TWI287558B - Translucent flame retardant polycarbonate compositions - Google Patents
Translucent flame retardant polycarbonate compositions Download PDFInfo
- Publication number
- TWI287558B TWI287558B TW091134519A TW91134519A TWI287558B TW I287558 B TWI287558 B TW I287558B TW 091134519 A TW091134519 A TW 091134519A TW 91134519 A TW91134519 A TW 91134519A TW I287558 B TWI287558 B TW I287558B
- Authority
- TW
- Taiwan
- Prior art keywords
- sulfonic acid
- polycarbonate
- aromatic
- composition
- flame retardant
- Prior art date
Links
- 239000004417 polycarbonate Substances 0.000 title claims abstract description 90
- 229920000515 polycarbonate Polymers 0.000 title claims abstract description 79
- 239000000203 mixture Substances 0.000 title claims abstract description 66
- 239000003063 flame retardant Substances 0.000 title claims abstract description 52
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims description 45
- -1 polytetrafluoroethylene Polymers 0.000 claims abstract description 49
- 239000004810 polytetrafluoroethylene Substances 0.000 claims abstract description 29
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims abstract description 29
- 229920005668 polycarbonate resin Polymers 0.000 claims abstract description 20
- 239000004431 polycarbonate resin Substances 0.000 claims abstract description 20
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims abstract description 10
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims abstract description 10
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910052794 bromium Inorganic materials 0.000 claims abstract description 10
- 239000000460 chlorine Substances 0.000 claims abstract description 10
- 229910052801 chlorine Inorganic materials 0.000 claims abstract description 10
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 59
- 125000003118 aryl group Chemical group 0.000 claims description 30
- 239000011347 resin Substances 0.000 claims description 28
- 229920005989 resin Polymers 0.000 claims description 28
- 239000000178 monomer Substances 0.000 claims description 24
- 125000004432 carbon atom Chemical group C* 0.000 claims description 13
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 claims description 13
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 11
- DHXVGJBLRPWPCS-UHFFFAOYSA-N Tetrahydropyran Chemical compound C1CCOCC1 DHXVGJBLRPWPCS-UHFFFAOYSA-N 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 10
- 230000002079 cooperative effect Effects 0.000 claims description 8
- 238000002834 transmittance Methods 0.000 claims description 8
- 229910052783 alkali metal Inorganic materials 0.000 claims description 7
- 230000005540 biological transmission Effects 0.000 claims description 7
- 150000002148 esters Chemical class 0.000 claims description 7
- 125000001931 aliphatic group Chemical group 0.000 claims description 6
- 239000003513 alkali Substances 0.000 claims description 6
- 150000008365 aromatic ketones Chemical class 0.000 claims description 6
- LVTHXRLARFLXNR-UHFFFAOYSA-M potassium;1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonate Chemical group [K+].[O-]S(=O)(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F LVTHXRLARFLXNR-UHFFFAOYSA-M 0.000 claims description 4
- 125000003545 alkoxy group Chemical group 0.000 claims description 3
- 125000004104 aryloxy group Chemical group 0.000 claims description 3
- VZXTWGWHSMCWGA-UHFFFAOYSA-N 1,3,5-triazine-2,4-diamine Chemical compound NC1=NC=NC(N)=N1 VZXTWGWHSMCWGA-UHFFFAOYSA-N 0.000 claims description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 238000006116 polymerization reaction Methods 0.000 claims description 2
- 239000004576 sand Substances 0.000 claims description 2
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical class CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 claims 5
- 150000001336 alkenes Chemical class 0.000 claims 5
- 150000008378 aryl ethers Chemical class 0.000 claims 5
- 125000000623 heterocyclic group Chemical group 0.000 claims 5
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 5
- LMGZGXSXHCMSAA-UHFFFAOYSA-N cyclodecane Chemical compound C1CCCCCCCCC1 LMGZGXSXHCMSAA-UHFFFAOYSA-N 0.000 claims 2
- 150000003460 sulfonic acids Chemical class 0.000 claims 2
- KVGOXGQSTGQXDD-UHFFFAOYSA-N 1-decane-sulfonic-acid Chemical compound CCCCCCCCCCS(O)(=O)=O KVGOXGQSTGQXDD-UHFFFAOYSA-N 0.000 claims 1
- MHZGKXUYDGKKIU-UHFFFAOYSA-N Decylamine Chemical compound CCCCCCCCCCN MHZGKXUYDGKKIU-UHFFFAOYSA-N 0.000 claims 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims 1
- 150000001735 carboxylic acids Chemical class 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 125000006612 decyloxy group Chemical group 0.000 claims 1
- 229910052731 fluorine Inorganic materials 0.000 claims 1
- 239000011737 fluorine Substances 0.000 claims 1
- 125000005702 oxyalkylene group Chemical group 0.000 claims 1
- 150000002926 oxygen Chemical class 0.000 claims 1
- 229920005672 polyolefin resin Polymers 0.000 claims 1
- 229910052814 silicon oxide Inorganic materials 0.000 claims 1
- 150000003568 thioethers Chemical class 0.000 claims 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 abstract description 3
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical class C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 8
- 229910052708 sodium Inorganic materials 0.000 description 7
- 239000011734 sodium Substances 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 6
- 239000006085 branching agent Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 238000009718 spray deposition Methods 0.000 description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 150000002430 hydrocarbons Chemical group 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 3
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 2
- PXKLMJQFEQBVLD-UHFFFAOYSA-N Bisphenol F Natural products C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 2
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- QMKYBPDZANOJGF-UHFFFAOYSA-N benzene-1,3,5-tricarboxylic acid Chemical compound OC(=O)C1=CC(C(O)=O)=CC(C(O)=O)=C1 QMKYBPDZANOJGF-UHFFFAOYSA-N 0.000 description 2
- 229920000402 bisphenol A polycarbonate polymer Polymers 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 2
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 150000002923 oximes Chemical class 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 2
- MXSFCLQVRKXOTH-UHFFFAOYSA-N 2,2,3,3,4,4-hexafluoropentanedioic acid;sodium Chemical compound [Na].[Na].OC(=O)C(F)(F)C(F)(F)C(F)(F)C(O)=O MXSFCLQVRKXOTH-UHFFFAOYSA-N 0.000 description 1
- YHLSJHLBXDIJSQ-UHFFFAOYSA-N 3-(4-phenylphenyl)propan-1-amine Chemical compound C1=CC(CCCN)=CC=C1C1=CC=CC=C1 YHLSJHLBXDIJSQ-UHFFFAOYSA-N 0.000 description 1
- GXDIDDARPBFKNG-UHFFFAOYSA-N 4,4'-(Butane-1,1-diyl)diphenol Chemical compound C=1C=C(O)C=CC=1C(CCC)C1=CC=C(O)C=C1 GXDIDDARPBFKNG-UHFFFAOYSA-N 0.000 description 1
- UITKHKNFVCYWNG-UHFFFAOYSA-N 4-(3,4-dicarboxybenzoyl)phthalic acid Chemical compound C1=C(C(O)=O)C(C(=O)O)=CC=C1C(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 UITKHKNFVCYWNG-UHFFFAOYSA-N 0.000 description 1
- RSSGMIIGVQRGDS-UHFFFAOYSA-N 4-[(4-hydroxyphenyl)-phenylmethyl]phenol Chemical compound C1=CC(O)=CC=C1C(C=1C=CC(O)=CC=1)C1=CC=CC=C1 RSSGMIIGVQRGDS-UHFFFAOYSA-N 0.000 description 1
- OVVCSFQRAXVPGT-UHFFFAOYSA-N 4-[1-(4-hydroxyphenyl)cyclopentyl]phenol Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)CCCC1 OVVCSFQRAXVPGT-UHFFFAOYSA-N 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- HTVITOHKHWFJKO-UHFFFAOYSA-N Bisphenol B Chemical compound C=1C=C(O)C=CC=1C(C)(CC)C1=CC=C(O)C=C1 HTVITOHKHWFJKO-UHFFFAOYSA-N 0.000 description 1
- QBNQSICHKHBQGG-UHFFFAOYSA-N C1(CCCCCCCCC1)C1OCCCC1 Chemical compound C1(CCCCCCCCC1)C1OCCCC1 QBNQSICHKHBQGG-UHFFFAOYSA-N 0.000 description 1
- BQYOQHRUNBPSDZ-UHFFFAOYSA-N ClCC(CCC(=O)OC(CCC(CCCCCC)CCl)=O)CCCCCC Chemical compound ClCC(CCC(=O)OC(CCC(CCCCCC)CCl)=O)CCCCCC BQYOQHRUNBPSDZ-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- DHSVOHAEDWPGBW-UHFFFAOYSA-N FC1=CC=C(C(=O)C2=CC=C(C=C2)F)C=C1.[Na].[Na] Chemical compound FC1=CC=C(C(=O)C2=CC=C(C=C2)F)C=C1.[Na].[Na] DHSVOHAEDWPGBW-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- CJPIDIRJSIUWRJ-UHFFFAOYSA-N benzene-1,2,4-tricarbonyl chloride Chemical compound ClC(=O)C1=CC=C(C(Cl)=O)C(C(Cl)=O)=C1 CJPIDIRJSIUWRJ-UHFFFAOYSA-N 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- QDHFHIQKOVNCNC-UHFFFAOYSA-M butane-1-sulfonate Chemical compound CCCCS([O-])(=O)=O QDHFHIQKOVNCNC-UHFFFAOYSA-M 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000001244 carboxylic acid anhydrides Chemical class 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 230000000875 corresponding effect Effects 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 150000001924 cycloalkanes Chemical class 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- UCIYGNATMHQYCT-UHFFFAOYSA-N cyclodecene Chemical class C1CCCCC=CCCC1 UCIYGNATMHQYCT-UHFFFAOYSA-N 0.000 description 1
- AASXHHHZCYMGHA-UHFFFAOYSA-N cyclodecyloxycyclodecane Chemical compound C1CCCCCCCCC1OC1CCCCCCCCC1 AASXHHHZCYMGHA-UHFFFAOYSA-N 0.000 description 1
- 125000000596 cyclohexenyl group Chemical group C1(=CCCCC1)* 0.000 description 1
- 125000004956 cyclohexylene group Chemical group 0.000 description 1
- 125000004210 cyclohexylmethyl group Chemical group [H]C([H])(*)C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C1([H])[H] 0.000 description 1
- 125000004979 cyclopentylene group Chemical group 0.000 description 1
- DIOQZVSQGTUSAI-NJFSPNSNSA-N decane Chemical compound CCCCCCCCC[14CH3] DIOQZVSQGTUSAI-NJFSPNSNSA-N 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- WZZLWPIYWZEJOX-UHFFFAOYSA-L disodium;naphthalene-2,6-disulfonate Chemical compound [Na+].[Na+].C1=C(S([O-])(=O)=O)C=CC2=CC(S(=O)(=O)[O-])=CC=C21 WZZLWPIYWZEJOX-UHFFFAOYSA-L 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000007323 disproportionation reaction Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 238000005227 gel permeation chromatography Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000010406 interfacial reaction Methods 0.000 description 1
- 238000006317 isomerization reaction Methods 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- JTJMJGYZQZDUJJ-UHFFFAOYSA-N phencyclidine Chemical compound C1CCCCN1C1(C=2C=CC=CC=2)CCCCC1 JTJMJGYZQZDUJJ-UHFFFAOYSA-N 0.000 description 1
- QIHPHPAXMIOJLH-UHFFFAOYSA-N phenol ruthenium Chemical compound [Ru].Oc1ccccc1.Oc1ccccc1 QIHPHPAXMIOJLH-UHFFFAOYSA-N 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
- 125000004351 phenylcyclohexyl group Chemical group C1(=CC=CC=C1)C1(CCCCC1)* 0.000 description 1
- 239000003504 photosensitizing agent Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- CMWLHUCXYAVSSD-UHFFFAOYSA-M potassium 1,1,2,2,3-pentafluorobutane-1-sulfonate Chemical compound FC(C(C(S(=O)(=O)[O-])(F)F)(F)F)C.[K+] CMWLHUCXYAVSSD-UHFFFAOYSA-M 0.000 description 1
- GLGXXYFYZWQGEL-UHFFFAOYSA-M potassium;trifluoromethanesulfonate Chemical compound [K+].[O-]S(=O)(=O)C(F)(F)F GLGXXYFYZWQGEL-UHFFFAOYSA-M 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- QBJDFZSOZNDVDE-UHFFFAOYSA-M sodium;1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonate Chemical group [Na+].[O-]S(=O)(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F QBJDFZSOZNDVDE-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229920000638 styrene acrylonitrile Polymers 0.000 description 1
- 239000011145 styrene acrylonitrile resin Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 239000003017 thermal stabilizer Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/541—Silicon-containing compounds containing oxygen
- C08K5/5415—Silicon-containing compounds containing oxygen containing at least one Si—O bond
- C08K5/5419—Silicon-containing compounds containing oxygen containing at least one Si—O bond containing at least one Si—C bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/02—Halogenated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/15—Heterocyclic compounds having oxygen in the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/41—Compounds containing sulfur bound to oxygen
- C08K5/42—Sulfonic acids; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/683,288 US6462111B1 (en) | 2001-12-10 | 2001-12-10 | Translucent flame retardant polycarbonate compositions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW200300782A TW200300782A (en) | 2003-06-16 |
| TWI287558B true TWI287558B (en) | 2007-10-01 |
Family
ID=24743369
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW091134519A TWI287558B (en) | 2001-12-10 | 2002-11-27 | Translucent flame retardant polycarbonate compositions |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US6462111B1 (https=) |
| EP (1) | EP1458799B1 (https=) |
| JP (2) | JP2005511843A (https=) |
| KR (1) | KR100899506B1 (https=) |
| CN (1) | CN100366668C (https=) |
| AU (1) | AU2002350134A1 (https=) |
| DE (1) | DE60223842T2 (https=) |
| TW (1) | TWI287558B (https=) |
| WO (1) | WO2003050176A1 (https=) |
Families Citing this family (44)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2428174B1 (en) | 2001-09-24 | 2014-01-08 | Applied Medical Resources Corporation | Bladeless obturator |
| CA2485481A1 (en) | 2002-05-16 | 2003-11-27 | Applied Medical Resources Corporation | Cone tip obturator |
| DE10247777A1 (de) * | 2002-10-14 | 2004-04-22 | Bayer Ag | Flammgeschützte Polycarbonate und Polyestercarbonate |
| US6790899B2 (en) * | 2002-10-29 | 2004-09-14 | General Electric Company | Method for making fire-retarded polycarbonate and related compositions |
| US7019059B2 (en) * | 2002-12-16 | 2006-03-28 | General Electric Company | Method for making fire-retarded glass-filled polycarbonate and related compositions |
| US20050009968A1 (en) * | 2003-06-28 | 2005-01-13 | General Electric Company | Transparent Flame Retardant Polycarbonate Compositions |
| EP1670349B9 (en) | 2003-10-03 | 2014-01-15 | Applied Medical Resources Corporation | Bladeless optical obturator |
| EP3431026B1 (en) | 2004-06-29 | 2020-09-23 | Applied Medical Resources Corporation | Insufflating optical surgical instrument |
| US7794644B2 (en) * | 2005-10-05 | 2010-09-14 | Applied Medical Resources Corporation | Thin-walled optical obturator |
| US20080015292A1 (en) * | 2006-07-12 | 2008-01-17 | General Electric Company | Flame retardant and scratch resistant thermoplastic polycarbonate compositions |
| WO2008043100A2 (en) | 2006-10-06 | 2008-04-10 | Applied Medical Resources Corporation | Visual insufflation port |
| JP5612242B2 (ja) * | 2007-05-31 | 2014-10-22 | 帝人株式会社 | 難燃性ポリカーボネート樹脂組成物 |
| JP5583883B2 (ja) * | 2007-05-31 | 2014-09-03 | 帝人株式会社 | 難燃性ポリカーボネート樹脂組成物 |
| US20090062438A1 (en) * | 2007-08-30 | 2009-03-05 | Van De Grampel Robert Dirk | Copolyestercarbonate compositions |
| US20090062439A1 (en) * | 2007-08-30 | 2009-03-05 | Van De Grampel Robert Dirk | Polyestercarbonate compositions |
| EP2837345B1 (en) | 2008-01-25 | 2016-10-05 | Applied Medical Resources Corporation | Insufflating access system |
| US9570211B2 (en) * | 2008-08-27 | 2017-02-14 | Covestro Llc | Transparent thermoplastic composition with improved electrical conductivity in the melt |
| EP2328487B1 (en) | 2008-09-29 | 2018-04-18 | Applied Medical Resources Corporation | First-entry trocar system |
| CN102666703B (zh) * | 2009-11-05 | 2014-12-24 | 拜尔材料科学股份公司 | 具有改进的阻燃性的聚碳酸酯板 |
| CN101704994B (zh) * | 2009-12-15 | 2012-01-18 | 重庆启蓝塑料有限公司 | 一种透明阻燃聚碳酸酯(pc)材料及其制备方法 |
| CN101851407B (zh) * | 2010-03-09 | 2013-08-07 | 上海锦湖日丽塑料有限公司 | 高表面光泽玻璃纤维增强阻燃聚碳酸脂组合物及制备方法 |
| EP2640782B1 (en) * | 2010-11-15 | 2021-04-07 | SHPP Global Technologies B.V. | Compositions and articles of manufacture containing siloxane |
| JP5267582B2 (ja) * | 2011-01-21 | 2013-08-21 | 三菱エンジニアリングプラスチックス株式会社 | 難燃性ポリカーボネート樹脂組成物及びこれを用いた成形体 |
| US9234096B2 (en) * | 2011-02-03 | 2016-01-12 | Sabic Global Technologies B.V. | Color and heat stable polycarbonate compositions and methods of making |
| US9453128B2 (en) | 2011-03-31 | 2016-09-27 | Sabic Global Technologies B.V. | Rail component comprising flame retardant compositions, and methods of manufacture |
| US9006324B2 (en) | 2011-03-31 | 2015-04-14 | Sabic Global Technologies B.V. | Flame retardant polycarbonate compositions, methods of manufacture, and articles formed therefrom |
| US8981015B2 (en) | 2011-03-31 | 2015-03-17 | Sabic Global Technologies B.V. | Flame retardant poly(siloxane) copolymer compositions, methods of manufacture, and articles formed therefrom |
| US8703855B2 (en) | 2011-03-31 | 2014-04-22 | Sabic Innovative Plastics Ip B.V. | Electrical tracking resistance compositions, methods and articles of manufacture |
| US8703856B2 (en) | 2011-03-31 | 2014-04-22 | Sabic Innovative Plastics Ip B.V. | Electrical tracking resistance compositions, methods and articles of manufacture |
| US9254148B2 (en) | 2011-05-02 | 2016-02-09 | Applied Medical Resources Corporation | Low-profile surgical universal access port |
| US8937127B2 (en) | 2011-09-30 | 2015-01-20 | Sabic Global Technologies B.V. | Flame retardant poly(siloxane-etherimide) copolymer compositions, methods of manufacture, and articles formed therefrom |
| US9127155B2 (en) | 2012-04-11 | 2015-09-08 | Sabic Global Technologies B.V. | Phosphorus free flame retardant composition |
| US8691915B2 (en) | 2012-04-23 | 2014-04-08 | Sabic Innovative Plastics Ip B.V. | Copolymers and polymer blends having improved refractive indices |
| US8877876B2 (en) * | 2012-06-29 | 2014-11-04 | Sabic Global Technologies B.V. | High-temperature plastic article |
| KR101402579B1 (ko) * | 2013-10-25 | 2014-05-30 | 주식회사 엘지화학 | 투명성과 난연성이 우수한 폴리카보네이트 수지 조성물 |
| WO2015140671A1 (en) * | 2014-03-20 | 2015-09-24 | Sabic Global Technologies B.V. | Polycarbonate compositions, methods of their manufacture, and articles thereof |
| US10005903B2 (en) | 2015-03-09 | 2018-06-26 | Sabic Global Technologies B.V. | Compositions and articles of manufacture containing branched polycarbonate |
| EP3320018B1 (en) * | 2015-07-09 | 2022-08-10 | SHPP Global Technologies B.V. | Polycarbonate compositions with improved flame retardance |
| KR20180071325A (ko) * | 2015-11-04 | 2018-06-27 | 사빅 글로벌 테크놀러지스 비.브이. | 광학 부품의 난연 특성, 발광 효율 및 빔 각도가 향상된 확산성 폴리카보네이트 복합체 |
| KR102007100B1 (ko) * | 2017-12-29 | 2019-08-02 | 롯데첨단소재(주) | 열가소성 수지 조성물 및 이로부터 형성된 성형품 |
| JP7252727B2 (ja) * | 2018-09-14 | 2023-04-05 | 出光興産株式会社 | ポリカーボネート系樹脂組成物 |
| CN112063148A (zh) * | 2020-09-16 | 2020-12-11 | 横店集团得邦工程塑料有限公司 | 一种具有高阻燃性能的耐水解pc复合材料及其制备方法 |
| EP4092070A1 (de) | 2021-05-17 | 2022-11-23 | Covestro Deutschland AG | Reduzierung des gehalts spezieller salze von sulfonsäure-, sulfonamiden- oder sulfonimidderivaten im abwasser |
| EP4092075A1 (de) | 2021-05-17 | 2022-11-23 | Covestro Deutschland AG | Flammwidrige zusammensetzung umfassend 0,040 bis 0,095 gew.-% eines flammschutzmittels |
Family Cites Families (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3635895A (en) | 1965-09-01 | 1972-01-18 | Gen Electric | Process for preparing thermoplastic polycarbonates |
| AT297333B (de) | 1969-06-13 | 1972-03-27 | Bayer Ag | Verfahren zur Herstellung von Polycarbonaten mit verminderter Brennbarkeit |
| US3751519A (en) | 1971-07-29 | 1973-08-07 | Gen Electric | Compatible polycarbonate-siloxane composition |
| US3775369A (en) | 1971-07-29 | 1973-11-27 | Phillips Petroleum Co | Method of polymerizing unsaturated monomers with organocalcium compounds |
| US4391935A (en) | 1974-08-09 | 1983-07-05 | General Electric Company | Flame retardant polycarbonate composition |
| US3971756A (en) | 1974-08-09 | 1976-07-27 | General Electric Company | Flame retardant polycarbonate composition |
| US4001184A (en) | 1975-03-31 | 1977-01-04 | General Electric Company | Process for preparing a branched polycarbonate |
| US4130530A (en) | 1977-04-08 | 1978-12-19 | General Electric Company | Cyclic siloxane plasticized polycarbonate composition |
| JPS55500687A (https=) * | 1978-06-22 | 1980-09-25 | ||
| US4217438A (en) | 1978-12-15 | 1980-08-12 | General Electric Company | Polycarbonate transesterification process |
| US4578409A (en) * | 1985-01-14 | 1986-03-25 | Mobay Chemical Corporation | Flame retarding silanes |
| US4753994A (en) * | 1986-12-02 | 1988-06-28 | Mobay Corporation | Flame retardant polycarbonate compositions |
| US4767818A (en) | 1987-03-23 | 1988-08-30 | General Electric Company | Low gloss, flame retardant polycarbonate compositions |
| US5102696A (en) | 1990-03-27 | 1992-04-07 | General Electric Company | Method of dispersing fluoropolymers on polycarbonate resins |
| EP0522751B1 (en) | 1991-07-01 | 1998-04-01 | General Electric Company | Polycarbonate-polysiloxane block copolymers |
| US5521230A (en) | 1992-11-17 | 1996-05-28 | General Electric Company | Method of dispersing solid additives in polymers and products made therewith |
| US6005025A (en) | 1992-11-17 | 1999-12-21 | General Electric Company | Method of dispersing solid additives in polymers and products made therewith |
| US5449710A (en) | 1993-05-18 | 1995-09-12 | Idemitsu Petrochemical Co., Ltd. | Flame retardative polycarbonate resin composition |
| JP3129374B2 (ja) | 1994-03-18 | 2001-01-29 | 出光石油化学株式会社 | 難燃性ポリカーボネート樹脂組成物 |
| US6001929A (en) | 1994-07-15 | 1999-12-14 | Idemitsu Petrochemical Co., Ltd. | Polycarbonate resin composition |
| JPH11140296A (ja) | 1997-08-29 | 1999-05-25 | General Electric Co <Ge> | ポリカーボネート成形組成物 |
| JP2000290487A (ja) * | 1999-02-03 | 2000-10-17 | Mitsubishi Engineering Plastics Corp | 難燃性ポリカーボネート樹脂組成物及びそれを用いた成形品 |
| JP4408309B2 (ja) * | 1999-04-23 | 2010-02-03 | 住友ダウ株式会社 | 難燃性ポリカーボネート樹脂組成物 |
| US6180702B1 (en) | 1999-08-09 | 2001-01-30 | Bayer Corporation | Flame retardant polycarbonate composition |
| JP2001200152A (ja) * | 2000-01-19 | 2001-07-24 | Mitsubishi Engineering Plastics Corp | 難燃性ポリカーボネート樹脂組成物 |
| JP4397501B2 (ja) * | 2000-03-28 | 2010-01-13 | 帝人化成株式会社 | 難燃性ポリカーボネート樹脂組成物 |
| US6353046B1 (en) * | 2000-04-28 | 2002-03-05 | General Electric Company | Fire-retarded polycarbonate resin composition |
-
2001
- 2001-12-10 US US09/683,288 patent/US6462111B1/en not_active Expired - Lifetime
-
2002
- 2002-11-04 WO PCT/US2002/035521 patent/WO2003050176A1/en not_active Ceased
- 2002-11-04 KR KR1020047008940A patent/KR100899506B1/ko not_active Expired - Fee Related
- 2002-11-04 EP EP02786662A patent/EP1458799B1/en not_active Expired - Lifetime
- 2002-11-04 DE DE60223842T patent/DE60223842T2/de not_active Expired - Lifetime
- 2002-11-04 AU AU2002350134A patent/AU2002350134A1/en not_active Abandoned
- 2002-11-04 CN CNB028277805A patent/CN100366668C/zh not_active Expired - Fee Related
- 2002-11-04 JP JP2003551198A patent/JP2005511843A/ja active Pending
- 2002-11-27 TW TW091134519A patent/TWI287558B/zh active
-
2010
- 2010-07-02 JP JP2010152059A patent/JP5480041B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP1458799A1 (en) | 2004-09-22 |
| JP5480041B2 (ja) | 2014-04-23 |
| KR20040071714A (ko) | 2004-08-12 |
| JP2005511843A (ja) | 2005-04-28 |
| JP2010248527A (ja) | 2010-11-04 |
| CN100366668C (zh) | 2008-02-06 |
| US6462111B1 (en) | 2002-10-08 |
| EP1458799B1 (en) | 2007-11-28 |
| AU2002350134A1 (en) | 2003-06-23 |
| KR100899506B1 (ko) | 2009-05-26 |
| TW200300782A (en) | 2003-06-16 |
| WO2003050176A1 (en) | 2003-06-19 |
| DE60223842T2 (de) | 2008-10-09 |
| DE60223842D1 (de) | 2008-01-10 |
| CN1617905A (zh) | 2005-05-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| TWI287558B (en) | Translucent flame retardant polycarbonate compositions | |
| TW544462B (en) | Flame-retardant polycarbonate resin compositions | |
| EP1412430B1 (en) | Transparent, fire-resistant polycarbonate compositions | |
| DE60021187T2 (de) | Flammhemmende polycarbonatharzzusammensetzung | |
| US7288579B2 (en) | Method for reducing haze in a fire resistant polycarbonate composition | |
| CA2231571C (en) | Carbonate polymer resins containing low volatility aromatic phosphate ester compounds | |
| EP1423469B1 (en) | Flame retardant polycarbonate compositions with improved weathering performance containing cyanoacrylic esters | |
| TW200906968A (en) | Clear and flame retardant polycarbonate resin film | |
| US20050009968A1 (en) | Transparent Flame Retardant Polycarbonate Compositions | |
| TWI304428B (en) | Flame-resistant polycarbonate compositions having increased chemical resistance | |
| JP3252882B2 (ja) | 安定化された難燃ポリカーボネート成形コンパンド | |
| US4880864A (en) | Thermoplastic polycarbonates and blends with enhanced flame retardant properties | |
| CA2026152C (en) | Flame retardant polycarbonate blends | |
| US4235978A (en) | Flame retardant composition | |
| JPH03200862A (ja) | 耐焔性をもつたポリジ有機シロキサン―ポリカーボネート・ブロツク共重合体 | |
| JPS608291A (ja) | ビス−（イミドスルフオン酸塩） | |
| JPS61231048A (ja) | 自消性ポリカーボネート組成物 | |
| JP2012067164A (ja) | 難燃性ポリカーボネート樹脂組成物 | |
| EP0176395B1 (fr) | Compositions de polycarbonates aromatiques à combustibilité retardée | |
| JP2003041113A (ja) | ポリカーボネート樹脂組成物 |