TW202313481A - 正極活性物質 - Google Patents
正極活性物質 Download PDFInfo
- Publication number
- TW202313481A TW202313481A TW111124229A TW111124229A TW202313481A TW 202313481 A TW202313481 A TW 202313481A TW 111124229 A TW111124229 A TW 111124229A TW 111124229 A TW111124229 A TW 111124229A TW 202313481 A TW202313481 A TW 202313481A
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- Prior art keywords
- positive electrode
- active material
- electrode active
- addition
- lithium
- Prior art date
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- 239000007774 positive electrode material Substances 0.000 title claims abstract description 328
- 239000013078 crystal Substances 0.000 claims abstract description 256
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 163
- 229910052744 lithium Inorganic materials 0.000 claims abstract description 154
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims abstract description 146
- 239000011777 magnesium Substances 0.000 claims abstract description 134
- 239000002344 surface layer Substances 0.000 claims abstract description 117
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 110
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 108
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 80
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 76
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 67
- 239000010941 cobalt Substances 0.000 claims abstract description 67
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 66
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 65
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 64
- 239000001301 oxygen Substances 0.000 claims abstract description 64
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 64
- 239000000654 additive Substances 0.000 claims description 127
- 230000000996 additive effect Effects 0.000 claims description 126
- 229910052731 fluorine Inorganic materials 0.000 claims description 81
- 239000011737 fluorine Substances 0.000 claims description 81
- 150000001768 cations Chemical class 0.000 claims description 37
- 238000009792 diffusion process Methods 0.000 claims description 15
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims 1
- 238000007599 discharging Methods 0.000 abstract description 27
- 230000007547 defect Effects 0.000 abstract description 19
- 239000006185 dispersion Substances 0.000 abstract 1
- 235000002639 sodium chloride Nutrition 0.000 description 107
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 106
- 239000011780 sodium chloride Substances 0.000 description 106
- 239000002131 composite material Substances 0.000 description 102
- 238000010438 heat treatment Methods 0.000 description 97
- 229910052723 transition metal Inorganic materials 0.000 description 87
- 150000003624 transition metals Chemical class 0.000 description 87
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 78
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 76
- 239000010410 layer Substances 0.000 description 73
- 238000000034 method Methods 0.000 description 73
- 229910021389 graphene Inorganic materials 0.000 description 71
- PQXKHYXIUOZZFA-UHFFFAOYSA-M lithium fluoride Chemical compound [Li+].[F-] PQXKHYXIUOZZFA-UHFFFAOYSA-M 0.000 description 69
- -1 O3'-type Substances 0.000 description 67
- 239000000463 material Substances 0.000 description 63
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- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 38
- 239000011149 active material Substances 0.000 description 38
- 238000004458 analytical method Methods 0.000 description 38
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- 238000009826 distribution Methods 0.000 description 35
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- BFZPBUKRYWOWDV-UHFFFAOYSA-N lithium;oxido(oxo)cobalt Chemical compound [Li+].[O-][Co]=O BFZPBUKRYWOWDV-UHFFFAOYSA-N 0.000 description 31
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- 230000000694 effects Effects 0.000 description 27
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- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 21
- 239000002184 metal Substances 0.000 description 21
- 229910000428 cobalt oxide Inorganic materials 0.000 description 20
- 150000001875 compounds Chemical class 0.000 description 20
- 239000000395 magnesium oxide Substances 0.000 description 20
- 239000012298 atmosphere Substances 0.000 description 19
- 230000008859 change Effects 0.000 description 19
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 19
- 239000007773 negative electrode material Substances 0.000 description 19
- 230000008569 process Effects 0.000 description 19
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- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 14
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- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
- H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
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- C—CHEMISTRY; METALLURGY
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- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G51/00—Compounds of cobalt
- C01G51/40—Complex oxides containing cobalt and at least one other metal element
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- H01M10/05—Accumulators with non-aqueous electrolyte
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- H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
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- H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
- H01M2004/028—Positive electrodes
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
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| CN120565649B (zh) * | 2025-07-29 | 2025-11-04 | 湖南美特新材料科技有限公司 | 多层核壳结构单晶钴酸锂正极材料及其制备方法和应用 |
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| JP6560917B2 (ja) * | 2015-07-09 | 2019-08-14 | マクセルホールディングス株式会社 | 正極材料、および正極材料を用いた非水電解質二次電池 |
| PL3788667T3 (pl) * | 2018-05-04 | 2025-04-22 | Umicore | Wtórna bateria na bazie litu i tlenku kobaltu zawierająca fluorowany elektrolit i materiał elektrody dodatniej do zastosowań wysokonapięciowych |
| CN115863743A (zh) * | 2018-08-03 | 2023-03-28 | 株式会社半导体能源研究所 | 锂离子二次电池 |
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| JPWO2023281346A1 (https=) | 2023-01-12 |
| US20240379941A1 (en) | 2024-11-14 |
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