TWI276643B - A process for the preparation of soft, low-shrinkage, thermoplastic polyurethane elastomers which can be easily released from the mold - Google Patents
A process for the preparation of soft, low-shrinkage, thermoplastic polyurethane elastomers which can be easily released from the mold Download PDFInfo
- Publication number
- TWI276643B TWI276643B TW092103584A TW92103584A TWI276643B TW I276643 B TWI276643 B TW I276643B TW 092103584 A TW092103584 A TW 092103584A TW 92103584 A TW92103584 A TW 92103584A TW I276643 B TWI276643 B TW I276643B
- Authority
- TW
- Taiwan
- Prior art keywords
- diisocyanate
- mixture
- number average
- average molecular
- molecular weight
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4854—Polyethers containing oxyalkylene groups having four carbon atoms in the alkylene group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4236—Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups
- C08G18/4238—Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups derived from dicarboxylic acids and dialcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2410/00—Soles
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10207774 | 2002-02-23 |
Publications (2)
Publication Number | Publication Date |
---|---|
TW200400209A TW200400209A (en) | 2004-01-01 |
TWI276643B true TWI276643B (en) | 2007-03-21 |
Family
ID=27635269
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
TW092103584A TWI276643B (en) | 2002-02-23 | 2003-02-21 | A process for the preparation of soft, low-shrinkage, thermoplastic polyurethane elastomers which can be easily released from the mold |
Country Status (15)
Country | Link |
---|---|
US (1) | US6790916B2 (fr) |
EP (1) | EP1338614B1 (fr) |
JP (2) | JP4866536B2 (fr) |
KR (1) | KR20030070543A (fr) |
CN (1) | CN100354332C (fr) |
AT (1) | ATE348849T1 (fr) |
AU (1) | AU2003200443B2 (fr) |
BR (1) | BR0300389A (fr) |
CA (1) | CA2420191A1 (fr) |
DE (1) | DE50306005D1 (fr) |
ES (1) | ES2279017T3 (fr) |
HK (1) | HK1056186A1 (fr) |
MX (1) | MXPA03001549A (fr) |
TW (1) | TWI276643B (fr) |
ZA (1) | ZA200301381B (fr) |
Families Citing this family (44)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002230404A (ja) * | 2001-02-02 | 2002-08-16 | Nec Corp | 広告ネットワークシステム、広告ネットワーク制御方法、広告サーバ、及びその制御プログラム |
DE50306005D1 (de) * | 2002-02-23 | 2007-02-01 | Bayer Materialscience Ag | Verfahren zur Herstellung von weichen, gut entformbaren thermoplastischen Polyurethanelastomeren mit geringer Schwindung |
WO2004039858A1 (fr) * | 2002-10-31 | 2004-05-13 | Kao Corporation | Mousse solide |
US20070158220A1 (en) * | 2004-01-07 | 2007-07-12 | Cleereman Robert J | Impact-resistant case with sealable opening |
JP4666278B2 (ja) * | 2004-02-13 | 2011-04-06 | 日本ポリウレタン工業株式会社 | 高通気性・低反発弾性のポリウレタンフォームの製造方法。 |
DE102004045619A1 (de) * | 2004-09-17 | 2006-04-06 | Basf Ag | Thermoplastische Polyurethane enthaltend Polytetrahydrofuran |
DE102005019663A1 (de) * | 2005-04-26 | 2006-11-02 | Basf Ag | Thermoplastische Polyurethane |
EP1719612A1 (fr) * | 2005-05-03 | 2006-11-08 | Vision Dynamics Holding B.V. | Procédé et dispositif pour la fabrication d'objets optiques |
CN101096409B (zh) * | 2006-06-26 | 2010-05-12 | 山东东大一诺威聚氨酯有限公司 | 一种用于鼠标垫的聚氨酯弹性体的制备方法 |
KR101340025B1 (ko) * | 2006-12-06 | 2013-12-10 | 루브리졸 어드밴스드 머티어리얼스, 인코포레이티드 | 가소제를 함유하지 않은 열가소성 폴리우레탄 수지 제조용조성물 및 이로부터 제조되는 저경도 폴리우레탄 수지 |
US20080139774A1 (en) * | 2006-12-11 | 2008-06-12 | Lawrey Bruce D | Soft thermoplastic polyurethane elastomers and processes for their preparation and use |
DE102007011239A1 (de) * | 2007-03-08 | 2008-11-06 | Bayer Materialscience Ag | Verfahren zur Herstellung von Formgedächtnisformkörpern mit einem breiten Einsatzbereich |
WO2009055361A1 (fr) * | 2007-10-22 | 2009-04-30 | Lubrizol Advanced Materials, Inc. | Polyuréthane thermoplastique souple, élastique, exempt de plastifiant et procédé pour synthétiser celui-ci |
CN102414236B (zh) | 2009-04-29 | 2013-10-16 | 巴斯夫欧洲公司 | 基于三羧酸的酯的软质热塑性聚氨酯 |
EP2513189B1 (fr) | 2009-12-16 | 2015-10-14 | Basf Se | Procédé de préparation de polyols de polyester, polyols de polyester préparés à l'aide de ces derniers et polyuréthanes obtenus à partir de ces derniers |
US20110190413A1 (en) * | 2010-02-04 | 2011-08-04 | Basf Se | Process for preparing polyesters, especially polyester alcohols |
WO2011095446A1 (fr) | 2010-02-04 | 2011-08-11 | Basf Se | Procédé de production de polyesters, en particulier de polyesters-alcools |
KR101805227B1 (ko) | 2010-05-14 | 2017-12-05 | 바스프 에스이 | 폴리에테롤의 제조 방법 |
EP2402382A1 (fr) | 2010-06-08 | 2012-01-04 | Basf Se | Procédé de rinçage de dispersions de polyols |
EP2394722A1 (fr) | 2010-06-08 | 2011-12-14 | Basf Se | Procédé de rinçage de dispersions de polyols |
KR101050266B1 (ko) * | 2010-08-02 | 2011-07-19 | 김재호 | 열가소성 폴리우레탄 탄성체를 이용한 축광성 성형 조성물 및 그 제조방법 |
CN102504181B (zh) * | 2011-09-30 | 2014-05-07 | 无锡双象化学工业有限公司 | 聚氨酯耐寒软质中低密度鞋用树脂及其制备方法 |
BR112014007306A2 (pt) * | 2011-09-30 | 2017-04-04 | Bayer Ip Gmbh | artigos extrudados homogêneos feitos a partir de poliuretanos termoplasticamente processáveis com base em poliéster-dióis formados a partir de ácido succínico e de 1,3-propanodiol |
ES2959200T3 (es) | 2013-06-04 | 2024-02-21 | Basf Se | Elastómeros termoplásticos de poliuretano blando y proceso para su preparación |
CN105637000A (zh) * | 2013-10-17 | 2016-06-01 | 三洋化成工业株式会社 | 聚氨酯树脂、聚氨酯树脂组合物以及聚氨酯树脂的制造方法 |
PL3099725T3 (pl) | 2014-01-30 | 2019-08-30 | Basf Se | Stabilizowane plastyfikatory do poliuretanu termoplastycznego |
WO2017050738A1 (fr) * | 2015-09-24 | 2017-03-30 | Basf Se | Polyuréthane thermoplastique |
CN106674471B (zh) | 2015-11-11 | 2019-09-03 | 万华化学集团股份有限公司 | 一种热塑性聚氨酯弹性体及其制备方法、用途和制品 |
CN106832213A (zh) * | 2017-02-21 | 2017-06-13 | 东莞市雄林新材料科技股份有限公司 | 一种光敏型tpu薄膜及其制备方法 |
CN107383853B (zh) * | 2017-06-28 | 2020-02-07 | 苏州奥斯汀新材料科技有限公司 | 一种高雾度高耐磨热塑性聚氨酯弹性体的制备方法 |
KR20200027977A (ko) | 2017-07-05 | 2020-03-13 | 바스프 에스이 | 황-함유 폴리에스테르 폴리올, 이의 제조 및 용도 |
CN110272528B (zh) * | 2018-03-16 | 2021-07-16 | 浙江华峰热塑性聚氨酯有限公司 | 热塑性聚氨酯的制备方法 |
CN111575817A (zh) * | 2019-02-19 | 2020-08-25 | 海宁新高纤维有限公司 | 一种热塑性聚氨酯纤维的制造方法 |
EP3772519A1 (fr) | 2019-08-07 | 2021-02-10 | Covestro Deutschland AG | Procédé de production de polymères de polyuréthane thermoplastiquement façonnables |
EP3812408A1 (fr) | 2019-10-23 | 2021-04-28 | Covestro Deutschland AG | Polymère de polyuréthane présentant une dureté <= 60 shore a et une bonne résistance à l'abrasion |
EP3812407A1 (fr) | 2019-10-23 | 2021-04-28 | Covestro Deutschland AG | Polymère de polyuréthane présentant une dureté de <= 60 shore a |
CN111019166A (zh) * | 2019-12-03 | 2020-04-17 | 东莞市雄林新材料科技股份有限公司 | 一种色口可调tpu薄膜及其制备方法 |
JP2023519814A (ja) | 2020-02-28 | 2023-05-15 | ビーエーエスエフ ソシエタス・ヨーロピア | 非一級ヒドロキシル基をベースとするフォーム |
WO2021200032A1 (fr) | 2020-03-31 | 2021-10-07 | 太陽インキ製造株式会社 | Composition de résine durcissable, produit durci et carte de circuit imprimé |
CN112646357B (zh) * | 2020-12-14 | 2023-01-10 | 东莞市雄林新材料科技股份有限公司 | 一种低收缩率tpu薄膜及其制备方法 |
CN114634623B (zh) * | 2020-12-16 | 2023-03-03 | 万华化学集团股份有限公司 | 一种大分子磷硅二元醇及其制备方法,一种快成型热塑性磷硅聚氨酯弹性体 |
TWI788086B (zh) * | 2021-11-04 | 2022-12-21 | 南亞塑膠工業股份有限公司 | 可適用於淋膜加工的熱塑性聚氨酯樹脂及其製造方法 |
CN114213621B (zh) * | 2022-01-19 | 2023-06-06 | 美瑞新材料创新中心(山东)有限公司 | 本体哑光热塑性聚氨酯弹性体材料及其制备方法和应用 |
EP4342924A1 (fr) | 2022-09-26 | 2024-03-27 | Covestro Deutschland AG | Procédé de préparation de polyuréthanes thermoplastiques contenant du polyéther |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1570673A1 (de) * | 1964-06-16 | 1970-01-22 | Goodrich Co B F | Verfahren zur Herstellung von thermoplastischen Polyesterurethanelastomeren |
US4202957A (en) * | 1974-09-09 | 1980-05-13 | The Upjohn Company | Thermoplastic polyurethane elastomers from polyoxypropylene polyoxyethylene block copolymers |
DE2842806A1 (de) * | 1978-09-30 | 1980-04-10 | Bayer Ag | Verfahren zur herstellung von polyurethan-elastomeren |
DE3323520A1 (de) | 1983-06-30 | 1985-01-10 | Basf Ag, 6700 Ludwigshafen | Weiche, gummielastische, thermoplastische polyurethane, verfahren zu deren herstellung und deren verwendung |
JPS61176624A (ja) * | 1985-02-01 | 1986-08-08 | Takeda Chem Ind Ltd | 軽中荷重用タイヤ |
DE3930523A1 (de) | 1989-09-13 | 1991-03-21 | Bayer Ag | Polyurethanelastomere mit geringer haerte |
DE4217367A1 (de) | 1992-05-26 | 1993-12-02 | Bayer Ag | Thermoplastisch verarbeitbare Polyurethan-Elastomere mit verbessertem Verarbeitungsverhalten und Verfahren zur Herstellung |
DE19625987A1 (de) | 1996-06-28 | 1998-01-02 | Bayer Ag | Verfahren zur kontinuierlichen Herstellung von thermoplastisch verarbeitbaren Polyurethanen mit verbessertem Verarbeitungsverhalten |
DE19907987C2 (de) | 1999-02-25 | 2001-05-23 | Bayer Ag | Weiche, thermoplastische Formmassen |
DE19939112A1 (de) | 1999-08-18 | 2001-02-22 | Basf Ag | Thermoplastische Polyurethane |
US6309313B1 (en) * | 1999-09-15 | 2001-10-30 | Uniroyal Chemical Company, Inc. | Low cost, resilient, shear resistant polyurethane elastomers for golf ball covers |
DE50306005D1 (de) * | 2002-02-23 | 2007-02-01 | Bayer Materialscience Ag | Verfahren zur Herstellung von weichen, gut entformbaren thermoplastischen Polyurethanelastomeren mit geringer Schwindung |
-
2003
- 2003-02-10 DE DE50306005T patent/DE50306005D1/de not_active Expired - Lifetime
- 2003-02-10 AT AT03002605T patent/ATE348849T1/de not_active IP Right Cessation
- 2003-02-10 EP EP03002605A patent/EP1338614B1/fr not_active Expired - Lifetime
- 2003-02-10 ES ES03002605T patent/ES2279017T3/es not_active Expired - Lifetime
- 2003-02-11 AU AU2003200443A patent/AU2003200443B2/en not_active Ceased
- 2003-02-18 CA CA002420191A patent/CA2420191A1/fr not_active Abandoned
- 2003-02-19 BR BR0300389-2A patent/BR0300389A/pt not_active IP Right Cessation
- 2003-02-19 US US10/368,708 patent/US6790916B2/en not_active Expired - Lifetime
- 2003-02-20 ZA ZA200301381A patent/ZA200301381B/xx unknown
- 2003-02-20 MX MXPA03001549A patent/MXPA03001549A/es active IP Right Grant
- 2003-02-20 JP JP2003042558A patent/JP4866536B2/ja not_active Expired - Fee Related
- 2003-02-21 TW TW092103584A patent/TWI276643B/zh not_active IP Right Cessation
- 2003-02-21 CN CNB031054552A patent/CN100354332C/zh not_active Expired - Lifetime
- 2003-02-22 KR KR10-2003-0011190A patent/KR20030070543A/ko not_active Application Discontinuation
- 2003-11-19 HK HK03108427A patent/HK1056186A1/xx not_active IP Right Cessation
-
2008
- 2008-05-30 JP JP2008143037A patent/JP2008202061A/ja active Pending
Also Published As
Publication number | Publication date |
---|---|
ZA200301381B (en) | 2004-02-20 |
AU2003200443B2 (en) | 2007-08-02 |
JP2003261642A (ja) | 2003-09-19 |
JP2008202061A (ja) | 2008-09-04 |
AU2003200443A1 (en) | 2003-09-11 |
EP1338614A1 (fr) | 2003-08-27 |
CN1439662A (zh) | 2003-09-03 |
ES2279017T3 (es) | 2007-08-16 |
MXPA03001549A (es) | 2005-02-14 |
US20030162932A1 (en) | 2003-08-28 |
KR20030070543A (ko) | 2003-08-30 |
ATE348849T1 (de) | 2007-01-15 |
CA2420191A1 (fr) | 2003-08-23 |
CN100354332C (zh) | 2007-12-12 |
US6790916B2 (en) | 2004-09-14 |
HK1056186A1 (en) | 2004-02-06 |
EP1338614B1 (fr) | 2006-12-20 |
TW200400209A (en) | 2004-01-01 |
BR0300389A (pt) | 2004-08-17 |
DE50306005D1 (de) | 2007-02-01 |
JP4866536B2 (ja) | 2012-02-01 |
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Legal Events
Date | Code | Title | Description |
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MM4A | Annulment or lapse of patent due to non-payment of fees |