TW294655B - - Google Patents
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- Publication number
- TW294655B TW294655B TW084104322A TW84104322A TW294655B TW 294655 B TW294655 B TW 294655B TW 084104322 A TW084104322 A TW 084104322A TW 84104322 A TW84104322 A TW 84104322A TW 294655 B TW294655 B TW 294655B
- Authority
- TW
- Taiwan
- Prior art keywords
- trioxane
- formaldehyde
- solvent
- gaseous
- mixture
- Prior art date
Links
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 61
- BGJSXRVXTHVRSN-UHFFFAOYSA-N 1,3,5-trioxane Chemical compound C1OCOCO1 BGJSXRVXTHVRSN-UHFFFAOYSA-N 0.000 claims description 30
- 239000002904 solvent Substances 0.000 claims description 21
- 238000000034 method Methods 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 13
- 239000007788 liquid Substances 0.000 claims description 12
- 238000004821 distillation Methods 0.000 claims description 10
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 claims description 9
- KVNYFPKFSJIPBJ-UHFFFAOYSA-N 1,2-diethylbenzene Chemical compound CCC1=CC=CC=C1CC KVNYFPKFSJIPBJ-UHFFFAOYSA-N 0.000 claims description 8
- 239000008096 xylene Substances 0.000 claims description 8
- 238000006243 chemical reaction Methods 0.000 claims description 7
- 238000005201 scrubbing Methods 0.000 claims description 7
- 238000011049 filling Methods 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 4
- 238000010992 reflux Methods 0.000 claims description 4
- 238000009835 boiling Methods 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 239000011541 reaction mixture Substances 0.000 claims description 3
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 2
- 150000008378 aryl ethers Chemical class 0.000 claims description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims description 2
- 239000003960 organic solvent Substances 0.000 claims description 2
- 229920000570 polyether Polymers 0.000 claims description 2
- 229920006395 saturated elastomer Polymers 0.000 claims description 2
- 150000003738 xylenes Chemical class 0.000 claims description 2
- 239000008246 gaseous mixture Substances 0.000 claims 1
- 239000000047 product Substances 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 6
- 238000006116 polymerization reaction Methods 0.000 description 5
- 238000000926 separation method Methods 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 4
- 150000001335 aliphatic alkanes Chemical class 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- ZBPDGNQKWYVCRM-UHFFFAOYSA-N formaldehyde trioxane Chemical compound O1OOCCC1.O1OOCCC1.C=O ZBPDGNQKWYVCRM-UHFFFAOYSA-N 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 239000013589 supplement Substances 0.000 description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- DHXVGJBLRPWPCS-UHFFFAOYSA-N Tetrahydropyran Chemical compound C1CCOCC1 DHXVGJBLRPWPCS-UHFFFAOYSA-N 0.000 description 1
- 239000003377 acid catalyst Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 239000008098 formaldehyde solution Substances 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D323/00—Heterocyclic compounds containing more than two oxygen atoms as the only ring hetero atoms
- C07D323/04—Six-membered rings
- C07D323/06—Trioxane
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/78—Separation; Purification; Stabilisation; Use of additives
- C07C45/783—Separation; Purification; Stabilisation; Use of additives by gas-liquid treatment, e.g. by gas-liquid absorption
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/78—Separation; Purification; Stabilisation; Use of additives
- C07C45/81—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
- C07C45/82—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Heterocyclic Compounds That Contain Two Or More Ring Oxygen Atoms (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4415332A DE4415332A1 (de) | 1994-05-02 | 1994-05-02 | Verfahren zur Trennung von Formaldehyd und Trioxan |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW294655B true TW294655B (enExample) | 1997-01-01 |
Family
ID=6517009
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW084104322A TW294655B (enExample) | 1994-05-02 | 1995-05-01 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US5872263A (enExample) |
| EP (1) | EP0680959B1 (enExample) |
| JP (1) | JPH07300441A (enExample) |
| DE (2) | DE4415332A1 (enExample) |
| TW (1) | TW294655B (enExample) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19833620A1 (de) * | 1998-07-25 | 2000-01-27 | Ticona Gmbh | Abtrennung von Trioxan aus gasförmigen Gemischen mit Formaldehyd |
| ES2171152B1 (es) | 2001-02-16 | 2003-10-01 | Patentes Novedades Sa | Procedimiento de separacion de una mezcla acuosa de trioxano y formaldehido y aplicaciones correspondientes. |
| JP2014024754A (ja) * | 2012-07-24 | 2014-02-06 | Polyplastics Co | トリオキサンを製造する方法及び装置 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2304080A (en) * | 1940-01-11 | 1942-12-08 | Du Pont | Preparation of alpha trioxymethylene |
| BE656705A (enExample) * | 1963-12-05 | |||
| NL132133C (enExample) * | 1965-05-04 | |||
| SE322234B (enExample) * | 1965-10-06 | 1970-04-06 | Perstorp Ab | |
| GB1171715A (en) * | 1966-04-08 | 1969-11-26 | Sir Soc Italiana Resine Spa | Process and Catalyst for Preparing Trioxane from Gaseous Formaldehyde |
| DE1668867A1 (de) * | 1968-01-24 | 1971-12-23 | Basf Ag | Verfahren zur Reinigung von 1,3,5-Trioxan |
| DE3508668A1 (de) * | 1984-04-13 | 1985-10-24 | Hoechst Ag, 6230 Frankfurt | Verfahren zur herstellung von reinem trioxan |
| JP2869259B2 (ja) * | 1992-08-04 | 1999-03-10 | ポリプラスチックス株式会社 | トリオキサンの製造方法 |
-
1994
- 1994-05-02 DE DE4415332A patent/DE4415332A1/de not_active Withdrawn
-
1995
- 1995-04-20 EP EP95105910A patent/EP0680959B1/de not_active Expired - Lifetime
- 1995-04-20 DE DE59502724T patent/DE59502724D1/de not_active Expired - Fee Related
- 1995-04-28 US US08/431,100 patent/US5872263A/en not_active Expired - Lifetime
- 1995-05-01 TW TW084104322A patent/TW294655B/zh active
- 1995-05-02 JP JP7108529A patent/JPH07300441A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| EP0680959B1 (de) | 1998-07-08 |
| DE4415332A1 (de) | 1995-11-09 |
| DE59502724D1 (de) | 1998-08-13 |
| EP0680959A1 (de) | 1995-11-08 |
| JPH07300441A (ja) | 1995-11-14 |
| US5872263A (en) | 1999-02-16 |
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