TW419534B - A zinc coated/electrogalvanized sheet or stripe - Google Patents

A zinc coated/electrogalvanized sheet or stripe Download PDF

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Publication number
TW419534B
TW419534B TW088117729A TW88117729A TW419534B TW 419534 B TW419534 B TW 419534B TW 088117729 A TW088117729 A TW 088117729A TW 88117729 A TW88117729 A TW 88117729A TW 419534 B TW419534 B TW 419534B
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Taiwan
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sheet
strip
zinc
layer
zinc oxide
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TW088117729A
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English (en)
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C Ramadeva Shastry
Stavros G Fountoulakis
Elmer J Wendell
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Bethlehem Steel Corp
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/30Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
    • C23C28/32Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer
    • C23C28/322Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer only coatings of metal elements only
    • C23C28/3225Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer only coatings of metal elements only with at least one zinc-based layer
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/04Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
    • C23C2/06Zinc or cadmium or alloys based thereon
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/26After-treatment
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/34Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the shape of the material to be treated
    • C23C2/36Elongated material
    • C23C2/40Plates; Strips
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/60Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using alkaline aqueous solutions with pH greater than 8
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/68Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous solutions with pH between 6 and 8
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/30Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
    • C23C28/34Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates
    • C23C28/345Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates with at least one oxide layer
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00Electroplating: Baths therefor
    • C25D3/02Electroplating: Baths therefor from solutions
    • C25D3/22Electroplating: Baths therefor from solutions of zinc
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/48After-treatment of electroplated surfaces
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D7/00Electroplating characterised by the article coated
    • C25D7/06Wires; Strips; Foils
    • C25D7/0614Strips or foils
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12493Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12535Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.] with additional, spatially distinct nonmetal component
    • Y10T428/12583Component contains compound of adjacent metal
    • Y10T428/1259Oxide
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12493Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12771Transition metal-base component
    • Y10T428/12785Group IIB metal-base component
    • Y10T428/12792Zn-base component
    • Y10T428/12799Next to Fe-base component [e.g., galvanized]

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mechanical Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Coating With Molten Metal (AREA)
  • Electroplating Methods And Accessories (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)
  • Electroplating And Plating Baths Therefor (AREA)
  • Chemical Treatment Of Metals (AREA)

Description

419534 Α7 Β7 五、發明説明(1 ) 發明背景 本發明係關於一種改良鍍鋅及鍍鋅合金片形銷之成形 性、熔接性及表面外觀之方法,特別本發明係針對改良電 鍍鋅片彤鋼之成形.性及熔接性。鍍鋅片形網用於多種不同 的汽車組件。例如熱浸鍍鋅片形綱用於汽車之表面外觀要 緊的部分,例如下車體、門梁及車厢内飾。它方面由於退 火鍍鋅、電鍍鋅及鍍鋅合金片形銷具有高度表面品質外觀 *故其用於汽車整痼外部例如門頂罩及車厢面蓋等高度光 澤塗漆整飾重要的部分。 鍍鋅片形銷產品於汽車市場上佔有極大佔有率,原因 爲其具有絕佳防蝕性及防機械損壊性。但某些情況下保護 性鍍鋅層比較鍍鋅合金層,就成形性和熔接性而言不利。 適用於Η肜產物之鍍鋅層於壓縮成形操作中容易變形 和擦傷。當成形衝頭接觸產物之鍍面時,鍍面擦傷並於模 具内部堆稹鋅片。鋅片又造成成形片形產物最终產品的表 面外觀瑕疵*欲克服此種問題,須要連續停機來維修,並 清潔壓機的成形模具。 經濟部中央標準局貝工消費合作社印製 ———— %τ. (請先閱讀背面之注項再填寫本頁) 鍍鋅銷片的熔接性也成問題。通常比鍍鋅合金或未鍍 鋅銷片之熔接性差。原因為鋅鏟層於電阻熔接過程中熔化 並與電極梢端的銅形成合金。化學反應造成熔接接點品質 不良且縮短熔接捎端赛命。 鍍鋅片形鏑遭遇的成彤及熔接困難為銷鑲造業眾所周 知。過去曾經多方面嘗試改良成形性及熔接性。對此問題 較有意義的解決辦法之一係於保護性鋅或鋅合金鍍層外面 本紙張尺度適用中囷國家榇準(CNS ) A4規格(210 X 297公釐) A7 B7 4 19534 五、發明説明(2 提供一層可改良成形性及熔接性之層。 1974年10月22日頒予Brown之美國專利3,843,494顯示 一種改良。Brown揭示一種方法包括於含鐵金靥基質上施 用各別鋅金屬層及鐵金属層之步驟,最外層為鐵金藤層, 其可促進多層鍍鋅含鐵基質藉電阻點熔接而熔接。 業界比較針對表面外観而非熔接性之另一改良示於美 國專利4, 707,415。此專利教示將鍍鋅合金片形銷浸泡於 酸性氧化溶液而以電化學方式於鋅合金鍍層表面上生成一 層鈍化狀態層。鈍化狀態層包括鋅和鎳之氧化物、氫氧化 物及硫化物中之至少一者。 美國專利4, 957,.594及5,203,986揭示於鋅及鋅合金銷 表面上生成氧化鋅層來改良熔接性。594號專利教示添加 氧化劑至醴性鍍浴而於電鍍操作中生成氧化鋅或氫氧化鋅 層。同理,98$號專利也教示於酸性鍍浴中經由使用氧化 劑生成氧化物層,但額外引進緩衝劑至浴中來控制pH值 經濟部中央標準局負工消費合作社印製 引進各種氧化劑及緩衝劑至鍍敷浴及镀浴中來改良成 形性及熔接性由操作觀點看來不合所需。此等添加劑溶液 產生複雜且有時無法預測的反應,其可能導致環保及產品 品質方面的問題。例如添加Ha 0於硫睃鋅鍍浴對鋅鍍層形 態可能造成不良衝擊且產生不適合汽車表面的鍍層。此等 添加劑也容易降低鍍敷生產線效率》此外當硝酸鹽或亞硝 酸鹽氧化劑加入鍍浴時,可能沈澱成錯合化合物,此乃環 保不兌許者,必須處理後才能抛寨。 本紙張尺度適用中國国家標卒(CNS ) A4現格(210Χ:Ϊ97公釐〉 5 經濟部中央標準局員工消費合作社印製 419534 五、發明説明(3 ) 業已發現前述問題可經由使用一種後鍍敷或後塗敷_ 性溶液處理而於片形鋼產物生成的鋅或鋅合金層外表面上 生成一塯氧化鋅層而避免。此種目標可經由將包括氧化劑 之鹼性溶液於與鑌敷浴或鍍浴分開的位置施用於鋅或鋅合 金層表面上逹成。鹼性溶液於鋅或鋅合金層’表面上生成一 層適當的氧化物層,改良成性彤及熔接性,又可避免環保 及產品品質問題。 發明概述 因此本發明之一個目的係數改良鍍敷或鍍鋅或鋅合金 片形銷產物之成形性及熔接性。 本發明之又_目的係提供具有絕佳表面品質及外觀同 時改良成形性及熔接性之鍍敷或鍍鋅或鋅合金Η形銷產物 〇 本ώ明之又一目的係於生成於片形銷產物的鋅或鋅合 金層表面上生成氧化物鍍堉來改良片形銷產物之成形性及 熔接性。_ 本發明之又另一目的係於生成於片彤銷產物的鋅或鋅 合金層表面上生成氧化物鍍層來改良片彩鏑產物之成形性 及熔接性而無須於鍍敷浴或鍍浴内引進添加劑。 最後本發明之又另一目的係經由施用包括氧化劑之鹼 性溶液至生成於片形銷產物上的鋅或鋅合金層表面而於其 表面上生成氧化層來改良片彩銷產物之成形性及熔接性而 減少環保衝擊,鹺性溶液係於與鍍敷浴或鍍浴分開的位置 施用。 本紙張尺度適用中國囷家梯準(CNS ) A4规格(210X297公釐) (請先閲讀背面之注意事項寫本頁)
、tT 6 419.5 34 ^ 五、發明説明(4 ) 本發明之其它目的及優點由說明書將顯然自明。 發明人發現前述目的可經由使用一種後鍍敷或後塗敷 方法於其至少一表面上生成有保謹性鋅或鋅合金曆的片形 銅產物來改良成彤性及熔接性而達成。該方法之步驟包括 浸沒片形網產物至至少含鋅之浴內而施用保護層,而浴中 移出片形銷產物,片形銷產物於其至少一面上生成有保護 性鋅或鋅合金層,及施用包括氧化劑之鹼性溶掖至保護層 而於其至少一面上生成鋅氧化物層,鹼性溶液係於與浴分 開的處所施用。 匾示之簡單說明 第1圖顯示本發明用於鍍鋅生產線之較佳具體例。 第2圖為類似第1圖之本發明之另一具體例。 第3圖為類似第1圖之本發明之又另一具體例。 第4画顯示本發明用於恰在鍍浴後進行清洗的鍍敷生 產線。 第5圖顯示本發明用於熱浸;鍍鋅生產線。 較佳具體例之說明 經濟部中央樣準局貝工消費合作社印製 (諳先聞讀背面之注意事項待填寫本頁) 改良鍍敷或鍍鋅或鋅合金片形銷產物之成形性及熔接 性之較佳方法包括後鍍敷步驟 > 施用包括氧化劑之鹼性溶 液至銪基材土的保護性鍍敷®或鍍層而於其至少一面上生 成鋅氧化物層,鹼性溶液係於與鍍敷浴或鍍浴分開的處斬 施用。參考附圖第1圖,無端式片形鏑長條1A於電鍍鋅生 產線A之最末鍍池2内電化學鍍敷。較佳具體例中片形網 浸沒於鍍鋅浴3並通過多對隔開的陽極4間而鍍敷無端式 本紙張尺度適用中國國家標隼(CNS ) A4規格(210X297公釐) 7 4195 34 A? B7 五、發明説明(5 ) 片形鋼長條1A兩側。但須了解可使用單一陽極來僅鍍敷銷 條一側而未悖離本發明之範圍。 最終鍍敷步驟完成後*如鍍池2之舉例說明,鍍鋅片 形銅長條繼繙朝向鹼性處理站5前進,於此處施用氧化劑 至保護性鋅層而於其表面上產生鋅氧化物層。有助於改良 此種鍍辞片形銷產物之成形性及熔接性。較佳具體例中長 條1A嗅種含氧化劑之經缓衝的鹼性溶液6。鹼處理站5包 含嗅頭7具有多痼噴嘴8可供施用鹼性溶液6至長條1A表 面0 鹾性溶液內之氧化劑與銷條上方的鍍鋅層反應生成鋅 氧化物外層,片形鋇長條1A朝向洗滌站9前進,於此處約 120乍之溫水清洗施用於鍍敷妥的片形產物上長達约20秒 。然後長條前進至乾燥站10,於此處使用風乾機或電阻乾 燥器或其它適當裝置乾燥器來乾燥片形辋產物,隨後片形 鋼缒績前進接受進一步加工例如上油,剪成定長,及捲曲 或盤曲供蓮輸。 經濟部中央標準局負工消費合作社印製 (請先Μ讀背面之注意事項#/^寫本頁) —腺· 參考附圖第2圖,連續片肜銷長條1A於類似第1圈所 示生產線之電鍍鋅生產線A之最末鍍池2接受電化學鍍敷 。最末鍍敷步驟完成後*鍍鋅片彤銷長條繼薄朝向鹾處理 站5前進,於此處氧化劑施用於保護性鋅層而於其表面上 產生鋅氧化物層。此種替代具體例中,長條1A浸沒於含氧 化劑之經緩衝的鹼性溶液6A。鹼處理站5包含一嫡浸沒棺 7a,其只有至少一根下沈辊8a可供導引長條1A進入鹼性溶 液内。 本紙張尺度適用中囯國赛镡牟(CNS ) Α4規格(210X 297公釐) 8 419534 A7 B7 五、發明説明(6 ) 經濟部中央標準局貝工消費合作社印装 參考附圖第3圖 > 連绪片形銷長條1A於亦類似第1圖 所示生產線之電鍍鋅生產線A之最末鍍池2接受電化學鍍 敷。最末鍍敷步驟芫成後,鍍鋅片彤銷長條繼續朝向鹼處 理站5前進,於此處氧化劑施用於保護性鋅描而於其表面 上產生鋅氧化物層。此種替代具體例中,鹼處理站5包含 滾塗裝置7b可供施用鹼性溶液至長條1A之一面或多面上而 生成鋅氧化物層。 發現處理站5之浸沒槽7內所含較佳驗性溶液6須為 氧化劑於pH 7-11範圍之經缓衝的鹼性溶液。試驗也顯示 欲生成大於0.15 g/m2之適當鋅氧化物層,鹼性溶液需施 用於保謹性鋅層於約20-5010溫度範圍經歴約1-17秒時間 。較佳處理方法及鹼性溶液係基於下述硏究。 準備實驗室試驗樣品,首先於鹼性溶液清潔樣品,然 後浸沒於酸浸浴内的活化,然後於表A所示鍍敷條件下電 鍍樣品τ。然後樣品噴灑表B所示多種龄性溶液*接著於約 49溫度以溫水清洗20秒然後熱風乾燥。經氧化的樣品最 終試驗其成形性及熔接性Μ及檢視表面品質及外觀。 由表Β所示該组鹼性溶液,發現使用包括30 g/1 H a〇: 之‘經緩衝的鹼性溶液製備的樣品具有最佳結果。也發現 Ha〇e可K 10 g/Ι至100 g/1 H8〇a之比率添加至鹼性溶液 ,以30 g/Ι至60 g/1 Ha〇a為較佳範圍,而以30 g/1 Ha〇a 爲龄性溶液之最佳配方。 利用此種知識,使用包括30 g/1 Ha〇a之經缓衝及未 經缓衝的鹼性溶篏製備進一步試驗樣品,樣品與使用業界 請 先 閲 面 之 注 意事 養 訂 本紙張尺度適用中國國家標準(CNS ) A4也格(210X297公釐) 4195 34 A 7 B7 _ ______________ . 五、發明説明(7 ) » 眾所周知的其它氧化方法製備的試驗樣品比較決定例如表 C所示樣品3,4及5之氧化物層係使用鍍鉑鈮不溶性陽 極之電化學方法生成。試驗全部樣品之成形性及焰接性。 試驗結果示於表C。 由此硏究工作結果發現較佳生成鋅氧化物層之後鍍敷 或後塗覆龄性溶液包括NaOH + NaHC〇3 + 30 g/1 Hb〇s, ?}1範圍約7.8-8.4,溫度範圍約20-50它。 參考附圖第4圖,後鍍敷或後塗覆鹼性處理發明之另 —具體例用於電鍍生產線B,B恰在最末鍍浴12之後有個 清洗站。電鍍生產線B包括一片無端式片形鋼長條1B於鍍 池12内於含鋅離子之鍍浴11内處理而於片形銷長條至少一 面上生成鋅或鋅合金保護層。鍍池包含多對互相隔開的陽 極13,片形钢長條於含離子之酸性浴11中作為陰極。經鍍 敷的片形鋼長條由鍍池中去除並前進至選擇性清洗步驟, Μ站14表示。 ! φΐ (請先閲讀背面之注意事項再填寫本頁)
、tT 經濟部4*央標準局另工消費合作社印裝 CNs'jT^ ( 21〇X297,a^ , 10 經濟部中央橾準局貝工消費合作社印製 419534 at . B7 五、發明説明丨3 )
表 A 浴 型 ' 硫酸鹽 Ζη* * 100 g/1 pH 1.5-2.8 溫 度 40-601C 鍍層重量 60 g/m2 電流密度 60 A/d m3 表 B 编號 後處理 表面薄膜内之 平均Zn〃重量 g/ma 化學溶掖 pH 1 NaOH η- 30 g/1 Ha〇a 10.03 0.195 2 Na0H+NaHC03+30 g/l Ha〇a 7.8 to 8.4 0.340 3 NaOH 10.03 0.071 4 NaOH + 10 g/1 NaHC〇3 8.26 0.149 5 NaOH + 3 g/1 Ha〇s 10.00 0.165. 6 NaOH+3g/l Ha〇a+5g/l NaHC03 8. 17 0.237 7 NaOH+3g/l Ha〇a+10g/l NaHC03 8.18 0.164 8 NaOH + 10 g/1 NaN.03 10.04 0.103 (請先Μ讀背面之注意事項,填寫本頁) 訂 本紙張尺度適用中國囤家梂準(CNS ) Α4规格(210Χ 297公釐} -11 - 經濟部中央樣準局員工消費合作社印製 419534 A7 B7 五、發明説明(9 ) ① σι CO EV3 — 光 m m 2: Μ Μ CU ρ sj as cn 3c ο α ο « *· on 口 〇 cn i—* D o〇 υι as "z: H fl> o o » 工 + 趙:z: ώί p> mt κ 2: 〇i ο m •TO m m Μ »1—^0 ο ο 0¾ -♦*— CG 〇d 私 EC + 菏 TIT^I M 十 0<i *3 ^ O o 菡s ο 雜 Η— <=> Qi 2: + M o + m.u CTQ 、 CT^ 〇 £J n ^ -f-UJ o 0¾ 1—· ί—* 3: Μ α μ 姻 浮怎 1 s跽蹢 Ξ蹂硇 謝 fi 1 1 >滿菡 ^ ϊ^· cr 瑙 離 a k ® * k Rfli 姻 縮 撖 θ„活浮 ΰδί 姻 m m 3 — υα CTi 之ai U1 Μ 1彌 o tNJ o to Ο ο :到 o oo CTN Ul Ul 0〇 LTt LO 各 h-* \D Ο \jn 曰《彌 ^ N- 1¾ 1~> to I-— un ί-Π 1~» oo 1—* υο U1 t—* \£3 〇 ι—* A Ο )—» CO o 加+, -¾ 1 η 阵 o CD CD ◦ Ο o 泰Μ 1~~* CO o o' v£> \J\ j—* >—* \〇 to o o )—* ο θ'» >—* k—k 娌 ^ m » L〇 ] H-* 浴. 鈿茄 办 ο to o 1 1 CTv o CTN ο ο 濫遂 ο o o ο ο mm m • ^^^1 I I !*-· 1^—· ^^^1 ^^^1 II -1 ^^^1 -- - - -ysu^ (請先聞讀背面之注意事項一^寫本頁) I --- n ---- —i It— 本紙張尺度逋用中國國家標準(CNS ) A4規格(21〇X 297公釐) 經濟部中央標準局貝工消費合作社印製 4 195 34 A7 B7 五、發明説明(10 ) 清洗站14包含任何適合清洗或清潔鍍鋅銷表面之清洗 裝置。本例中發明人使用噴灑清洗。清洗包括水清洗、稀 睃清洗如稀硫酸溶液清洗或含鋅離子之酸性清洗。 於站14清洗處理後,於電解質站16電解質施用於保護 性鋅或鋅合金展。第2圖中片形銷長條浸泡於浸沒棺內所 含之電解質溶液15内。此步驟係於鹼性溶液處理前進行而 於保護層表面上生成鋅電解質層。_解質可藉桊界已知任 何其它適當手段例如噴灑滾塗等施用於片形銷長條之鍍面 上。但須了解於站16施用電解質溶液之方法並非電化學輔 助方法。此外也須了解若站14之酸性清洗包括鋅離子濃度 於約40 g/Ι之範圍,則施用電解質溶液至片形鋼之站16可 於第4圖教示之方法中刪除。 於施用電解質溶液至長條之步驟後,長條前進至類似 第1 - 3圖所示處理站之鹼性溶液處理站5,或桊界已知 施用鹸性溶液至長條表面之任何類似裝置。此種情況下處 理站5包括滾塗裝置17來施用鹼性溶液至保護性鋅或鋅合 金層而於其至少一面上生成鋅氣化物層。 鋅氧化物層生成後,長條前進至洗滌站18,於此處約 120T之溫水清洗施用至經鍍敷的片形產物經歴約20秒時 間。然後長條前進至乾燥站19,於此處使用風乾機或電阻 乾操器或任何其它裝置乾燥器來乾燥清洗妥的片形產物, 隨後片形銅前進接受進一步加工處理例如上油,剪成定長 或捲曲或盤曲供運輸。 第5圖顯示本發明用於熱浸鍍鋅生產線。熱浸鍍鋅生 本紙張尺度適用中國國家標準(CNS ) Α4規格(210\297公釐) (請先閲讀背面之注意事項『填寫本頁) 、?τ 13 419534 A7 B7 五、發明説明(11 ) 產線C包括一條無端式片形網長條1C浸沒於槽21内所含之 熱浸鋅或鋅合金浴20内。某些例中片形銷長條通過一根通 風管22進入熱浸浴。長條藉下沈辊23浸沒於浴内而通過兩 粮氣髏擦拭裝置24間來從銷片表面上去除過量鍍層。此時 片形辆條可於烘箱内退火產生俗稱_退火鍍鋅的退火產品, 或跳過退火步驟而以熱浸鍍鮮產品出售。兩種情況下,熱 浸產品皆有電解質溶液25M類似第4圖所示之方法步驟中 施用於其鍍面。 參考第5圖,熱浸鍍敷產物浸沒於含有包括鋅離子之 電解質溶液25之槽26內。此步驟係於施用鹼性溶液處理而 於熱浸鍍層表面上形成鋅氧化物層之前進行。如前述,電 解質可藉業界已知任何適當裝置例如噴塗或滾塗施用於片 形飼條的熱浸鍍鋅面上。然而亦須了解施用電解質溶液25 之步驟非電化學輔助方法。 施用電解質溶液後長條前進至類似第1及2圖所示處 理站之鹼性溶液處理站5。鍍敷線C所示處理站5包括一 部噴蕕装置27來施用含氧化劑之鹼性溶骹至熱浸鍍鋅片形 銷表面。 經濟部中央槁準局員工消費合作社印製 1J —»^^1 ^^^^1 —Hu m ^^1 7 -戈 . " Ή (請先閱讀背面之注意事項忠^-寫本頁) 齡性溶液造成鋅氧化物層於長條表面生成後,銷條前 進至清滌站28,於此處施用水清洗至鍍鋅片彤產物。然後 銷絛前進至乾燥站29,於此處使用風乾或電阻乾燥器或其 它適當乾燥器裝置來乾燥清洗妥的片形產物,隨後銷片鈕 續接受進一步處理例如上油、剪成定長及捲曲或盤曲供蓮 _ 0 本紙張尺度適用中國國家標準(CNS ) A4規格(2IOX297公釐) -14 - A7 B7 419534 五、發明説明(12) 第1 - 5圖所示之任一具體例中,包括氧化劑之經缀 衝或未绖緩衝鹼性溶液皆可用來於鍍敷妥的片形銷產物至 少一面上生成氧化物層。. 雖然已經就較佳設計描述本發明但須了解可遵照本發 明之一般原則做出進一歩修改,利用及/或調整且包含屬 於相關業界之已知或習知實務範圍内且可應用至本文所述 中心特性且落入隨附之申請專利範圍界定之本發明範圍内 之其它偏離本揭示内容之例。 元件標號對照 請 先 閱 讀 背 之 注 意 事 項 f 經濟部中央標準局員工消費合作社印製 1 . . _ · 片形銷長條 10, 19,29 ----乾燥站 2, 12 _ _ ..鍍池 11 · ; * 鍍浴 3 … 鍍鋅浴 12 ' - 鍍池 4,13 _ ..陽極 13 - * * 陽極 5 _ 鹼處理站 14 · * 清洗站 6 » 6a … ..經缓衝的鹼性溶液 15, 25 . ••電解質溶液 7…. 噴頭 16 p 電解質站 7 3 .... 浸沒搰 20 ' * * 熱浸鍍鋅或鋅合金浴 7b,17 . ...•滾塗裝置 21, 26 · · 槽 8 · . _ 噴嘴 22 * « » · 通風管 8a,23 . ...下沈辊 24 » · » 氣醱擦拭裝置 9,18,28 ——洗滌站 27 丨* · 噴濯裝置 訂 本紙張尺度適用中國國家標準(CNS ) A4規格(210X 297公釐)

Claims (1)

  1. A8R8C8D8
    經濟部智慧財產局員工消費合作社印製 419534 申印專利範圍 種電鍍鋅片或長條’其具有改良的成形性及溶接 性,該薄片或長條由以下步驟製成: a) 提供一電鍍鋅薄片或長條; b) 化學地施用一具有7.8至8.4之pH值範圍的鹼性 緩衝溶液至該電鍍鋅薄板或長條; c) 施用該驗性緩衝溶液歷時一段足夠時間以於該 電鍍鋅的薄片或長條上形成一氧化鋅層,該層 有至少為0.340 g/m2的Zn++濃度,該具有已形 成的氧化辞保護層的薄片或長條藉由一為至少 為1_401吋的極限圓頂高度與一為至少為〇1〇6的 摩擦係數之測量結果而具有改善的成形性,以 及藉由至少4000次的熔接稍端壽命周期數的測 量結果而具有改善的嫁接性。 如申請專利範圍第1項之薄片或長條,其中該氧化鋅層 有—超過0_15 g/m2的塗層重量。 —種鍍鋅薄片或長條,其具有改良的成形性及熔接性, 該薄片或長條由以下步驟製成: a) 提供一鍍鋅薄片或長條; b) 化學地施用一具有7.8至8.4之PH範圍的鹼性緩 衝溶液至該鑛辞薄板或長條; c) 施用該鹼性緩衝溶液歷時一段足夠時間以於該 鐘鋅的薄片或長條上形成一氧化鋅層,該層有 一至少為0_340 g/m2的Zn++濃度,該具有已形成 的氧化辞保護層的薄片或長條藉由一為至少 ___ -4- 本紙張尺度適用國國家標準(CNSM4規格⑵Ο X 297公楚) (請先閱讀背面之注意事項再填寫本頁)
    經濟部智慧財產局員工消費合作枉印製 419534 g ___ D8 六、申請專利範圍 1.401吋的極限圓頂高度與一為至少0.106的摩擦 係數之測量結果而具有改善的成形性,以及藉 由至少4000次的熔接稍端壽命周期數的測量結 果而具有改善的炫接性。 4.如申請專利範圍第3項之薄片或長條,其中該氧化鋅層 有一超過0.15 g/m2的塗層重量。 5,一種鍍鋅薄片或長條,其具有改善的成形性或是熔接 性,該薄片或長條包含有: 於一鐘鋅薄片或長條的至少一面上形成一層氧化 鋅層’該薄層有至少為3.40g/m2的Zn++濃度,該具 有已形成的氧化鋅保護層的薄片或長條藉由一為 至少1.401吋的極限圓頂高度與一為至少〇.1〇6的摩 擦係數之測夏結果而具有改善的成形性,以及藉 由至少4000 -欠的炼接稍端壽命周期數的測量結果 具有改善的熔接性。 6. 如申請專利範圍第5項之薄片或長條,其中該氧化鋅層 有一超過0.15 g/m2的塗層重量。 7, 如申請專利範圍第5項的薄片或長條,其中該薄片或長 條為電鍍鋅薄片或長條^ (請先閱讀背面之注意事項再填寫本頁)
    ----1 —訂---------線·- 本紙張〜X遇财關家鮮(CNS) AI規格 297公釐)
TW088117729A 1995-05-23 1996-05-03 A zinc coated/electrogalvanized sheet or stripe TW419534B (en)

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US5660707A (en) 1997-08-26
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