TW466129B - Method of making supersaturated oxygenated liquid - Google Patents
Method of making supersaturated oxygenated liquid Download PDFInfo
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- TW466129B TW466129B TW089112885A TW89112885A TW466129B TW 466129 B TW466129 B TW 466129B TW 089112885 A TW089112885 A TW 089112885A TW 89112885 A TW89112885 A TW 89112885A TW 466129 B TW466129 B TW 466129B
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- ozone
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- oxygenated
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- 239000007788 liquid Substances 0.000 title claims abstract description 67
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 10
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims abstract description 80
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 49
- 239000001301 oxygen Substances 0.000 claims abstract description 49
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 49
- 239000007789 gas Substances 0.000 claims abstract description 22
- 238000000034 method Methods 0.000 claims description 18
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 11
- 238000012856 packing Methods 0.000 claims description 4
- 238000005086 pumping Methods 0.000 claims 1
- 238000004064 recycling Methods 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 36
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 16
- 229910052757 nitrogen Inorganic materials 0.000 description 8
- 235000019645 odor Nutrition 0.000 description 6
- 230000002079 cooperative effect Effects 0.000 description 5
- 229910052500 inorganic mineral Inorganic materials 0.000 description 5
- 239000011707 mineral Substances 0.000 description 5
- 150000002926 oxygen Chemical class 0.000 description 5
- 230000007423 decrease Effects 0.000 description 4
- 230000008014 freezing Effects 0.000 description 4
- 238000007710 freezing Methods 0.000 description 4
- 230000035939 shock Effects 0.000 description 4
- 241000894006 Bacteria Species 0.000 description 3
- 238000007689 inspection Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000010791 quenching Methods 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- 235000012206 bottled water Nutrition 0.000 description 2
- 238000006213 oxygenation reaction Methods 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 208000005156 Dehydration Diseases 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- OGIIWTRTOXDWEH-UHFFFAOYSA-N [O].[O-][O+]=O Chemical compound [O].[O-][O+]=O OGIIWTRTOXDWEH-UHFFFAOYSA-N 0.000 description 1
- 238000005273 aeration Methods 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000008451 emotion Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 229910052704 radon Inorganic materials 0.000 description 1
- SYUHGPGVQRZVTB-UHFFFAOYSA-N radon atom Chemical compound [Rn] SYUHGPGVQRZVTB-UHFFFAOYSA-N 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
- 238000011268 retreatment Methods 0.000 description 1
- 238000001223 reverse osmosis Methods 0.000 description 1
- 239000011555 saturated liquid Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/78—Treatment of water, waste water, or sewage by oxidation with ozone
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/20—Mixing gases with liquids
- B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
- B01F23/232—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using flow-mixing means for introducing the gases, e.g. baffles
- B01F23/2321—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using flow-mixing means for introducing the gases, e.g. baffles by moving liquid and gas in counter current
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/20—Mixing gases with liquids
- B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
- B01F23/237—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids characterised by the physical or chemical properties of gases or vapours introduced in the liquid media
- B01F23/2376—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids characterised by the physical or chemical properties of gases or vapours introduced in the liquid media characterised by the gas being introduced
- B01F23/23761—Aerating, i.e. introducing oxygen containing gas in liquids
- B01F23/237612—Oxygen
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/20—Mixing gases with liquids
- B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
- B01F23/237—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids characterised by the physical or chemical properties of gases or vapours introduced in the liquid media
- B01F23/2376—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids characterised by the physical or chemical properties of gases or vapours introduced in the liquid media characterised by the gas being introduced
- B01F23/23761—Aerating, i.e. introducing oxygen containing gas in liquids
- B01F23/237613—Ozone
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
- B01F25/30—Injector mixers
- B01F25/31—Injector mixers in conduits or tubes through which the main component flows
- B01F25/312—Injector mixers in conduits or tubes through which the main component flows with Venturi elements; Details thereof
- B01F25/3122—Injector mixers in conduits or tubes through which the main component flows with Venturi elements; Details thereof the material flowing at a supersonic velocity thereby creating shock waves
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F2101/00—Mixing characterised by the nature of the mixed materials or by the application field
- B01F2101/06—Mixing of food ingredients
- B01F2101/14—Mixing of ingredients for non-alcoholic beverages; Dissolving sugar in water
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/20—Mixing gases with liquids
- B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/20—Mixing gases with liquids
- B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
- B01F23/237—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids characterised by the physical or chemical properties of gases or vapours introduced in the liquid media
- B01F23/2373—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids characterised by the physical or chemical properties of gases or vapours introduced in the liquid media for obtaining fine bubbles, i.e. bubbles with a size below 100 µm
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/20—Treatment of water, waste water, or sewage by degassing, i.e. liberation of dissolved gases
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/78—Details relating to ozone treatment devices
- C02F2201/782—Ozone generators
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S261/00—Gas and liquid contact apparatus
- Y10S261/78—Sonic flow
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- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Mechanical Engineering (AREA)
- Thermal Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
- Food Preservation Except Freezing, Refrigeration, And Drying (AREA)
- Mixers With Rotating Receptacles And Mixers With Vibration Mechanisms (AREA)
- Physical Water Treatments (AREA)
- Oxygen, Ozone, And Oxides In General (AREA)
Description
4 6 61 2 9 A7 _B7__ 五、發明說明(/ ) 發明領域 C請先閱讀背面之注意事項再赛寫本頁> 本發明大致關於一種製造超飽和充氧液體之方法。更 特別地,本發明係關於製造超飽和充氧水,及將氧維持在 容器中之方法。 發明背景 近年來,消費者對於運動飮料之需求已實質上增加。運 動飮料,特別是使用充氧液體或甚至超飽和充氧氧氣,已 比碳酸蘇打更受歡迎。一些運動飮料加入礦物質以減緩 脫水症狀及提供幫助葡萄糖供應以製造能量。爲了對運 動飮料提供所需之充氧液體,將液體(例如,礦泉水)超飽 和至遠超過來自空氣分離之氧之正常量程度 '爲必要的。 爲了人體消耗而將液體滅菌及淨化亦爲必要的。 此技藝之作業已嚐試藉由降低水溫然後在使用盤之接 觸裝中將氧與水加壓,以努力驅使溶解之氧至高平衡含 量而增加氧在水中之平衡濃度。其使用純氧_。然而,已測 量之最大氧濃度僅爲約50毫克/公升。 經濟部智慧財產局員工消費合作社印製 在瓶裝水中得到高氧濃度爲特別困難的,因爲先行硏究 係針對製造”平衡氧”水,而非”超飽和氧”水。超飽和定義 爲其中溶解比水在平衡時可接受更多之氧之非穩定程 序。如果接觸裝置可提供充份之停留時間及保持氧氣爲 純的,則在5°C之急冷水溫可達到約50ppm之平衡濃度。 然而,礦泉水或任何來自天然來源之水含特定量之溶解 空氣》因爲空氣含79¾之氮,先行技藝使用之純氧自空氣 除去氮而形成低於1 00%之氧之混合物。因此,水與以替 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 4661 2 9 A7 B7 五、發明說明(>) 代純氣之氣體混合物建立平衡。由於熱量洩漏及管線磨 擦,如先行技藝將氣急冷及加壓僅可得到一部份之所需平 衡氣濃度。 此外,自水去除細菌通常藉逆驂透進行,其亦對水提供 不欲之味遒。有時藉由將空氣送經臭氧産生器而使用含 臭氣。任何未使用之臭氧自臭氣接觸裝置排氣^通常結 果為適當之氣溶解過程及有效之淨化過程。 因此希望一種新穎之方法以製造阻礙及防止細菌生長 之超飽和充氣液體。 g彥明概要 本發明之一種狀態傜關於一種製造超飽和充氣液體之 方法,其包括將高氣含量氣體引入臭氧産生器以製造臭氣, 在大氣壓力將臭氧送至接觸槽以製造充氧化與含臭氧液 體,及將充氧與含臭液體送至線上超音波混合器之接觸 迴路中以製造實質上純的超飽和充氣與含臭氣液體。 本發明之另一種狀態傺關於一種製造瓶裝超飽和充氧 液體之方法,其包括將髙氣含量氣體引入臭氧産生器以製 造臭氣,在大氣壓力將臭氧送至接觸槽以製造充氧與含 臭氣液,將充氣與含臭氣液體送至線上起音波混合器之接 觸迴路中以製造實質上純的超飽和充氣與含臭氧液體,及 將實質上純的超飽和充氣與含臭氣液體充瑱至瓶中及加 蓋。較佳為,此液體為水。 在此使用之名詞”實質上純的超飽和充.氣與含臭氣液 體”指已在接觸槽中處理且通過本發明之混合器之液體。
一 4 U 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) (請先閱讀背面之注§項再填窝本頁) 裝-------訂-------破 經濟部智慧財產局員工消費合作社印製 4661 2 9 A7 B7 五、發明說明(4 ) 通常,實質上純的超飽和充:氧1¾含臭氧液體具有離開接觸槽 者爲至少約30.毫克/公升至約50毫克/公升,較佳爲至少 40毫克/公升之溶解氧濃度。 圖式詳細說明 熟悉此技藝者可由以下較佳具體實施例之說明了解其 他之目的、特點及優點,而且唯一之附圖提供本發明方法 之略示圖。 發明詳細說明 本發明提供以氧將液體(較佳爲水)超飽和之節省成本 之方法.,而且亦提供且氧及同時提供淨化之超飽和和瓶裝 液體。 第一步驟爲自空氣排除溶解之氮。其藉由同時組合以 臭氧滅菌之步驟及平衡除去而進行。以純氧取代供應臭 氧產生器之空氣,因此無新鮮之氮來源(在此情形作爲情 氣)加入此系統° 臭氧產生器可使用純氧製造約10%至約15%之臭氧,而 使用空氣僅可製造約2%至約3%之臭氧。 將由純氧產生之臭氧送至在大氣壓力操作之臭氧接觸 器。臭氧用以破壞細菌且去除來自礦物與泉水之氣味及 有害有機物。在消耗氣體自臭氧接觸器排氣時,使用其餘 約85 %至9 0%之氧作爲除去氣體以去除溶解之氮。在或接 近大氣壓力操作臭氧接觸器使臭氧產生機械有效地操作, 而且有效地除去氮氣。 ‘可針對接觸槽冷凍。冷凍可爲封閉冷凍迴路之形式》 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) :---·!---1 裝---. .. (請先閱讀背面之注意事項再填寫本頁) 訂‘ 經濟部智慧財產局負工消費合作社印製 4 6 612 9 Δ7 Α7 _ Β7 經濟部智慧財產局員工消費合作社印製 五、發明說明(4 ) 較佳爲將接觸槽急冷至約3°C至約9°C,較佳爲約5°C之 平衡。 ., ’ 使用臭氧及純氧,離開臭氧接觸槽之液體具有接近約30 毫克/公升至約50.毫克/公升,較佳爲40毫克/公升之溶 解氧濃度。離開臭氧接觸器之水亦含溶解之臭氧。此溶 解之臭氧最終分解成氧與液體,提供以平衡上限將液體超 飽和之另一個來源。然而,臭氧僅具有數分鐘之有限儲存 壽命。因此,此含臭氧液體必須超飽和及儘快地瓶裝。爲 了完成此項工作,其以需要數秒級數之停留時之線上超音 波混合器進行。 爲了將含臭氧液體超飽和,將氧氣加入液體。使用泵以 將氧與臭充氧液體混合物加速至超音波速度》在氣泡存 在下,在超音波二相流動中音速由約5 ,000英呎/秒(在液 體中)降至低於約50英呎/秒》在速度降低時,形成震波 而將氣泡破碎成極微大小。由於震波在約90psig壓力發 生,液體可達到超過80毫克/公升,較佳爲90毫克/公升 之超飽和氧濃度。接觸迴路使極微氣泡及液體有數秒之 額外接觸時間。 在離開接觸迴路時,以純氧及溶解之臭氧將液體超飽 和。立即將仍含極微氧氣泡之超飽和充氧液體送至將其 瓶裝之充塡器。超飽和氧在壓力下降時離開溶液。在將 液體充塡至瓶中時,壓力可下降至大氣壓力,除非使用加 壓充塡機。在線上仍有壓力下降而降低總壓力。因此,立 _即將瓶充塡及加蓋爲重要的。極微氧氣泡降低氧自溶液 -6- (請先閱讀背面之注意事項再填寫本頁) 裝— IJI 訂 _!!
, 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) A7 經濟部智慧財產局員工消費合作社印製 4 6 61 2 9 -------- 五、發明說明(f ) 散逸之速率。其亦對瓶之上頭空間提供氣氈。只要充塡 及加蓋可在比氧離開瓶之散發速率高之速率實行,可得到 超飽和溶液。 在將瓶加蓋之後.,液解之臭氧分解成臭氧及液體,增加 瓶蓋液體之超飽和程度。溶解之臭氧提供之額外氧超過 補償在充塡及加蓋操作之最後步騾之損失。在超飽和步 驟後立即進行最後之充塡及加蓋步驟爲重要的。 消耗之臭氧,及來自臭氧接觸器之氧,可用以在充塡前 沖洗空瓶。此步驟幫助排除瓶中之空氣及將其滅菌。 亦可將另一個實質上^充氧及氧臭氧液體流再循環及 進料至接觸槽之底部。 實例 第1圖敘述在臭氧接觸槽中將水超飽和之二階段方法。 略示地,此方法以系統,1 0進行。將臭氧/純氧混合物I 2 加入臭氧接觸槽1 6之底部。將水1 4引入接觸槽1 6之頂 部。離開臭氧接觸槽16底部之臭氧/氧化混合物18通過 七段離心泵20而形成超飽和充氧混合物22,然後送至流 量計24及除去器26,然後至孔口板30而形成超飽和充 氧液體50。超飽和充氧液體50在離開前通過濾器44成 爲超飽和充氧液體46以充塡。在充塡以流量計40及檢 視鏡42監視超飽和充氧液體46之流動。檢視鏡36及壓 力計3 4監測超飽和液體在孔口板3 0之流動。在孔口板 30.之前將除去器26及氧28線上安置。旁通閥38調節 '超飽和充氧液體48且選擇性地將超飽和充氧液體48引 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐)
4 6 61 2 9 A7 B7 五、發明說明(以 回接觸槽1 6之底部。冷凍迴路-5 2提供冷凍以將接觸槽 】6中之液體急冷° 更常爲,此步驟包括同時組合使用臭氧之滅菌步驟及平 衡除去。以純氧取.代供應臭氧產生器之空氣,因此防止任 何新鮮之氮來源進入系統中作爲惰氣•臭氧產生器使用 純氧製造約10¾至約15%之臭氧,相對地,在臭氧產生器中 僅使用空氣僅製造約2%至約3 %之臭氧。將以純氧產生之 臭氧送至在大氣壓力操作之臭氧接觸器。臭氧破壞細菌 且去除來自礦物或泉水之氣味及有害有機物。在消耗氣 體自臭氧接觸器頂部排氣時,使用其餘約85%至90%之氧 作爲除去氣體以去除溶解之氮。 在接觸上之冷動迴路將其中之含臭氧及充氧水急冷。 使用臭氧及純氧,離開臭氧接觸器之水具有約33毫克/ 公升至約39毫克/公升之溶解氧濃度" 使用離心泵將臭氧/氧飽和水泵離奥氧接觸器以將水之 壓力增至約^Opsig至約90psig。視瓶子大小及機械之 充塡速率而定,流速爲約25gpm至約75gpm。在超音波混 合器之前將氧加入泵之下游。將約180 scf/小時之氧進 料至35gpm之水中。一般而言,可將約170scf /小時至約 190scf/小時之氧進料至約30gpm至約40gpm之水中。在 氣泡存在下,在超音波二相流動中音速由5,000英呎/秒 (在液體中)降至低於50英呎/秒。在速度降低時,形成震 波而將氣泡破碎成極微大小。由於震波在約90psig壓力 發生,水達到超過90毫克/公升之超飽和氧濃度。 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 閲 讀 背 面 之 注 項 填 寫 本 頁 經濟部智慧財產局員工消費合作社印製 4661 2 9 A7 B7 經濟部智慧財產局員工消費合作社印製 五、發明說明(7 ) 2”接觸迴路使極微氣泡及水有數秒之額外接觸時間。 +在迴轉迴路使用五個3 / 4 ”內徑之孔口板以再分配二相混 合物。 在離開接觸迴路時,以純氧及溶解之臭氧將水超飽和。 立即將仍含極微氧氣泡之超飽和充氧水送至將其瓶裝 之充塡器。超飽和氧在壓力下降時離開溶液。在將水充 塡至瓶中時,壓力下降至大氣壓力,除非使用加壓充塡 機。在線上仍有壓力下降而降低總壓力。因此,立即將瓶 充塡及加蓋。極微氧氣泡降低氧自溶液散逸之速率。其 亦對瓶之上頭空間提供氣氈。只要充塡及加蓋可在比氣 離開瓶之散發速率髙之速率實行,可得到超飽和溶液。 一種在以超飽和充氧及含臭氧水充塡瓶時維持臭氧與 氧濃度之替代方法爲藉由壓力充塡實質上純的充氧及含 臭氧液體》 另一種在瓶中提供高濃度超飽和及含臭氧水之方法爲 藉由在充塡前對瓶施加相對壓力。降低瓶中之氣體壓力 可藉由使用氧或臭氧將瓶中內容物撒出以充塡而完成。 在充塡機停止或流速降低時,打開旁通閥以使超飽和水 再循環回到使含臭氧槽。如此防止管路壓力過大。使甩 濾器去除任何特定物質。然而,以緊密方式配置流量計, 檢視鏡、及塡料以使充塡機之距離最小。 . 在將瓶加蓋後,溶解之臭氧分解成臭氧及水而增加瓶裝 水中之氧超飽和程度。溶解之臭氧提供之額外氧超過補 償在充塡及加蓋操作之最後步驟之損失。在超飽和步驟 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐〉 - i—'ί'ί d''1裝·!ml — 訂 *!1 * (請先閱讀背面之注意事項/再療寫本頁)
I 線、- 46612 9 A7 _B7_ 五、發明說明(3 ) 後立即進行最後之充填及加蓋步驟為重要的。 消耗之臭氣及來自臭氧接觸器之氧可用以在充槙前沖 洗空瓶。此步驟幫助排除瓶中之空氣及將其滅菌。 將另一個實質上純充氣及含臭氧水流再循環及接觸槽 之底部以對此方法提供適當之壓力。 僅為了方便而在一或更多個圔式中顯示本發明之特定 特擻,各項特徽均可其他依照本發明之特點一起組合。 熟悉此技藝者應了解尚有替代的具體實施例,並且該等 具體宵施例傜包括在申諳專利範圍之範圍内。 符號之說明 (請先閲讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 10" •糸 統 12- 臭 氧 /純氣混合物 14“ 水 16.· 臭 氧 接 At» 觸 槽 18« 含 臭 氧 充 氧 混 合物 2 0*· 七 段 離 心 泵 2 2·· 超 飽 和 充 氣 混 合物 2 4·, 流 量 計 2 6- 除 去 器 2 8.· 氣 3 0- 孔 Ρ 板 3 4·* 壓 力 計 3 6·· 檢 視 鏡 本紙張尺度適用中國國家標準(CNS>A4規格(210 X 297公Μ ) 4661 2 9 A7 _B7 五、發明說明() 38.. .旁通閥 4 0 ...流量計 . 4 2 ...檢視鏡 44 ...過濾器 46.. .超飽和充氧液體 48.. .超飽和充氧液體 5 0...超飽和充氧液體 5 2...冷凍迴路 (請先閱讀背面之注意事項再淡寫本頁) 裝—--訂--------線· 經濟部智慧財產局員工消費合作社印製 -11- 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐)
Claims (1)
- 46612 9 A8 B8 C8 D8 申請專利範圍 1, —種製造超飽和充氧液體之方法,其包括 a) 將高氧含量氣體引入臭氧產生器以製造臭氧; b) 在大氣壓力將該臭氧送至接觸槽以製造充氧與含 臭氧液體;及 c) 將該充氧與含臭氧液體送至線上超音波混合器之 接觸迴路中以製造實質上純的超飽和充氧與含臭氧液 體。 2. 如申請專利範圍第1項之方法,其中該高氧含量氣體爲 純氧" 如申請專利範圍第1項之方法,其進一步争^該臭充(請先閲讀背面之;i意事項再填寫本頁) i 經濟部智慧財產局員工消費合作社印製 氧液體分解成氧與液體 •如申請專利範圍第兮:方養:.擊包TS在離心泵中 發生將充氧與含體混合物#至該線上超音波混 合器之該接觸迴路中,以在每分鐘約25至約75加侖之 速率將液體壓力由約50增至90psig。 .如申請専利範圍第1項之方法,其進一步包括將該實質 上純的超飽和充氧與含臭氧液體再循環至該接觸槽。 .一種製造瓶裝超飽和充氧液體之方法,其包括 a) 將高氧含量氣體引入臭氧產生器以製造臭氧; b) 在大氣壓力將臭氧送至接觸槽以製造充氧與含臭 液體; c) 將該充氧與含臭液體送至線上超音波混合器之接 觸迴路中以製造實質上純的超飽和充氧與含臭液體;及 d) 將該實質上純的超飽和充氧與含臭氧液體充塡至 -12- 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公Μ ) -浪---------訂---------線"^ 4661 2 9 申請專利範圍 A8 B8 C8 D8(請先閱讀背面之注意事項再填寫本頁) 裝--------訂---------線- 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐)
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US09/345,099 US6250609B1 (en) | 1999-06-30 | 1999-06-30 | Method of making supersaturated oxygenated liquid |
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TW466129B true TW466129B (en) | 2001-12-01 |
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US (1) | US6250609B1 (zh) |
EP (1) | EP1064987A1 (zh) |
JP (1) | JP3770776B2 (zh) |
KR (1) | KR100499179B1 (zh) |
CN (1) | CN1280796A (zh) |
AR (1) | AR024604A1 (zh) |
AU (1) | AU774501B2 (zh) |
BR (1) | BR0002897A (zh) |
CA (1) | CA2313176A1 (zh) |
ID (1) | ID26446A (zh) |
MX (1) | MXPA00006496A (zh) |
PL (1) | PL341084A1 (zh) |
TW (1) | TW466129B (zh) |
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1999
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2000
- 2000-06-12 ID IDP20000485D patent/ID26446A/id unknown
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- 2000-06-29 KR KR10-2000-0036339A patent/KR100499179B1/ko not_active IP Right Cessation
- 2000-06-29 CA CA002313176A patent/CA2313176A1/en not_active Abandoned
- 2000-06-29 PL PL00341084A patent/PL341084A1/xx unknown
- 2000-06-29 AR ARP000103283A patent/AR024604A1/es not_active Application Discontinuation
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- 2000-06-29 JP JP2000195888A patent/JP3770776B2/ja not_active Expired - Fee Related
- 2000-06-29 AU AU43732/00A patent/AU774501B2/en not_active Ceased
- 2000-06-29 CN CN00118457A patent/CN1280796A/zh active Pending
- 2000-06-29 EP EP00113143A patent/EP1064987A1/en not_active Withdrawn
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BR0002897A (pt) | 2001-01-30 |
MXPA00006496A (es) | 2002-03-08 |
AR024604A1 (es) | 2002-10-16 |
ID26446A (id) | 2001-01-04 |
KR100499179B1 (ko) | 2005-07-04 |
CA2313176A1 (en) | 2000-12-30 |
AU774501B2 (en) | 2004-07-01 |
CN1280796A (zh) | 2001-01-24 |
JP3770776B2 (ja) | 2006-04-26 |
US6250609B1 (en) | 2001-06-26 |
AU4373200A (en) | 2001-01-04 |
KR20010049662A (ko) | 2001-06-15 |
EP1064987A1 (en) | 2001-01-03 |
JP2001054725A (ja) | 2001-02-27 |
PL341084A1 (en) | 2001-01-02 |
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