TWI292408B - Class fiber reinforced polyurethane/polyisocyanurate foam - Google Patents
Class fiber reinforced polyurethane/polyisocyanurate foam Download PDFInfo
- Publication number
- TWI292408B TWI292408B TW095104891A TW95104891A TWI292408B TW I292408 B TWI292408 B TW I292408B TW 095104891 A TW095104891 A TW 095104891A TW 95104891 A TW95104891 A TW 95104891A TW I292408 B TWI292408 B TW I292408B
- Authority
- TW
- Taiwan
- Prior art keywords
- foam
- polyol
- glass fiber
- reinforced
- mass
- Prior art date
Links
- 239000006260 foam Substances 0.000 title claims description 116
- 229920000582 polyisocyanurate Polymers 0.000 title claims description 13
- 239000011495 polyisocyanurate Substances 0.000 title claims description 12
- 239000004814 polyurethane Substances 0.000 title claims description 10
- 229920002635 polyurethane Polymers 0.000 title claims description 8
- 239000000835 fiber Substances 0.000 title description 7
- 239000003365 glass fiber Substances 0.000 claims description 110
- 239000000203 mixture Substances 0.000 claims description 92
- 229920005862 polyol Polymers 0.000 claims description 91
- 150000003077 polyols Chemical class 0.000 claims description 91
- 238000009472 formulation Methods 0.000 claims description 52
- 239000012948 isocyanate Substances 0.000 claims description 39
- 150000002513 isocyanates Chemical class 0.000 claims description 38
- 239000003054 catalyst Substances 0.000 claims description 32
- 239000004604 Blowing Agent Substances 0.000 claims description 18
- 239000011230 binding agent Substances 0.000 claims description 18
- 239000003995 emulsifying agent Substances 0.000 claims description 13
- 239000003063 flame retardant Substances 0.000 claims description 13
- 239000011152 fibreglass Substances 0.000 claims description 12
- 238000005520 cutting process Methods 0.000 claims description 11
- -1 potassium carboxylates Chemical class 0.000 claims description 11
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 10
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical class [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 10
- 150000003512 tertiary amines Chemical class 0.000 claims description 10
- 238000004519 manufacturing process Methods 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 claims description 7
- 125000000524 functional group Chemical group 0.000 claims description 7
- 239000011591 potassium Substances 0.000 claims description 7
- 229910052700 potassium Inorganic materials 0.000 claims description 7
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 5
- 239000004088 foaming agent Substances 0.000 claims description 5
- 229920000570 polyether Polymers 0.000 claims description 5
- 239000002666 chemical blowing agent Substances 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 238000005187 foaming Methods 0.000 claims description 3
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 claims description 3
- 229920000768 polyamine Polymers 0.000 claims description 3
- 235000010290 biphenyl Nutrition 0.000 claims 1
- 239000004305 biphenyl Substances 0.000 claims 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims 1
- 229920000728 polyester Polymers 0.000 claims 1
- 238000007711 solidification Methods 0.000 claims 1
- 230000008023 solidification Effects 0.000 claims 1
- 230000008961 swelling Effects 0.000 claims 1
- 239000007789 gas Substances 0.000 description 30
- 238000007906 compression Methods 0.000 description 16
- 230000006835 compression Effects 0.000 description 15
- 238000009826 distribution Methods 0.000 description 15
- 238000006243 chemical reaction Methods 0.000 description 11
- 238000009413 insulation Methods 0.000 description 8
- 239000000654 additive Substances 0.000 description 6
- 238000005470 impregnation Methods 0.000 description 5
- 238000005259 measurement Methods 0.000 description 5
- 229920005906 polyester polyol Polymers 0.000 description 5
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 4
- 230000001070 adhesive effect Effects 0.000 description 4
- 238000012669 compression test Methods 0.000 description 4
- 239000011810 insulating material Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- ZUFQCVZBBNZMKD-UHFFFAOYSA-M potassium 2-ethylhexanoate Chemical compound [K+].CCCCC(CC)C([O-])=O ZUFQCVZBBNZMKD-UHFFFAOYSA-M 0.000 description 4
- 230000009257 reactivity Effects 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 238000009864 tensile test Methods 0.000 description 3
- HHDUMDVQUCBCEY-UHFFFAOYSA-N 4-[10,15,20-tris(4-carboxyphenyl)-21,23-dihydroporphyrin-5-yl]benzoic acid Chemical compound OC(=O)c1ccc(cc1)-c1c2ccc(n2)c(-c2ccc(cc2)C(O)=O)c2ccc([nH]2)c(-c2ccc(cc2)C(O)=O)c2ccc(n2)c(-c2ccc(cc2)C(O)=O)c2ccc1[nH]2 HHDUMDVQUCBCEY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 125000003277 amino group Chemical group 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000006073 displacement reaction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- 230000010494 opalescence Effects 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 239000008259 solid foam Substances 0.000 description 2
- 239000000600 sorbitol Substances 0.000 description 2
- 125000006850 spacer group Chemical group 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- WZLFPVPRZGTCKP-UHFFFAOYSA-N 1,1,1,3,3-pentafluorobutane Chemical compound CC(F)(F)CC(F)(F)F WZLFPVPRZGTCKP-UHFFFAOYSA-N 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical group NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 1
- 208000034656 Contusions Diseases 0.000 description 1
- 239000004971 Cross linker Substances 0.000 description 1
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 229920005830 Polyurethane Foam Polymers 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical class CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 125000003158 alcohol group Chemical group 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229920003232 aliphatic polyester Polymers 0.000 description 1
- RJGDLRCDCYRQOQ-UHFFFAOYSA-N anthrone Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3CC2=C1 RJGDLRCDCYRQOQ-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 208000034526 bruise Diseases 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- KYKAJFCTULSVSH-UHFFFAOYSA-N chloro(fluoro)methane Chemical compound F[C]Cl KYKAJFCTULSVSH-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical class CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 description 1
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000007380 fibre production Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- YLQWCDOCJODRMT-UHFFFAOYSA-N fluoren-9-one Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3C2=C1 YLQWCDOCJODRMT-UHFFFAOYSA-N 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 150000002314 glycerols Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 239000012774 insulation material Substances 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- PGYPOBZJRVSMDS-UHFFFAOYSA-N loperamide hydrochloride Chemical compound Cl.C=1C=CC=CC=1C(C=1C=CC=CC=1)(C(=O)N(C)C)CCN(CC1)CCC1(O)C1=CC=C(Cl)C=C1 PGYPOBZJRVSMDS-UHFFFAOYSA-N 0.000 description 1
- 239000000693 micelle Substances 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 150000002923 oximes Chemical class 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N phthalic anhydride Chemical class C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- 239000011120 plywood Substances 0.000 description 1
- 229920001228 polyisocyanate Polymers 0.000 description 1
- 239000005056 polyisocyanate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 150000004053 quinones Chemical class 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 239000011949 solid catalyst Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 description 1
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 1
- 230000001960 triggered effect Effects 0.000 description 1
- 238000005829 trimerization reaction Methods 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 239000000052 vinegar Substances 0.000 description 1
- 235000021419 vinegar Nutrition 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
- C08G18/4018—Mixtures of compounds of group C08G18/42 with compounds of group C08G18/48
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0085—Use of fibrous compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/143—Halogen containing compounds
- C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
- C08J9/146—Halogen containing compounds containing carbon, halogen and hydrogen only only fluorine as halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/0058—≥50 and <150kg/m3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2115/00—Oligomerisation
- C08G2115/02—Oligomerisation to isocyanurate groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Polyurethanes Or Polyureas (AREA)
- Reinforced Plastic Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0502227A FR2882756B1 (fr) | 2005-03-04 | 2005-03-04 | Mousse de polyurethanne-polyisocyanurate renforcee de fibres de verre |
| FR0511111A FR2882755A1 (fr) | 2005-03-04 | 2005-10-28 | Mousse de polyurethanne/polyisocyanurate renforcee de fibres de verre |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW200639202A TW200639202A (en) | 2006-11-16 |
| TWI292408B true TWI292408B (en) | 2008-01-11 |
Family
ID=35285410
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW095104891A TWI292408B (en) | 2005-03-04 | 2006-02-14 | Class fiber reinforced polyurethane/polyisocyanurate foam |
Country Status (4)
| Country | Link |
|---|---|
| CN (1) | CN100434451C (enrdf_load_stackoverflow) |
| FR (2) | FR2882756B1 (enrdf_load_stackoverflow) |
| RU (1) | RU2317307C2 (enrdf_load_stackoverflow) |
| TW (1) | TWI292408B (enrdf_load_stackoverflow) |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101191010B (zh) * | 2006-11-20 | 2011-06-15 | 中国船舶重工集团公司第七二五研究所 | 一种聚氨酯泡沫塑料的纤维增强改性方法 |
| CN100485001C (zh) * | 2007-02-12 | 2009-05-06 | 江苏双良复合材料有限公司 | 连续玻纤纱增强硬质聚氨酯微泡的型材制品及其共挤成型工艺 |
| CN101029456B (zh) * | 2007-03-06 | 2010-05-19 | 天津工业大学 | 一种弹性非织造材料基材及其制造方法 |
| WO2010066635A1 (de) * | 2008-12-10 | 2010-06-17 | Basf Se | Wassergetriebene hartschaumstoffe mit verbesserten mechanischen eigenschaften bei tiefen temperaturen |
| ITMI20100440A1 (it) * | 2010-03-18 | 2011-09-19 | Dow Global Technologies Inc | Processo per la preparazione di poliuretani rinforzati con fibre lunghe che contengono riempitivi particolati |
| CN101781395B (zh) * | 2010-03-30 | 2011-08-31 | 上海交通大学 | 硬质聚氨酯绝热保温发泡材料及其制备方法 |
| RU2465141C2 (ru) * | 2011-01-12 | 2012-10-27 | Государственное образовательное учреждение высшего профессионального образования Балтийский государственный технический университет "ВОЕНМЕХ" им. Д.Ф. Устинова (БГТУ "ВОЕНМЕХ") | Способ формирования армированной дискретными элементами газонаполненной пластмассы |
| JP2013043374A (ja) * | 2011-08-24 | 2013-03-04 | Nakagawa Sangyo Kk | 自動車用内装基材の製造方法 |
| CN102504164B (zh) * | 2011-11-22 | 2013-10-16 | 中国农业大学 | 一种增强型玉米芯基聚氨酯泡沫材料的制造方法 |
| TWI477552B (zh) * | 2012-06-28 | 2015-03-21 | 防火聚胺酯材料及防火結構 | |
| FR2993270B1 (fr) * | 2012-07-12 | 2015-08-07 | Rhodia Operations | Procede de moussage chimique en presence de charges de renfort |
| RU2638302C2 (ru) * | 2012-08-20 | 2017-12-15 | Байер Матириальсайенс Аг | Усиленные волокнами композиционные конструктивные элементы и их изготовление |
| CN104540865B (zh) * | 2012-08-20 | 2017-03-01 | 科思创德国股份有限公司 | 聚氨酯浇注树脂和由其制成的灌封料 |
| CN103641984B (zh) * | 2013-11-13 | 2016-06-08 | 安徽金马海绵有限公司 | 一种增强海绵及其制备方法 |
| CN107090074A (zh) * | 2016-02-17 | 2017-08-25 | 江苏雅克科技股份有限公司 | 一种高阻燃型玻纤增强硬质聚氨酯超低温保温材料及其制法 |
| CN107099018A (zh) * | 2016-02-22 | 2017-08-29 | 江苏雅克科技股份有限公司 | 一种环保型发泡剂生产的耐超低温无卤阻燃玻纤增强型硬质聚氨酯保温材料及其制备方法 |
| CA3019617C (en) * | 2016-05-04 | 2024-06-25 | Covestro Deutschland Ag | Method for producing a polyisocyanurate composite material |
| CN108148166A (zh) * | 2016-12-05 | 2018-06-12 | 江苏雅克科技股份有限公司 | 聚氨酯保温复合材料 |
| CN107459617A (zh) * | 2017-07-11 | 2017-12-12 | 上海交通大学 | 一种lng船用梯度增强绝热材料及其短流程制备方法 |
| CN108997550A (zh) * | 2018-06-27 | 2018-12-14 | 扬中市天正合成材料研究中心 | 用于牵引车燃油箱的环保阻燃发泡材料及制备方法 |
| CN109503792A (zh) * | 2018-11-08 | 2019-03-22 | 青岛正能交通装备有限公司 | 一种聚氨酯发泡标准动车组操控台面罩及其制备方法 |
| FR3088571B1 (fr) * | 2018-11-19 | 2021-12-17 | Gaztransport Et Technigaz | Procede et systeme de preparation d’un bloc de mousse polyurethane/polyisocyanurate d’un massif d’isolation thermique d’une cuve |
| FR3091705B1 (fr) * | 2019-01-16 | 2022-08-26 | Gaztransport Et Technigaz | Procede de preparation d’un bloc de mousse polyurethane/polyisocyanurate d’un massif d’isolation thermique d’une cuve |
| FR3092837B1 (fr) * | 2019-02-18 | 2021-08-27 | Gaztransport Et Technigaz | Copolymeres methacrylates, et leurs utilisations pour la preparation de mousse polyurethane |
| FR3094451B1 (fr) | 2019-03-26 | 2022-12-23 | Gaztransport Et Technigaz | Bloc de mousse polyuréthane/polyisocyanurate d’un massif d’isolation thermique d’une cuve et son procédé de préparation |
| FR3094449B1 (fr) | 2019-03-26 | 2022-12-23 | Gaztransport Et Technigaz | Bloc de mousse polyuréthane/polyisocyanurate d’un massif d’isolation thermique d’une cuve et son procédé de préparation |
| CN110699858A (zh) * | 2019-11-14 | 2020-01-17 | 江苏九鼎新材料股份有限公司 | 用于聚氨酯增强的连续玻璃纤维毡的制造方法及其应用 |
| US20210230346A1 (en) * | 2020-01-27 | 2021-07-29 | Toyo Quality One Corporation | Sound absorbing urethane foam |
| WO2022268328A1 (fr) | 2021-06-24 | 2022-12-29 | Gaztransport Et Technigaz | Compositions de copolymères méthacrylates et d'agent gonflant, et leurs utilisations pour la préparation de mousse polyuréthane |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL6501850A (enrdf_load_stackoverflow) * | 1965-03-03 | 1966-08-16 | ||
| NL7115115A (enrdf_load_stackoverflow) * | 1971-11-03 | 1973-05-07 | ||
| US3895159A (en) * | 1972-11-13 | 1975-07-15 | Ataka & Company Ltd | Cryogenic insulating material |
| US4680214A (en) * | 1986-03-12 | 1987-07-14 | Polymetrics Corporation | Reinforced foam composites |
| FR2599468B1 (fr) * | 1986-06-03 | 1988-08-05 | Technigaz | Structure de paroi thermiquement isolante de reservoir etanche |
| JP2001247647A (ja) * | 2000-03-08 | 2001-09-11 | Nkk Corp | 硬質ポリウレタンフォーム用原液組成物及び超低温用断熱パネルの製造方法 |
| KR100416834B1 (ko) * | 2001-07-05 | 2004-02-05 | 주식회사 한국화이바 | 연속식 스트랜드 매트가 포함된 유리섬유강화 폴리우레탄폼 제조방법 및 장치 |
-
2005
- 2005-03-04 FR FR0502227A patent/FR2882756B1/fr not_active Expired - Fee Related
- 2005-10-28 FR FR0511111A patent/FR2882755A1/fr active Granted
-
2006
- 2006-02-14 TW TW095104891A patent/TWI292408B/zh not_active IP Right Cessation
- 2006-03-02 CN CNB200610058849XA patent/CN100434451C/zh not_active Expired - Fee Related
- 2006-03-03 RU RU2006106649/04A patent/RU2317307C2/ru not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| CN100434451C (zh) | 2008-11-19 |
| FR2882756B1 (fr) | 2007-04-27 |
| RU2317307C2 (ru) | 2008-02-20 |
| CN1834130A (zh) | 2006-09-20 |
| FR2882755A1 (fr) | 2006-09-08 |
| FR2882756A1 (fr) | 2006-09-08 |
| RU2006106649A (ru) | 2007-09-10 |
| TW200639202A (en) | 2006-11-16 |
| FR2882755B1 (enrdf_load_stackoverflow) | 2007-04-27 |
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