CN100434451C - 玻璃纤维增强的聚氨酯/聚异氰脲酸酯泡沫塑料 - Google Patents
玻璃纤维增强的聚氨酯/聚异氰脲酸酯泡沫塑料 Download PDFInfo
- Publication number
- CN100434451C CN100434451C CNB200610058849XA CN200610058849A CN100434451C CN 100434451 C CN100434451 C CN 100434451C CN B200610058849X A CNB200610058849X A CN B200610058849XA CN 200610058849 A CN200610058849 A CN 200610058849A CN 100434451 C CN100434451 C CN 100434451C
- Authority
- CN
- China
- Prior art keywords
- porous plastics
- glass fibre
- polyvalent alcohol
- foam
- prescription
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000011495 polyisocyanurate Substances 0.000 title claims abstract description 13
- 229920000582 polyisocyanurate Polymers 0.000 title claims abstract description 8
- 239000006260 foam Substances 0.000 title abstract description 16
- 239000003365 glass fiber Substances 0.000 claims abstract description 95
- 229920005862 polyol Polymers 0.000 claims abstract description 35
- 150000003077 polyols Chemical class 0.000 claims abstract description 35
- 239000012948 isocyanate Substances 0.000 claims abstract description 31
- 150000002513 isocyanates Chemical class 0.000 claims abstract description 30
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 16
- 239000004033 plastic Substances 0.000 claims description 124
- 229920003023 plastic Polymers 0.000 claims description 124
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 58
- 239000003795 chemical substances by application Substances 0.000 claims description 38
- 239000011152 fibreglass Substances 0.000 claims description 31
- 238000012360 testing method Methods 0.000 claims description 30
- 238000009413 insulation Methods 0.000 claims description 27
- 239000003063 flame retardant Substances 0.000 claims description 14
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 12
- 230000002708 enhancing effect Effects 0.000 claims description 11
- 238000005516 engineering process Methods 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 8
- 150000003512 tertiary amines Chemical class 0.000 claims description 8
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 claims description 7
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 7
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 6
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 6
- 229920005906 polyester polyol Polymers 0.000 claims description 6
- 229920000570 polyether Polymers 0.000 claims description 6
- 239000011591 potassium Substances 0.000 claims description 6
- 229910052700 potassium Inorganic materials 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 6
- 238000012546 transfer Methods 0.000 claims description 6
- 238000005187 foaming Methods 0.000 claims description 5
- 239000004088 foaming agent Substances 0.000 claims description 5
- 150000003839 salts Chemical class 0.000 claims description 5
- 230000015572 biosynthetic process Effects 0.000 claims description 4
- 238000002955 isolation Methods 0.000 claims description 4
- 239000000203 mixture Substances 0.000 abstract description 36
- 239000003054 catalyst Substances 0.000 abstract description 7
- 239000002666 chemical blowing agent Substances 0.000 abstract 1
- 229920002635 polyurethane Polymers 0.000 abstract 1
- 239000004814 polyurethane Substances 0.000 abstract 1
- 239000003340 retarding agent Substances 0.000 abstract 1
- 239000007789 gas Substances 0.000 description 31
- 230000006835 compression Effects 0.000 description 17
- 238000007906 compression Methods 0.000 description 17
- 238000006243 chemical reaction Methods 0.000 description 16
- 238000004519 manufacturing process Methods 0.000 description 8
- 239000000654 additive Substances 0.000 description 7
- 230000008901 benefit Effects 0.000 description 7
- 239000006071 cream Substances 0.000 description 7
- 239000000835 fiber Substances 0.000 description 6
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 5
- 230000000996 additive effect Effects 0.000 description 5
- 239000011230 binding agent Substances 0.000 description 5
- 239000012774 insulation material Substances 0.000 description 5
- 239000011148 porous material Substances 0.000 description 5
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 4
- 230000000875 corresponding effect Effects 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 229920001296 polysiloxane Polymers 0.000 description 4
- RLEFZEWKMQQZOA-UHFFFAOYSA-M potassium;octanoate Chemical compound [K+].CCCCCCCC([O-])=O RLEFZEWKMQQZOA-UHFFFAOYSA-M 0.000 description 4
- 230000009257 reactivity Effects 0.000 description 4
- 238000005728 strengthening Methods 0.000 description 4
- 239000004593 Epoxy Substances 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 238000005520 cutting process Methods 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 238000005755 formation reaction Methods 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- -1 isocyanate compound Chemical class 0.000 description 3
- 238000002803 maceration Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 238000007348 radical reaction Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 238000004026 adhesive bonding Methods 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- KYKAJFCTULSVSH-UHFFFAOYSA-N chloro(fluoro)methane Chemical compound F[C]Cl KYKAJFCTULSVSH-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000002939 deleterious effect Effects 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 238000006073 displacement reaction Methods 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- 230000003387 muscular Effects 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 238000004088 simulation Methods 0.000 description 2
- 239000000600 sorbitol Substances 0.000 description 2
- 238000003892 spreading Methods 0.000 description 2
- 230000007480 spreading Effects 0.000 description 2
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 2
- KMOUUZVZFBCRAM-OLQVQODUSA-N (3as,7ar)-3a,4,7,7a-tetrahydro-2-benzofuran-1,3-dione Chemical class C1C=CC[C@@H]2C(=O)OC(=O)[C@@H]21 KMOUUZVZFBCRAM-OLQVQODUSA-N 0.000 description 1
- QBUKAFSEUHGMMX-MTJSOVHGSA-N (5z)-5-[[3-(1-hydroxyethyl)thiophen-2-yl]methylidene]-10-methoxy-2,2,4-trimethyl-1h-chromeno[3,4-f]quinolin-9-ol Chemical compound C1=CC=2NC(C)(C)C=C(C)C=2C2=C1C=1C(OC)=C(O)C=CC=1O\C2=C/C=1SC=CC=1C(C)O QBUKAFSEUHGMMX-MTJSOVHGSA-N 0.000 description 1
- WZLFPVPRZGTCKP-UHFFFAOYSA-N 1,1,1,3,3-pentafluorobutane Chemical compound CC(F)(F)CC(F)(F)F WZLFPVPRZGTCKP-UHFFFAOYSA-N 0.000 description 1
- FRCHKSNAZZFGCA-UHFFFAOYSA-N 1,1-dichloro-1-fluoroethane Chemical compound CC(F)(Cl)Cl FRCHKSNAZZFGCA-UHFFFAOYSA-N 0.000 description 1
- 208000035126 Facies Diseases 0.000 description 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
- 230000001154 acute effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229920003232 aliphatic polyester Polymers 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000013213 extrapolation Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000007380 fibre production Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 150000002314 glycerols Chemical class 0.000 description 1
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical group C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical group OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- PGYPOBZJRVSMDS-UHFFFAOYSA-N loperamide hydrochloride Chemical group Cl.C=1C=CC=CC=1C(C=1C=CC=CC=1)(C(=O)N(C)C)CCN(CC1)CCC1(O)C1=CC=C(Cl)C=C1 PGYPOBZJRVSMDS-UHFFFAOYSA-N 0.000 description 1
- 239000003863 metallic catalyst Substances 0.000 description 1
- HKKDKUMUWRTAIA-UHFFFAOYSA-N nitridooxidocarbon(.) Chemical compound [O]C#N HKKDKUMUWRTAIA-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- MSSNHSVIGIHOJA-UHFFFAOYSA-N pentafluoropropane Chemical compound FC(F)CC(F)(F)F MSSNHSVIGIHOJA-UHFFFAOYSA-N 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001228 polyisocyanate Polymers 0.000 description 1
- 239000005056 polyisocyanate Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 235000019633 pungent taste Nutrition 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 239000012970 tertiary amine catalyst Substances 0.000 description 1
- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 description 1
- 238000013519 translation Methods 0.000 description 1
- 238000005829 trimerization reaction Methods 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
- C08G18/4018—Mixtures of compounds of group C08G18/42 with compounds of group C08G18/48
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0085—Use of fibrous compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/143—Halogen containing compounds
- C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
- C08J9/146—Halogen containing compounds containing carbon, halogen and hydrogen only only fluorine as halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/0058—≥50 and <150kg/m3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2115/00—Oligomerisation
- C08G2115/02—Oligomerisation to isocyanurate groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Polyurethanes Or Polyureas (AREA)
- Reinforced Plastic Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0502227 | 2005-03-04 | ||
FR0502227A FR2882756B1 (fr) | 2005-03-04 | 2005-03-04 | Mousse de polyurethanne-polyisocyanurate renforcee de fibres de verre |
FR0511111 | 2005-10-28 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1834130A CN1834130A (zh) | 2006-09-20 |
CN100434451C true CN100434451C (zh) | 2008-11-19 |
Family
ID=35285410
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB200610058849XA Expired - Fee Related CN100434451C (zh) | 2005-03-04 | 2006-03-02 | 玻璃纤维增强的聚氨酯/聚异氰脲酸酯泡沫塑料 |
Country Status (4)
Country | Link |
---|---|
CN (1) | CN100434451C (enrdf_load_stackoverflow) |
FR (2) | FR2882756B1 (enrdf_load_stackoverflow) |
RU (1) | RU2317307C2 (enrdf_load_stackoverflow) |
TW (1) | TWI292408B (enrdf_load_stackoverflow) |
Families Citing this family (29)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101191010B (zh) * | 2006-11-20 | 2011-06-15 | 中国船舶重工集团公司第七二五研究所 | 一种聚氨酯泡沫塑料的纤维增强改性方法 |
CN100485001C (zh) * | 2007-02-12 | 2009-05-06 | 江苏双良复合材料有限公司 | 连续玻纤纱增强硬质聚氨酯微泡的型材制品及其共挤成型工艺 |
CN101029456B (zh) * | 2007-03-06 | 2010-05-19 | 天津工业大学 | 一种弹性非织造材料基材及其制造方法 |
WO2010066635A1 (de) * | 2008-12-10 | 2010-06-17 | Basf Se | Wassergetriebene hartschaumstoffe mit verbesserten mechanischen eigenschaften bei tiefen temperaturen |
ITMI20100440A1 (it) * | 2010-03-18 | 2011-09-19 | Dow Global Technologies Inc | Processo per la preparazione di poliuretani rinforzati con fibre lunghe che contengono riempitivi particolati |
CN101781395B (zh) * | 2010-03-30 | 2011-08-31 | 上海交通大学 | 硬质聚氨酯绝热保温发泡材料及其制备方法 |
RU2465141C2 (ru) * | 2011-01-12 | 2012-10-27 | Государственное образовательное учреждение высшего профессионального образования Балтийский государственный технический университет "ВОЕНМЕХ" им. Д.Ф. Устинова (БГТУ "ВОЕНМЕХ") | Способ формирования армированной дискретными элементами газонаполненной пластмассы |
JP2013043374A (ja) * | 2011-08-24 | 2013-03-04 | Nakagawa Sangyo Kk | 自動車用内装基材の製造方法 |
CN102504164B (zh) * | 2011-11-22 | 2013-10-16 | 中国农业大学 | 一种增强型玉米芯基聚氨酯泡沫材料的制造方法 |
TWI477552B (zh) * | 2012-06-28 | 2015-03-21 | 防火聚胺酯材料及防火結構 | |
FR2993270B1 (fr) * | 2012-07-12 | 2015-08-07 | Rhodia Operations | Procede de moussage chimique en presence de charges de renfort |
RU2638302C2 (ru) * | 2012-08-20 | 2017-12-15 | Байер Матириальсайенс Аг | Усиленные волокнами композиционные конструктивные элементы и их изготовление |
CN104540865B (zh) * | 2012-08-20 | 2017-03-01 | 科思创德国股份有限公司 | 聚氨酯浇注树脂和由其制成的灌封料 |
CN103641984B (zh) * | 2013-11-13 | 2016-06-08 | 安徽金马海绵有限公司 | 一种增强海绵及其制备方法 |
CN107090074A (zh) * | 2016-02-17 | 2017-08-25 | 江苏雅克科技股份有限公司 | 一种高阻燃型玻纤增强硬质聚氨酯超低温保温材料及其制法 |
CN107099018A (zh) * | 2016-02-22 | 2017-08-29 | 江苏雅克科技股份有限公司 | 一种环保型发泡剂生产的耐超低温无卤阻燃玻纤增强型硬质聚氨酯保温材料及其制备方法 |
CA3019617C (en) * | 2016-05-04 | 2024-06-25 | Covestro Deutschland Ag | Method for producing a polyisocyanurate composite material |
CN108148166A (zh) * | 2016-12-05 | 2018-06-12 | 江苏雅克科技股份有限公司 | 聚氨酯保温复合材料 |
CN107459617A (zh) * | 2017-07-11 | 2017-12-12 | 上海交通大学 | 一种lng船用梯度增强绝热材料及其短流程制备方法 |
CN108997550A (zh) * | 2018-06-27 | 2018-12-14 | 扬中市天正合成材料研究中心 | 用于牵引车燃油箱的环保阻燃发泡材料及制备方法 |
CN109503792A (zh) * | 2018-11-08 | 2019-03-22 | 青岛正能交通装备有限公司 | 一种聚氨酯发泡标准动车组操控台面罩及其制备方法 |
FR3088571B1 (fr) * | 2018-11-19 | 2021-12-17 | Gaztransport Et Technigaz | Procede et systeme de preparation d’un bloc de mousse polyurethane/polyisocyanurate d’un massif d’isolation thermique d’une cuve |
FR3091705B1 (fr) * | 2019-01-16 | 2022-08-26 | Gaztransport Et Technigaz | Procede de preparation d’un bloc de mousse polyurethane/polyisocyanurate d’un massif d’isolation thermique d’une cuve |
FR3092837B1 (fr) * | 2019-02-18 | 2021-08-27 | Gaztransport Et Technigaz | Copolymeres methacrylates, et leurs utilisations pour la preparation de mousse polyurethane |
FR3094451B1 (fr) | 2019-03-26 | 2022-12-23 | Gaztransport Et Technigaz | Bloc de mousse polyuréthane/polyisocyanurate d’un massif d’isolation thermique d’une cuve et son procédé de préparation |
FR3094449B1 (fr) | 2019-03-26 | 2022-12-23 | Gaztransport Et Technigaz | Bloc de mousse polyuréthane/polyisocyanurate d’un massif d’isolation thermique d’une cuve et son procédé de préparation |
CN110699858A (zh) * | 2019-11-14 | 2020-01-17 | 江苏九鼎新材料股份有限公司 | 用于聚氨酯增强的连续玻璃纤维毡的制造方法及其应用 |
US20210230346A1 (en) * | 2020-01-27 | 2021-07-29 | Toyo Quality One Corporation | Sound absorbing urethane foam |
WO2022268328A1 (fr) | 2021-06-24 | 2022-12-29 | Gaztransport Et Technigaz | Compositions de copolymères méthacrylates et d'agent gonflant, et leurs utilisations pour la préparation de mousse polyuréthane |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001247647A (ja) * | 2000-03-08 | 2001-09-11 | Nkk Corp | 硬質ポリウレタンフォーム用原液組成物及び超低温用断熱パネルの製造方法 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL6501850A (enrdf_load_stackoverflow) * | 1965-03-03 | 1966-08-16 | ||
NL7115115A (enrdf_load_stackoverflow) * | 1971-11-03 | 1973-05-07 | ||
US3895159A (en) * | 1972-11-13 | 1975-07-15 | Ataka & Company Ltd | Cryogenic insulating material |
US4680214A (en) * | 1986-03-12 | 1987-07-14 | Polymetrics Corporation | Reinforced foam composites |
FR2599468B1 (fr) * | 1986-06-03 | 1988-08-05 | Technigaz | Structure de paroi thermiquement isolante de reservoir etanche |
KR100416834B1 (ko) * | 2001-07-05 | 2004-02-05 | 주식회사 한국화이바 | 연속식 스트랜드 매트가 포함된 유리섬유강화 폴리우레탄폼 제조방법 및 장치 |
-
2005
- 2005-03-04 FR FR0502227A patent/FR2882756B1/fr not_active Expired - Fee Related
- 2005-10-28 FR FR0511111A patent/FR2882755A1/fr active Granted
-
2006
- 2006-02-14 TW TW095104891A patent/TWI292408B/zh not_active IP Right Cessation
- 2006-03-02 CN CNB200610058849XA patent/CN100434451C/zh not_active Expired - Fee Related
- 2006-03-03 RU RU2006106649/04A patent/RU2317307C2/ru not_active IP Right Cessation
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001247647A (ja) * | 2000-03-08 | 2001-09-11 | Nkk Corp | 硬質ポリウレタンフォーム用原液組成物及び超低温用断熱パネルの製造方法 |
Also Published As
Publication number | Publication date |
---|---|
FR2882756B1 (fr) | 2007-04-27 |
RU2317307C2 (ru) | 2008-02-20 |
TWI292408B (en) | 2008-01-11 |
CN1834130A (zh) | 2006-09-20 |
FR2882755A1 (fr) | 2006-09-08 |
FR2882756A1 (fr) | 2006-09-08 |
RU2006106649A (ru) | 2007-09-10 |
TW200639202A (en) | 2006-11-16 |
FR2882755B1 (enrdf_load_stackoverflow) | 2007-04-27 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN100434451C (zh) | 玻璃纤维增强的聚氨酯/聚异氰脲酸酯泡沫塑料 | |
US20070015842A1 (en) | Glass fiber reinforced polyurethane/polyisocyanurate foam | |
CN102203156B (zh) | 闭孔刚性聚氨酯泡沫体的制备方法 | |
CN1899693B (zh) | 三聚催化剂 | |
US20080234402A1 (en) | Polyisocyanurate Rigid Foam and Method for the Production Thereof | |
EP1230297B1 (en) | Process for making rigid and flexible polyurethane foams containing a fire-retardant | |
JP5677974B2 (ja) | 低温における機械的性質が向上した水膨張性硬質フォーム | |
CN101970534B (zh) | 绝热的基于基异氰酸酯的泡沫体 | |
CN101578312A (zh) | 用于液化天然气罐绝热的水发泡硬质泡沫 | |
AU2010332880B2 (en) | Polyurethane composite system having high compressive strength and rigidity | |
CN1064978C (zh) | 在烃发泡剂存在下制备聚氨酯泡沫材料的方法 | |
CN101235128A (zh) | 连续纤维增强聚氨酯泡沫材料及其制造方法 | |
CN104151517A (zh) | 一种高阻燃聚氨酯改性的聚异氰脲酸酯硬泡外墙保温材料及其制备方法 | |
WO2013013391A1 (en) | An isocyanate-based polymer foam composite with improved thermal insulation properties | |
CN113166367A (zh) | 硬质聚氨酯泡沫配制物以及由其制备的泡沫 | |
US10982039B2 (en) | PUR/PIR rigid foams made of polyaddition oligoesters | |
CN110804149A (zh) | Lng液货围护系统用增强型聚氨酯保温材料及其制备方法 | |
KR20230119888A (ko) | 난연 조성물 및 이를 이용한 준불연 우레탄 단열재 | |
JP2020180169A (ja) | ポリウレタンフォーム形成性組成物 | |
US20230340181A1 (en) | Hcfo-containing isocyanate-reactive compositions, related foam-forming compositions and flame retardant pur-pir foams | |
US20220372287A1 (en) | Isocyanate-reactive composition | |
US4184022A (en) | Polyisocyanurate foam comprising reaction product of a polyisocyanate and a polyol mixture comprising a carboxylic ester polyol and a resole polyether polyol using a catalyst comprising dimethylethanolamine and an alkali metal salt of a carboxylic acid | |
KR20210132653A (ko) | 메타크릴레이트 공중합체, 및 폴리우레탄 폼의 제조를 위한 그것의 사용 | |
KR100278364B1 (ko) | 초저온 보냉용 유리섬유강화 폴리우레탄 폼 및 그것을 이용한 단열재 | |
WO2020023223A1 (en) | A foam composition and a foam composite made therefrom |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
CI02 | Correction of invention patent application |
Correction item: Priority Correct: 2005.10.28 FR 0511111 False: Lack of priority second Number: 38 Page: The title page Volume: 22 |
|
COR | Change of bibliographic data |
Free format text: CORRECT: PRIORITY; FROM: MISSING THE SECOND ARTICLE OF PRIORITY TO: 2005.10.28 FR 0511111 |
|
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
CF01 | Termination of patent right due to non-payment of annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20081119 |