之酸之單價基;或為單價矽基,較佳為具有從2至18個C-原子之脂肪族羧酸、具有從7至15個C-原子之環脂肪族羧酸、具有從3至5個C-原子之α,β-不飽和羧酸或具有從7至15個C-原子之芳香族羧酸的醯基,其中在脂肪族、環脂肪族或芳香族部分中的羧酸可被從1至3個-COOZ1
基團取代,其中Z1
為氫、C1
-C20
烷基、C3
-C12
烯基、C5
-C7
環烷基、苯基或苯甲基,或當n=2時,則G為C2
-C12
伸烷基、C4
-C12
伸烯基、伸茬基、脂肪族-、環脂肪族-、芳脂肪族-或芳香族-二羧酸、二胺基甲酸或含磷之酸之二價酸基;或為二價矽基,較佳為具有從2至36個C-原子之脂肪族二羧酸、具有從8至14個C-原子之環脂肪族或芳香族二羧酸、具有從8至14個C-原子之環脂肪族或芳香族二胺基甲酸的醯基,其中在脂肪族、環脂肪族或芳香族部分中的二羧酸可被1或2個-COOZ1
基團取代,其中Z1
如上述所定義;或當n=3時,則
G為脂肪族-、環脂肪族-或芳香族-三羧酸之三價酸基,其中在脂肪族、環脂肪族或芳香族部分中的該基可被-COOZ1
取代,其中Z1
如上述所定義,或為芳香族三胺基甲酸或含磷之酸之三價酸基,或為三價矽基;及當n=4時,則G為脂肪族-、環脂肪族-或芳香族-四羧酸之四價酸基。
例如,本發明的受阻羥胺酯具有式(IA),其中n為1或2,R1
’、R2
’及R3
’各自為氫及Ra
為C2
-C18
烷醯基或C3
-C6
烯醯基,及G為具有從12至18個C-原子之脂肪族單羧酸的醯基或具有從4至12個C-原子之脂肪族二羧酸的二醯基。
被定義為C1
-C18
烷基的G可如下述所定義,或可為例如正-十三烷基、正-十四烷基、正-十六烷基或正-十八烷基。
作為G的羧酸之單價醯基可為例如醋酸、己酸、硬脂酸、丙烯酸、甲基丙烯酸、苯甲酸或β-(3,5-二-第三丁基-4-羥苯基)丙酸的醯基;較佳為硬脂酸、丙烯酸或甲基丙烯酸的醯基。
單價矽基G可為例如基-(Cn
H2n
)-Si(Z’)2
Z”,其中n為從2至5之整數,以及Z’及Z”彼此各自獨立為C1
-C4
烷基或C1
-C4
烷氧基。
作為G的二羧酸之二價酸基可為例如丙二酸、丁二酸、戊二酸、己二酸、庚二酸、癸二酸、馬來酸、伊康酸、苯二甲酸、二丁基丙二酸、二苯甲基丙二酸、丁基(3,5-二-第三丁基-4-羥苯甲基)丙二酸或二環庚烯羧酸的酸基。
作為G的三羧酸之三價基可為例如偏苯三甲酸、檸檬酸或氮基三醋酸的酸基。
作為G的四羧酸之四價基可為例如丁烷-1,2,3,4-四羧酸或焦蜜石酸之四價酸基。
作為G的二胺基甲酸之二價基可為例如六亞甲基二胺基甲酸基或2,4-亞甲苯基二胺基甲酸基。
較佳的化合物為其中n為1或2,R1
’、R2
’及R3
’各自為氫及Ra
為C2
-C18
烷醯基或C3
-C6
烯醯基,以及G為具有從12至18個C-原子之脂肪族單羧酸的醯基或具有從4至12個C-原子之脂肪族二羧酸的二醯基之化合物(IA)。
羥胺酯可具有式IB
其中n為1或2,以及Ra
、R1
’、R2
’及R3
’具有如以式IA所定義;G1
為氫、C1
-C12
烷基、C2
-C5
羥烷基、C5
-C7
環烷基、C7
-C8
芳烷基、C2
-C18
烷醯基、C3
-C5
烯醯基或苯甲醯基,或為下列基團:
其中Ra
、R1
’、R2
’及R3
’如上述所定義;及G2
具有下列意義:當n=1時,則G2
為氫、C1
-C18
烷基、C3
-C8
烯基、C5
-C7
環烷基、攜帶羥基、氰基、烷氧羰基或甲醯胺基作為取代基之C1
-C4
烷基、環氧丙基或基團-CH2
-CH(OH)-Z或CONH-Z,其中Z為氫、甲基或苯基;或當n=2時,則G2
為C2
-C12
伸烷基、C6
-C12
伸芳基、伸茬基或-CH2
CH(OH)-CH2
-或-CH2
-CH(OH)-CH2
-O-D-O-基團,其中D為C2
-C10
伸烷基、C6
-C15
伸芳基、C6
-C12
環伸烷基;或其先決條件係G1
不為烷醯基、烯醯基或苯甲醯基時,則G2
也可為1-側氧-C2
-C12
伸烷基、脂肪族-、環脂肪族-或芳香族-二羧酸或二胺基甲酸之二價基;或為-CO-基團;或當n=1時,則G1
與G2
可一起為脂肪族-、環脂肪族-或芳香族-1,2-二羧酸或1,3-二羧酸之二價基。
C1
-C12
烷基及C1
-C18
烷基取代基如上述以式(IA)所定義。
C5
-C7
環烷基係以環己基較佳。
C7
-C8
芳烷基G1
係以2-苯乙基或苯甲基較佳。
C2
-C5
羥烷基G1
係以2-羥乙基或2-或3-羥丙基較佳。
C2
-C18
烷醯基G1
可為例如丙醯基、丁醯基、辛醯基、十二烷醯基、十六烷醯基、十八烷醯基,以乙醯基較佳。
C3
-C5
烯醯基G1
係以丙烯醯基較佳。
C2
-C8
烯基G2
可為例如烯丙基、甲基烯丙基、2-丁烯基、2-戊烯基、2-己烯基或2-辛烯基。
經羥基-、氰基-、烷氧羰基-或甲醯胺基-取代之C1
-C4
烷基G2
可為例如2-羥乙基、2-羥丙基、2-氰乙基、甲氧基羰甲基、2-乙氧基羰乙基、2-胺基羰丙基或2-(二甲胺基羰基)乙基。
C2
-C12
伸烷基G2
可為例如伸乙基、伸丙基、2,2-二甲基伸丙基、四亞甲基、六亞甲基、八亞甲基、十亞甲基或十二亞甲基。
C6
-C15
伸芳基G2
可為例如鄰-、間-或對-伸苯基、1,4-伸萘基或4,4’-伸聯苯基。
C6
-C12
-環伸烷基G2
係以環伸己基較佳。
例如,本發明的羥胺酯具有式IC
其中n為1或2,以及Ra
、R1
’、R2
’及R3
’具有如以式IA所定義;及當n=1時,則G3
為C2
-C8
伸烷基、C2
-C8
羥基伸烷基或C4
-C24
醯氧基伸烷基,或當n=2時,則G3
為基團(-CH2
)2
C(CH2
-)2
。
例如,本發明的羥胺酯具有式IC,其中Ra
、R1
’、R2
’及R3
’具有如以式IA所定義及G3
為C2
-C8
伸烷基或C4
-C24
醯氧基伸烷基。
C2
-C8
伸烷基或C2
-C8
羥基伸烷基G3
可為例如伸乙基、1-甲基伸乙基、伸丙基、2-乙基伸丙基或2-乙基-2-羥甲基伸丙基。
C4
-C24
-醯氧基伸烷基G3
可為例如2-乙基-2-乙醯氧基甲基伸丙基。
羥胺酯可具有式ID、IE或IF
其中n為1或2,以及Ra
、R1
’、R2
’及R3
’具有如以式IA所定義;及G4
為氫、C1
-C12
烷基、烯丙基、苯甲基、環氧丙基或C2
-C6
烷氧基烷基;及G5
具有下列意義:當n=1時,則G5
為氫、C1
-C12
烷基、C3
-C5
烯基、C7
-C9
芳烷基、C5
-C7
環烷基、C2
-C4
羥烷基、C2
-C6
烷氧基烷基、C6
-C10
芳基、環氧丙基或基團:-(CH2
)p
-COO-Q或-(CH2
)p
-O-CO-Q,其中p為1或2及Q為C1
-C4
烷基或苯基;或當n=2時,則G5
為C2
-C12
伸烷基、C4
-C12
伸烯基、C6
-C12
伸芳基、基團-CH2
-CH(OH)-CH2
-O-D-O-CH2
-CH(OH)-CH2
-,其中D為C2
-C10
-伸烷基、C6
-C15
伸芳基或C6
-C12
-環伸烷基,或為基團-CH2
CH(OZ’)CH2
-(OCH2
-CH(OZ’)CH2
)2
-,其中Z’為氫、C1
-C18
烷基、烯丙基、苯甲基、C2
-C12
烷醯基或苯甲醯基;T1
及T2
彼此各自獨立為氫、C1
-C18
烷基、C6
-C10
芳基或C7
-C9
芳烷基,每一個可被鹵素或C1
-C4
烷基取代;或T1
及T2
與連接彼等的碳原子一起形成C5
-C14
環烷烴環。
取代基C1
-C12
烷基為例如甲基、乙基、正丙基、異丙基、正丁基、第二丁基、第三丁基、正己基、正辛基、2-乙基己基、正壬基、正癸基、正-十一烷基或正-十二烷基。
被定義為C1
-C18
-烷基的取代基可為例如上述基團,或為例如正-十三烷基、正-十四烷基、正-十六烷基或正-十八烷基。
C2
-C6
烷氧基烷基為例如甲氧基甲基、乙氧基甲基、丙氧基甲基、第三丁氧基甲基、2-乙氧基乙基、2-或3-乙氧基正丙基、2-正丁氧基乙基、2-第三丁氧基乙基、2-異丙氧基乙基或2-或3-正丙氧基正丙基。
C3
-C5
烯基G5
可為例如1-丙烯基、烯丙基、甲基烯丙基、2-丁烯基或2-戊烯基。
C7
-C9
芳烷基G5
、T1
及T2
係以2-苯乙基或苯甲基較佳。當T1
及T2
與碳原子一起形成環烷烴環時,則該環可為例如環戊烷、環己烷、環辛烷或環十二烷環。
C2
-C4
羥烷基G5
可為例如2-羥乙基、2-或3-羥基正丙基或2-、3-或4-羥基正丁基。
C6
-C10
芳基G5
、T1
及T2
係以苯基或α-或β-萘基較佳,每一個可被鹵素或C1
-C4
烷基取代。
C2
-C12
伸烷基G5
可為例如伸乙基、伸丙基、2,2-二甲基伸丙基、四亞甲基、六亞甲基、八亞甲基、十亞甲基或十二亞甲基。
C4
-C12
伸烯基G5
係以2-伸丁烯基、2-伸戊烯基或3-伸己烯基較佳。
C6
-C12
伸芳基G5
可為例如鄰-、間-或對-伸苯基、1,4-伸萘基或4,4’-伸聯苯基。
C2
-C12
-烷醯基Z’係以例如乙醯基較佳,並也可為丙醯基、丁醯基、正辛醯基或正-十二烷醯基。
C2
-C10
伸烷基、C6
-C15
伸芳基及C6
-C12
環伸烷基D具有如以式IB所定義。
本發明的受阻羥胺酯可具有式IG
其中n=1或2,以及G6
為下列基團:
或
其中Ra
、R1
’、R2
’及R3
’具有如以式IA所定義,以及R3
’及R4
’各自為氫或甲基,或一起形成取代基=O;E為-O-或-NG1
-;A為C2
-C6
-伸烷基或-(CH2
)3
-O-,以及x或為0或為1;G1
為氫、C1
-C12
烷基、C2
-C5
羥烷基或C5
-C7
環烷基;G7
與G6
相同,或為基團-NG9
G10
、-OG11
、-NHCH2
OG11
或-N(CH2
OG11
)2
中之一;當n=1時,則G8
與G6
或G7
相同;及當n=2時,則G8
為基團-E-B-E-,其中B為C2
-C8
-伸烷基或被1或2個-NG9
-基團間斷之C2
-C8
-伸烷基,以及G9
為C1
-C12
烷基、環己基、苯甲基或C1
-C4
羥烷基,或為下列基團:
G10
為C1
-C12
-烷基、環己基、苯甲基或C1
-C4
-羥烷基,以及G11
為氫、C1
-C12
-烷基或苯基;及G9
與G10
一起為C4
-C5
-伸烷基或C4
-C5
氧雜伸烷基。
G9
與G10
可進一步一起為例如C4
-C5
-伸烷基、C4
-C5
氧雜伸烷基,例如,四亞甲基、五亞甲基或3-氧雜五亞甲基,或為對應之C4
-C5
硫雜伸烷基,例如,基團
C1
-C12
烷基為例如甲基、乙基、正丙基、正丁基、第二丁基、第三丁基、正己基、正辛基、2-乙基己基、正壬基、正癸基、正-十一烷基或正-十二烷基。
C1
-C4
羥烷基為例如2-羥乙基、2-或3-羥丙基或2-、3-或4-羥基正丁基。C2
-C6
伸烷基A可為例如伸乙基、伸丙基、2,2-二甲基伸丙基、四亞甲基或六亞甲基。
受阻羥胺酯化合物可具有式IH
其中n為大於2之整數,以及R1
’、R2
’及R3
’具有如以式IA所定義,及B為二價取代基。
B為例如C1
-C12
-伸烷基,例如,亞甲基、伸乙基、伸丙基、2,2-二甲基伸丙基或四亞甲基、六亞甲基、八亞甲基、十亞甲基或十二亞甲基,C6
-C15
伸芳基,例如,下列基團:
其中X為二價取代基,例如,如上述所定義之C1
-C12
伸烷基、-O-、-(C=O)-、-S-或-S(=O)2
-。
本發明的式(IH)之聚酯也可對應於其中下列基團
被適合的二元醇部分置換的化合物,該二元醇係衍生自例如脂肪族、環脂肪族或芳香族二元醇。
脂肪族二元醇可包括從2至12個C-原子,環脂肪族二元醇可包括從5至8個C-原子及芳香族二元醇可包括從6至15個C-原子。
具有分子量在從150至40000之範圍內的聚氧伸烷二醇也有可能。
芳香族二元醇為其中兩個羥基與芳香族烴基或不同的芳香族烴基結合的化合物。
可使聚酯以少量,例如,以所存在的二羧酸為基準計從0.1至3.0莫耳%之超過雙官能性以上的單體(例如新戊四醇、偏苯三甲酸、1,3,5-三(羥苯基)苯、2,4-二羥基苯甲酸或2-(4-羥苯基)-2-(2,4-二羥丙基)丙烷)方式支鏈化。
適合的脂肪族二元醇為直鏈及支鏈脂肪族乙二醇,特別為那些在分子中具有從2至12個,較佳為從2至6個C-原子者,例如,乙二醇、1,2-與1,3-丙二醇、1,2-、1,3-、2,3-或1,4-丁二醇、戊二醇、新戊二醇、1,6-己二醇、1,12-十二烷二醇。
適合的環脂肪族二元醇為例如1,4-二羥基環己烷。更多適合的二元醇為例如1,4-雙(羥甲基)環己烷、芳香族-脂肪族二元醇,如對-亞二甲苯基二醇或2,5-二氯基-對-亞二甲苯基二醇、2,2-(β-羥乙氧基苯基)丙烷,以及也為聚氧伸烷二醇,如二伸乙甘醇、三伸乙甘醇、聚乙二醇或聚丙二醇。伸烷二元醇係以直鏈較佳,並特別包括從2至4個C-原子。
較佳的二元醇為伸烷二元醇、1,4-二羥基環己烷及1,4-雙(羥甲基)環己烷。特別優先選擇為乙二醇、1,4-丁二醇及1,2-與1,3-丙二醇。
更多適合的脂肪族二元醇為β-羥烷基化,特別為β-羥乙基化雙酚,如2,2-雙[4’-(β-羥乙氧基)苯基]丙烷。
更多適合的脂肪族二元醇群組係由在美國專利申請案第3,867,400號及第3,954,790號中所述之雜環型二元醇所組成。實例為:N,N’-雙(β-羥乙基)-5,5-二甲基尿囊素、N,N’-雙(β-羥丙基)-5,5-二甲基尿囊素、亞甲基雙[N-(β-羥乙基)-5-甲基-5-乙基尿囊素]、亞甲基雙[N-(β-羥乙基)-5,5-二甲基尿囊素]、N,N’-雙(β-羥乙基)苯并咪唑酮、N,N’-雙(β-羥乙基)(四氯基)苯并咪唑酮或N,N’-雙(β-羥乙基)(四溴基)苯并咪唑酮。
適合的芳香族二元醇為具有一個芳香族單元之二酚,特別為具有兩個芳香族單元之二元醇,在每一芳香族單元上攜帶羥基。應瞭解芳香族單元為有意義的芳香族烴基,如伸苯基或伸萘基。除了例如氫醌、間苯二酚或1,5-、2,6-與2,7-二羥萘之外,可特別述及雙酚雙(對-羥苯基)醚或硫醚、雙(對-羥苯基)碸、雙(對-羥苯基)甲烷、2,2’-雙(4-羥苯基)聯苯、苯基氫醌、1,2-雙(對-羥苯基)乙烷、1-苯基雙(對-羥苯基)甲烷、二苯基雙(對-羥苯基)甲烷、二苯基雙(對-羥苯基)乙烷、雙(3,5-二甲基-4-羥苯基)碸、雙(3,5-二甲基-4-羥苯基)-對-二異丙苯、雙(3,5-二甲基-4-羥苯基)-間-二異丙苯、2,2-雙(3’,5’-二甲基-4’-羥苯基)丙烷、1,1-或2,2-雙(對-羥苯基)丁烷、2,2-雙(對-羥苯基)六氟丙烷、1,1-二氯基-或1,1,1-三氯基-2,2-雙(對-羥苯基)乙烷、1,1-雙(對-羥苯基)環戊烷及特別為2,2-雙(對-羥苯基)丙烷(雙酚A)與1,1-雙(對-羥苯基)環己烷(雙酚C)。
被取代或未被取代之伸烷基的實例為亞甲基、伸乙基、苯基亞甲基、二苯基亞甲基及甲苯基亞甲基。
亞環烷基的實例為亞環戊基、亞環己基、亞環庚基及亞環辛基。
C6
-C10
芳基為例如苯基或萘基,但是也包含經C1
-C4
烷基取代之苯基。經烷基取代之苯基的實例為乙苯、甲苯、二甲苯與其異構物、1,3,5-三甲苯或異丙苯。
烷基為支鏈或非支鏈基,例如,甲基、乙基、丙基、異丙基、正丁基、第二丁基、異丁基、第三丁基、2-乙基丁基、正戊基、異戊基、1-甲基戊基、1,3-二甲基丁基、正己基、1-甲基己基、正庚基、異庚基、1,1,3,3-四甲基丁基、1-甲基庚基、3-甲基庚基、正辛基、2-乙基己基、1,1,3-三甲基己基、1,1,3,3-四甲基戊基、壬基、癸基、十一烷基、1-甲基十一烷基、十二烷基、1,1,3,3,5,5-六甲基己基、十三烷基、十四烷基、十五烷基、十六烷基、十七烷基、十八烷基、二十烷基或二十二烷基。
羥胺酯加入熱塑性聚合物中可在其中將聚合物熔融及與添加劑混合物的所有習知的混合機器中進行。適合的機器為那些熟習所屬技術領域者已知。彼等優先為混合機、捏合機及擠壓機。
該方法較佳地在加工期間引入添加劑的擠壓機中進行。
特別佳的加工機器為單螺旋擠壓機、對轉式與共轉式雙螺旋擠壓機、行星齒輪式擠壓機、環式擠壓機或共捏合機。可使用具備至少一個可被施予真空的氣體移除室的加工機器。
適合的擠壓器及捏合機被敘述在例如Handbuch der Kunststoffextrusion,Vol.1 Grundlagen,Editors F.Hensen,W.Knappe,H.Potente,1989,pp.3-7,ISBN:3-446-14339-4(Vol.2 Extrusionsanlagen 1986,ISBN 3-446-14329-7)中。
例如,螺旋長度為1-60螺旋直徑,以35-48螺旋直徑較佳。螺旋的旋轉速度係以每分鐘計10-600轉(rpm)較佳,以25-300 rpm最特別佳。
最大的輸出量係依據螺旋直徑、旋轉速度及驅動力而定。本發明的方法也可藉由改變所述及的參數或使用輸送劑量的秤重機器而在小於最大輸出量的水平下進行。
如果加入數種組份時,則可將這些組份預混合或單獨加入。
在併入添加劑期間,聚合物必須接受一段足夠長時間的上升溫度。溫度通常大於聚合物的軟化點。
在本發明的方法較佳的具體實例中,使用低於280℃之溫度範圍,特別從約160℃至280℃。在特別佳的方法變體中,使用從約200℃至270℃之溫度範圍。
上述羥胺酯適合在化合期間較少聚丙烯、丙烯共聚物及聚丙烯摻合物的分子量,彼等會在化合期間影響聚合物鏈的降解。所提供的是例如具有窄的分子量分布的非常均勻之聚丙烯聚合物。該聚丙烯就駐極體應用而言極佳。
另一選擇地,併入也可在仍不會引起聚合物(潛伏化合物)分解的溫度下進行。以該方式所製備的聚合物接著可被加熱第二次及接受一段足夠長時間的上升溫度,使得發生所欲之聚合物降解。
在本發明的方法及組成物中,含有上述羥胺酯之化合物係以聚合物量為基準計從約0.001至5.0重量%之濃度存在,特別從0.01至2.0重量%,而以從0.02至1.0重量%特別佳。羥胺酯可以單獨的化合物或成為混合物加入聚合物中。
添加劑併入聚合物中可藉由例如使用在該方法技術中習知的方法使上述羥胺酯或其混合物及若有要求時更多的添加劑混合至聚合物中而進行。
也可將羥胺酯加入具有母料形式的聚合物中,其中這些化合物係以例如從約1.0至25.0重量%的濃度存在。本發明因此進一步提供其中本發明的化合物係以約1.0-25.0重量%的濃度存在且可加入熱塑性聚合物中的濃縮物。
本發明的另一觀點係共同使用特定的其它添加劑與本發明的羥胺酯。將這些特定的其它添加劑以與羥胺酯相同的方式併入。
例如,除了本發明的羥胺酯化合物之外,受阻胺光穩定劑(HALS)的穩定劑類別也有利於在本發明的方法及組成物中使用。
本發明的位阻胺穩定劑包括至少一部分的下式
其中虛線代表連接至基團及取代基之鍵;其中G1
、G2
、G3
、G4
及G5
獨立為1至8個碳原子之烷基,或G1
與G2
或G3
與G4
一起為五亞甲基。
受阻胺被揭示在例如美國專利申請案第5,004,770號、第5,204,473號、第5,096,950號、第5,300,544號、第5,112,890號、第5,124,378號、第5,145,893號、第5,216,156號、第5,844,026號、第5,980,783號、第6,046,304號、第6,117,995號、第6,271,377號、第6,297,299號、第6,392,041號、第6,376,584號與第6,472,456號及在2000年11月16日提出申請的美國申請案第09/714,717號與在2002年8月6日提出申請的美國申請案第10/485,377號中。
以上所引述之美國專利申請案第6,271,377號、第6,392,041號及第6,376,584號揭示受阻羥基烷氧胺穩定劑。
適合的受阻胺係選自由下列所組成的群組:1)1-環己氧基-2,2,6,6-四甲基-4-十八烷胺基六氫吡啶2)癸二酸雙(2,2,6,6-四甲基六氫吡啶-4-基)酯3)癸二酸雙(1-乙醯氧基-2,2,6,6-四甲基六氫吡啶-4-基)酯4)癸二酸雙(1,2,2,6,6-五甲基六氫吡啶-4-基)酯5)癸二酸雙(1-環己氧基-2,2,6,6-四甲基六氫吡啶-4-基)酯6)癸二酸雙(1-辛氧基-2,2,6,6-四甲基六氫吡啶-4-基)酯7)癸二酸雙(1-醯基-2,2,6,6-四甲基六氫吡啶-4-基)酯8)丙二酸雙(1,2,2,6,6-五甲基六氫吡啶-4-基)-正丁基-3,5-二-第三丁基-4-羥基苯甲酯9)2,4-雙[(1-環己氧基-2,2,6,6-四甲基六氫吡啶-4-基)丁胺基]-6-(2-羥乙基胺基-s-三10)己二酸雙(1-環己氧基-2,2,6,6-四甲基六氫吡啶-4-基)酯11)2,4-雙[(1-環己氧基-2,2,6,6-四甲基六氫吡啶-4-基)丁胺基]-6-氯基-s-三12)1-(2-羥基-2-甲基丙氧基)-4-羥基-2,2,6,6-四甲基六氫吡啶13)1-(2-羥基-2-甲基丙氧基)-4-酮基-2,2,6,6-四甲基六氫吡啶14)1-(2-羥基-2-甲基丙氧基)-4-十八烷醯氧基-2,2,6,6-四甲基六氫吡啶15)癸二酸雙(1-(2-羥基-2-甲基丙氧基)-2,2,6,6-四甲基六氫吡啶-4-基)酯16)己二酸雙(1-(2-羥基-2-甲基丙氧基)-2,2,6,6-四甲基六氫吡啶-4-基)酯17)2,4-雙{N-[1-(2-羥基-2-甲基丙氧基)-2,2,6,6-四甲基六氫吡啶-4-基]-N-丁胺基}-6-(2-羥乙基胺基)-s-三18)4-苯甲醯基-2,2,6,6-四甲基六氫吡啶19)丙二酸二-(1,2,2,6,6-五甲基六氫吡啶-4-基)-對-甲氧基亞苯甲酯20)4-硬脂醯氧基-2,2,6,6-四甲基六氫吡啶21)丁二酸雙(1-辛氧基-2,2,6,6-四甲基六氫吡啶基)酯22)1,2,2,6,6-五甲基-4-胺基六氫吡啶23)2-十一烷基-7,7,9,9-四甲基-1-氧雜-3,8-二氮雜-4-酮基螺旋[4,5]癸烷24)氮基三醋酸三(2,2,6,6-四甲基-4-六氫吡啶基)酯25)氮基三醋酸三(2-羥基-3-(胺基-(2,2,6,6-四甲基六氫吡啶-4-基)丙基)酯26)1,2,3,4-丁烷四羧酸四(2,2,6,6-四甲基-4-六氫吡啶基)酯27)1,2,3,4-丁烷四羧酸四(1,2,2,6,6-五甲基-4-六氫吡啶基)酯28)1,1’-(1,2-乙烷二基)-雙(3,3,5,5-四甲基-4-六氫吡酮)29)3-正辛基-7,7,9,9-四甲基-1,3,8-三氮雜螺旋[4,5]癸烷-2,4-二酮30)8-乙醯基-3-十二烷基-7,7,9,9-四甲基-1,3,8-三氮雜螺旋[4,5]癸烷-2,4-二酮31)3-十二烷基-1-(2,2,6,6-四甲基-4-六氫吡啶基)-吡咯啶-2,5-二酮32)3-十二烷基-1-(1,2,2,6,6-五甲基-4-六氫吡啶基)-吡咯啶-2,5-二酮33)N,N’-雙-甲醯基-N,N’-雙(2,2,6,6-四甲基-4-六氫吡啶基)六亞甲二胺34)2,4-雙[(1-環己氧基-2,2,6,6-六氫吡啶-4-基)丁胺基]-6-氯基-s-三與N,N’-雙(3-胺丙基)乙二胺之反應產物35)1-(2-羥乙基)-2,2,6,6-四甲基-4-羥基六氫吡啶與丁二酸之縮合物36)N,N’-雙(2,2,6,6-四甲基-4-六氫吡啶基)-六亞甲二胺與4-第三辛胺基-2,6-二氯基-1,3,5-三之直鏈或環型縮合物37)N,N’-雙(2,2,6,6-四甲基-4-六氫吡啶基)-六亞甲二胺與4-環己胺基-2,6-二氯基-1,3,5-三之直鏈或環型縮合物38)N,N’-雙(2,2,6,6-四甲基-4-六氫吡啶基)-六亞甲二胺與4-嗎啉基-2,6-二氯基-1,3,5-三之直鏈或環型縮合物39)N,N’-雙(1,2,2,6,6-五甲基-4-六氫吡啶基)-六亞甲二胺與4-嗎啉基-2,6-二氯基-1,3,5-三之直鏈或環型縮合物40)2-氯基-4,6-雙(4-正丁胺基-2,2,6,6-四甲基六氫吡啶基)-1,3,5-三與1,2-雙(3-胺丙基胺基)乙烷之縮合物41)2-氯基-4,6-雙(4-正丁胺基-1,2,2,6,6-五甲基六氫吡啶基)-1,3,5-三與1,2-雙(3-胺丙基胺基)乙烷之縮合物42)7,7,9,9-四甲基-2-環十一烷基-1-氧雜-3,8-二氮雜-4-酮基螺旋[4,5]癸烷與表氯醇之反應產物43)聚[甲基-(3-氧基-(2,2,6,6-四甲基六氫吡啶-4-基)丙基)]矽氧烷,CAS第182635-99-0號44)馬來酸酐-C18
-C22
-α-烯烴-共聚物與2,2,6,6-四甲基-4-胺基六氫吡啶之反應產物45)寡聚合化合物,其為4,4’-六亞甲基雙(胺基-2,2,6,6-四甲基六氫吡啶)與以2-氯基-4,6-雙(二丁胺基)-s-三末端封閉之2,4-二氯基-6-[(2,2,6,6-四甲基六氫吡啶-4-基)丁胺基]-s-三之縮合產物46)寡聚合化合物,其為4,4’-六亞甲基雙(胺基-1,2,2,6,6-五甲基六氫吡啶)與以2-氯基-4,6-雙(二丁胺基)-s-三末端封閉之2,4-二氯基-6-[(1,2,2,6,6-五甲基六氫吡啶-4-基)丁胺基]-s-三之縮合產物47)寡聚合化合物,其為4,4’-六亞甲基雙(胺基-1-丙氧基-2,2,6,6-四甲基六氫吡啶)與以2-氯基-4,6-雙(二丁胺基)-s-三末端封閉之2,4-二氯基-6-[(1-丙氧基-2,2,6,6-四甲基六氫吡啶-4-基)丁胺基]-s-三之縮合產物48)寡聚合化合物,其為4,4’-六亞甲基雙(胺基-1-醯氧基-2,2,6,6-四甲基六氫吡啶)與以2-氯基-4,6-雙(二丁胺基)-s-三末端封閉之2,4-二氯基-6-[(1-醯氧基-2,2,6,6-四甲基六氫吡啶-4-基)丁胺基]-s-三之縮合產物49)藉由以1,2-雙(3-胺丙基胺基)乙烷與三聚氯化氰反應所獲得的產物與2,2,6,6-四甲基六氫吡啶-4-基丁胺反應所獲得的產物。
也包括的是任何上述化合物的位阻N-H、N-甲基、N-甲氧基、N-丙氧基、N-辛氧基、N-環己氧基及N-(2-羥基-2-甲基丙氧基)類似物。
已知為羥苯基烷基膦酸酯或單酯之添加劑群組也有利於在本發明的方法及組成物中使用。羥苯基烷基膦酸酯或單酯被揭示在例如美國專利發表申請案第2004/0106767號中。羥苯基烷基膦酸酯或單酯具有下式
其中R6
為異丙基、第三丁基、環己基或被1-3個C1
-C4
烷基取代之環己基,R7
為氫、C1
-C4
烷基、環己基或被1-3個C1
-C4
烷基取代之環己基,R8
為C1
-C20
烷基、未被取代或被C1
-C4
烷基取代之苯基或萘基,R9
為氫、C1
-C20
烷基、未被取代或被C1
-C4
烷基取代之苯基或萘基,或對應於:;其中M+
為r-價金屬陽離子,p為1、2、3、4、5或6,及r為1、2或3。
例如,本發明的羥苯基烷基膦酸酯或單酯為式P1或P2化合物:
本發明的方法及組成物可進一步包括選自芳香族參-醯胺成核劑類別之添加劑。參-醯胺成核劑被揭示在例如2004年2月9日提出申請發表的美國申請案第2005/0203226號與第10/544,508號及在WO 2004/072168中。
芳香族三-醯胺具有例如下式
其中R1
、R2
及R3
彼此獨立為C1
-C20
烷基、被C1
-C10
烷胺基取代之C2
-C20
烷基、二(C1
-C10
烷基)胺基、C1
-C10
烷氧基或羥基、C3
-C20
烯基、C5
-C12
環烷基、被1-3個C1
-C10
烷基取代之C5
-C12
環烷基、環己基甲基、被1、2或3個C1
-C10
烷基取代之環己基甲基、C5
-C9
環烯基、被1-3個C1
-C10
烷基取代之C5
-C9
環烯基、苯基、被1-3個選自由C1
-C10
烷基、C1
-C10
烷氧基、羥基、鹵素、三鹵甲基、三鹵甲氧基、苯甲醯基、苯胺基、醯胺基及苯偶氮所組成的群組之取代基取代之苯基、C7
-C9
苯烷基、在苯基上被1-3個選自由C1
-C10
烷基、C1
-C10
烷氧基及羥基所組成的群組之取代基取代之C7
-C9
苯烷基、萘基、被C1
-C10
烷基取代之萘基、金鋼烷基或5至6員雜環基。
芳香族三-醯胺具有例如下式
其中R1
、R2
及R3
,或Y1
、Y2
及Y3
,或Z1
、Z2
及Z3
彼此獨立為未被取代或被1-3個羥基取代之C1
-C20
烷基;未被取代或被1-3個羥基取代之C2
-C20
烯基;由氧或硫間斷之C2
-C20
烷基;未被取代或被1-3個C1
-C20
烷基取代之C3
-C12
環烷基;未被取代或被1-3個C1
-C20
烷基取代之(C3
-C12
環烷基)-C1
-C10
烷基;未被取代或被1-3個C1
-C20
烷基取代之雙[C3
-C12
環烷基]-C1
-C10
烷基;未被取代或被1-3個C1
-C20
烷基取代之具有5至20個碳原子之雙環或三環烴基;未被取代或被1-3個選自由C1
-C20
烷基、C1
-C20
烷氧基、C1
-C20
烷胺基、二(C1
-C20
烷基)胺基、羥基及硝基所組成的群組之取代基取代之苯基;未被取代或被1-3個選自由C1
-C20
烷基、C3
-C12
環烷基、苯基、C1
-C20
烷氧基及羥基所組成的群組之取代基取代之苯基-C1
-C20
烷基;未被取代或被1-3個C1
-C20
烷基取代之苯基乙烯基;未被取代或被1-3個C1
-C20
烷基取代之聯苯基-(C1
-C10
烷基);未被取代或被1-3個C1
-C20
烷基取代之萘基;未被取代或被1-3個C1
-C20
烷基取代之萘基-C1
-C20
烷基;未被取代或被1-3個C1
-C20
烷基取代之萘氧基甲基;伸聯苯基;芴基;蒽基;未被取代或被1-3個C1
-C20
烷基取代之5-或6-員雜環基;含有至少一個鹵素之C1
-C20
烴基;或三(C1
-C10
烷基)矽基(C1
-C10
烷基);其先決條件係R1
、R2
及R3
,或Y1
、Y2
及Y3
,或Z1
、Z2
及Z3
中至少一者為未被取代或被至少一個羥基取代之支鏈C3
-C20
烷基;被氧或硫間斷之C2
-C20
烷基;未被取代或被1-3個C1
-C20
烷基取代之C3
-C12
環烷基;
未被取代或被1-3個C1
-C20
烷基取代之(C3
-C12
環烷基)-C1
-C10
烷基;未被取代或被1-3個C1
-C20
烷基取代之具有5至20個碳原子之雙環或三環烴基;未被取代或被1-3個選自由C1
-C20
烷基、C1
-C20
烷氧基、C1
-C20
烷胺基、二(C1
-C20
烷基)胺基、羥基及硝基所組成的群組之取代基取代之苯基;未被取代或被1-3個選自由C1
-C20
烷基、C3
-C12
環烷基、苯基、C1
-C20
烷氧基及羥基所組成的群組之取代基取代之苯基-C1
-C20
烷基;未被取代或被1-3個C1
-C20
烷基取代之聯苯基-(C1
-C10
烷基);未被取代或被1-3個C1
-C20
烷基取代之萘基-(C1
-C10
烷基);三(C1
-C10
烷基)矽基(C1
-C10
烷基)。
根據較佳的具體實例,R1
、R2
及R3
,或Y1
、Y2
及Y3
,或Z1
、Z2
及Z3
中至少一者為支鏈C3
-C20
烷基;或未被取代或被1-3個C1
-C20
烷基取代之C3
-C12
環烷基。
根據特別佳的具體實例,R1
、R2
及R3
,或Y1
、Y2
及Y3
,或Z1
、Z2
及Z3
中至少一者為支鏈C3
-C10
烷基。
更多的受阻胺光穩定劑、羥苯基烷基膦酸酯或單酯及芳香族參-醯胺成核劑添加劑係使用與本發明的羥胺酯相同的水平。
下列的實施例進一步說明本發明。所有的百分比係以重量百分比計,除非有其它另外的指示。
下列的受阻羥胺酯化合物係根據發表的美國申請案第2003/016494而製備。
,,,,,,,,,的聚合物。
將上述的羥胺酯化合物以0.05重量%之水平單獨地熔融化合在聚丙烯中。0.1重量份之硬脂酸鈣也被併入聚丙烯中。所得顆粒以熔噴法方式紡絲,獲得不織物。使不織物接受電暈處理。
不織物展現極佳的熱穩定性。不織物也長期抓住電荷,即不織物具有良好的電荷穩定性。
將具有35、25或12之熔融流動指數(MFI)的聚丙烯以轉筒混合,以包括以聚合物重量為基準計5.0重量%之位阻胺(HALS)、2.0重量%之位阻羥苯基烷基膦酸單酯(HPPME)或0.5重量%之芳香族參-醯胺(TA)。
將這些混合物使用Leistritz 27毫米雙螺旋擠壓器單獨地化合。將熔融物在水槽中冷卻,並將線束經由Conair-Jetro 340型造粒機轉化成小粒。所收集的小粒被認為是母料。將聚丙烯與適量的母料及本發明的受阻羥胺酯(HHAE)以轉筒混合,供每一次評估。轉筒混合係經由Marion Mixer SPS 1224,其為槳式慢速RPM混合機。這些被認為是最終的混合物。將每45公斤的最終混合物使用500毫米Reifenhuser熔噴試驗性管線(Melt Blowing Pilot Line)轉化成熔噴之不織紡織品。接著將聚丙烯網以電暈放電處理。
樣品係使用TSI過濾器測試儀(Filter Tester)(8130型)測試,其中使用100平方公分的試驗面積,將氯化鈉氣霧以每分鐘32公升噴霧。結果出現在下列的表中。
本發明的添加劑有效提供具有熱及電荷穩定性之聚丙烯,如以過濾效率及過濾效率損失所測量。
Claims (9)
- 一種製備具有增強的熱及電荷穩定性之駐極體組成物的方法,該方法包含熔融摻合熱塑性聚合物與有效穩定量之至少一種受阻羥胺酯化合物,該化合物包括至少一部分的式I
- 根據申請專利範圍第1項之製備駐極體組成物之方法,其中該熱塑性組成物為不織聚丙烯網。
- 根據申請專利範圍第1項之製備駐極體組成物之方法,其中該駐極處理為電暈處理。
- 根據申請專利範圍第1項之製備駐極體組成物之方法,其中該受阻羥胺酯化合物具有式IA
- 根據申請專利範圍第1項之製備駐極體組成物之方法,其中該受阻羥胺酯具有式IC
- 根據申請專利範圍第1項之製備駐極體組成物之方法,其中該受阻羥胺酯具有式IC
- 根據申請專利範圍第1項之製備駐極體組成物之方法,其中該受阻羥胺酯具有式IG
- 根據申請專利範圍第1項之製備駐極體組成物之方法,其中已於該熱塑性聚合物中進一步併入選自由受阻胺光穩定劑、羥苯基烷基膦酸酯或單酯及芳香族參-醯胺成核劑所組成的群組之添加劑。
- 一種藉由根據申請專利範圍第1項之方法所獲得的駐極體組成物。
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US20080249269A1 (en) * | 2007-04-05 | 2008-10-09 | Hui Chin | Electret materials |
JP5215411B2 (ja) * | 2007-12-06 | 2013-06-19 | スリーエム イノベイティブ プロパティズ カンパニー | 電荷強化添加剤を備えたエレクトレットウェブ |
JP5141526B2 (ja) * | 2008-01-21 | 2013-02-13 | Jnc株式会社 | フィルター |
WO2010123810A2 (en) * | 2009-04-21 | 2010-10-28 | Basf Performance Products Llc | Rotomolding process for polyethylene articles |
MX2013004669A (es) | 2010-10-25 | 2013-09-06 | Rick L Chapman | Materiales para filtracion utilizando mezclas de fibra que contienen fibras formadas estrategicamente y/o agentes para control de cargas. |
CA2909670A1 (en) * | 2013-04-19 | 2014-10-23 | 3M Innovative Properties Company | Electret webs with charge-enhancing additives |
JP2017094250A (ja) * | 2015-11-20 | 2017-06-01 | 東洋紡株式会社 | エレクトレット濾材、それを用いたフィルター、およびエレクトレット濾材の製造方法 |
CN109196155A (zh) * | 2016-05-31 | 2019-01-11 | 巴斯夫欧洲公司 | 由双组分纤维制成的非织造织物 |
JP2018095973A (ja) | 2016-12-08 | 2018-06-21 | 東レ株式会社 | メルトブロー不織布 |
JP6771591B2 (ja) | 2017-02-01 | 2020-10-21 | 株式会社ユポ・コーポレーション | エネルギー変換フィルム、及びこれを用いたエネルギー変換素子 |
US11081285B2 (en) | 2019-05-08 | 2021-08-03 | Deborah Duen Ling Chung | Electrically conductive electret and associated electret-based power source and self-powered structure |
WO2021111290A1 (en) * | 2019-12-03 | 2021-06-10 | 3M Innovative Properties Company | Aromatic-heterocyclic ring melt additives |
CN111560137B (zh) * | 2020-05-28 | 2020-10-16 | 金发科技股份有限公司 | 一种用于口罩熔喷无纺布的驻极母粒及其制备方法与应用 |
US20240009606A1 (en) | 2020-12-18 | 2024-01-11 | 3M Innovative Properties Company | Electrets comprising a substituted cyclotriphosphazene compound and articles therefrom |
EP4032598B1 (en) | 2021-01-21 | 2023-07-12 | Borealis AG | Polypropylene composition containing a new charge-stabilizing agent for electret melt blown webs |
WO2023074758A1 (ja) * | 2021-10-29 | 2023-05-04 | 東洋紡株式会社 | エレクトレット、エレクトレットフィルター、及びエレクトレットの製造方法 |
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US57710A (en) * | 1866-09-04 | Improvement in grain-binders | ||
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EP0365481A1 (en) * | 1988-10-19 | 1990-04-25 | Ciba-Geigy Ag | Polymeric substrates stabilized with N-substituted hindered amines |
JP3286998B2 (ja) * | 1992-01-08 | 2002-05-27 | 東レ株式会社 | 抗菌性エレクトレット材料 |
IT1273607B (it) * | 1995-04-26 | 1997-07-08 | Ciba Geigy Spa | Combinazione di stabilizzanti per polimeri sintetici organici |
US6123752A (en) | 1998-09-03 | 2000-09-26 | 3M Innovative Properties Company | High efficiency synthetic filter medium |
US6406657B1 (en) * | 1999-10-08 | 2002-06-18 | 3M Innovative Properties Company | Method and apparatus for making a fibrous electret web using a wetting liquid and an aqueous polar liquid |
US6743464B1 (en) | 2000-04-13 | 2004-06-01 | 3M Innovative Properties Company | Method of making electrets through vapor condensation |
US7030196B2 (en) | 2000-05-19 | 2006-04-18 | Ciba Specialty Chemicals Corporation | Process for reducing the molecular weight of polypropylene |
JP2002309099A (ja) * | 2001-04-09 | 2002-10-23 | Toyobo Co Ltd | エレクトレット材料 |
US6969484B2 (en) * | 2001-06-18 | 2005-11-29 | Toray Industries, Inc. | Manufacturing method and device for electret processed product |
JP4133830B2 (ja) * | 2002-01-11 | 2008-08-13 | 日本バイリーン株式会社 | エレクトレット体の製造方法及び製造装置 |
WO2003087211A2 (en) * | 2002-04-17 | 2003-10-23 | Ciba Specialty Chemicals Holding Inc. | Flame retardant polymer compositions containing hydroxylamine esters |
CA2577500C (en) * | 2004-09-09 | 2013-01-22 | Ciba Specialty Chemicals Holding Inc. | Degradation of polypropylene with hydroxylamine ester compositions |
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KR101360872B1 (ko) | 2014-02-11 |
TW200745242A (en) | 2007-12-16 |
US20100112886A1 (en) | 2010-05-06 |
JP2009533505A (ja) | 2009-09-17 |
US7666931B2 (en) | 2010-02-23 |
EP2005453B1 (en) | 2009-09-09 |
CN101421802A (zh) | 2009-04-29 |
ATE442658T1 (de) | 2009-09-15 |
US20070235903A1 (en) | 2007-10-11 |
ES2330691T3 (es) | 2009-12-14 |
JP5318751B2 (ja) | 2013-10-16 |
US7947767B2 (en) | 2011-05-24 |
WO2007115963A1 (en) | 2007-10-18 |
CN101421802B (zh) | 2011-06-08 |
KR20090006073A (ko) | 2009-01-14 |
DE602007002389D1 (de) | 2009-10-22 |
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