TWI377181B - - Google Patents
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- Publication number
- TWI377181B TWI377181B TW097139757A TW97139757A TWI377181B TW I377181 B TWI377181 B TW I377181B TW 097139757 A TW097139757 A TW 097139757A TW 97139757 A TW97139757 A TW 97139757A TW I377181 B TWI377181 B TW I377181B
- Authority
- TW
- Taiwan
- Prior art keywords
- glass
- mass
- alkali
- raw material
- base material
- Prior art date
Links
- 239000011521 glass Substances 0.000 claims description 290
- 239000002994 raw material Substances 0.000 claims description 88
- 239000000463 material Substances 0.000 claims description 69
- 239000006060 molten glass Substances 0.000 claims description 64
- 239000000203 mixture Substances 0.000 claims description 36
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 34
- 238000002844 melting Methods 0.000 claims description 29
- 230000008018 melting Effects 0.000 claims description 28
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 27
- 229910052796 boron Inorganic materials 0.000 claims description 27
- 239000002245 particle Substances 0.000 claims description 26
- 238000004519 manufacturing process Methods 0.000 claims description 25
- 239000008395 clarifying agent Substances 0.000 claims description 22
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims description 17
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 12
- 229910052782 aluminium Inorganic materials 0.000 claims description 10
- 229910052681 coesite Inorganic materials 0.000 claims description 10
- 229910052906 cristobalite Inorganic materials 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 10
- 229910052682 stishovite Inorganic materials 0.000 claims description 10
- 229910052905 tridymite Inorganic materials 0.000 claims description 10
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 8
- 229910002651 NO3 Inorganic materials 0.000 claims description 7
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 7
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 6
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 3
- 229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 claims description 3
- ZADPBFCGQRWHPN-UHFFFAOYSA-N boronic acid Chemical compound OBO ZADPBFCGQRWHPN-UHFFFAOYSA-N 0.000 claims description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 2
- 239000002131 composite material Substances 0.000 claims 4
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims 1
- 239000002585 base Substances 0.000 description 43
- 239000004576 sand Substances 0.000 description 20
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 15
- 229960002645 boric acid Drugs 0.000 description 15
- 235000010338 boric acid Nutrition 0.000 description 15
- 230000000694 effects Effects 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 229910052684 Cerium Inorganic materials 0.000 description 10
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 10
- 238000005352 clarification Methods 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 10
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 10
- 239000002253 acid Substances 0.000 description 9
- 238000004031 devitrification Methods 0.000 description 8
- 238000011156 evaluation Methods 0.000 description 8
- 239000007789 gas Substances 0.000 description 8
- 238000005191 phase separation Methods 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- 239000000758 substrate Substances 0.000 description 7
- 239000003513 alkali Substances 0.000 description 6
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 6
- 150000001342 alkaline earth metals Chemical class 0.000 description 6
- 229910000420 cerium oxide Inorganic materials 0.000 description 6
- 239000004973 liquid crystal related substance Substances 0.000 description 6
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 6
- VGTPKLINSHNZRD-UHFFFAOYSA-N oxoborinic acid Chemical compound OB=O VGTPKLINSHNZRD-UHFFFAOYSA-N 0.000 description 6
- 229910052712 strontium Inorganic materials 0.000 description 6
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 6
- 238000004220 aggregation Methods 0.000 description 5
- 230000002776 aggregation Effects 0.000 description 5
- 150000001341 alkaline earth metal compounds Chemical class 0.000 description 5
- 239000006063 cullet Substances 0.000 description 5
- 229910052697 platinum Inorganic materials 0.000 description 5
- 229910000272 alkali metal oxide Inorganic materials 0.000 description 4
- 150000008064 anhydrides Chemical class 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- 229910004298 SiO 2 Inorganic materials 0.000 description 3
- 239000004327 boric acid Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000005520 cutting process Methods 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 239000000156 glass melt Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 238000010583 slow cooling Methods 0.000 description 3
- 239000002344 surface layer Substances 0.000 description 3
- 238000009834 vaporization Methods 0.000 description 3
- 230000008016 vaporization Effects 0.000 description 3
- 229910018626 Al(OH) Inorganic materials 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 101100496858 Mus musculus Colec12 gene Proteins 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical compound [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 2
- 150000001639 boron compounds Chemical class 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 239000005357 flat glass Substances 0.000 description 2
- 150000002222 fluorine compounds Chemical class 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 229910021653 sulphate ion Inorganic materials 0.000 description 2
- XDVOLDOITVSJGL-UHFFFAOYSA-N 3,7-dihydroxy-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound O1B(O)OB2OB(O)OB1O2 XDVOLDOITVSJGL-UHFFFAOYSA-N 0.000 description 1
- 229910004261 CaF 2 Inorganic materials 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910019440 Mg(OH) Inorganic materials 0.000 description 1
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 1
- 229910052770 Uranium Inorganic materials 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052925 anhydrite Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000013077 target material Substances 0.000 description 1
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 description 1
- 238000009849 vacuum degassing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B5/00—Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
- C03B5/16—Special features of the melting process; Auxiliary means specially adapted for glass-melting furnaces
- C03B5/225—Refining
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/089—Glass compositions containing silica with 40% to 90% silica, by weight containing boron
- C03C3/091—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/50—Glass production, e.g. reusing waste heat during processing or shaping
- Y02P40/57—Improving the yield, e-g- reduction of reject rates
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Glass Compositions (AREA)
- Glass Melting And Manufacturing (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2007277802 | 2007-10-25 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW200927686A TW200927686A (en) | 2009-07-01 |
| TWI377181B true TWI377181B (https=) | 2012-11-21 |
Family
ID=40579420
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW097139757A TW200927686A (en) | 2007-10-25 | 2008-10-16 | Method for production of non-alkali glass |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JP5267464B2 (https=) |
| KR (1) | KR101489983B1 (https=) |
| CN (1) | CN101808951B (https=) |
| TW (1) | TW200927686A (https=) |
| WO (1) | WO2009054314A1 (https=) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8975199B2 (en) | 2011-08-12 | 2015-03-10 | Corsam Technologies Llc | Fusion formable alkali-free intermediate thermal expansion coefficient glass |
| CN102471134B (zh) * | 2009-07-02 | 2015-04-15 | 旭硝子株式会社 | 无碱玻璃及其制造方法 |
| JP2013147355A (ja) * | 2010-04-28 | 2013-08-01 | Asahi Glass Co Ltd | ガラス板の製造方法およびガラス板 |
| KR101752033B1 (ko) | 2010-12-07 | 2017-06-28 | 아사히 가라스 가부시키가이샤 | 무알칼리 유리 및 무알칼리 유리의 제조 방법 |
| WO2012090783A1 (ja) | 2010-12-27 | 2012-07-05 | 旭硝子株式会社 | 無アルカリガラスおよび無アルカリガラスの製造方法 |
| EP2716613B1 (en) * | 2011-05-25 | 2019-05-22 | AGC Inc. | Granules and method for their production, method for producing molten glass, and method for producing glass product |
| DE102012202695B4 (de) * | 2012-02-22 | 2015-10-22 | Schott Ag | Verfahren zur Herstellung von Gläsern und Glaskeramiken, LAS-Glas und LAS-Glaskeramiken und deren Verwendung |
| CN104136383B (zh) * | 2012-02-27 | 2016-09-28 | 旭硝子株式会社 | 无碱玻璃的制造方法 |
| WO2013145922A1 (ja) * | 2012-03-27 | 2013-10-03 | 旭硝子株式会社 | ガラス板の製造方法 |
| JP6376326B2 (ja) * | 2013-05-31 | 2018-08-22 | 日本電気硝子株式会社 | ガラス繊維組成物、ガラス繊維及びガラス繊維の製造方法 |
| JP6376325B2 (ja) * | 2013-06-21 | 2018-08-22 | 日本電気硝子株式会社 | ガラス繊維用組成物、ガラス繊維及びガラス繊維の製造方法 |
| KR102133339B1 (ko) * | 2013-09-20 | 2020-07-13 | 에이지씨 가부시키가이샤 | 무알칼리 유리 |
| JP2017007870A (ja) * | 2013-11-13 | 2017-01-12 | 旭硝子株式会社 | 板ガラスの製造方法 |
| JP7153241B2 (ja) * | 2017-09-05 | 2022-10-14 | 日本電気硝子株式会社 | 無アルカリガラス基板の製造方法及び無アルカリガラス基板 |
| WO2019093129A1 (ja) * | 2017-11-08 | 2019-05-16 | 日本電気硝子株式会社 | 無アルカリガラス基板の製造方法及び無アルカリガラス基板 |
| US12043566B2 (en) * | 2018-04-09 | 2024-07-23 | Nippon Sheet Glass Company, Limited | Glass fiber and method for producing the same |
| CN111606563A (zh) * | 2020-06-10 | 2020-09-01 | 河南新正方电子科技有限公司 | 一种抗摔钢化玻璃碗及其制备方法 |
| CN115087626A (zh) * | 2020-06-25 | 2022-09-20 | 日本电气硝子株式会社 | 低碱玻璃板的制造方法和低碱玻璃板 |
| JP7807724B2 (ja) * | 2020-07-08 | 2026-01-28 | 日本電気硝子株式会社 | ガラス、強化ガラス及び強化ガラスの製造方法 |
| CN116075487A (zh) * | 2020-09-10 | 2023-05-05 | 日本电气硝子株式会社 | 低碱玻璃板的制备方法和低碱玻璃板 |
| JP7623629B2 (ja) * | 2020-12-17 | 2025-01-29 | 日本電気硝子株式会社 | 無アルカリガラス基板の製造方法 |
| KR102931575B1 (ko) | 2021-07-07 | 2026-02-27 | 에이지씨 가부시키가이샤 | 투입 원료의 선정 장치 및 투입 원료의 선정 방법 |
| CN114477762B (zh) * | 2021-12-24 | 2024-03-15 | 中建材玻璃新材料研究院集团有限公司 | 一种无硼铝硅酸盐玻璃 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11310433A (ja) * | 1998-04-27 | 1999-11-09 | Central Glass Co Ltd | 表示装置用基板ガラス |
| DE19934072C2 (de) * | 1999-07-23 | 2001-06-13 | Schott Glas | Alkalifreies Aluminoborosilicatglas, seine Verwendungen und Verfahren zu seiner Herstellung |
| JP2004067408A (ja) | 2002-08-02 | 2004-03-04 | Nippon Electric Glass Co Ltd | 無アルカリガラスの製造方法 |
| JP2004091244A (ja) * | 2002-08-30 | 2004-03-25 | Nippon Electric Glass Co Ltd | 無アルカリガラス基板及びその製造方法 |
| JP4737709B2 (ja) * | 2004-03-22 | 2011-08-03 | 日本電気硝子株式会社 | ディスプレイ基板用ガラスの製造方法 |
| US20080090717A1 (en) * | 2004-12-16 | 2008-04-17 | Nippon Sheet Glass Company, Limited | Glass Composition And Process For Producing The Same |
| JP4946216B2 (ja) * | 2005-07-06 | 2012-06-06 | 旭硝子株式会社 | 無アルカリガラスの製造方法 |
-
2008
- 2008-10-16 CN CN2008801096803A patent/CN101808951B/zh active Active
- 2008-10-16 TW TW097139757A patent/TW200927686A/zh unknown
- 2008-10-16 JP JP2009538150A patent/JP5267464B2/ja active Active
- 2008-10-16 WO PCT/JP2008/068798 patent/WO2009054314A1/ja not_active Ceased
- 2008-10-16 KR KR1020107003470A patent/KR101489983B1/ko active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN101808951B (zh) | 2013-08-14 |
| JPWO2009054314A1 (ja) | 2011-03-03 |
| KR20100085900A (ko) | 2010-07-29 |
| CN101808951A (zh) | 2010-08-18 |
| KR101489983B1 (ko) | 2015-02-04 |
| WO2009054314A1 (ja) | 2009-04-30 |
| TW200927686A (en) | 2009-07-01 |
| JP5267464B2 (ja) | 2013-08-21 |
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