TW202106948A - 防污結構及其製備方法 - Google Patents

防污結構及其製備方法 Download PDF

Info

Publication number
TW202106948A
TW202106948A TW108145528A TW108145528A TW202106948A TW 202106948 A TW202106948 A TW 202106948A TW 108145528 A TW108145528 A TW 108145528A TW 108145528 A TW108145528 A TW 108145528A TW 202106948 A TW202106948 A TW 202106948A
Authority
TW
Taiwan
Prior art keywords
alcohol
water
resistant
composition
fouling
Prior art date
Application number
TW108145528A
Other languages
English (en)
Other versions
TWI692563B (zh
Inventor
張清祥
葉國興
王俊傑
Original Assignee
健豐全球貿易股份有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 健豐全球貿易股份有限公司 filed Critical 健豐全球貿易股份有限公司
Priority to US16/810,873 priority Critical patent/US11414553B2/en
Priority to US16/810,875 priority patent/US20210040349A1/en
Priority to EP20170899.7A priority patent/EP3772550B1/en
Application granted granted Critical
Publication of TWI692563B publication Critical patent/TWI692563B/zh
Priority to AU2020203070A priority patent/AU2020203070A1/en
Priority to JP2020130062A priority patent/JP6991607B2/ja
Publication of TW202106948A publication Critical patent/TW202106948A/zh

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1693—Antifouling paints; Underwater paints as part of a multilayer system
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/14—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
    • D06N3/145—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes two or more layers of polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
    • C08G18/797—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing carbodiimide and/or uretone-imine groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08L27/18—Homopolymers or copolymers or tetrafluoroethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04—Polyurethanes
    • C08L75/06—Polyurethanes from polyesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04—Polyurethanes
    • C08L75/08—Polyurethanes from polyethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C09D175/06—Polyurethanes from polyesters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C09D175/08—Polyurethanes from polyethers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
    • C09D5/1662—Synthetic film-forming substance
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1687—Use of special additives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/42—Gloss-reducing agents
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/47—Levelling agents
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0059—Organic ingredients with special effects, e.g. oil- or water-repellent, antimicrobial, flame-resistant, magnetic, bactericidal, odour-influencing agents; perfumes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0068—Polymeric granules, particles or powder, e.g. core-shell particles, microcapsules
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/047—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with fluoropolymers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/128—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with silicon polymers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/14—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
    • D06N3/142—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes mixture of polyurethanes with other resins in the same layer
    • D06N3/143—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes mixture of polyurethanes with other resins in the same layer with polyurethanes and other polycondensation or polyaddition products, e.g. aminoplast
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/18—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials
    • D06N3/183—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials the layers are one next to the other
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/22—Compounds containing nitrogen bound to another nitrogen atom
    • C08K5/23—Azo-compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/54—Silicon-containing compounds
    • C08K5/541—Silicon-containing compounds containing oxygen
    • C08K5/5415—Silicon-containing compounds containing oxygen containing at least one Si—O bond
    • C08K5/5419—Silicon-containing compounds containing oxygen containing at least one Si—O bond containing at least one Si—C bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2201/00—Chemical constitution of the fibres, threads or yarns
    • D06N2201/02—Synthetic macromolecular fibres
    • D06N2201/0281—Polyurethane fibres
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2203/00—Macromolecular materials of the coating layers
    • D06N2203/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N2203/042—Polyolefin (co)polymers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2203/00—Macromolecular materials of the coating layers
    • D06N2203/06—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N2203/066—Silicon polymers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2203/00—Macromolecular materials of the coating layers
    • D06N2203/06—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N2203/068—Polyurethanes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/14—Properties of the materials having chemical properties
    • D06N2209/146—Soilproof, soil repellent
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0086—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
    • D06N3/0088—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by directly applying the resin
    • D06N3/009—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by directly applying the resin by spraying components on the web

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Textile Engineering (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
  • Laminated Bodies (AREA)
  • Paints Or Removers (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

一種防污結構，包含：一耐酒精層；以及一水性防污層，其係位於該耐酒精層之上，其中，該耐酒精層係由一耐酒精組合物經固化後形成，該耐酒精組合物包含聚氨酯樹脂，以及其中，該水性防污層係由一水性防污組合物經固化後形成，該水性防污組合物係包含聚氨酯樹脂、水、矽氧烷樹脂、水性特氟龍樹脂及有機矽油。本發明之防污結構可應用於人造合成皮或布料中。本發明亦包含一種上述防污結構的製備方法。

Description

防污結構及其製備方法
本申請係關於一種防污結構，具體而言，涉及一種於合成皮材料表面上的防污結構。本申請亦關於一種防污結構的製備方法，具體而言，涉及一種合成皮表面上的防污結構的製備方法。
人造合成皮的應用非常廣，全球每年的使用量持續穩定成長，然其運用在成衣、家具、壁材和公共場所時，時常面臨到其表面容易遇到髒污或是人為塗鴉，且無法完全清潔乾淨，使其使用壽命因為外觀影響而大為縮短，對環境造成負擔，故如能開發出有效防止髒污污染，容易清潔保養且清潔溶劑不會造成表面受損的防污結構，將會使相關產業商品壽命提高，減緩替換率，進而減少對於地球環境的衝擊，以達到綠色商品。
有鑑於先前技術中的缺陷，本發明係提供一種防污結構及其製備方法。
為達上述目的及其他目的，本發明係提供一種防污結構，包含： 一耐酒精層；以及 一水性防污層，其係位於該耐酒精層之上， 其中，該耐酒精層係由一耐酒精組合物經固化後形成，該耐酒精組合物包含聚氨酯樹脂，以及 其中，該水性防污層係由一水性防污組合物經固化後形成，該水性防污組合物係包含聚氨酯樹脂、水、矽氧烷樹脂、水性特氟龍樹脂及有機矽油。
上述之防污結構，其中，該耐酒精組合物可包含： 30-50重量百分比的聚醚和聚酯型的脂肪族水性聚氨酯樹脂；以及 進一步包含： 40-70重量百分比的水。
上述之防污結構，其中，該耐酒精組合物可進一步包含： 0.01-3重量百分比的濕潤劑； 0.01-2重量百分比的氮丙啶交聯劑； 0.01-1重量百分比的消泡劑；以及 0.5-2.5重量百分比的聚碳化二亞銨交聯劑。
上述之防污結構，其中，該耐酒精組合物可包含： 70-90重量百分比的耐水解耐黃變聚醚型聚氨酯樹脂；以及 進一步包含： 5-15重量百分比的三聚氰胺型二液型交聯劑；以及 4-15重量百分比的二液型化學促進劑。
上述之防污結構，其中，該耐酒精組合物可進一步包含： 0.01-2重量百分比的消光劑。
上述之防污結構，其中，該水性防污組合物可包含： 5-40重量百分比的聚醚和聚酯型的脂肪族耐水解水性聚氨酯樹脂； 40-70重量百分比的水； 5-30重量百分比的矽氧烷樹脂； 1-10重量百分比的水性特氟龍樹脂；以及 1-10重量百分比的有機矽油。
上述之防污結構，其中，該水性防污組合物可進一步包含： 0.1-3重量百分比的異氰酸鹽交聯劑； 0.1-3重量百分比的增黏劑； 0.1-3重量百分比的濕潤劑； 0.01-3重量百分比的消泡劑； 5-15重量百分比的皮革滑爽劑；以及 0.01-1重量百分比的消光劑。
上述之防污結構可位於一基材之上，且該耐酒精層係位於該水性防污層與該基材之間，該基材可由選自紡織品、聚氨酯及聚氯乙烯所組成之群組的材料所構成。在一實施方式中，該基材可為紡織品、聚氨酯(Polyurethane, PU)、水性PU、聚氯乙烯(Polyvinyl chloride, PVC)、半PU/PVC、熱塑性聚氨酯(Thermoplastic polyurethane, TPU)、熱塑性聚烯烴(Thermoplastic olefin, TPO)、熱塑性硫化橡膠(Thermoplastic vulcanizate, TPV)、熱塑性苯乙烯(Thermoplastic styrene, TPS)、熱塑性聚醚酯彈性體(Thermoplastic polyether ester elastomer, TPEE)及熱塑性聚醯胺(Thermoplastic polyamide, TPA)，以及由上述材料所組合成之複合結構。
為達上述目的及其他目的，本發明係提供一種防污結構之製備方法，包含： a) 於一基材上塗覆一耐酒精組合物，並在80-160℃下使該耐酒精組合物乾燥，以形成一耐酒精層； b) 於該耐酒精層上塗覆一水性防污組合物，並在140℃以上使該水性防污組合物乾燥，以形成一水性防污層， 其中，該耐酒精層係由一耐酒精組合物經固化後形成，該耐酒精組合物 包含聚氨酯樹脂，以及 其中，該水性防污層係由一水性防污組合物經固化後形成，該水性防污組合物係包含聚氨酯樹脂、水、矽氧烷樹脂、水性特氟龍樹脂及有機矽油。
上述之製備方法，其中，步驟a)及步驟b)之乾燥時間可為1-5分鐘，於一特定實施方式中，步驟a)及步驟b)之乾燥時間可為3分鐘。
上述之製備方法，其中，該耐酒精組合物及該水性防污組合物可分別以噴塗的方式塗覆於該基材及該耐酒精層上。
上述之製備方法，其中，塗覆方式可為噴塗、浸塗、淋塗、漆塗、旋塗、真空塗、滾塗及直塗。
本發明之防污結構可應用於合成皮的表面。具備本發明之防污結構的合成皮，其表面使用旅館專用圓珠筆是畫不上去的，一般油性筆和水性筆是很難畫上去，且一旦畫上去，也可以輕易用乾布擦拭掉大部分的痕跡範圍，再加上使用市售清潔劑或酒精溶液擦拭後，可以達到完全去除污漬，恢復成原本合成皮材料的表面觀感。
在習知技術中，於合成皮表面所形成之防污結構中沒有耐酒精材料做基層，使得該結構很容易在溶劑的擦拭下，被破壞或是快速遞減其防污能力，原因在於防污原料與被保護的合成皮料接著程度變差，以致該層容易成為一次可犧牲性防污層，不具商業價值與實用性。
相較之下，本發明之防污結構中係以耐酒精材料做為水性防污原料處理前的基礎層。在一較佳實施方式中，水性防污原料係於耐酒精層尚未熟成(與基材表面反應未完全)前噴塗加工，並於高溫下使兩層同時熟成結合(完全反應)，此外耐酒精層本身也有簡易防塗鴉效果。此加工反應流程，在於避免耐酒精層因高溫反應完全後，造成本水性防污原料無法再與耐酒精層有效接著，以至於防污層脫模。
據上，本發明之防污結構包含水性防污層和耐酒精層，其可作為各種不同材質之基材上之保護層。
在一實施方式中，以本發明之包含水性防污層和耐酒精層的防污結構覆蓋的合成皮材料可以使用酒精溶液和市售清潔劑反覆擦拭至少30次以上，防污能力才會開始有下降的趨勢。
為充分瞭解本發明之目的、特徵及功效，茲藉由下述具體之實施例，對本發明做一詳細說明，說明如後：
實施例1-1：
如圖1所示，實施例1之防污結構10，包含：一耐酒精層12；以及一水性防污層13，其係位於該耐酒精層12之上。本實施例中，防污結構10係位於一基材20之上，其中耐酒精層12係位於水性防污層13與基材20之間。
本實施例中，基材20係為水性PU合成皮，但本發明並不限於此。在一實施方式中，該基材可為紡織品、聚氨酯(Polyurethane, PU)皮、水性PU皮、聚氯乙烯(Polyvinyl chloride, PVC)皮、半PU/PVC皮、熱塑性聚氨酯(Thermoplastic polyurethane, TPU)皮、熱塑性聚烯烴(Thermoplastic olefin, TPO)、熱塑性硫化橡膠(Thermoplastic vulcanizate, TPV)、熱塑性苯乙烯(Thermoplastic styrene, TPS)、熱塑性聚醚酯彈性體(Thermoplastic polyether ester elastomer, TPEE)及熱塑性聚醯胺(Thermoplastic polyamide, TPA)，以及由上述材料所組合成的複合結構。
本實施例之防污結構10的製備流程如下： a) 於基材20上塗覆一耐酒精組合物，並在90-120℃下乾燥1-5分鐘，以形成耐酒精層12； b) 於耐酒精層12上塗覆一水性防污組合物，並在140℃以上乾燥1-5分鐘，以形成水性防污層13，
應了解，以上步驟a)及步驟b)中的乾燥溫度及時間僅作為示例，而不應解讀為限制本發明之範圍。在不脫離所附申請專利範圍的範疇的前提下，本發明所屬技術領域中具有通常知識者，可依自行其需求來適當地調整步驟a)及步驟b)中的乾燥溫度及時間。在一實施方式中，步驟b)可在140-145℃下乾燥。
在本實施例中，耐酒精組合物及水性防污組合物係以噴塗的方式塗覆，但本發明並不限於此，本發明所屬技術領域中具有通常知識者可依自行其需求來選擇適當的塗覆方式。可應用於本發明之防污結構之製備方法的塗覆方式包含但不限於：噴塗、浸塗、淋塗、漆塗、旋塗、真空塗、滾塗及直塗。
在本實施例中，耐酒精層12係由耐酒精組合物A經固化後形成，該耐酒精組合物A之組成成分係如下列表1所示：
表1
組成成分 重量百分比
耐酒精組合物A 耐酒精組合物B 耐酒精組合物C
脂肪族水性聚氨酯樹脂(聚醚和聚酯型)(Aliphatic water-based PU resin (polyether & polyester type)) ( 型號: F-363，購自Chain Chemical Co., Ltd.) 30 42 50
濕潤劑 (Wetting agent) (型號:OFX-5211，購自 Guang zhou HT-Chemical Co., Ltd.) 0.5 1.5 3
氮丙啶交聯劑(Aziridine crosslinker) (型號PZ-33，購自PolyAziridine LLC) 1 1.5 2
消泡劑(Antifoaming Agent) (型號A5757，購自Sigma-Aldrich) 0 0.5 1
聚碳化二亞銨交聯劑 (Polycarbodiimide crosslinker) (型號 V-02-L2，購自An Fong Development Co., Ltd.) 0.7 1.4 2.1
水 67.8 53.1 41.9
在本實施例中，水性防污層13係由水性防污組合物A經固化後形成，該水性防污組合物A之組成成分係如下列表2所示：
表2
組成成分 重量百分比
水性防污組合物A 水性防污組合物B 水性防污組合物C
脂肪族耐水解水性聚氨酯樹脂(聚醚和聚酯型) (Aliphatic & hydrolysis-resistant water-based PU resin (polyether & polyester type)) (型號JW-25A-2，購自Jiuh Yi Chemical Industrial Co. Ltd.) 6.6 19.4 28.9
異氰酸鹽交聯劑(Isocyanate crosslinker) (型號EC-385，購自SiwoChem) 0.6 1.9 2.9
水 58.5 50.2 43.6
矽氧烷樹脂(Polymerized siloxanes) (型號PA-8316，購自Guang zhou HT-Chemical Co., Ltd.) 15.3 13.4 12
水性特氟龍樹脂(Water-based polytetrafluoroethylene (PTFE)) (型號Teflon™ PTFE ，購自Dupont Chemours) 2 1.1 1
有機矽油(Silicone oil) (型號85409-1L，購自Sigma-Aldrich) 2.0 1.7 1.4
增黏劑(Tackifier) (型號 CA-909，購自Xuanning Chemical Technology) 0.5 0.4 0.3
濕潤劑 (Wetting agent) (型號:OFX-5211，購自 Guang zhou HT-Chemical Co., Ltd.) 0.3 0.2 0.2
消泡劑(Antifoaming Agent) (型號A5757，購自Sigma-Aldrich 0.1 0.1 0.1
皮革滑爽劑(Leather slipping agent) (型號: AQUADERM ADDITIVE GF，購自Lanxess (Changzhou) Co., Ltd.) 13.1 11.1 9.6
消光粉(matting powder) (型號: ACEMATT® TS-100，購自 EVONIK) 1 0.5 0
應了解，以上表1及表2所列之各組成成分之產品型號、供應商以及重量百分比僅作為示例，而不應解讀為限制本發明之範圍。在不脫離所附申請專利範圍的範疇的前提下，本發明所屬技術領域中具有通常知識者，可依自行其需求來針對各組成成分選擇合適之產品型號及供應商，以及調整適當的重量百分比。在本實施例中，係示例性地使用消光粉來做為消光劑(Matting agent)，但本發明不限於此，亦可選用其他型態(例如：液狀)之消光劑。特別地，在一實施方式中，該耐酒精組合物可不含濕潤劑 (Wetting agent)、氮丙啶交聯劑及消泡劑。此外，在一實施方式中，該水性防污組合物可不含消泡劑及消光劑。
圖2係為實施例1之防污結構10的照片，其中頂層(a)係為由耐酒精層12及水性防污層13所構成之防污結構10；基材20則包含：(b)表層，其係由水性PU表面所構成；(c)中間層，其係由水性發泡PU所構成；以及(d)紡織品。
實施例1-2
實施例1-2之防污結構及其製備流程大致上與實施例1-1相同，其差別僅在於實施例1-2中，耐酒精層係由耐酒精組合物B經固化後形成，該耐酒精組合物B之組成成分係如前揭表1所示；以及水性防污層係由水性防污組合物B經固化後形成，該水性防污組合物B之組成成分係如前揭表2所示。
實施例1-3
實施例1-3之防污結構及其製備流程大致上與實施例1-1相同，其差別僅在於實施例1-3中，耐酒精層係由耐酒精組合物C經固化後形成，該耐酒精組合物C之組成成分係如前揭表1所示；以及水性防污層係由水性防污組合物C經固化後形成，該水性防污組合物C之組成成分係如前揭表2所示。
實施例2-1：
與實施例1-1類似，實施例2-1之防污結構，包含：一耐酒精層；以及一水性防污層，其係位於該耐酒精層之上。本實施例中，防污結構係位於一基材之上，其中耐酒精層係位於水性防污層與基材之間。
本實施例中，基材係為溶劑型PU合成皮，但本發明並不限於此。在一實施方式中，該基材可為紡織品、聚氨酯(Polyurethane, PU)皮、水性PU皮、聚氯乙烯(Polyvinyl chloride, PVC)皮、半PU/PVC皮、熱塑性聚氨酯(Thermoplastic polyurethane, TPU)皮、熱塑性聚烯烴(Thermoplastic olefin, TPO)、熱塑性硫化橡膠(Thermoplastic vulcanizate, TPV)、熱塑性苯乙烯(Thermoplastic styrene, TPS)、熱塑性聚醚酯彈性體(Thermoplastic polyether ester elastomer, TPEE)及熱塑性聚醯胺(Thermoplastic polyamide, TPA)，以及由上述材料所組合成的複合結構。
本實施例之防污結構的製備流程如下： a) 於基材上塗覆一耐酒精組合物，並在90-130℃下乾燥1-5分鐘，以形成耐酒精層； b) 於耐酒精層上塗覆一水性防污組合物，並在140℃以上乾燥1-5分鐘，以形成水性防污層，
應了解，以上步驟a)及步驟b)中的乾燥溫度及時間僅作為示例，而不應解讀為限制本發明之範圍。在不脫離所附申請專利範圍的範疇的前提下，本發明所屬技術領域中具有通常知識者，可依自行其需求來適當地調整步驟a)及步驟b)中的乾燥溫度及時間。在一實施方式中，步驟b)可在140-145℃下乾燥。
在本實施例中，耐酒精組合物及水性防污組合物係以噴塗的方式塗覆，但本發明並不限於此，本發明所屬技術領域中具有通常知識者可依自行其需求來選擇適當的塗覆方式。可應用於本發明之防污結構之製備方法的塗覆方式包含但不限於：噴塗、浸塗、淋塗、漆塗、旋塗、真空塗、滾塗及直塗。
在本實施例中，耐酒精層係由耐酒精組合物D經固化後形成，該耐酒精組合物D之組成成分係如下列表3所示：
表3
組成成分 重量百分比
耐酒精組合物D 耐酒精組合物E 耐酒精組合物F
耐水解耐黃變聚醚型聚氨酯樹脂(Hydrolysis-resistant & yellowing-resistant PU resin (polyether type)) (型號 SC-8200G，購自Guangzhou Songjeong Chemical Co., Ltd.) 76 82 88
二液型交聯劑(三聚氰胺型) (Two-component crosslinker (melamine type)) (型號SH-82，購自Guangzhou Songjeong Chemical Co., Ltd.) 11 8.2 5.3
消光粉(matting powder) (型號: ACEMATT® TS-100，購自 EVONIK) 1.5 1.6 1.8
二液型化學促進劑(Two-component chemical promoter) (型號SE-82，購自Guangzhou Songjeong Chemical Co., Ltd.) 11.5 8.2 4.9
在本實施例中，水性防污層係由水性防污組合物D經固化後形成，該水性防污組合物D之組成成分係如下列表4所示：
表4
組成成分 重量百分比
水性防污組合物D 水性防污組合物E 水性防污組合物F
脂肪族耐水解水性聚氨酯樹脂(聚醚和聚酯型) (Aliphatic & hydrolysis-resistant  water-based PU resin (polyether & polyester type)) (型號JW-25A-2，購自Jiuh Yi Chemical Industrial Co. Ltd.) 6.6 19.4 28.9
異氰酸鹽交聯劑(Isocyanate crosslinker) (型號EC-385，購自SiwoChem) 0.6 1.9 2.9
水 58.5 50.2 43.6
矽氧烷樹脂(Polymerized siloxanes) (型號PA-8316，購自Guang zhou HT-Chemical Co., Ltd.) 15.3 13.4 12
水性特氟龍樹脂(Water-based polytetrafluoroethylene (PTFE)) (型號Teflon™ PTFE，購自Dupont Chemours) 2 1.1 1
有機矽油(Silicone oil) (型號85409-1L，購自Sigma-Aldrich) 2.0 1.7 1.4
增黏劑(Tackifier) (型號 CA-909，購自Xuanning Chemical Technology) 0.5 0.4 0.3
濕潤劑 (Wetting agent) (型號:OFX-5211，購自 Guang zhou HT-Chemical Co., Ltd.) 0.3 0.2 0.2
消泡劑(Antifoaming agent) (型號A5757，購自Sigma-Aldrich) 0.1 0.1 0.1
皮革滑爽劑(Leather slipping agent) (型號: AQUADERM ADDITIVE GF，購自Lanxess (Changzhou) Co., Ltd.) 13.1 11.1 9.6
消光粉(matting powder) (型號: ACEMATT® TS-100，購自 EVONIK) 1 0.5 0
應了解，以上表3及表4所列之各組成成分之產品型號、供應商以及重量百分比僅作為示例，而不應解讀為限制本發明之範圍。在不脫離所附 申請專利範圍的範疇的前提下，本發明所屬技術領域中具有通常知識者，可依自行其需求來針對各組成成分選擇合適之產品型號及供應商，以及調整適當的重量百分比。在本實施例中，係示例性地使用消光粉來做為消光劑(Matting agent)，但本發明不限於此，亦可選用其他型態(例如：液狀)之消光劑。特別地，在一實施方式中，該耐酒精組合物可不含消光劑。此外，在一實施方式中，該水性防污組合物可不含消泡劑及消光劑。
實施例2-2
實施例2-2之防污結構及其製備流程大致上與實施例2-1相同，其差別僅在於實施例2-2中，耐酒精層係由耐酒精組合物E經固化後形成，該耐酒精組合物E之組成成分係如前揭表3所示；以及水性防污層係由水性防污組合物E經固化後形成，該水性防污組合物E之組成成分係如前揭表4所示。
實施例2-3
實施例2-3之防污結構及其製備流程大致上與實施例2-1相同，其差別僅在於實施例2-3中，耐酒精層係由耐酒精組合物F經固化後形成，該耐酒精組合物F之組成成分係如前揭表3所示；以及水性防污層係由水性防污組合物F經固化後形成，該水性防污組合物F之組成成分係如前揭表4所示。
測試例：
針對上述實施例1-1至1-3以及2-1至2-3之防污結構進行測試。首先，係以特定污染物污染實施例1-1至1-3以及2-1至2-3之防污結構，待經歷特定時間後進行擦拭，評價污漬殘留的程度，其結果係如下列表5所示。
表5 實施例1-1：
              測試時間   測試要項(級數) 3分鐘內擦拭 3小時後擦拭 24小時後擦拭
乾布擦拭 酒精擦拭* 乾布擦拭 酒精擦拭* 乾布擦拭 酒精擦拭*
牛仔布(色移行) 5 5 5 5 5 5
旅館專用圓珠筆 5 5 5 5 5 5
馬克筆 5 5 5 5 4 4.5
紅茶 5 5 5 5 5 5
咖啡 5 5 5 5 5 5
番茄醬 5 5 5 5 5 5
芥末 5 5 5 5 4 4.5
可樂 5 5 5 5 5 5
醬油 5 5 5 5 5 5
實施例1-2：
              測試時間   測試要項(級數) 3分鐘內擦拭 3小時後擦拭 24小時後擦拭
乾布擦拭 酒精擦拭* 乾布擦拭 酒精擦拭* 乾布擦拭 酒精擦拭*
牛仔布(色移行) 5 5 5 5 5 5
旅館專用圓珠筆 5 5 5 5 5 5
馬克筆 5 5 5 5 4.5 5
紅茶 5 5 5 5 5 5
咖啡 5 5 5 5 5 5
番茄醬 5 5 5 5 5 5
芥末 5 5 5 5 4.5 5
可樂 5 5 5 5 5 5
醬油 5 5 5 5 5 5
實施例1-3：
              測試時間   測試要項(級數) 3分鐘內擦拭 3小時後擦拭 24小時後擦拭
乾布擦拭 酒精擦拭* 乾布擦拭 酒精擦拭* 乾布擦拭 酒精擦拭*
牛仔布(色移行) 5 5 5 5 5 5
旅館專用圓珠筆 5 5 5 5 5 5
馬克筆 5 5 4.5 5 3.5 4
紅茶 5 5 5 5 5 5
咖啡 5 5 5 5 5 5
番茄醬 5 5 5 5 5 5
芥末 5 5 4.5 5 3.5 4 
可樂 5 5 5 5 5 5
醬油 5 5 5 5 5 5
實施例2-1：
              測試時間   測試要項(級數) 3分鐘內擦拭 3小時後擦拭 24小時後擦拭
乾布擦拭 酒精擦拭* 乾布擦拭 酒精擦拭* 乾布擦拭 酒精擦拭*
牛仔布(色移行) 5 5 5 5 5 5
旅館專用圓珠筆 5 5 5 5 5 5
馬克筆 5 5 5 5 4 4.5
紅茶 5 5 5 5 5 5
咖啡 5 5 5 5 5 5
番茄醬 5 5 5 5 5 5
芥末 5 5 5 5 4 4.5
可樂 5 5 5 5 5 5
醬油 5 5 5 5 5 5
實施例2-2：
              測試時間   測試要項(級數) 3分鐘內擦拭 3小時後擦拭 24小時後擦拭
乾布擦拭 酒精擦拭* 乾布擦拭 酒精擦拭* 乾布擦拭 酒精擦拭*
牛仔布(色移行) 5 5 5 5 5 5
旅館專用圓珠筆 5 5 5 5 5 5
馬克筆 5 5 5 5 4.5 5
紅茶 5 5 5 5 5 5
咖啡 5 5 5 5 5 5
番茄醬 5 5 5 5 5 5
芥末 5 5 5 5 4.5 5
可樂 5 5 5 5 5 5
醬油 5 5 5 5 5 5
實施例2-3：
              測試時間   測試要項(級數) 3分鐘內擦拭 3小時後擦拭 24小時後擦拭
乾布擦拭 酒精擦拭* 乾布擦拭 酒精擦拭* 乾布擦拭 酒精擦拭*
牛仔布(色移行) 5 5 5 5 5 5
旅館專用圓珠筆 5 5 5 5 5 5
馬克筆 5 5 4.5 5 3.5 4
紅茶 5 5 5 5 5 5
咖啡 5 5 5 5 5 5
番茄醬 5 5 5 5 5 5
芥末 5 5 4.5 5 3.5 4 
可樂 5 5 5 5 5 5
醬油 5 5 5 5 5 5
*代表先使用乾布擦拭後，再使用95%酒精溶液擦拭 防污級數說明： 第5級 無污漬 第4級 輕微污漬 第3級 明顯污漬 第2級 大量污漬 第1級 過多污漬
表5中，係以0.5作為評量之基數，舉例來說，4.5代表防污級數係介於第4級至第5級之間。遭受到表5中的各種污染物污染的本發明之防污結構，在經過95%酒精溶液的擦拭後，皆可達到無污漬或輕微污漬的程度。由此可見，本發明之防污結構對於各種污染物皆具有良好的防污能力。
本發明之防污結構與先前技術之防污材料在合成皮加工上差異性主要在於： 1.   市售大部分廠牌合成皮加工防污材料大都以二液型溶劑交聯樹脂為主，因其成分包含有機溶劑，故會有揮發性有機化合物(Volatile Organic Compounds, VOC)揮發的問題。 2.   市售應用於皮革上的防污材料都是屬於高硬度樹脂，而本發明之防污結構所使用的水性PU是低硬度樹脂，故不會有高硬度溶劑型樹脂加工於軟性皮料上時，有耐曲折上的疑慮。 3.   目前常見的合成皮材料經本發明之防污結構處理後，原子筆是畫不太上去的，即使畫的上去也可輕鬆擦掉，而經市售之防污材料處理的合成皮材料則是容易畫上去的，且通常須使用清潔劑才能擦拭掉，亦有時效性問題，通常需在三小時內擦拭，超過24小時則無法清除，而本發明之防污結構則無上述問題(參見表5)。 4.   市售水性防污材料通常會有牛仔布色移行的問題。 5.   市售大部分廠牌合成皮加工防污材料並非在常見合成皮種類都能加工。 6.   本發明之防污結構藉由水性防污層與耐酒精層的結合產生更強的保護層，使其可以被酒精溶液反覆擦拭清潔至少30次以上，而不至於減損其防污能力。
本發明之防污結構具有下列優點： 1.   原料主體可使用的水性PU樹脂餘料，其可以再回收添加使用。 2.   無味無毒性，減少對環境影響，符合世界環保趨勢。 3.   高溫壓花後耐黃變性佳，也無焦臭味，無造成VOC釋放的問題。
本發明在上文中已以較佳實施例揭露，然熟習本項技術者應理解的是，該實施例僅用於描繪本發明，而不應解讀為限制本發明之範圍。應注意的是，舉凡與該實施例等效之變化與置換，均應設為涵蓋於本發明之範疇內。因此，本發明之保護範圍當以申請專利範圍所界定者為準。
10:防污結構 12:耐酒精層 13:水性防污層 20:基材 (a):頂層 (b):表層 (c):中間層 (d):紡織品
為了便於描述與清晰，圖式中各層之厚度或尺寸被加以放大、省略或概要的描繪。同時，各元件之尺寸並不完全反映其真實尺寸。 ［圖1］      係為實施例1之防污結構及基材的示意圖；以及 ［圖2］      係為實施例1之防污結構及基材的照片。
10:防污結構
12:耐酒精層
13:水性防污層
20:基材

Claims (10)

  1. 一種防污結構，包含： 一耐酒精層；以及 一水性防污層，其係位於該耐酒精層之上， 其中，該耐酒精層係由一耐酒精組合物經固化後形成，該耐酒精組合物包含聚氨酯樹脂，以及 其中，該水性防污層係由一水性防污組合物經固化後形成，該水性防污組合物係包含聚氨酯樹脂、水、矽氧烷樹脂、水性特氟龍樹脂及有機矽油。
  2. 如請求項1所述之防污結構，其中，該耐酒精組合物包含： 30-50重量百分比的聚醚和聚酯型的脂肪族水性聚氨酯樹脂；以及 進一步包含： 40-70重量百分比的水。
  3. 如請求項2所述之防污結構，其中，該耐酒精組合物進一步包含： 0.01-3重量百分比的濕潤劑； 0.01-2重量百分比的氮丙啶交聯劑； 0.01-1重量百分比的消泡劑；以及 0.5-2.5重量百分比的聚碳化二亞銨交聯劑。
  4. 如請求項1所述之防污結構，其中，該耐酒精組合物包含： 70-90重量百分比的耐水解耐黃變聚醚型聚氨酯樹脂；以及 進一步包含： 5-15重量百分比的三聚氰胺型二液型交聯劑；以及 4-15重量百分比的二液型化學促進劑。
  5. 如請求項4所述之防污結構，其中，該耐酒精組合物進一步包含： 0.01-2重量百分比的消光劑。
  6. 如請求項1所述之防污結構，其中，該水性防污組合物包含： 5-40重量百分比的聚醚和聚酯型的脂肪族耐水解水性聚氨酯樹脂； 40-70重量百分比的水； 5-30重量百分比的矽氧烷樹脂； 1-10重量百分比的水性特氟龍樹脂；以及 1-10重量百分比的有機矽油。
  7. 如請求項6所述之防污結構，其中，該水性防污組合物進一步包含： 0.1-3重量百分比的異氰酸鹽交聯劑； 0.1-3重量百分比的增黏劑； 0.1-3重量百分比的濕潤劑； 0.01-3重量百分比的消泡劑； 5-15重量百分比的皮革滑爽劑；以及 0.01-1重量百分比的消光劑。
  8. 如請求項1所述之防污結構，其中，該防污結構係位於一基材之上，且該耐酒精層係位於該水性防污層與該基材之間，該基材係由選自紡織品、聚氨酯、聚氯乙烯、熱塑性聚氨酯、熱塑性聚烯烴、熱塑性硫化橡膠、熱塑性苯乙烯、熱塑性聚醚酯彈性體及熱塑性聚醯胺所組成之群組的材料所構成。
  9. 一種防污結構之製備方法，包含： a) 於一基材上塗覆一耐酒精組合物，並在80-160℃下使該耐酒精組合物乾燥，以形成一耐酒精層； b) 於該耐酒精層上塗覆一水性防污組合物，並在140℃以上使該水性防污組合物乾燥，以形成一水性防污層， 其中，該耐酒精層係由一耐酒精組合物經固化後形成，該耐酒精組合物 包含聚氨酯樹脂，以及 其中，該水性防污層係由一水性防污組合物經固化後形成，該水性防污組合物係包含聚氨酯樹脂、水、矽氧烷樹脂、水性特氟龍樹脂及有機矽油。
  10. 如請求項9所述之製備方法，其中，該耐酒精組合物及該水性防污組合物係分別以噴塗的方式塗覆於該基材及該耐酒精層上。
TW108145528A 2019-08-06 2019-12-12 防污結構及其製備方法 TWI692563B (zh)

Priority Applications (5)

Application Number Priority Date Filing Date Title
US16/810,873 US11414553B2 (en) 2019-08-06 2020-03-06 Fouling-proof structure
US16/810,875 US20210040349A1 (en) 2019-08-06 2020-03-06 Method of producing a fouling-proof structure
EP20170899.7A EP3772550B1 (en) 2019-08-06 2020-04-22 Stain-proof structure and production method thereof
AU2020203070A AU2020203070A1 (en) 2019-08-06 2020-05-08 Fouling-Proof Structure And Production Method Thereof
JP2020130062A JP6991607B2 (ja) 2019-08-06 2020-07-31 防汚構造及びその製造方法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
TW108127961 2019-08-06
TW108127961 2019-08-06

Publications (2)

Publication Number Publication Date
TWI692563B TWI692563B (zh) 2020-05-01
TW202106948A true TW202106948A (zh) 2021-02-16

Family

ID=71896295

Family Applications (1)

Application Number Title Priority Date Filing Date
TW108145528A TWI692563B (zh) 2019-08-06 2019-12-12 防污結構及其製備方法

Country Status (5)

Country Link
US (2) US20210040349A1 (zh)
EP (1) EP3772550B1 (zh)
JP (1) JP6991607B2 (zh)
AU (1) AU2020203070A1 (zh)
TW (1) TWI692563B (zh)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI692563B (zh) * 2019-08-06 2020-05-01 健豐全球貿易股份有限公司 防污結構及其製備方法

Family Cites Families (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3962369A (en) * 1973-05-16 1976-06-08 Ppg Industries, Inc. Sealer-primer for elastomeric coatings
JPH11170448A (ja) * 1997-12-12 1999-06-29 Dainippon Printing Co Ltd 化粧シート
DE19945848A1 (de) * 1999-09-24 2001-04-05 Henkel Kgaa Beschichtungsmittel für Elastomere
JP5469837B2 (ja) * 2007-09-12 2014-04-16 富士フイルム株式会社 親水性組成物
US9005591B2 (en) * 2008-05-16 2015-04-14 Avon Products, Inc. Compositions for imparting hydrophobicity and water repellency to hair
JP2011052336A (ja) * 2009-08-31 2011-03-17 Kuraray Co Ltd 耐アルコール性に優れた皮革様シート及びその製造方法
WO2011034931A2 (en) * 2009-09-15 2011-03-24 Reactive Surface, Ltd. Anti-fouling paints and coatings
WO2012162640A2 (en) * 2011-05-25 2012-11-29 Diversey, Inc. Surface coating system and method of using surface coating system
US8795780B2 (en) * 2011-08-04 2014-08-05 Soon Kie JUNG Textile fabric sheet having stain and liquid resistance and the preparation method thereof
US9103067B2 (en) * 2011-08-04 2015-08-11 Soon Kie JUNG Textile fabric sheet having stain and liquid resistance and the preparation method thereof
US9322130B2 (en) * 2011-08-04 2016-04-26 Soon Kie JUNG Textile fabric sheet having stain and liquid resistance and the preparation method thereof
CN103103776A (zh) * 2011-11-14 2013-05-15 江苏宝泽高分子材料股份有限公司 一种合成革用雾面变色长毛印刷处理剂及其制备方法
WO2013078190A1 (en) * 2011-11-21 2013-05-30 3M Innovative Properties Company A paint protective film comprising nanoparticles
JP5578195B2 (ja) * 2012-05-14 2014-08-27 大日本印刷株式会社 壁装用化粧シート
WO2016152631A1 (ja) * 2015-03-26 2016-09-29 リンテック株式会社 塗膜保護フィルム
KR102289888B1 (ko) * 2017-01-17 2021-08-13 아크조노벨코팅스인터내셔널비.브이. 방오 코팅 조성물, 이러한 코팅 조성물로 코팅된 기판, 및 이러한 코팅 조성물의 용도
SG11201908605XA (en) * 2017-03-29 2019-10-30 I Tech Ab Antifouling article
US20190039361A1 (en) * 2017-08-02 2019-02-07 Covestro Llc One component polyurethane dispersion for vinyl windows, glass, and other substrates
CN107313263A (zh) * 2017-08-18 2017-11-03 安徽安利材料科技股份有限公司 耐有机溶剂沙发家具用聚氨酯合成革的制备方法
JP2019065426A (ja) * 2017-10-02 2019-04-25 アキレス株式会社 耐久性に優れた防汚性能を有する合成皮革
CN207452155U (zh) * 2017-10-31 2018-06-05 明新旭腾新材料股份有限公司 一种耐擦拭汽车皮革
CN207619705U (zh) * 2017-11-30 2018-07-17 清远市齐力合成革有限公司 一种水性丝光绒感聚氨酯合成革
CN109233535A (zh) * 2018-07-02 2019-01-18 安徽玉堂雨具有限公司 一种pu合成革的防污处理剂
CN109354994B (zh) * 2018-09-30 2020-11-03 佛山阳光逸采涂料科技有限公司 一种uv led水性紫外光固化红木家具涂料及其制备方法
US20200247940A1 (en) * 2019-02-05 2020-08-06 Covestro Llc Stable one component polyurethane dispersions for vinyl windows
TWI692563B (zh) * 2019-08-06 2020-05-01 健豐全球貿易股份有限公司 防污結構及其製備方法

Also Published As

Publication number Publication date
TWI692563B (zh) 2020-05-01
JP6991607B2 (ja) 2022-02-03
AU2020203070A1 (en) 2021-02-25
EP3772550B1 (en) 2024-03-06
US11414553B2 (en) 2022-08-16
US20210040332A1 (en) 2021-02-11
EP3772550A1 (en) 2021-02-10
US20210040349A1 (en) 2021-02-11
JP2021024281A (ja) 2021-02-22
EP3772550C0 (en) 2024-03-06

Similar Documents

Publication Publication Date Title
US9273214B1 (en) Removable spray coating and application method
CN108165152A (zh) 一种水性低哑光防刮涂层及其使用方法
CA2850663A1 (en) Textile fabric sheet having stain and liquid resistance and the preparation method thereof
TW202106948A (zh) 防污結構及其製備方法
CN103850120A (zh) 一种装饰材料防污处理剂的配方及制备方法和应用
CN101748607A (zh) 一种易去污高耐磨耐久沙发家俱用合成革的生产方法
KR101235568B1 (ko) 오염물질에 의한 표면오염제거용 코팅제 및 그 제조방법
JP2007191820A (ja) 防汚性合成皮革
US20130035012A1 (en) Textile fabric sheet having stain and liquid resistance and the preparation method thereof
US8742004B1 (en) Coating system having long-term durability and chemical resistance
KR102054764B1 (ko) 방오 성능을 갖는 인조가죽 원단의 제조방법
CN101003044A (zh) 轿车漆面中浅层划伤的修补方法
CN105383100A (zh) 一种自清洗无纺布
CN104179017B (zh) 一种水性表面处理浆料以及清洁化生产易去污型合成革的方法
CN109468847B (zh) 一种超双疏纺织品整理剂及其制备方法和应用
CN104826785A (zh) 一种用于汽车漆面及轮毂的镀晶液的使用方法
JP6000604B2 (ja) ゴム塗装方法並びにこのゴム塗装方法で使用されるゴム用塗料、ゴム用塗料組成物及びゴム塗装用下地処理剤
CN110983805B (zh) 一种耐腐蚀耐磨的人造革及其制备方法
CN108753168A (zh) 具有抗污能力的环保擦涂型硬质木蜡油及其制备方法与应用
US7851546B2 (en) Liquid plasticizing resin and use of such a resin
CN112063297A (zh) 一种纳米自清洁防涂鸦涂液
CN114149738A (zh) 一种应用于三聚氰胺板的聚氨酯底漆
US11248130B2 (en) Vehicle interior protective coating
CN110982405B (zh) 一种防涂鸦表面处理液及其制备方法
CN110218512A (zh) 一种高光镜面漆及其制备方法和应用