TWI378823B - Use of titanium dioxide mixtures for producing catalysts - Google Patents

Use of titanium dioxide mixtures for producing catalysts Download PDF

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Publication number
TWI378823B
TWI378823B TW094140707A TW94140707A TWI378823B TW I378823 B TWI378823 B TW I378823B TW 094140707 A TW094140707 A TW 094140707A TW 94140707 A TW94140707 A TW 94140707A TW I378823 B TWI378823 B TW I378823B
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TW
Taiwan
Prior art keywords
weight
catalyst
titanium dioxide
active composition
surface area
Prior art date
Application number
TW094140707A
Other languages
English (en)
Chinese (zh)
Other versions
TW200626232A (en
Inventor
Samuel Neto
Sebastian Storck
Juergen Zuehlke
Frank Rosowski
Original Assignee
Basf Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Ag filed Critical Basf Ag
Publication of TW200626232A publication Critical patent/TW200626232A/zh
Application granted granted Critical
Publication of TWI378823B publication Critical patent/TWI378823B/zh

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063Titanium; Oxides or hydroxides thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002Mixed oxides other than spinels, e.g. perovskite
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/20Vanadium, niobium or tantalum
    • B01J23/22Vanadium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/19Catalysts containing parts with different compositions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61Surface area
    • B01J35/61310-100 m2/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0215Coating
    • B01J37/0232Coating by pulverisation
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/255Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
    • C07C51/265Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting having alkyl side chains which are oxidised to carboxyl groups
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/31Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting
    • C07C51/313Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting with molecular oxygen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Furan Compounds (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
TW094140707A 2004-11-18 2005-11-18 Use of titanium dioxide mixtures for producing catalysts TWI378823B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE102004055807 2004-11-18

Publications (2)

Publication Number Publication Date
TW200626232A TW200626232A (en) 2006-08-01
TWI378823B true TWI378823B (en) 2012-12-11

Family

ID=35734926

Family Applications (1)

Application Number Title Priority Date Filing Date
TW094140707A TWI378823B (en) 2004-11-18 2005-11-18 Use of titanium dioxide mixtures for producing catalysts

Country Status (10)

Country Link
US (1) US7851398B2 (enExample)
EP (1) EP1814660A1 (enExample)
JP (1) JP5174462B2 (enExample)
KR (1) KR101308197B1 (enExample)
CN (1) CN101060927B (enExample)
BR (1) BRPI0517850A (enExample)
MX (1) MX2007005850A (enExample)
RU (1) RU2007122282A (enExample)
TW (1) TWI378823B (enExample)
WO (1) WO2006053732A1 (enExample)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10334132A1 (de) 2003-07-25 2005-04-07 Basf Ag Silber, Vanadium und ein Promotormetall enthaltendes Multimetalloxid und dessen Verwendung
DE102004026472A1 (de) * 2004-05-29 2005-12-22 Süd-Chemie AG Mehrlagen-Katalysator zur Herstellung von Phthalsäureanhydrid
WO2005115615A1 (de) * 2004-05-29 2005-12-08 Süd-Chemie AG Katalysator sowie verfahren zur herstellung von phthalsäureanhydrid
DE102005009473A1 (de) * 2005-03-02 2006-09-07 Süd-Chemie AG Mehrlagen-Katalysator zur Herstellung von Phthalsäureanhydrid
TWI376266B (en) * 2005-03-02 2012-11-11 Sued Chemie Ag Process for manufacture of a multiple layer catalyst for producing phthalic acid anhydride
MX2007014147A (es) * 2005-05-22 2008-03-18 Sued Chemie Ag Catalizador constituido de multiples capas para producir anhidrido ftalico.
WO2007116018A1 (de) * 2006-04-12 2007-10-18 Basf Se Katalysatorsystem zur herstellung von carbonsäuren und/oder carbonsäurenanhydriden
DE102008011011A1 (de) * 2008-02-01 2009-08-06 Breimair, Josef, Dr. Katalysator für die katalytische Gasphasenoxidation von aromatischen Kohlenwasserstoffen zu Aldehyden, Carbonsäuren und/oder Carbonsäureanhydriden, insbesondere zu Phthalsäureanhydrid
US20110230668A1 (en) * 2010-03-19 2011-09-22 Basf Se Catalyst for gas phase oxidations based on low-sulfur and low-calcium titanium dioxide
TW201138955A (en) * 2010-03-19 2011-11-16 Basf Se Catalyst for gas phase oxidations based on low-sulfur and low-calcium titanium dioxide
WO2012001620A1 (de) * 2010-06-30 2012-01-05 Basf Se Mehrlagenkatalysator zur herstellung von phthalsäureanhydrid und verfahren zur herstellung von phthalsäureanhydrid
US8652988B2 (en) 2011-04-27 2014-02-18 Celanese International Corporation Catalyst for producing acrylic acids and acrylates
US8642498B2 (en) * 2011-05-11 2014-02-04 Celanese International Corporation Catalysts for producing acrylic acids and acrylates
US8883672B2 (en) * 2011-09-16 2014-11-11 Eastman Chemical Company Process for preparing modified V-Ti-P catalysts for synthesis of 2,3-unsaturated carboxylic acids
US8669201B2 (en) * 2012-03-13 2014-03-11 Celanese International Corporation Catalyst for producing acrylic acids and acrylates
DE102013000648A1 (de) * 2013-01-16 2014-07-17 Clariant International Ltd. Verfahren zur Optimierung der Aktivmassenbeladung eines Phthalsäureanhydrid-Katalysators
JP6466429B2 (ja) 2013-06-26 2019-02-06 ビーエーエスエフ ソシエタス・ヨーロピアBasf Se 気相酸化反応器を始動するための方法

Family Cites Families (21)

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DE2005969A1 (en) 1970-02-10 1971-08-26 Badische Anilin & Soda Fabrik AG, 6700 Ludwigshafen Dicarboxylic acids/and acid anhydridespreparation by isothe - process
DE2106796C3 (de) * 1971-02-12 1981-09-24 Wacker-Chemie GmbH, 8000 München Verfahren zur Herstellung Festbettkatalysatoren mit einem Überzug aus Vanadiumpentoxid und Titandioxid
DE2925682A1 (de) * 1979-06-26 1981-01-29 Basf Ag Vanadinpentoxid, titandioxid, phosphor, rubidium und/oder caesium und ggf. zirkondioxid enthaltender traegerkatalysator
DE3114492A1 (de) 1981-04-10 1982-10-28 Degussa Ag, 6000 Frankfurt Zahnpflegemittel
JPS63253080A (ja) * 1987-04-10 1988-10-20 Nippon Steel Chem Co Ltd 無水フタル酸の製造方法
FR2678807A1 (fr) * 1991-07-09 1993-01-15 Rhone Poulenc Chimie Melanges aqueux homogenes, stables et versables et utilisation desdits melanges pour preparer des dispersions de substances insolubles dans l'eau.
US5235071A (en) * 1991-07-10 1993-08-10 Nippon Shokubai Co., Ltd. Catalyst for producing phthalic anhydride and process by using the same
EP0539878B1 (en) * 1991-10-25 1996-01-10 Nippon Shokubai Co., Ltd. Method for production of phthalic anhydride by vapor-phase oxidation of mixture of ortho-xylene with naphthalene
DE19519172A1 (de) * 1995-05-24 1996-11-28 Consortium Elektrochem Ind Trägerkatalysator für Gasphasenoxidationsreaktoren
TW415939B (en) * 1996-10-23 2000-12-21 Nippon Steel Chemical Co Gas-phase oxidization process and process for the preparation of phthalic anhydride
SE507313C2 (sv) 1997-02-25 1998-05-11 Neste Oy Förfarande för framställning av ftalsyraanhydrid
DE19707943C2 (de) * 1997-02-27 1999-07-08 Basf Ag Verfahren zur Herstellung von Phthalsäureanhydrid und Katalysator hierfür
DE19823262A1 (de) * 1998-05-26 1999-12-02 Basf Ag Verfahren zur Herstellung von Phthalsäureanhydrid
DE19824532A1 (de) 1998-06-03 1999-12-09 Basf Ag Verfahren zur Herstellung von Schalenkatalysatoren für die katalytische Gasphasenoxidation von aromatischen Kohlenwasserstoffen und so erhältliche Katalysatoren
DE19839001A1 (de) * 1998-08-27 2000-03-02 Basf Ag Schalenkatalysatoren für die katalytische Gasphasenoxidation von aromatischen Kohlenwasserstoffen
CN1280979A (zh) * 1999-06-24 2001-01-24 株式会社日本触媒 用于生产邻苯二甲酸酐的方法
JP4180316B2 (ja) * 2002-07-05 2008-11-12 日揮触媒化成株式会社 管状酸化チタン粒子および管状酸化チタン粒子の製造方法
DE10323818A1 (de) * 2003-05-23 2004-12-09 Basf Ag Katalysatorsysteme zur Herstellung von Phthalsäureanhydrid
DE10323461A1 (de) * 2003-05-23 2004-12-09 Basf Ag Herstellung von Aldehyden, Carbonsäuren und/oder Carbonsäureanhydriden mittels Vanadiumoxid, Titandioxid und Antimonoxid enthaltender Katalysatoren
DE10323817A1 (de) * 2003-05-23 2004-12-09 Basf Ag Verfahren zur Herstellung von Phthalsäureanhydrid
DE10335346A1 (de) * 2003-08-01 2005-02-24 Basf Ag Katalysator für Gasphasenoxidationen

Also Published As

Publication number Publication date
TW200626232A (en) 2006-08-01
RU2007122282A (ru) 2008-12-27
US20080064594A1 (en) 2008-03-13
EP1814660A1 (de) 2007-08-08
US7851398B2 (en) 2010-12-14
CN101060927B (zh) 2011-05-11
JP2008520418A (ja) 2008-06-19
MX2007005850A (es) 2007-06-15
KR101308197B1 (ko) 2013-09-13
CN101060927A (zh) 2007-10-24
JP5174462B2 (ja) 2013-04-03
WO2006053732A1 (de) 2006-05-26
KR20070086369A (ko) 2007-08-27
BRPI0517850A (pt) 2008-10-21

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