TWI365766B - Catalysts having enhanced stability, efficiency and/or activity for alkylene oxide production - Google Patents

Catalysts having enhanced stability, efficiency and/or activity for alkylene oxide production

Info

Publication number
TWI365766B
TWI365766B TW093131330A TW93131330A TWI365766B TW I365766 B TWI365766 B TW I365766B TW 093131330 A TW093131330 A TW 093131330A TW 93131330 A TW93131330 A TW 93131330A TW I365766 B TWI365766 B TW I365766B
Authority
TW
Taiwan
Prior art keywords
catalysts
activity
efficiency
alkylene oxide
enhanced stability
Prior art date
Application number
TW093131330A
Other languages
English (en)
Other versions
TW200523022A (en
Inventor
Thomas Szymanski
Juliana G Serafin
Seyed R Seyedmonir
Albert Cheng-Yu Liu
Hwaili Soo
Original Assignee
Dow Technology Investments Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=34520043&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=TWI365766(B) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Dow Technology Investments Llc filed Critical Dow Technology Investments Llc
Publication of TW200523022A publication Critical patent/TW200523022A/zh
Application granted granted Critical
Publication of TWI365766B publication Critical patent/TWI365766B/zh

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/50—Silver
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/683—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten
    • B01J23/686—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten with molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/688—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0203—Impregnation the impregnation liquid containing organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/612—Surface area less than 10 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/657—Pore diameter larger than 1000 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Epoxy Compounds (AREA)
  • Catalysts (AREA)
TW093131330A 2003-10-16 2004-10-15 Catalysts having enhanced stability, efficiency and/or activity for alkylene oxide production TWI365766B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US51197503P 2003-10-16 2003-10-16

Publications (2)

Publication Number Publication Date
TW200523022A TW200523022A (en) 2005-07-16
TWI365766B true TWI365766B (en) 2012-06-11

Family

ID=34520043

Family Applications (2)

Application Number Title Priority Date Filing Date
TW099126064A TWI433720B (zh) 2003-10-16 2004-10-15 具有增進之安定性、效率及／或活性以供製造氧化烯用的催化劑
TW093131330A TWI365766B (en) 2003-10-16 2004-10-15 Catalysts having enhanced stability, efficiency and/or activity for alkylene oxide production

Family Applications Before (1)

Application Number Title Priority Date Filing Date
TW099126064A TWI433720B (zh) 2003-10-16 2004-10-15 具有增進之安定性、效率及／或活性以供製造氧化烯用的催化劑

Country Status (10)

Country Link
US (5) US20070111886A1 (zh)
EP (2) EP1675678B1 (zh)
JP (2) JP4824569B2 (zh)
CN (3) CN101767039B (zh)
AR (1) AR046294A1 (zh)
AT (1) ATE526082T1 (zh)
CA (1) CA2541992C (zh)
RU (1) RU2360735C2 (zh)
TW (2) TWI433720B (zh)
WO (1) WO2005039757A1 (zh)

Families Citing this family (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SG177010A1 (en) * 2003-08-22 2012-01-30 Dow Technology Investments Llc Improved alumina carriers and silver-based catalysts for the production of alkylene oxides
CA2538989A1 (en) * 2003-08-22 2005-03-17 Union Carbide Chemicals & Plastics Technology Corporation Modified alumina carriers and silver-based catalysts for the production of alkylene oxides
EP1675678B1 (en) 2003-10-16 2011-09-28 Dow Technology Investments LLC Catalysts having enhanced stability, efficiency and/or activity for alkylene oxide production
RU2007101728A (ru) 2004-06-18 2008-07-27 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. (NL) Способ получения оксида олефина, 1,2-диола, 1,2-диолового эфира или алканоламина
TW200616989A (en) * 2004-06-18 2006-06-01 Shell Int Research A process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, or an alkanolamine
US8536083B2 (en) * 2004-09-01 2013-09-17 Shell Oil Company Olefin epoxidation process, a catalyst for use in the process, a carrier for use in preparing the catalyst, and a process for preparing the carrier
BRPI0514814A (pt) * 2004-09-01 2008-06-24 Shell Int Research processo de epoxidação de olefina, um catalisador para uso no processo, um veìculo para uso na preparação do catalisador, e processo para preparar o veìculo
JP5063367B2 (ja) * 2005-02-21 2012-10-31 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー オレフィンエポキシ化方法、この方法において使用する触媒、この触媒を作製する際に使用する担体、およびこの担体を作製する方法
US8791280B2 (en) * 2005-08-10 2014-07-29 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Process for preparation of catalyst carrier and its use in catalyst preparation
US8242045B2 (en) * 2006-01-12 2012-08-14 Siemens Energy, Inc. Ceramic wash-coat for catalyst support
US7932408B2 (en) * 2006-09-29 2011-04-26 Scientific Design Company, Inc. Catalyst with bimodal pore size distribution and the use thereof
US7977274B2 (en) 2006-09-29 2011-07-12 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Catalyst with bimodal pore size distribution and the use thereof
US20100056816A1 (en) * 2006-11-01 2010-03-04 Wallin Sten A Shaped porous bodies of alpha-alumina and methods for the preparation thereof
TWI446963B (zh) * 2007-05-09 2014-08-01 Shell Int Research 環氧化催化劑、製備該催化劑之方法及製備烯烴氧化物、１，２－二醇、１，２－二醇醚、１，２－碳酸酯或烷醇胺之方法
US10532989B2 (en) * 2007-05-09 2020-01-14 Shell Oil Company Epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine
US7507845B1 (en) * 2007-08-27 2009-03-24 Sd Lizenzverwertungsgesellschaft Mbh & Co Kg Process for production of an olefin oxide
US7910518B2 (en) * 2008-03-10 2011-03-22 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Geometrically sized solid shaped carrier for olefin epoxidation catalyst
EP2293872A1 (en) * 2008-04-30 2011-03-16 Dow Technology Investments LLC Porous body precursors, shaped porous bodies, processes for making them, and end-use products based upon the same
CN102015101B (zh) * 2008-04-30 2013-11-06 陶氏技术投资有限公司 多孔体前体,成形多孔体,它们的制备方法和基于它们的终端产品
WO2009134851A1 (en) * 2008-04-30 2009-11-05 Dow Technology Investments, Llc Porous body precursors, shaped porous bodies, processes for making them, and end-use products based upon the same
SG194340A1 (en) * 2009-04-21 2013-11-29 Dow Technology Investments Llc Epoxidation reactions and operating conditions thereof
CN102458651B (zh) * 2009-04-21 2015-06-10 陶氏技术投资有限公司 铼助催化的环氧化催化剂及其制造和使用方法
WO2010126680A2 (en) 2009-04-29 2010-11-04 Dow Technology Investments Llc Porous body precursors, shaped porous bodies, processes for making them, and end-use products based upon the same
US8586769B2 (en) * 2010-06-04 2013-11-19 Scientific Design Company, Inc. Carrier for ethylene oxide catalysts
US20120304620A1 (en) * 2011-06-01 2012-12-06 Aerojet-General Corporation Catalyst, gas generator, and thruster with improved thermal capability and corrosion resistance
JP2013193040A (ja) * 2012-03-21 2013-09-30 Nippon Shokubai Co Ltd エチレンオキシド製造用触媒およびそれを用いたエチレンオキシド製造方法
WO2013148417A1 (en) 2012-03-27 2013-10-03 Dow Technology Investments Llc Method of making a manganese containing supported silver catalyst intermediate
KR101481479B1 (ko) * 2012-06-29 2015-01-13 한국에너지기술연구원 세라믹 다공체의 제조방법 및 세라믹 다공체 제조용 조성물
EP2938435A4 (en) 2012-12-31 2016-10-05 Scient Design Co CALCINATION PROCESS FOR PREPARING AN IMPROVED ETHYLENE OXIDE CATALYST
CN113603658A (zh) * 2015-08-28 2021-11-05 利安德化学技术有限公司 环氧化工艺及其使用的催化剂
WO2019154863A1 (en) 2018-02-07 2019-08-15 Basf Se Method for preparing a silver impregnation solution
EP3639923A1 (en) 2018-10-15 2020-04-22 Basf Se Process for producing ethylene oxide by gas-phase oxidation of ethylene
EP3639924A1 (en) 2018-10-15 2020-04-22 Basf Se Catalyst for producing ethylene oxide by gas-phase oxidation
ZA201906807B (en) * 2018-11-21 2020-07-29 Indian Oil Corp Ltd Highly active catalyst for dehydrogenation of alkanes and method of preparation thereof
EP3659703A1 (en) 2018-11-28 2020-06-03 Basf Se Catalyst for producing ethylene oxide by gas-phase oxidation
CN112007625B (zh) * 2019-05-28 2023-05-30 中国石油化工股份有限公司 一种α-氧化铝载体及制备方法和银催化剂与应用
TW202239752A (zh) 2020-12-29 2022-10-16 荷蘭商蜆殼國際研究所 用於生產環氧乙烷之製程
CA3224814A1 (en) 2021-07-15 2023-01-19 Karena SMOLL Alkylene oxide catalyst that can be manufactured rapidly in one step

Family Cites Families (91)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20370A (en) 1858-05-25 rands
US2040782A (en) 1936-05-12 Manufacture of olefine oxides
US2294383A (en) * 1942-09-01 Process for the preparation of
USRE20370E (en) 1937-05-18 Process for the production of
US2209908A (en) * 1938-07-14 1940-07-30 Calorider Corp Contact mass for use in the catalytic vapor phase oxidation of organic compounds
US2177361A (en) * 1939-06-22 1939-10-24 Us Ind Alcohol Co Production of olefin oxides
US2593097A (en) * 1950-12-09 1952-04-15 Ethyl Corp Zirconium oxide-silicon oxide silver catalyst support and process using the same
NL7015145A (zh) * 1969-10-29 1971-05-04
US3962136A (en) * 1972-01-07 1976-06-08 Shell Oil Company Catalyst for production of ethylene oxide
US3950507A (en) * 1974-03-19 1976-04-13 Boreskov Georgy Konstantinovic Method for producing granulated porous corundum
DE2967112D1 (en) 1978-02-10 1984-08-23 Ici Plc Production of olefine oxides
US4916243A (en) 1979-03-20 1990-04-10 Union Carbide Chemicals And Plastics Company Inc. New catalyst composition and process for oxidation of ethylene to ethylene oxide
US4318896A (en) * 1980-04-14 1982-03-09 Uop Inc. Manufacture of alumina particles
US4379134A (en) 1981-02-13 1983-04-05 Union Carbide Corporation Process of preparing high purity alumina bodies
HU185474B (en) * 1981-11-10 1985-02-28 Almasfuezitoei Timfoeldgyar Process for preparing alpha-aluminium oxyde poor in alkali for ceramic purposes
US4428863A (en) * 1982-07-06 1984-01-31 The Dow Chemical Company Alumina compositions of improved strength useful as catalyst supports
US4845296A (en) * 1983-12-13 1989-07-04 Union Carbide Corporation Process for preparing alkanolamines
GB8423044D0 (en) * 1984-09-12 1984-10-17 Ici Plc Production of ethylene oxide
US4650782A (en) * 1984-11-21 1987-03-17 Allied Corporation Lead-tolerant catalyst for treating exhaust gas in the presence of SO2
US4994587A (en) * 1985-08-12 1991-02-19 Union Carbide Chemicals And Plastics Company, Inc. Catalytic system for epoxidation of alkenes employing low sodium catalyst supports
US4994589A (en) * 1985-08-13 1991-02-19 Union Carbide Chemicals And Plastics Company Inc. Catalytic system for epoxidation of alkenes
US4994588A (en) 1985-08-13 1991-02-19 Union Carbide Chemicals And Plastics Company Inc. Fluorine-containing catalytic system for expoxidation of alkenes
NL8502993A (nl) 1985-11-01 1987-06-01 Dow Chemical Nederland Zilverkatalysator, alsmede werkwijze voor de bereiding daarvan.
US4615875A (en) * 1986-02-03 1986-10-07 Allied Corporation Process for preparing high purity alpha-alumina
GB8610441D0 (en) * 1986-04-29 1986-06-04 Shell Int Research Preparation of silver-containing catalyst
GB8611121D0 (en) * 1986-05-07 1986-06-11 Shell Int Research Silver catalyst
JPH084745B2 (ja) 1986-05-09 1996-01-24 三菱化学株式会社 エチレンオキシド製造用銀触媒
GB2190855A (en) 1986-05-28 1987-12-02 Shell Int Research Process for the preparation of a silver-containing catalyst
US4847064A (en) 1987-12-23 1989-07-11 Aluminum Company Of America Economical process for alpha alumina production
IL84232A (en) 1986-10-31 1992-06-21 Shell Int Research Catalyst and process for the catalytic production of ethylene oxide
US4761394A (en) * 1986-10-31 1988-08-02 Shell Oil Company Ethylene oxide catalyst and process for preparing the catalyst
US4766105A (en) * 1986-10-31 1988-08-23 Shell Oil Company Ethylene oxide catalyst and process for preparing the catalyst
GB8626687D0 (en) 1986-11-07 1986-12-10 Shell Int Research Preparing silver catalyst
US4908343A (en) * 1987-02-20 1990-03-13 Union Carbide Chemicals And Plastics Company Inc. Catalyst composition for oxidation of ethylene to ethylene oxide
US5057481A (en) * 1987-02-20 1991-10-15 Union Carbide Chemicals And Plastics Technology Corporation Catalyst composition for oxidation of ethylene to ethylene oxide
CN1009437B (zh) 1988-02-03 1990-09-05 中国石油化工总公司 乙烯氧化制环氧乙烷高效银催化剂
US4888317A (en) * 1988-07-15 1989-12-19 Corning Incorporated Catalyst-agglomerate bodies encapsulated in a structure and method for their production
US4912077A (en) * 1988-07-15 1990-03-27 Corning Incorporated Catalytically active materials and method for their preparation
CA1339317C (en) 1988-07-25 1997-08-19 Ann Marie Lauritzen Process for producing ethylene oxide
CA1337722C (en) * 1989-04-18 1995-12-12 Madan Mohan Bhasin Alkylene oxide catalysts having enhanced activity and/or stability
US5015614A (en) * 1989-07-03 1991-05-14 Exxon Research And Engineering Company Novel alumina support materials
US5051395A (en) * 1989-09-25 1991-09-24 Union Carbide Chemicals And Plastics Technology Corporation Alkylene oxide catalysts having enhanced activity and/or efficiency
US5187140A (en) * 1989-10-18 1993-02-16 Union Carbide Chemicals & Plastics Technology Corporation Alkylene oxide catalysts containing high silver content
US5248557A (en) * 1990-12-07 1993-09-28 E. I. Du Pont De Nemours And Company Coated refractory composition and method for making the same
US5187241A (en) * 1990-05-15 1993-02-16 International Business Machines Corporation Isoimide modifications of a polyimide and reaction thereof with nucleophiles
AU639326B2 (en) * 1990-05-23 1993-07-22 Atochem Ceramic preforms comprising monocrystalline hexagonal platelets of alpha-alumina, their production and applications thereof
ATE170425T1 (de) * 1990-10-12 1998-09-15 Union Carbide Chem Plastic Alkylenoxid-katalysator mit verbesserter aktivität und/oder stabilität
JPH04298241A (ja) 1990-10-12 1992-10-22 Union Carbide Chem & Plast Co Inc 向上した安定性を有する超高性能アルキレンオキシド触媒
US5100859A (en) 1991-01-22 1992-03-31 Norton Company Catalyst carrier
US5145824A (en) * 1991-01-22 1992-09-08 Shell Oil Company Ethylene oxide catalyst
US5242551A (en) * 1991-03-28 1993-09-07 International Business Machines Corporation Electron induced transformation of an isoimide to an n-imide and uses thereof
JPH04329279A (ja) * 1991-04-30 1992-11-18 Yamaichi Electron Co Ltd 電気部品用ソケット
JP3744010B2 (ja) * 1993-06-30 2006-02-08 住友化学株式会社 α−アルミナ粉末の製造方法
RU2129465C1 (ru) 1993-07-07 1999-04-27 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Катализатор эпоксидирования и способ его получения
US5384302A (en) 1993-09-08 1995-01-24 Norton Chemical Process Products Corp. Catalyst carrier
US5380697A (en) * 1993-09-08 1995-01-10 Shell Oil Company Ethylene oxide catalyst and process
DE69510989T2 (de) 1994-04-28 2000-01-20 Sumitomo Chemical Co Verfahren zur Herstellung von Alpha-Aluminiumoxidpulver
AUPN053395A0 (en) 1995-01-12 1995-02-09 Alcoa Of Australia Limited Production of alpha alumina
US5739075A (en) * 1995-10-06 1998-04-14 Shell Oil Company Process for preparing ethylene oxide catalysts
US5733842A (en) * 1996-04-30 1998-03-31 Norton Checmical Process Products Corporation Method of making porous catalyst carrier without the addition of pore forming agents
US5801259A (en) 1996-04-30 1998-09-01 Shell Oil Company Ethylene oxide catalyst and process
US5981427A (en) * 1996-09-04 1999-11-09 Engelhard Corporation Catalyst composition
US5703001A (en) 1996-10-25 1997-12-30 Scientific Design Company, Inc. Promoted silver catalyst
US5780656A (en) * 1997-04-14 1998-07-14 Scientific Design Company, Inc. Ethylene oxide catalyst and process
CN1101272C (zh) 1997-11-12 2003-02-12 中国石油化工集团公司北京燕山石油化工公司研究院 一种氧化铝载体的制造方法及其用途
US6350421B1 (en) * 1998-08-24 2002-02-26 Dmc2 Degussa Metals Catalysts Cerdec Ag Nitrogen oxide storage material and nitrogen oxide storing catalyst prepared therefrom
JP4794042B2 (ja) 1998-09-14 2011-10-12 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー オレフィンの気相エポキシ化用触媒、およびその調製
KR100572966B1 (ko) 1998-09-14 2006-04-24 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 촉매 성질 개선을 위해 촉매 표면으로부터 이온성 종의제거방법
CA2343784C (en) 1998-09-14 2007-11-13 Shell Internationale Research Maatschappij B.V. Process for preparing epoxidation catalysts with improved properties
CN100349660C (zh) * 1998-10-19 2007-11-21 Toto株式会社 防污性材料、其制造方法及用于该方法的涂料组合物和装置
AU754631B2 (en) 1998-11-17 2002-11-21 Nippon Shokubai Co., Ltd. Carrier for catalyst for use in production of ethylene oxide, catalyst for use in production of ethylene oxide, and method for production of ethylene oxide
US6203773B1 (en) * 1999-07-12 2001-03-20 Alcoa Inc. Low temperature mineralization of alumina
US6417136B2 (en) * 1999-09-17 2002-07-09 Phillips Petroleum Company Hydrocarbon hydrogenation catalyst and process
DE19959525A1 (de) 1999-12-09 2001-06-13 Bayer Ag Katalysatoren auf Basis Edelmetall- und Titan-haltiger, organisch-anorganisch Hybridmaterialien zur selektiven Oxidation von Kohlenwasserstoffen
DE10023717A1 (de) 2000-05-17 2001-11-22 Bayer Ag Formkörper, Verfahren zu dessen Herstellung und Verwendung dieser Formkörper zur selektiven Oxidation von Kohlenwasserstoffen
DE10137784A1 (de) 2001-08-02 2003-02-13 Bayer Ag Verfahren zur Herstellung von Alkenoxiden aus Alkenen
JP4050041B2 (ja) * 2001-11-06 2008-02-20 株式会社日本触媒 酸化エチレン製造用触媒、その製造方法および当該触媒による酸化エチレンの製造方法
MXPA04004639A (es) 2001-11-20 2005-05-17 Shell Int Research Proceso y sistema para la epoxidacion de una olefina.
AU2003217756B2 (en) * 2002-02-25 2008-11-20 Shell Internationale Research Maatschappij B.V. Supported silver catalyst and an epoxidation process using the catalyst
US6831037B2 (en) 2002-02-25 2004-12-14 Saint-Gobain Norpro Corporation Catalyst carriers
US6667270B2 (en) * 2002-05-22 2003-12-23 Shell Oil Company Bismuth-and phosphorus-containing catalyst support, reforming catalysts made from same, method of making and naphtha reforming process
CN1175932C (zh) 2002-07-10 2004-11-17 中国石油化工股份有限公司 乙烯环氧化银催化剂的制备方法
US7341976B2 (en) * 2002-10-16 2008-03-11 Conocophillips Company Stabilized boehmite-derived catalyst supports, catalysts, methods of making and using
CA2538989A1 (en) 2003-08-22 2005-03-17 Union Carbide Chemicals & Plastics Technology Corporation Modified alumina carriers and silver-based catalysts for the production of alkylene oxides
SG177010A1 (en) 2003-08-22 2012-01-30 Dow Technology Investments Llc Improved alumina carriers and silver-based catalysts for the production of alkylene oxides
EP1675678B1 (en) 2003-10-16 2011-09-28 Dow Technology Investments LLC Catalysts having enhanced stability, efficiency and/or activity for alkylene oxide production
TW200616989A (en) * 2004-06-18 2006-06-01 Shell Int Research A process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, or an alkanolamine
RU2007101728A (ru) * 2004-06-18 2008-07-27 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. (NL) Способ получения оксида олефина, 1,2-диола, 1,2-диолового эфира или алканоламина
BRPI0514814A (pt) * 2004-09-01 2008-06-24 Shell Int Research processo de epoxidação de olefina, um catalisador para uso no processo, um veìculo para uso na preparação do catalisador, e processo para preparar o veìculo
CN100408169C (zh) 2005-01-11 2008-08-06 中国石化北京燕化石油化工股份有限公司 用于生产环氧乙烷的银催化剂、其制备方法及其应用
JP5063367B2 (ja) 2005-02-21 2012-10-31 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー オレフィンエポキシ化方法、この方法において使用する触媒、この触媒を作製する際に使用する担体、およびこの担体を作製する方法

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US20090291847A1 (en) 2009-11-26
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