TW419534B - A zinc coated/electrogalvanized sheet or stripe - Google Patents
A zinc coated/electrogalvanized sheet or stripe Download PDFInfo
- Publication number
- TW419534B TW419534B TW088117729A TW88117729A TW419534B TW 419534 B TW419534 B TW 419534B TW 088117729 A TW088117729 A TW 088117729A TW 88117729 A TW88117729 A TW 88117729A TW 419534 B TW419534 B TW 419534B
- Authority
- TW
- Taiwan
- Prior art keywords
- sheet
- strip
- zinc
- layer
- zinc oxide
- Prior art date
Links
- 239000011701 zinc Substances 0.000 title claims abstract description 37
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title claims abstract description 34
- 229910052725 zinc Inorganic materials 0.000 title claims abstract description 34
- 239000010410 layer Substances 0.000 claims abstract description 61
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 48
- 239000011787 zinc oxide Substances 0.000 claims abstract description 24
- 238000000576 coating method Methods 0.000 claims abstract description 15
- 239000011241 protective layer Substances 0.000 claims abstract description 7
- 239000011248 coating agent Substances 0.000 claims description 12
- 238000003466 welding Methods 0.000 claims description 9
- 238000012360 testing method Methods 0.000 claims description 6
- 238000011049 filling Methods 0.000 claims description 4
- 230000003647 oxidation Effects 0.000 claims description 4
- 238000007254 oxidation reaction Methods 0.000 claims description 4
- 238000005259 measurement Methods 0.000 claims 5
- 239000007853 buffer solution Substances 0.000 claims 4
- 238000003723 Smelting Methods 0.000 claims 1
- 238000012795 verification Methods 0.000 claims 1
- 238000007747 plating Methods 0.000 abstract description 45
- 239000012670 alkaline solution Substances 0.000 abstract description 31
- 229910001297 Zn alloy Inorganic materials 0.000 abstract description 20
- 229910000831 Steel Inorganic materials 0.000 abstract description 12
- 238000000034 method Methods 0.000 abstract description 12
- 239000010959 steel Substances 0.000 abstract description 12
- 230000001681 protective effect Effects 0.000 abstract description 11
- 239000000243 solution Substances 0.000 abstract description 11
- 239000000047 product Substances 0.000 description 31
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 25
- 238000004140 cleaning Methods 0.000 description 18
- 239000007800 oxidant agent Substances 0.000 description 16
- 239000008151 electrolyte solution Substances 0.000 description 9
- 238000005246 galvanizing Methods 0.000 description 8
- 238000012545 processing Methods 0.000 description 7
- 239000003513 alkali Substances 0.000 description 6
- 229910045601 alloy Inorganic materials 0.000 description 6
- 239000000956 alloy Substances 0.000 description 6
- 230000002079 cooperative effect Effects 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 239000003792 electrolyte Substances 0.000 description 5
- 238000007654 immersion Methods 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 230000001590 oxidative effect Effects 0.000 description 5
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 description 4
- 229910052802 copper Inorganic materials 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 235000015170 shellfish Nutrition 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 230000032683 aging Effects 0.000 description 3
- 238000005520 cutting process Methods 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 238000007761 roller coating Methods 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000000872 buffer Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 238000002161 passivation Methods 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 229940098465 tincture Drugs 0.000 description 2
- 241000345998 Calamus manan Species 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 229910052688 Gadolinium Inorganic materials 0.000 description 1
- 240000000233 Melia azedarach Species 0.000 description 1
- 235000006679 Mentha X verticillata Nutrition 0.000 description 1
- 235000002899 Mentha suaveolens Nutrition 0.000 description 1
- 235000001636 Mentha x rotundifolia Nutrition 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- 240000002853 Nelumbo nucifera Species 0.000 description 1
- 235000006508 Nelumbo nucifera Nutrition 0.000 description 1
- 235000006510 Nelumbo pentapetala Nutrition 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 1
- 208000034804 Product quality issues Diseases 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- 238000002848 electrochemical method Methods 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 230000002431 foraging effect Effects 0.000 description 1
- UIWYJDYFSGRHKR-UHFFFAOYSA-N gadolinium atom Chemical compound [Gd] UIWYJDYFSGRHKR-UHFFFAOYSA-N 0.000 description 1
- 210000004907 gland Anatomy 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- NPEWZDADCAZMNF-UHFFFAOYSA-N gold iron Chemical group [Fe].[Au] NPEWZDADCAZMNF-UHFFFAOYSA-N 0.000 description 1
- 229910052735 hafnium Inorganic materials 0.000 description 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000009533 lab test Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910000480 nickel oxide Inorganic materials 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000010955 niobium Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical class [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 235000012950 rattan cane Nutrition 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000035943 smell Effects 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000010129 solution processing Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-N sulfurothioic S-acid Chemical compound OS(O)(=O)=S DHCDFWKWKRSZHF-UHFFFAOYSA-N 0.000 description 1
- 239000012085 test solution Substances 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- UGZADUVQMDAIAO-UHFFFAOYSA-L zinc hydroxide Chemical compound [OH-].[OH-].[Zn+2] UGZADUVQMDAIAO-UHFFFAOYSA-L 0.000 description 1
- 229940007718 zinc hydroxide Drugs 0.000 description 1
- 229910021511 zinc hydroxide Inorganic materials 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
- C23C28/32—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer
- C23C28/322—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer only coatings of metal elements only
- C23C28/3225—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer only coatings of metal elements only with at least one zinc-based layer
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/04—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
- C23C2/06—Zinc or cadmium or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/26—After-treatment
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/34—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the shape of the material to be treated
- C23C2/36—Elongated material
- C23C2/40—Plates; Strips
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/60—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using alkaline aqueous solutions with pH greater than 8
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/68—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous solutions with pH between 6 and 8
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
- C23C28/34—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates
- C23C28/345—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates with at least one oxide layer
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/22—Electroplating: Baths therefor from solutions of zinc
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/48—After-treatment of electroplated surfaces
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D7/00—Electroplating characterised by the article coated
- C25D7/06—Wires; Strips; Foils
- C25D7/0614—Strips or foils
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12535—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.] with additional, spatially distinct nonmetal component
- Y10T428/12583—Component contains compound of adjacent metal
- Y10T428/1259—Oxide
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12771—Transition metal-base component
- Y10T428/12785—Group IIB metal-base component
- Y10T428/12792—Zn-base component
- Y10T428/12799—Next to Fe-base component [e.g., galvanized]
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mechanical Engineering (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Electrochemistry (AREA)
- Coating With Molten Metal (AREA)
- Electroplating Methods And Accessories (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Electroplating And Plating Baths Therefor (AREA)
- Chemical Treatment Of Metals (AREA)
Description
419534 Α7 Β7 五、發明説明(1 ) 發明背景 本發明係關於一種改良鍍鋅及鍍鋅合金片形銷之成形 性、熔接性及表面外觀之方法,特別本發明係針對改良電 鍍鋅片彤鋼之成形.性及熔接性。鍍鋅片形網用於多種不同 的汽車組件。例如熱浸鍍鋅片形綱用於汽車之表面外觀要 緊的部分,例如下車體、門梁及車厢内飾。它方面由於退 火鍍鋅、電鍍鋅及鍍鋅合金片形銷具有高度表面品質外觀 *故其用於汽車整痼外部例如門頂罩及車厢面蓋等高度光 澤塗漆整飾重要的部分。 鍍鋅片形銷產品於汽車市場上佔有極大佔有率,原因 爲其具有絕佳防蝕性及防機械損壊性。但某些情況下保護 性鍍鋅層比較鍍鋅合金層,就成形性和熔接性而言不利。 適用於Η肜產物之鍍鋅層於壓縮成形操作中容易變形 和擦傷。當成形衝頭接觸產物之鍍面時,鍍面擦傷並於模 具内部堆稹鋅片。鋅片又造成成形片形產物最终產品的表 面外觀瑕疵*欲克服此種問題,須要連續停機來維修,並 清潔壓機的成形模具。 經濟部中央標準局貝工消費合作社印製 ———— %τ. (請先閱讀背面之注項再填寫本頁) 鍍鋅銷片的熔接性也成問題。通常比鍍鋅合金或未鍍 鋅銷片之熔接性差。原因為鋅鏟層於電阻熔接過程中熔化 並與電極梢端的銅形成合金。化學反應造成熔接接點品質 不良且縮短熔接捎端赛命。 鍍鋅片形鏑遭遇的成彤及熔接困難為銷鑲造業眾所周 知。過去曾經多方面嘗試改良成形性及熔接性。對此問題 較有意義的解決辦法之一係於保護性鋅或鋅合金鍍層外面 本紙張尺度適用中囷國家榇準(CNS ) A4規格(210 X 297公釐) A7 B7 4 19534 五、發明説明(2 提供一層可改良成形性及熔接性之層。 1974年10月22日頒予Brown之美國專利3,843,494顯示 一種改良。Brown揭示一種方法包括於含鐵金靥基質上施 用各別鋅金屬層及鐵金属層之步驟,最外層為鐵金藤層, 其可促進多層鍍鋅含鐵基質藉電阻點熔接而熔接。 業界比較針對表面外観而非熔接性之另一改良示於美 國專利4, 707,415。此專利教示將鍍鋅合金片形銷浸泡於 酸性氧化溶液而以電化學方式於鋅合金鍍層表面上生成一 層鈍化狀態層。鈍化狀態層包括鋅和鎳之氧化物、氫氧化 物及硫化物中之至少一者。 美國專利4, 957,.594及5,203,986揭示於鋅及鋅合金銷 表面上生成氧化鋅層來改良熔接性。594號專利教示添加 氧化劑至醴性鍍浴而於電鍍操作中生成氧化鋅或氫氧化鋅 層。同理,98$號專利也教示於酸性鍍浴中經由使用氧化 劑生成氧化物層,但額外引進緩衝劑至浴中來控制pH值 經濟部中央標準局負工消費合作社印製 引進各種氧化劑及緩衝劑至鍍敷浴及镀浴中來改良成 形性及熔接性由操作觀點看來不合所需。此等添加劑溶液 產生複雜且有時無法預測的反應,其可能導致環保及產品 品質方面的問題。例如添加Ha 0於硫睃鋅鍍浴對鋅鍍層形 態可能造成不良衝擊且產生不適合汽車表面的鍍層。此等 添加劑也容易降低鍍敷生產線效率》此外當硝酸鹽或亞硝 酸鹽氧化劑加入鍍浴時,可能沈澱成錯合化合物,此乃環 保不兌許者,必須處理後才能抛寨。 本紙張尺度適用中國国家標卒(CNS ) A4現格(210Χ:Ϊ97公釐〉 5 經濟部中央標準局員工消費合作社印製 419534 五、發明説明(3 ) 業已發現前述問題可經由使用一種後鍍敷或後塗敷_ 性溶液處理而於片形鋼產物生成的鋅或鋅合金層外表面上 生成一塯氧化鋅層而避免。此種目標可經由將包括氧化劑 之鹼性溶液於與鑌敷浴或鍍浴分開的位置施用於鋅或鋅合 金層表面上逹成。鹼性溶液於鋅或鋅合金層’表面上生成一 層適當的氧化物層,改良成性彤及熔接性,又可避免環保 及產品品質問題。 發明概述 因此本發明之一個目的係數改良鍍敷或鍍鋅或鋅合金 片形銷產物之成形性及熔接性。 本發明之又_目的係提供具有絕佳表面品質及外觀同 時改良成形性及熔接性之鍍敷或鍍鋅或鋅合金Η形銷產物 〇 本ώ明之又一目的係於生成於片形銷產物的鋅或鋅合 金層表面上生成氧化物鍍堉來改良片形銷產物之成形性及 熔接性。_ 本發明之又另一目的係於生成於片彤銷產物的鋅或鋅 合金層表面上生成氧化物鍍層來改良片彩鏑產物之成形性 及熔接性而無須於鍍敷浴或鍍浴内引進添加劑。 最後本發明之又另一目的係經由施用包括氧化劑之鹼 性溶液至生成於片形銷產物上的鋅或鋅合金層表面而於其 表面上生成氧化層來改良片彩銷產物之成形性及熔接性而 減少環保衝擊,鹺性溶液係於與鍍敷浴或鍍浴分開的位置 施用。 本紙張尺度適用中國囷家梯準(CNS ) A4规格(210X297公釐) (請先閲讀背面之注意事項寫本頁)
、tT 6 419.5 34 ^ 五、發明説明(4 ) 本發明之其它目的及優點由說明書將顯然自明。 發明人發現前述目的可經由使用一種後鍍敷或後塗敷 方法於其至少一表面上生成有保謹性鋅或鋅合金曆的片形 銅產物來改良成彤性及熔接性而達成。該方法之步驟包括 浸沒片形網產物至至少含鋅之浴內而施用保護層,而浴中 移出片形銷產物,片形銷產物於其至少一面上生成有保護 性鋅或鋅合金層,及施用包括氧化劑之鹼性溶掖至保護層 而於其至少一面上生成鋅氧化物層,鹼性溶液係於與浴分 開的處所施用。 匾示之簡單說明 第1圖顯示本發明用於鍍鋅生產線之較佳具體例。 第2圖為類似第1圖之本發明之另一具體例。 第3圖為類似第1圖之本發明之又另一具體例。 第4画顯示本發明用於恰在鍍浴後進行清洗的鍍敷生 產線。 第5圖顯示本發明用於熱浸;鍍鋅生產線。 較佳具體例之說明 經濟部中央樣準局貝工消費合作社印製 (諳先聞讀背面之注意事項待填寫本頁) 改良鍍敷或鍍鋅或鋅合金片形銷產物之成形性及熔接 性之較佳方法包括後鍍敷步驟 > 施用包括氧化劑之鹼性溶 液至銪基材土的保護性鍍敷®或鍍層而於其至少一面上生 成鋅氧化物層,鹼性溶液係於與鍍敷浴或鍍浴分開的處斬 施用。參考附圖第1圖,無端式片形鏑長條1A於電鍍鋅生 產線A之最末鍍池2内電化學鍍敷。較佳具體例中片形網 浸沒於鍍鋅浴3並通過多對隔開的陽極4間而鍍敷無端式 本紙張尺度適用中國國家標隼(CNS ) A4規格(210X297公釐) 7 4195 34 A? B7 五、發明説明(5 ) 片形鋼長條1A兩側。但須了解可使用單一陽極來僅鍍敷銷 條一側而未悖離本發明之範圍。 最終鍍敷步驟完成後*如鍍池2之舉例說明,鍍鋅片 形銅長條繼繙朝向鹼性處理站5前進,於此處施用氧化劑 至保護性鋅層而於其表面上產生鋅氧化物層。有助於改良 此種鍍辞片形銷產物之成形性及熔接性。較佳具體例中長 條1A嗅種含氧化劑之經缓衝的鹼性溶液6。鹼處理站5包 含嗅頭7具有多痼噴嘴8可供施用鹼性溶液6至長條1A表 面0 鹾性溶液內之氧化劑與銷條上方的鍍鋅層反應生成鋅 氧化物外層,片形鋇長條1A朝向洗滌站9前進,於此處約 120乍之溫水清洗施用於鍍敷妥的片形產物上長達约20秒 。然後長條前進至乾燥站10,於此處使用風乾機或電阻乾 燥器或其它適當裝置乾燥器來乾燥片形辋產物,隨後片形 鋼缒績前進接受進一步加工例如上油,剪成定長,及捲曲 或盤曲供蓮輸。 經濟部中央標準局負工消費合作社印製 (請先Μ讀背面之注意事項#/^寫本頁) —腺· 參考附圖第2圖,連續片肜銷長條1A於類似第1圈所 示生產線之電鍍鋅生產線A之最末鍍池2接受電化學鍍敷 。最末鍍敷步驟完成後*鍍鋅片彤銷長條繼薄朝向鹾處理 站5前進,於此處氧化劑施用於保護性鋅層而於其表面上 產生鋅氧化物層。此種替代具體例中,長條1A浸沒於含氧 化劑之經緩衝的鹼性溶液6A。鹼處理站5包含一嫡浸沒棺 7a,其只有至少一根下沈辊8a可供導引長條1A進入鹼性溶 液内。 本紙張尺度適用中囯國赛镡牟(CNS ) Α4規格(210X 297公釐) 8 419534 A7 B7 五、發明説明(6 ) 經濟部中央標準局貝工消費合作社印装 參考附圖第3圖 > 連绪片形銷長條1A於亦類似第1圖 所示生產線之電鍍鋅生產線A之最末鍍池2接受電化學鍍 敷。最末鍍敷步驟芫成後,鍍鋅片彤銷長條繼續朝向鹼處 理站5前進,於此處氧化劑施用於保護性鋅描而於其表面 上產生鋅氧化物層。此種替代具體例中,鹼處理站5包含 滾塗裝置7b可供施用鹼性溶液至長條1A之一面或多面上而 生成鋅氧化物層。 發現處理站5之浸沒槽7內所含較佳驗性溶液6須為 氧化劑於pH 7-11範圍之經缓衝的鹼性溶液。試驗也顯示 欲生成大於0.15 g/m2之適當鋅氧化物層,鹼性溶液需施 用於保謹性鋅層於約20-5010溫度範圍經歴約1-17秒時間 。較佳處理方法及鹼性溶液係基於下述硏究。 準備實驗室試驗樣品,首先於鹼性溶液清潔樣品,然 後浸沒於酸浸浴内的活化,然後於表A所示鍍敷條件下電 鍍樣品τ。然後樣品噴灑表B所示多種龄性溶液*接著於約 49溫度以溫水清洗20秒然後熱風乾燥。經氧化的樣品最 終試驗其成形性及熔接性Μ及檢視表面品質及外觀。 由表Β所示該组鹼性溶液,發現使用包括30 g/1 H a〇: 之‘經緩衝的鹼性溶液製備的樣品具有最佳結果。也發現 Ha〇e可K 10 g/Ι至100 g/1 H8〇a之比率添加至鹼性溶液 ,以30 g/Ι至60 g/1 Ha〇a為較佳範圍,而以30 g/1 Ha〇a 爲龄性溶液之最佳配方。 利用此種知識,使用包括30 g/1 Ha〇a之經缓衝及未 經缓衝的鹼性溶篏製備進一步試驗樣品,樣品與使用業界 請 先 閲 面 之 注 意事 養 訂 本紙張尺度適用中國國家標準(CNS ) A4也格(210X297公釐) 4195 34 A 7 B7 _ ______________ . 五、發明説明(7 ) » 眾所周知的其它氧化方法製備的試驗樣品比較決定例如表 C所示樣品3,4及5之氧化物層係使用鍍鉑鈮不溶性陽 極之電化學方法生成。試驗全部樣品之成形性及焰接性。 試驗結果示於表C。 由此硏究工作結果發現較佳生成鋅氧化物層之後鍍敷 或後塗覆龄性溶液包括NaOH + NaHC〇3 + 30 g/1 Hb〇s, ?}1範圍約7.8-8.4,溫度範圍約20-50它。 參考附圖第4圖,後鍍敷或後塗覆鹼性處理發明之另 —具體例用於電鍍生產線B,B恰在最末鍍浴12之後有個 清洗站。電鍍生產線B包括一片無端式片形鋼長條1B於鍍 池12内於含鋅離子之鍍浴11内處理而於片形銷長條至少一 面上生成鋅或鋅合金保護層。鍍池包含多對互相隔開的陽 極13,片形钢長條於含離子之酸性浴11中作為陰極。經鍍 敷的片形鋼長條由鍍池中去除並前進至選擇性清洗步驟, Μ站14表示。 ! φΐ (請先閲讀背面之注意事項再填寫本頁)
、tT 經濟部4*央標準局另工消費合作社印裝 CNs'jT^ ( 21〇X297,a^ , 10 經濟部中央橾準局貝工消費合作社印製 419534 at . B7 五、發明説明丨3 )
表 A 浴 型 ' 硫酸鹽 Ζη* * 100 g/1 pH 1.5-2.8 溫 度 40-601C 鍍層重量 60 g/m2 電流密度 60 A/d m3 表 B 编號 後處理 表面薄膜内之 平均Zn〃重量 g/ma 化學溶掖 pH 1 NaOH η- 30 g/1 Ha〇a 10.03 0.195 2 Na0H+NaHC03+30 g/l Ha〇a 7.8 to 8.4 0.340 3 NaOH 10.03 0.071 4 NaOH + 10 g/1 NaHC〇3 8.26 0.149 5 NaOH + 3 g/1 Ha〇s 10.00 0.165. 6 NaOH+3g/l Ha〇a+5g/l NaHC03 8. 17 0.237 7 NaOH+3g/l Ha〇a+10g/l NaHC03 8.18 0.164 8 NaOH + 10 g/1 NaN.03 10.04 0.103 (請先Μ讀背面之注意事項,填寫本頁) 訂 本紙張尺度適用中國囤家梂準(CNS ) Α4规格(210Χ 297公釐} -11 - 經濟部中央樣準局員工消費合作社印製 419534 A7 B7 五、發明説明(9 ) ① σι CO EV3 — 光 m m 2: Μ Μ CU ρ sj as cn 3c ο α ο « *· on 口 〇 cn i—* D o〇 υι as "z: H fl> o o » 工 + 趙:z: ώί p> mt κ 2: 〇i ο m •TO m m Μ »1—^0 ο ο 0¾ -♦*— CG 〇d 私 EC + 菏 TIT^I M 十 0<i *3 ^ O o 菡s ο 雜 Η— <=> Qi 2: + M o + m.u CTQ 、 CT^ 〇 £J n ^ -f-UJ o 0¾ 1—· ί—* 3: Μ α μ 姻 浮怎 1 s跽蹢 Ξ蹂硇 謝 fi 1 1 >滿菡 ^ ϊ^· cr 瑙 離 a k ® * k Rfli 姻 縮 撖 θ„活浮 ΰδί 姻 m m 3 — υα CTi 之ai U1 Μ 1彌 o tNJ o to Ο ο :到 o oo CTN Ul Ul 0〇 LTt LO 各 h-* \D Ο \jn 曰《彌 ^ N- 1¾ 1~> to I-— un ί-Π 1~» oo 1—* υο U1 t—* \£3 〇 ι—* A Ο )—» CO o 加+, -¾ 1 η 阵 o CD CD ◦ Ο o 泰Μ 1~~* CO o o' v£> \J\ j—* >—* \〇 to o o )—* ο θ'» >—* k—k 娌 ^ m » L〇 ] H-* 浴. 鈿茄 办 ο to o 1 1 CTv o CTN ο ο 濫遂 ο o o ο ο mm m • ^^^1 I I !*-· 1^—· ^^^1 ^^^1 II -1 ^^^1 -- - - -ysu^ (請先聞讀背面之注意事項一^寫本頁) I --- n ---- —i It— 本紙張尺度逋用中國國家標準(CNS ) A4規格(21〇X 297公釐) 經濟部中央標準局貝工消費合作社印製 4 195 34 A7 B7 五、發明説明(10 ) 清洗站14包含任何適合清洗或清潔鍍鋅銷表面之清洗 裝置。本例中發明人使用噴灑清洗。清洗包括水清洗、稀 睃清洗如稀硫酸溶液清洗或含鋅離子之酸性清洗。 於站14清洗處理後,於電解質站16電解質施用於保護 性鋅或鋅合金展。第2圖中片形銷長條浸泡於浸沒棺內所 含之電解質溶液15内。此步驟係於鹼性溶液處理前進行而 於保護層表面上生成鋅電解質層。_解質可藉桊界已知任 何其它適當手段例如噴灑滾塗等施用於片形銷長條之鍍面 上。但須了解於站16施用電解質溶液之方法並非電化學輔 助方法。此外也須了解若站14之酸性清洗包括鋅離子濃度 於約40 g/Ι之範圍,則施用電解質溶液至片形鋼之站16可 於第4圖教示之方法中刪除。 於施用電解質溶液至長條之步驟後,長條前進至類似 第1 - 3圖所示處理站之鹼性溶液處理站5,或桊界已知 施用鹸性溶液至長條表面之任何類似裝置。此種情況下處 理站5包括滾塗裝置17來施用鹼性溶液至保護性鋅或鋅合 金層而於其至少一面上生成鋅氣化物層。 鋅氧化物層生成後,長條前進至洗滌站18,於此處約 120T之溫水清洗施用至經鍍敷的片形產物經歴約20秒時 間。然後長條前進至乾燥站19,於此處使用風乾機或電阻 乾操器或任何其它裝置乾燥器來乾燥清洗妥的片形產物, 隨後片形銅前進接受進一步加工處理例如上油,剪成定長 或捲曲或盤曲供運輸。 第5圖顯示本發明用於熱浸鍍鋅生產線。熱浸鍍鋅生 本紙張尺度適用中國國家標準(CNS ) Α4規格(210\297公釐) (請先閲讀背面之注意事項『填寫本頁) 、?τ 13 419534 A7 B7 五、發明説明(11 ) 產線C包括一條無端式片形網長條1C浸沒於槽21内所含之 熱浸鋅或鋅合金浴20内。某些例中片形銷長條通過一根通 風管22進入熱浸浴。長條藉下沈辊23浸沒於浴内而通過兩 粮氣髏擦拭裝置24間來從銷片表面上去除過量鍍層。此時 片形辆條可於烘箱内退火產生俗稱_退火鍍鋅的退火產品, 或跳過退火步驟而以熱浸鍍鮮產品出售。兩種情況下,熱 浸產品皆有電解質溶液25M類似第4圖所示之方法步驟中 施用於其鍍面。 參考第5圖,熱浸鍍敷產物浸沒於含有包括鋅離子之 電解質溶液25之槽26內。此步驟係於施用鹼性溶液處理而 於熱浸鍍層表面上形成鋅氧化物層之前進行。如前述,電 解質可藉業界已知任何適當裝置例如噴塗或滾塗施用於片 形飼條的熱浸鍍鋅面上。然而亦須了解施用電解質溶液25 之步驟非電化學輔助方法。 施用電解質溶液後長條前進至類似第1及2圖所示處 理站之鹼性溶液處理站5。鍍敷線C所示處理站5包括一 部噴蕕装置27來施用含氧化劑之鹼性溶骹至熱浸鍍鋅片形 銷表面。 經濟部中央槁準局員工消費合作社印製 1J —»^^1 ^^^^1 —Hu m ^^1 7 -戈 . " Ή (請先閱讀背面之注意事項忠^-寫本頁) 齡性溶液造成鋅氧化物層於長條表面生成後,銷條前 進至清滌站28,於此處施用水清洗至鍍鋅片彤產物。然後 銷絛前進至乾燥站29,於此處使用風乾或電阻乾燥器或其 它適當乾燥器裝置來乾燥清洗妥的片形產物,隨後銷片鈕 續接受進一步處理例如上油、剪成定長及捲曲或盤曲供蓮 _ 0 本紙張尺度適用中國國家標準(CNS ) A4規格(2IOX297公釐) -14 - A7 B7 419534 五、發明説明(12) 第1 - 5圖所示之任一具體例中,包括氧化劑之經缀 衝或未绖緩衝鹼性溶液皆可用來於鍍敷妥的片形銷產物至 少一面上生成氧化物層。. 雖然已經就較佳設計描述本發明但須了解可遵照本發 明之一般原則做出進一歩修改,利用及/或調整且包含屬 於相關業界之已知或習知實務範圍内且可應用至本文所述 中心特性且落入隨附之申請專利範圍界定之本發明範圍内 之其它偏離本揭示内容之例。 元件標號對照 請 先 閱 讀 背 之 注 意 事 項 f 經濟部中央標準局員工消費合作社印製 1 . . _ · 片形銷長條 10, 19,29 ----乾燥站 2, 12 _ _ ..鍍池 11 · ; * 鍍浴 3 … 鍍鋅浴 12 ' - 鍍池 4,13 _ ..陽極 13 - * * 陽極 5 _ 鹼處理站 14 · * 清洗站 6 » 6a … ..經缓衝的鹼性溶液 15, 25 . ••電解質溶液 7…. 噴頭 16 p 電解質站 7 3 .... 浸沒搰 20 ' * * 熱浸鍍鋅或鋅合金浴 7b,17 . ...•滾塗裝置 21, 26 · · 槽 8 · . _ 噴嘴 22 * « » · 通風管 8a,23 . ...下沈辊 24 » · » 氣醱擦拭裝置 9,18,28 ——洗滌站 27 丨* · 噴濯裝置 訂 本紙張尺度適用中國國家標準(CNS ) A4規格(210X 297公釐)
Claims (1)
- A8R8C8D8經濟部智慧財產局員工消費合作社印製 419534 申印專利範圍 種電鍍鋅片或長條’其具有改良的成形性及溶接 性,該薄片或長條由以下步驟製成: a) 提供一電鍍鋅薄片或長條; b) 化學地施用一具有7.8至8.4之pH值範圍的鹼性 緩衝溶液至該電鍍鋅薄板或長條; c) 施用該驗性緩衝溶液歷時一段足夠時間以於該 電鍍鋅的薄片或長條上形成一氧化鋅層,該層 有至少為0.340 g/m2的Zn++濃度,該具有已形 成的氧化辞保護層的薄片或長條藉由一為至少 為1_401吋的極限圓頂高度與一為至少為〇1〇6的 摩擦係數之測量結果而具有改善的成形性,以 及藉由至少4000次的熔接稍端壽命周期數的測 量結果而具有改善的嫁接性。 如申請專利範圍第1項之薄片或長條,其中該氧化鋅層 有—超過0_15 g/m2的塗層重量。 —種鍍鋅薄片或長條,其具有改良的成形性及熔接性, 該薄片或長條由以下步驟製成: a) 提供一鍍鋅薄片或長條; b) 化學地施用一具有7.8至8.4之PH範圍的鹼性緩 衝溶液至該鑛辞薄板或長條; c) 施用該鹼性緩衝溶液歷時一段足夠時間以於該 鐘鋅的薄片或長條上形成一氧化鋅層,該層有 一至少為0_340 g/m2的Zn++濃度,該具有已形成 的氧化辞保護層的薄片或長條藉由一為至少 ___ -4- 本紙張尺度適用國國家標準(CNSM4規格⑵Ο X 297公楚) (請先閱讀背面之注意事項再填寫本頁)經濟部智慧財產局員工消費合作枉印製 419534 g ___ D8 六、申請專利範圍 1.401吋的極限圓頂高度與一為至少0.106的摩擦 係數之測量結果而具有改善的成形性,以及藉 由至少4000次的熔接稍端壽命周期數的測量結 果而具有改善的炫接性。 4.如申請專利範圍第3項之薄片或長條,其中該氧化鋅層 有一超過0.15 g/m2的塗層重量。 5,一種鍍鋅薄片或長條,其具有改善的成形性或是熔接 性,該薄片或長條包含有: 於一鐘鋅薄片或長條的至少一面上形成一層氧化 鋅層’該薄層有至少為3.40g/m2的Zn++濃度,該具 有已形成的氧化鋅保護層的薄片或長條藉由一為 至少1.401吋的極限圓頂高度與一為至少〇.1〇6的摩 擦係數之測夏結果而具有改善的成形性,以及藉 由至少4000 -欠的炼接稍端壽命周期數的測量結果 具有改善的熔接性。 6. 如申請專利範圍第5項之薄片或長條,其中該氧化鋅層 有一超過0.15 g/m2的塗層重量。 7, 如申請專利範圍第5項的薄片或長條,其中該薄片或長 條為電鍍鋅薄片或長條^ (請先閱讀背面之注意事項再填寫本頁)----1 —訂---------線·- 本紙張〜X遇财關家鮮(CNS) AI規格 297公釐)
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US44765695A | 1995-05-23 | 1995-05-23 |
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TW085105315A TW401468B (en) | 1995-05-23 | 1996-05-03 | Process for improving the formability and weldability properties of zinc coated sheet steel |
TW088117729A TW419534B (en) | 1995-05-23 | 1996-05-03 | A zinc coated/electrogalvanized sheet or stripe |
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EP (1) | EP0744475B1 (zh) |
JP (1) | JPH08325791A (zh) |
KR (1) | KR100292229B1 (zh) |
AT (1) | ATE175730T1 (zh) |
BR (1) | BR9602406A (zh) |
CA (1) | CA2175105C (zh) |
DE (1) | DE69601323T2 (zh) |
TW (2) | TW401468B (zh) |
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JP3435255B2 (ja) * | 1995-05-30 | 2003-08-11 | 新日本製鐵株式会社 | 潤滑性に優れた電気亜鉛系めっき鋼板の製造設備 |
JPH08325790A (ja) * | 1995-05-31 | 1996-12-10 | Nippon Steel Corp | 潤滑性に優れた電気亜鉛系めっき熱延鋼板の製造設備 |
US6599643B2 (en) | 1997-01-31 | 2003-07-29 | Elisha Holding Llc | Energy enhanced process for treating a conductive surface and products formed thereby |
US6592738B2 (en) | 1997-01-31 | 2003-07-15 | Elisha Holding Llc | Electrolytic process for treating a conductive surface and products formed thereby |
US6322687B1 (en) | 1997-01-31 | 2001-11-27 | Elisha Technologies Co Llc | Electrolytic process for forming a mineral |
US6149794A (en) * | 1997-01-31 | 2000-11-21 | Elisha Technologies Co Llc | Method for cathodically treating an electrically conductive zinc surface |
US6231686B1 (en) | 1997-11-10 | 2001-05-15 | Ltv Steel Company, Inc. | Formability of metal having a zinc layer |
CN100434564C (zh) * | 2001-10-23 | 2008-11-19 | 住友金属工业株式会社 | 热压成型方法,其电镀钢材及其制备方法 |
US20040188262A1 (en) * | 2002-02-05 | 2004-09-30 | Heimann Robert L. | Method for treating metallic surfaces and products formed thereby |
AU2003209010A1 (en) * | 2002-02-05 | 2003-09-02 | Elisha Holding Llc | Method for treating metallic surfaces and products formed thereby |
JP4617826B2 (ja) * | 2004-10-26 | 2011-01-26 | 凸版印刷株式会社 | 黒化処理装置 |
JP5354166B2 (ja) * | 2007-12-27 | 2013-11-27 | Jfeスチール株式会社 | 亜鉛系めっき鋼板の製造方法 |
KR101360802B1 (ko) | 2008-12-16 | 2014-02-10 | 제이에프이 스틸 가부시키가이샤 | 아연계 도금 강판의 제조 방법 |
DE102009053368A1 (de) * | 2009-11-14 | 2011-05-19 | Bayerische Motoren Werke Aktiengesellschaft | Verfahren und Fertigungsanlage zum Herstellen eines Blechformteils mit einer Korrosionsschutzbeschichtung |
MX369049B (es) * | 2011-07-15 | 2019-10-28 | Tata Steel Nederland Tech Bv | Aparato para producir aceros recocidos y proceso para producir dichos aceros. |
BR112015010909A2 (pt) | 2012-11-19 | 2017-07-11 | Chemetall Gmbh | processo para revestir superfícies metálicas com camadas de óxido de zinco nanocristalinas, composições aquosas para esse fim e uso das superfícies revestidas dessa maneira |
EP2851452B1 (de) * | 2013-09-19 | 2019-04-17 | Fuchs Petrolub SE | Anorganische Funktionsschicht auf feuerverzinktem Stahl als Umformhilfe |
EP3161176B1 (en) | 2014-06-27 | 2018-12-19 | Henkel AG & Co. KGaA | Dry lubricant for zinc coated steel |
EP3470553A4 (en) * | 2016-06-09 | 2019-08-21 | JFE Steel Corporation | METHOD FOR PRODUCING A GALVANIZED STEEL PLATE AND MANUFACTURING DEVICE THEREFOR |
CN107739809B (zh) * | 2017-10-24 | 2019-03-08 | 浙江博星工贸有限公司 | 一种奥氏体不锈钢钢带的固溶处理方法 |
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US3415692A (en) * | 1965-03-12 | 1968-12-10 | Combustion Eng | Method of passivating metal surfaces |
GB1281872A (en) * | 1969-07-02 | 1972-07-19 | British Steel Corp | Improvements in or relating to the formation of zinc-iron-coatings |
JPS5413858B2 (zh) * | 1974-05-20 | 1979-06-02 | ||
US4707415A (en) * | 1985-03-30 | 1987-11-17 | Sumitomo Metal Industries, Ltd. | Steel strips with corrosion resistant surface layers having good appearance |
JPH01149996A (ja) * | 1987-12-08 | 1989-06-13 | Nippon Steel Corp | スポット溶接性に優れためっき鋼板の製造方法 |
EP0329057B1 (en) * | 1988-02-19 | 1994-08-10 | Nippon Steel Corporation | Use of a zinc- or zinc alloy-coated steel sheet having excellent spot-weldability |
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JPH0421751A (ja) * | 1990-05-16 | 1992-01-24 | Kawasaki Steel Corp | スポット溶接性,化成処理及びプレス加工時の摺動性に優れた溶融亜鉛系めっき鋼板の製造方法 |
-
1996
- 1996-04-26 CA CA002175105A patent/CA2175105C/en not_active Expired - Fee Related
- 1996-05-03 TW TW085105315A patent/TW401468B/zh not_active IP Right Cessation
- 1996-05-03 TW TW088117729A patent/TW419534B/zh active
- 1996-05-09 KR KR1019960015162A patent/KR100292229B1/ko not_active IP Right Cessation
- 1996-05-14 EP EP96107647A patent/EP0744475B1/en not_active Expired - Lifetime
- 1996-05-14 DE DE69601323T patent/DE69601323T2/de not_active Expired - Fee Related
- 1996-05-14 AT AT96107647T patent/ATE175730T1/de not_active IP Right Cessation
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EP0744475B1 (en) | 1999-01-13 |
BR9602406A (pt) | 1998-10-06 |
DE69601323T2 (de) | 1999-09-09 |
JPH08325791A (ja) | 1996-12-10 |
TW401468B (en) | 2000-08-11 |
US5660707A (en) | 1997-08-26 |
CA2175105C (en) | 1999-09-21 |
KR100292229B1 (ko) | 2001-06-01 |
KR960041398A (ko) | 1996-12-19 |
DE69601323D1 (de) | 1999-02-25 |
US5714049A (en) | 1998-02-03 |
EP0744475A1 (en) | 1996-11-27 |
ATE175730T1 (de) | 1999-01-15 |
CA2175105A1 (en) | 1996-11-24 |
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