TWI341219B - Catalyst for producing methacrylic acid and preparation method thereof - Google Patents

Catalyst for producing methacrylic acid and preparation method thereof

Info

Publication number
TWI341219B
TWI341219B TW093104115A TW93104115A TWI341219B TW I341219 B TWI341219 B TW I341219B TW 093104115 A TW093104115 A TW 093104115A TW 93104115 A TW93104115 A TW 93104115A TW I341219 B TWI341219 B TW I341219B
Authority
TW
Taiwan
Prior art keywords
catalyst
preparation
methacrylic acid
producing methacrylic
producing
Prior art date
Application number
TW093104115A
Other languages
English (en)
Other versions
TW200425951A (en
Inventor
Atsushi Sudo
Yoshimasa Seo
Hideki Sugi
Original Assignee
Nippon Kayaku Kk
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Kayaku Kk filed Critical Nippon Kayaku Kk
Publication of TW200425951A publication Critical patent/TW200425951A/zh
Application granted granted Critical
Publication of TWI341219B publication Critical patent/TWI341219B/zh

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/24—Nitrogen compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8877—Vanadium, tantalum, niobium or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198—Vanadium
    • B01J27/199—Vanadium with chromium, molybdenum, tungsten or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0219—Coating the coating containing organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0221—Coating of particles

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
TW093104115A 2003-02-20 2004-02-19 Catalyst for producing methacrylic acid and preparation method thereof TWI341219B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2003042259 2003-02-20

Publications (2)

Publication Number Publication Date
TW200425951A TW200425951A (en) 2004-12-01
TWI341219B true TWI341219B (en) 2011-05-01

Family

ID=32905345

Family Applications (1)

Application Number Title Priority Date Filing Date
TW093104115A TWI341219B (en) 2003-02-20 2004-02-19 Catalyst for producing methacrylic acid and preparation method thereof

Country Status (11)

Country Link
US (1) US7825061B2 (zh)
EP (2) EP1595600B1 (zh)
JP (1) JP4478107B2 (zh)
KR (1) KR100972813B1 (zh)
CN (1) CN100457264C (zh)
BR (1) BRPI0407442A (zh)
MX (1) MXPA05008754A (zh)
MY (1) MY144325A (zh)
TW (1) TWI341219B (zh)
WO (1) WO2004073857A1 (zh)
ZA (1) ZA200507363B (zh)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI341219B (en) * 2003-02-20 2011-05-01 Nippon Kayaku Kk Catalyst for producing methacrylic acid and preparation method thereof
JP4756890B2 (ja) 2005-03-29 2011-08-24 日本化薬株式会社 メタクリル酸製造用触媒及びその製造方法
JP2006314923A (ja) * 2005-05-12 2006-11-24 Nippon Kayaku Co Ltd メタクリル酸製造用触媒の製造方法
US7732367B2 (en) * 2005-07-25 2010-06-08 Saudi Basic Industries Corporation Catalyst for methacrolein oxidation and method for making and using same
US7273829B2 (en) * 2005-12-22 2007-09-25 Saudi Basic Industries Corporation Catalyst for oxidation of saturated and unsaturated aldehydes to unsaturated carboxylic acid, method of making and method of using thereof
JP5090796B2 (ja) * 2007-06-08 2012-12-05 三菱レイヨン株式会社 メタクリル酸製造用触媒及びその製造方法並びにメタクリル酸の製造方法
JP5574434B2 (ja) * 2008-11-06 2014-08-20 日本化薬株式会社 メタクリル酸の製造方法及びメタクリル酸製造用触媒
JP5570142B2 (ja) * 2009-05-26 2014-08-13 日本化薬株式会社 メタクリル酸製造触媒の製造方法およびメタクリル酸の製造方法
US8481448B2 (en) * 2010-07-19 2013-07-09 Saudi Basic Industries Corporation Catalyst for oxidation of saturated and unsaturated aldehydes to unsaturated carboxylic acid, method of making and method of using thereof
JP2012110806A (ja) * 2010-11-22 2012-06-14 Nippon Kayaku Co Ltd メタクリル酸製造触媒の製造方法およびメタクリル酸の製造方法
JP2011152543A (ja) * 2011-04-28 2011-08-11 Nippon Kayaku Co Ltd メタクリル酸製造用触媒の製造方法
JP5973999B2 (ja) * 2011-11-17 2016-08-23 日本化薬株式会社 メタクリル酸製造用触媒及びそれを用いたメタクリル酸の製造方法
WO2013172414A1 (ja) * 2012-05-18 2013-11-21 日本化薬株式会社 メタクリル酸製造用触媒、その製造方法及び該触媒を用いるメタクリル酸の製造方法
US9751822B2 (en) * 2013-10-10 2017-09-05 Nippon Kayaku Kabushiki Kaisha Method for producing unsaturated carboxylic acid and supported catalyst
WO2015163020A1 (ja) * 2014-04-22 2015-10-29 株式会社ダイセル アルデヒド類製造用固体触媒、及びアルデヒド類の製造方法
CN104001543B (zh) * 2014-06-09 2016-08-03 中国科学院过程工程研究所 一种甲基丙烯醛氧化制甲基丙烯酸的催化剂及其制备方法
EP3892367A1 (en) 2020-04-09 2021-10-13 Röhm GmbH A tube bundle reactor and method for the production of methacrylic acid through the partial oxidation of methacrolein
CN111871418B (zh) * 2020-06-29 2023-05-26 润泰化学（泰兴）有限公司 一种用于甲醇乙醇一步法合成异丁醛的包覆型纳米催化剂及制备方法

Family Cites Families (24)

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DE2460541C3 (de) * 1973-12-29 1979-10-18 Nippon Shokubai Kagaku Kogyo Co. Ltd., Osaka (Japan) Phosphor, Molybdän und Vanadium sowie gegebenenfalls Kupfer, Kobalt, Zirkon, Wismut, Antimon und/oder Arsen enthaltender Oxydkatalysator und dessen Verwendung zur Herstellung von Methacrylsäure
US4136110A (en) * 1975-08-18 1979-01-23 The Standard Oil Company Process for the preparation of unsaturated acids from unsaturated aldehydes
JPS552619A (en) * 1978-06-21 1980-01-10 Nippon Kayaku Co Ltd Preparation of methacrylic acid and catalyst
JPS55124734A (en) * 1979-03-22 1980-09-26 Nippon Kayaku Co Ltd Preparation of methacrylic acid
JPS5811416A (ja) 1981-07-15 1983-01-22 Shinko Electric Co Ltd 移送装置
JPS5924140A (ja) 1982-07-29 1984-02-07 Matsushita Electric Ind Co Ltd 熱交換器
JPS59115750A (ja) * 1982-12-22 1984-07-04 Nippon Shokubai Kagaku Kogyo Co Ltd メタクリル酸合成用触媒
GB2177875A (en) 1985-07-08 1987-01-28 Philips Electronic Associated Radio transmission system
JPS6230177A (ja) 1985-07-31 1987-02-09 Nitto Electric Ind Co Ltd 樹脂製補強材
JP3101821B2 (ja) 1990-02-15 2000-10-23 三菱レイヨン株式会社 メタクリル酸製造用触媒の調製法
JPH047037A (ja) * 1990-04-23 1992-01-10 Mitsubishi Rayon Co Ltd メタクリル酸製造用触媒の調製法
JPH0531368A (ja) 1990-11-14 1993-02-09 Mitsui Toatsu Chem Inc メタクリル酸製造用触媒及びメタクリル酸の製造方法
JP3120484B2 (ja) * 1991-08-28 2000-12-25 株式会社日立製作所 受変電装置
JPH08196908A (ja) 1995-01-24 1996-08-06 Mitsui Toatsu Chem Inc メタクリル酸製造用触媒及びメタクリル酸の製造方法
US6043184A (en) * 1998-01-05 2000-03-28 Sunoco, Inc. (R&M) Heteropoly acids supported on polyoxometallate salts and their preparation
JP3765664B2 (ja) 1998-02-13 2006-04-12 三井化学株式会社 メタクリル酸製造用触媒及びメタクリル酸の製造方法
JPH11226412A (ja) 1998-02-17 1999-08-24 Mitsubishi Rayon Co Ltd メタクリル酸製造用触媒の製造方法およびメタクリル酸の製造方法
JP3995381B2 (ja) 1999-02-08 2007-10-24 三菱レイヨン株式会社 メタクリル酸製造用触媒およびメタクリル酸の製造方法
JP3767309B2 (ja) 2000-03-07 2006-04-19 住友化学株式会社 ヘテロポリ酸系触媒の製造方法およびメタクリル酸の製造方法
JP3763246B2 (ja) * 2000-04-06 2006-04-05 住友化学株式会社 ヘテロポリ酸系触媒の再生方法およびメタクリル酸の製造方法
JP4671320B2 (ja) * 2000-09-21 2011-04-13 日本化薬株式会社 メタクリル酸製造用被覆触媒の製法
CZ2003731A3 (cs) 2000-09-21 2003-10-15 Nippon Kayaku Kabushiki Kaisha Katalyzátor pro výrobu kyseliny methakrylové, potažený katalyzátor a způsob jeho výroby
TWI341219B (en) * 2003-02-20 2011-05-01 Nippon Kayaku Kk Catalyst for producing methacrylic acid and preparation method thereof
EP1629889B1 (en) * 2003-05-30 2012-05-02 Nippon Kayaku Kabushiki Kaisha Process for producing catalyst for methacrylic acid production

Also Published As

Publication number Publication date
TW200425951A (en) 2004-12-01
EP1595600A1 (en) 2005-11-16
CN1750878A (zh) 2006-03-22
MXPA05008754A (es) 2005-10-05
US7825061B2 (en) 2010-11-02
EP1595600B1 (en) 2014-06-25
KR100972813B1 (ko) 2010-07-28
CN100457264C (zh) 2009-02-04
EP1595600A4 (en) 2007-03-21
JP4478107B2 (ja) 2010-06-09
BRPI0407442A (pt) 2006-01-31
JPWO2004073857A1 (ja) 2006-06-01
KR20050098919A (ko) 2005-10-12
US20060154811A1 (en) 2006-07-13
EP2374538A1 (en) 2011-10-12
WO2004073857A1 (ja) 2004-09-02
ZA200507363B (en) 2006-10-25
MY144325A (en) 2011-08-29

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MM4A Annulment or lapse of patent due to non-payment of fees