TW412509B - Alkylation of benzene to form linear alkylbenzenes using fluorine-containing mordenites - Google Patents

Alkylation of benzene to form linear alkylbenzenes using fluorine-containing mordenites Download PDF

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Publication number
TW412509B
TW412509B TW086103010A TW86103010A TW412509B TW 412509 B TW412509 B TW 412509B TW 086103010 A TW086103010 A TW 086103010A TW 86103010 A TW86103010 A TW 86103010A TW 412509 B TW412509 B TW 412509B
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TW
Taiwan
Prior art keywords
mordenite
patent application
benzene
hydrogen fluoride
fluorinated
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Application number
TW086103010A
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English (en)
Chinese (zh)
Inventor
P Eugene Dai
John F Knifton
Prakasa Rao Anantaneni
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Huntsman Spec Chem Corp
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Publication of TW412509B publication Critical patent/TW412509B/zh

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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/026—After-treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/14—Fractional distillation or use of a fractionation or rectification column
    • B01D3/32—Other features of fractionating columns ; Constructional details of fractionating columns not provided for in groups B01D3/16 - B01D3/30
    • B01D3/322—Reboiler specifications
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/22—Halogenating
    • B01J37/26—Fluorinating
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/16—After treatment, characterised by the effect to be obtained to increase the Si/Al ratio; Dealumination
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/16—Clays or other mineral silicates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • C07C2529/16—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
TW086103010A 1996-02-08 1997-03-11 Alkylation of benzene to form linear alkylbenzenes using fluorine-containing mordenites TW412509B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/598,692 US5847254A (en) 1996-02-08 1996-02-08 Alkylation of benzene to form linear alkylbenzenes using fluorine-containing mordenites

Publications (1)

Publication Number Publication Date
TW412509B true TW412509B (en) 2000-11-21

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
TW086103010A TW412509B (en) 1996-02-08 1997-03-11 Alkylation of benzene to form linear alkylbenzenes using fluorine-containing mordenites

Country Status (12)

Country Link
US (1) US5847254A (de)
EP (1) EP0882003B1 (de)
JP (1) JP2000504691A (de)
KR (1) KR19990082298A (de)
CN (2) CN1075047C (de)
CA (1) CA2244834A1 (de)
DE (1) DE69712188T2 (de)
ES (1) ES2176688T3 (de)
ID (2) ID15926A (de)
RU (1) RU2185358C2 (de)
TW (1) TW412509B (de)
WO (1) WO1997029063A1 (de)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6166281A (en) * 1996-02-08 2000-12-26 Huntsman Petrochemical Corporation Alkylation of benzene to form linear alkylbenzenes using fluorine-containing mordenites
US6133492A (en) * 1996-02-08 2000-10-17 Huntsman Petrochemical Corporation Alkylation of benzene to form linear alkylbenzenes using fluorine-containing mordenites
PH11998001775B1 (en) * 1997-07-21 2004-02-11 Procter & Gamble Improved alkyl aryl sulfonate surfactants
DE69814641T2 (de) 1997-07-21 2004-03-25 The Procter & Gamble Company, Cincinnati Verbessertes alkylarylsulfonattensid
AU8124498A (en) 1997-07-21 1999-02-16 Procter & Gamble Company, The Cleaning products comprising improved alkylarylsulfonate surfactants prepared via vinylidene olefins and processes for preparation thereof
CA2297648C (en) 1997-07-21 2004-11-23 The Procter & Gamble Company Improved processes for making alkylbenzenesulfonate surfactants and products thereof
TR200000796T2 (tr) 1997-07-21 2000-07-21 The Procter & Gamble Company Kristalinitesi kesintiye uğramış yüzey aktif madde karışımları içeren deterjan kompozisyonları
CA2298618C (en) 1997-08-08 2007-04-03 The Procter & Gamble Company Improved processes for making surfactants via adsorptive separation and products thereof
WO2000042140A1 (en) 1999-01-11 2000-07-20 Huntsman Petrochemical Corporation Surfactant compositions containing alkoxylated amines
EP1022325A3 (de) 1999-01-20 2003-01-02 The Procter & Gamble Company Harte Oberflächenreiniger enthaltend modifizierte Alkylbenzolsulfonate
EP1022326A1 (de) 1999-01-20 2000-07-26 The Procter & Gamble Company Reinigungszusammensetzungen für harte Oberflächen enthaltend modifizierte Alkylbenzylsulfonate
US7189885B1 (en) 2003-10-07 2007-03-13 Uop Llc Staged process for producing linear 2-phenyl-alkanes
JP2007317170A (ja) * 2006-04-28 2007-12-06 Renesas Technology Corp Ｉｃモジュールおよび携帯電話
CN101386782B (zh) * 2007-09-10 2011-04-20 中国石油天然气股份有限公司 一种烷基化合成c14-c20驱油用烷基苯的方法
RU2460715C2 (ru) * 2007-12-04 2012-09-10 Сепса Кимика, С.А. Способ получения моноалкилированных ароматических соединений с высокой линейностью и регулируемой изомерией
WO2010062605A1 (en) 2008-10-27 2010-06-03 Stepan Company Alkylaryl sulfonates with reduced sulfone levels and methods for their preparation
EP2986371A4 (de) 2013-04-19 2017-02-08 Reliance Industries Limited Ionische flüssigverbindung
US9611188B1 (en) 2016-02-17 2017-04-04 Chevron Phillips Chemical Company Lp Aromatic alkylation using chemically-treated solid oxides
CN108217679B (zh) * 2016-12-09 2020-03-27 中国科学院大连化学物理研究所 一种丝光沸石分子筛、其制备方法及应用
CN114602537A (zh) * 2020-12-08 2022-06-10 中国科学院大连化学物理研究所 一种改性丝光沸石分子筛催化剂及其制备方法和应用
RU2756954C1 (ru) * 2020-12-09 2021-10-07 Акционерное общество "Газпромнефть - Омский НПЗ" (АО "Газпромнефть-ОНПЗ") Способ получения алкилпроизводных аренов

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US3436432A (en) * 1968-03-29 1969-04-01 Universal Oil Prod Co Process for alkylation of aromatics using a halogen-containing aluminosilicate-alumina catalyst
US4301317A (en) * 1979-11-20 1981-11-17 Mobil Oil Corporation Preparation of 2-phenylalkanes
US4570027A (en) * 1984-04-27 1986-02-11 Exxon Research And Engineering Co. Alkylation of aromatic molecules using a silica-alumina catalyst derived from zeolite
JPS60228435A (ja) * 1984-04-27 1985-11-13 エクソン・リサ−チ・アンド・エンジニアリング・カンパニ− 大孔径無定形シリカ−アルミナ触媒を使用する芳香族分子のアルキル化
JPH06104630B2 (ja) * 1986-11-11 1994-12-21 三井石油化学工業株式会社 アルキル基置換芳香族炭化水素の製造方法
US4731497A (en) * 1986-12-29 1988-03-15 Atlantic Richfield Company Alkylation of aromatics with alpha-olefins
US4973780A (en) * 1988-04-27 1990-11-27 Lummus Crest, Inc. Alkylation of benzene in a moving bed
ES2007545A6 (es) * 1988-08-03 1989-06-16 Petroquimica Espanola S A Petr Proceso de alquilacion catalitica en lecho fijo de hidrocarburos aromaticos.
US5082990A (en) * 1988-10-28 1992-01-21 Chevron Research And Technology Company Alkylation of aromatics-containing refinery streams
US5523061A (en) * 1988-11-22 1996-06-04 China Petrochemical Corporation (Sinopec) Equipment for catalytic distillation
US5034564A (en) * 1990-04-12 1991-07-23 Uop Production of alkyl aromatic compounds
US5308592A (en) * 1990-12-03 1994-05-03 China Petrochemical Corporation (Sinopec) Equipment for mixed phase reaction distillation
BR9107311A (pt) * 1991-06-21 1995-04-25 Dow Chemical Co Processo para alquilar benzeno ou benzeno substituído.
US5344997A (en) * 1991-12-23 1994-09-06 Uop Alkylation of aromatics using a fluorided silica-alumina catalyst
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US5449501A (en) * 1994-03-29 1995-09-12 Uop Apparatus and process for catalytic distillation

Also Published As

Publication number Publication date
WO1997029063A1 (en) 1997-08-14
EP0882003A1 (de) 1998-12-09
JP2000504691A (ja) 2000-04-18
ID15926A (id) 1997-08-21
US5847254A (en) 1998-12-08
CN1210509A (zh) 1999-03-10
DE69712188D1 (de) 2002-05-29
CA2244834A1 (en) 1997-08-14
EP0882003B1 (de) 2002-04-24
DE69712188T2 (de) 2002-08-14
KR19990082298A (ko) 1999-11-25
CN1348922A (zh) 2002-05-15
RU2185358C2 (ru) 2002-07-20
ID28641A (id) 1997-08-21
CN1075047C (zh) 2001-11-21
ES2176688T3 (es) 2002-12-01

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