TW414998B - Method of mounting and demounting a semiconductor wafer and substance mixture suitable for carrying out the method - Google Patents

Method of mounting and demounting a semiconductor wafer and substance mixture suitable for carrying out the method Download PDF

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TW414998B
TW414998B TW087120907A TW87120907A TW414998B TW 414998 B TW414998 B TW 414998B TW 087120907 A TW087120907 A TW 087120907A TW 87120907 A TW87120907 A TW 87120907A TW 414998 B TW414998 B TW 414998B
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substance mixture
semiconductor wafer
rosin resin
scope
patent application
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Robert Rurlaender
Franz Mangs
Norbert Franze
Anton Dr Schnegg
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Wacker Siltronic Halbleitermat
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/67Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
    • H01L21/683Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping
    • H01L21/6835Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping using temporarily an auxiliary support
    • H01L21/6836Wafer tapes, e.g. grinding or dicing support tapes
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    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/30Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
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    • H01L24/00Arrangements for connecting or disconnecting semiconductor or solid-state bodies; Methods or apparatus related thereto
    • H01L24/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L24/26Layer connectors, e.g. plate connectors, solder or adhesive layers; Manufacturing methods related thereto
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    • H01L24/00Arrangements for connecting or disconnecting semiconductor or solid-state bodies; Methods or apparatus related thereto
    • H01L24/80Methods for connecting semiconductor or other solid state bodies using means for bonding being attached to, or being formed on, the surface to be connected
    • H01L24/83Methods for connecting semiconductor or other solid state bodies using means for bonding being attached to, or being formed on, the surface to be connected using a layer connector
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2221/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof covered by H01L21/00
    • H01L2221/67Apparatus for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components; Apparatus not specifically provided for elsewhere
    • H01L2221/683Apparatus for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components; Apparatus not specifically provided for elsewhere for supporting or gripping
    • H01L2221/68304Apparatus for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components; Apparatus not specifically provided for elsewhere for supporting or gripping using temporarily an auxiliary support
    • H01L2221/68327Apparatus for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components; Apparatus not specifically provided for elsewhere for supporting or gripping using temporarily an auxiliary support used during dicing or grinding
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/80Methods for connecting semiconductor or other solid state bodies using means for bonding being attached to, or being formed on, the surface to be connected
    • H01L2224/83Methods for connecting semiconductor or other solid state bodies using means for bonding being attached to, or being formed on, the surface to be connected using a layer connector
    • H01L2224/8319Arrangement of the layer connectors prior to mounting
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
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    • H01L2224/80Methods for connecting semiconductor or other solid state bodies using means for bonding being attached to, or being formed on, the surface to be connected
    • H01L2224/83Methods for connecting semiconductor or other solid state bodies using means for bonding being attached to, or being formed on, the surface to be connected using a layer connector
    • H01L2224/838Bonding techniques
    • H01L2224/8385Bonding techniques using a polymer adhesive, e.g. an adhesive based on silicone, epoxy, polyimide, polyester
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  • Condensed Matter Physics & Semiconductors (AREA)
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  • Mechanical Treatment Of Semiconductor (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Description

414998 A7 經濟部中央樣準局負工消費合作社印製 五、發明説明(l ) 本發明與安裝(固定)及拆卸半導體晶圓之方法有闞, 其中半導體晶圓與一載體盤間之物質混合物將二者随溫度 變化而黏結及固化接合,且該物質混合物含有松香樹脂, 該松香樹脂係經化學修飾及酯化,於抛光該半導體晶圓之 後,該固化接合即行鬆開。再者,本發明與水溶性物質混 合物有闞,在乾烽之情況下該水溶性物質混合物随溫度不 同而黏結及固化,且該混合物含有經化學修飾及酯化之松 香樹脂,適於實施該方法。 拋光半導體晶圓正面時,係將該半導體晶圓之背面安 裝在一載體盤上。半導體晶圓與該載體盤係由一随溫度變 化而黏結及固化之黏著劑薄層接合0該黏著劑必備之特別 條件是:有助於抛光。該載體盤必須適於均勻塗佈該黏著 劑。該黏著劑之黏著作用必須眼於一狹窄之溫度範圍内。 在拋光時,必須持績保持固體狀態,俾半導體晶圓能持績 附著於載體盤上。尤其所用黏著劑不得對拋光後之半導體 晶圓之彤狀有負面影響。經拋光之半導體晶圓之表面必須 儘可能的平整。拋光後,該黏著劑應苛容易地自載體盤及 該半導體晶圓上除去。最後,該黏著劑不可釋放出任何物 質(尤其微蠆金屬),以免污染該半導體晶圓。 松香樹脂及其衍生物之黏著作用随溫度變化而不同。 但截自目前為止,仍未能確定一種以松香樹腊為主成分之 黏著劑可完全符合上述條件。 本發明與安裝及拆卸半導體晶圓之方法有闞,其中半 導體晶圓與載體盤間之物質混合物將二者随溫度變化而黏 -3 - ----------装------.玎------1 (’請先閱瘦背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS ) A4規格(210X29:/公釐) 414998 Α7 Β7 經濟部中央標準局貝工消費合作社印製 五、發明説明(2 ) 結及固化接合,且該物質混合物含有松香樹脂,該松番樹 脂係經化學修飾及酯化,於拋光該半導體晶圓之後,該固 化之接合即行鬆開。該方法包括用水將該接合鬆開。再者 ,本發明與該物質混合物有關,該混合物含有一化學通式 為NR1!?2!?3之胺,該胺可皂化該松香樹脂,在Rl、R2及R3 之基中至少有一個是脂族醇之基,且在1000毫巴壓力下該 胺之沸點超過150T。 尤其本發明值得注意的是,在混合及加熱該物質混合 物時,無易燃溶劑或有害健康之氣體釋出,所以該等物質 不需昂資之安全措施β此外,加熱至較低溫度,該等物質 即可轉變成黏著狀態,且即使在固化態亦可完全溶解於水 。再者,該方法不會在經拋光之半導體晶圓表面上留下次 微米趿之波紋。 該物質混合物含有化學修飾及酯化之松香樹脂。該產 品市上可以購得。該松香樹腊以從粗質松油(原高油)真空 蒸鑕製得者為佳。尤其該物質混合物所用者係由粗質松油 經再真空蒸餾所得分子董分布較窄之部分。由此方法製得 之松香樹腊(「松油松腊」)得再加以化學修飾及酯化。最 好該松香樹1旨之修飾作用係藉助於一種化合物之反應,該 化合物係遘自一髑包括順丁烯二酸、順丁烯二酐及反丁烯 二酸之族群。經修飾後之樹腊随後最好再用醇加以酯化, 該醇係番自一個包括丙三酵及異戊四醇之族群。經化學修 飾及酯化之松香樹腊,其酸值應為50至250,尤以100至 140[毫公克氫氧化鉀/公克樹腊],其軟化點為60至U0P, -4 - f請先閱1 讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS ) A4规格(210X297公釐) 414996 Α7 Β7 經濟部中央標準局貝工消费合作社印裝 五、發明説明(3 ) 尤以90至UOC更佳。特別好的是瑞典之亞利桑納化學公 司出品之樹腊,該樹脂市上可購得,商名Ber8vik nxx ,其中XX係出廠批號,例如:⑼,01等。 依照本發明,經修飾及酯化之松番樹脂係用以製造物 質混合物,該混合物含有一化學通式nr1r2r3之胺,在Rl 、R2及R3基中至少一個基係一脂族酵之基,且在1000毫巴 壓力下該胺之沸點超過1501。特別好的是使用三乙醇胺 。尤其更好的是:三異丙醇胺、二異丙醇胺及二乙醇胺。 松香樹脂之皂化作用係在有溶於水中之胺存在之情況下實 施;在該等情況下該樹脂皂溶解於水相肉。 依照一特別好之配方,該物質混合物之姐成分為: 15至20%重量比烴化學修飾及酯化之松香樹脂·, 5至10¾重量比三乙醇胺; 高達2¾重虽比之非離子型界面活性劑,尤以壬基酿聚醚為 佳,係用作增塑劑; 達10¾重量比酵溶解劑,尤以異丙醇更佳; 高達0.05¾重量比之染料,尤Μ結晶紫、螢光染料(例如: 玫瑰精β及朝紅),及深色、水溶性食用染料(例如:孔雀綠) 為佳;及 湊成總量逵1005;重量比所需之水。 該物霣混合物之黏度業經加Μ調整,俾該載體盤苟均 勻地塗以該物質混合物。經塗被後,該物質涓合物變乾而 彤成一随潙度變化之黏著性及固化之物質。該物質之黏著 作用僅發生在較窄之溫度範圍(黏著區,「膠黏區」)内, -5 一 ---------^------’玎------.^ (讀先聞_讀背面之注意事項再填寫本頁〕 本紙張尺度適用中國國家標準(CNS Μ4規格(21〇χ297公釐) 414998 A7 B7 經濟部中央標隼局員工消費合作社印製 五、發明説明(4 ) 尤M45至85t:為佳。在一熱融黏著劑之案例中,該物質經 加熱至超過膠黏區内之高溫,其黏著作用即減低。為固化 半導體晶圓與載體盤間之接合,先將該載體盤加熱至膠黏 區內之溫度,再將一涸或更多個晶圓置於該載體盤上。當 載體盤冷卻時,該物質即固化且將半導體晶圓與載體盤堅 固地接合。通常在拋光期間即使30至501C之溫度情況下該 接合仍保持堅固。俟該半導體晶圓經拋光之後,半導體晶 圓與載體盤間之接合曆即行鬆開。使其與水接觸此項工作 即可達成,其中水溫以15至2510為佳。水可將該物質混合 物之殘留物自半導體晶圓上及載體盤上完全清除掉。 該物質湄合物之製備可藉下列諸實驗例加以清楚地說 明。 實驗例1) 在室溫及不停搜拌之情況下,將139,26公斤去離子水 ,14.74公斤三乙醇胺(80^重量比),4.52公斤壬基酚聚艇 ,19.64公斤纯異丙醇及0.1公斤孔雀綠依序加入35.74公 斤Bergvik M-106樹脂內。俟固體溶解後,經由一 5徹米袋 滤器將該混合物加以過濾並傾入若干容器罐内。在25¾溫 度下該溶液之黏度為22平方公厘/秒。乾燥物質混合物之 膠黏區係在49至72t之溫度範圍内。 實驗例2) 在室溫及不停攪拌之情況下,將138.5公斤去離子水 ,14.4公斤三乙醇胺(80¾重童比),4.50公斤壬基酚聚醚 ,19.7公斤純異丙醇及0.1公斤結晶紫依序加入35.74公斤 一 6 - ---------^------ir------m (.讀先閱ir背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS ) A4現格(2IOX297公釐) 414998 A7 A7 B7 五、發明説明(5 ) Bergvik M-106樹脂内。俟固體溶解後,經由一 5微米袋濾 器將該混合物加以過滤並傾入若干容器罐内。在251C溫度 下該溶液之黏度為22平方公厘/秒。乾煉物質混合物之膠 黏區係在60至80t之溫度範圍内。 實驗例3) 在室溫及不停攪拌之情況下,將276.50公斤去離子水 ,23.12公斤三乙醇胺(80¾重量比),8.42公斤壬基酚聚醚 ,25公斤纯異丙醇及0.185公斤玫瑰精B依序加人66.28公 FBergvik M-106樹脂內。俟固體溶解後,經由一 5微米袋 漶器將該混合物加以過滤並傾入若千容器罐肉。在2510溫 度下該溶液之黏度為22平方公厘/秒。乾烽物質混合物之 膠黏區係在66至79t:之溫度範圍肉。 I---------裝-- (請先閲tr背面之注意事項再填寫本買) 訂 涑 經濟部中央標準局員工消費合作社印裝 -Ί 一 本紙張又度適用中國國家楼準(CNS )人4規潘(210X297公釐)

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  1. 0牟Α μ目修i/更正/補寿_5修正 0牟Α μ目修i/更正/補寿_5修正 經濟部智慧財產局員Η消費合作杜印製 六、申請專利範圍 1' 一種安裝及拆卸半導體晶圓之方法,其中半導醴晶圓 與載體盤間之物質混合物將二者隨溫度變化而黏結及固化 接合’且該物質混合物含有松香樹脂,該松香樹脂係經化 學修姊及酯化,於拋光該半導嫌晶圓之後,該固化接合即 行鬆開,該方法包括用水鬆開該固化之接合β 2·如申請專利範圍第1項之方法,其辛該乾燥之物質混 合物僅在45至85°C之溫度範圍内發生黏結作用。 3·如申請專利範圍第1或2項之方法,其中該經固化之 接合係用水鬆開且載體盤上或半導體晶圓上並不留下該接 合之殘留物。 4· 一種水溶性物質混合物,在乾燥狀態下,該混合物隨 溫度變化而黏著及固化,且其中含有松香樹脂,該松香樹 脂係經化學修飾及酯化’該物質混合物含有一化學通式為 NRiR2!^之胺,該胺與松香樹脂實施皂化作用,且Rl、r2 及R3基中至少一個基係一脂族醇之基,且該胺在1000毫 巴壓力下之沸點超過15trt。 5·如申請專利範圍第4項之物質混合物,其中該胺係選 自一個包括三乙酵胺、三異丙醇胺、二異丙醇胺及二乙醇 胺之族群。 6·如申請專利範圍第4項之物質混合物,其中該松香樹 脂實施化學修飾反應所用之化合物係選自一個包括順丁稀 二酸、順丁烯二酐及反丁烯二酸之族群。 7·如申請專利範圍第4項之物質混合物,其中該松香樹 脂實施酯化所用之醇係選自一個包括丙三醇及異戊四醇之 8 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) --I I--I I III—^.1111111 訂--------- (諳先閱讀背面之注意事項再填寫本頁) 0牟Α μ目修i/更正/補寿_5修正 0牟Α μ目修i/更正/補寿_5修正 經濟部智慧財產局員Η消費合作杜印製 六、申請專利範圍 1' 一種安裝及拆卸半導體晶圓之方法,其中半導醴晶圓 與載體盤間之物質混合物將二者隨溫度變化而黏結及固化 接合’且該物質混合物含有松香樹脂,該松香樹脂係經化 學修姊及酯化,於拋光該半導嫌晶圓之後,該固化接合即 行鬆開,該方法包括用水鬆開該固化之接合β 2·如申請專利範圍第1項之方法,其辛該乾燥之物質混 合物僅在45至85°C之溫度範圍内發生黏結作用。 3·如申請專利範圍第1或2項之方法,其中該經固化之 接合係用水鬆開且載體盤上或半導體晶圓上並不留下該接 合之殘留物。 4· 一種水溶性物質混合物,在乾燥狀態下,該混合物隨 溫度變化而黏著及固化,且其中含有松香樹脂,該松香樹 脂係經化學修飾及酯化’該物質混合物含有一化學通式為 NRiR2!^之胺,該胺與松香樹脂實施皂化作用,且Rl、r2 及R3基中至少一個基係一脂族醇之基,且該胺在1000毫 巴壓力下之沸點超過15trt。 5·如申請專利範圍第4項之物質混合物,其中該胺係選 自一個包括三乙酵胺、三異丙醇胺、二異丙醇胺及二乙醇 胺之族群。 6·如申請專利範圍第4項之物質混合物,其中該松香樹 脂實施化學修飾反應所用之化合物係選自一個包括順丁稀 二酸、順丁烯二酐及反丁烯二酸之族群。 7·如申請專利範圍第4項之物質混合物,其中該松香樹 脂實施酯化所用之醇係選自一個包括丙三醇及異戊四醇之 8 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) --I I--I I III—^.1111111 訂--------- (諳先閱讀背面之注意事項再填寫本頁) AS B8 C8 D8 414^^8 六、申請專利範圍 族群。 8·如申請專利範圍第4、5、6或7項之物質混合物,其 組成分為· 15至20%重量比經化學修飾及酯化之松香樹脂; 5至10%重量比三乙醇胺; 高達2%重量比之非離子型界面活性劑; 高達10%重量比之醇溶解劑; 高達0.05%重量比之染料;及 湊成總量達100%重量比所需之水。 {請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印制衣 本紙張尺度適用中國國家標準(CNS)A4規格(210x 297公釐)
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FR2600663B1 (fr) * 1986-06-27 1988-08-05 Charbonnages Ste Chimique Compositions pour adhesifs thermofusibles reticulables, les adhesifs correspondants ainsi que leurs procedes de preparation et d'application
SE9203499L (sv) * 1992-11-20 1994-05-21 Eka Nobel Ab Kolofoniumderivat som ytaktivt medel
EP0601615A1 (en) 1992-12-08 1994-06-15 Koninklijke Philips Electronics N.V. Method of manufacturing a semiconductor device whereby a semiconductor body is temporarily fastened to a further body for a processing operation
JP3845486B2 (ja) 1996-02-23 2006-11-15 ザ・インクテック株式会社 精密加工用仮着接着剤

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JPH11238711A (ja) 1999-08-31
SG67579A1 (en) 1999-09-21
DE59800557D1 (de) 2001-04-26
EP0924759B1 (de) 2001-03-21
DE19756614A1 (de) 1999-07-01
KR19990063063A (ko) 1999-07-26
EP0924759A2 (de) 1999-06-23
EP0924759A3 (de) 1999-09-08
KR100284583B1 (ko) 2001-11-02
JP3032973B2 (ja) 2000-04-17
US6171385B1 (en) 2001-01-09

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