TW201833053A - 一種玻璃容器矽膠塗層的製作方法 - Google Patents

一種玻璃容器矽膠塗層的製作方法 Download PDF

Info

Publication number
TW201833053A
TW201833053A TW107100184A TW107100184A TW201833053A TW 201833053 A TW201833053 A TW 201833053A TW 107100184 A TW107100184 A TW 107100184A TW 107100184 A TW107100184 A TW 107100184A TW 201833053 A TW201833053 A TW 201833053A
Authority
TW
Taiwan
Prior art keywords
layer
glass container
silicone
liquid silicone
silicone rubber
Prior art date
Application number
TW107100184A
Other languages
English (en)
Other versions
TWI658020B (zh
Inventor
明安國
Original Assignee
大陸商深圳市邦嘉實業有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 大陸商深圳市邦嘉實業有限公司 filed Critical 大陸商深圳市邦嘉實業有限公司
Publication of TW201833053A publication Critical patent/TW201833053A/zh
Application granted granted Critical
Publication of TWI658020B publication Critical patent/TWI658020B/zh

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04Polysiloxanes
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/3405Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of organic materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/10798Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing silicone
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/28Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
    • B32B27/283Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42 comprising polysiloxanes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/001General methods for coating; Devices therefor
    • C03C17/003General methods for coating; Devices therefor for hollow ware, e.g. containers
    • C03C17/005Coating the outside
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/006Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
    • C03C17/007Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character containing a dispersed phase, e.g. particles, fibres or flakes, in a continuous phase
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/006Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
    • C03C17/008Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character comprising a mixture of materials covered by two or more of the groups C03C17/02, C03C17/06, C03C17/22 and C03C17/28
    • C03C17/009Mixtures of organic and inorganic materials, e.g. ormosils and ormocers
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/28Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
    • C03C17/30Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material with silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/42Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating of an organic material and at least one non-metal coating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04Polysiloxanes
    • C08G77/12Polysiloxanes containing silicon bound to hydrogen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04Polysiloxanes
    • C08G77/20Polysiloxanes containing silicon bound to unsaturated aliphatic groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04Polysiloxanes
    • C08L83/06Polysiloxanes containing silicon bound to oxygen-containing groups
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J183/00Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Adhesives based on derivatives of such polymers
    • C09J183/04Polysiloxanes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2383/00Polysiloxanes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2439/00Containers; Receptacles
    • B32B2439/40Closed containers
    • B32B2439/60Bottles
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00Coatings on glass
    • C03C2217/40Coatings comprising at least one inhomogeneous layer
    • C03C2217/43Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase
    • C03C2217/44Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the composition of the continuous phase
    • C03C2217/445Organic continuous phases
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00Coatings on glass
    • C03C2217/40Coatings comprising at least one inhomogeneous layer
    • C03C2217/43Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase
    • C03C2217/46Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase
    • C03C2217/47Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase consisting of a specific material
    • C03C2217/475Inorganic materials
    • C03C2217/478Silica
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00Coatings on glass
    • C03C2217/70Properties of coatings
    • C03C2217/78Coatings specially designed to be durable, e.g. scratch-resistant
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2218/00Methods for coating glass
    • C03C2218/10Deposition methods
    • C03C2218/11Deposition methods from solutions or suspensions
    • C03C2218/112Deposition methods from solutions or suspensions by spraying
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2218/00Methods for coating glass
    • C03C2218/30Aspects of methods for coating glass not covered above
    • C03C2218/32After-treatment
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Inorganic Chemistry (AREA)
  • Composite Materials (AREA)
  • Dispersion Chemistry (AREA)
  • Details Of Rigid Or Semi-Rigid Containers (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Surface Treatment Of Glass (AREA)
  • Paints Or Removers (AREA)
  • Glass Melting And Manufacturing (AREA)
  • Laminated Bodies (AREA)

Abstract

本發明提供了一種玻璃容器矽膠塗層的製作方法,包括如下步驟:準備玻璃容器,且將玻璃容器外表面進行清潔處理;在玻璃容器外表面噴塗一層黏結層,且在黏結層的外表面噴塗一層液體矽膠層或直接在玻璃容器外表面噴塗一層自黏結的液體矽膠層;液體矽膠為有色或無色液體矽膠,所述自黏結的液體矽膠層黏度為1000-2000cst,本發明的有益效果在於:製作方法簡單,無需對基材表面進行特殊處理,即可將液體矽膠噴塗在玻璃容器表面;玻璃容器表面的矽膠層會有明顯的自淺到深或自深到淺的顏色變化;玻璃容器表面的矽膠外表面的矽膠層整體厚度一致,非常美觀,在硫化成型的矽膠外表面再增加一層矽膠手感油;手感舒適,富有質感;為了增強產品預示功能,豐富產品色彩。

Description

一種玻璃容器矽膠塗層的製作方法
本發明涉及一種玻璃容器矽膠塗層的方法,尤其涉及一種玻璃容器矽膠塗層的製作方法。
市面上的自黏結成型的液體矽橡膠對基材(如玻璃、金屬、塑料等)的黏附力較差,如需要黏結力強,需要作基材表面處理,製作方法繁瑣;對基材表面進行複雜處理後再噴塗的矽膠層沒有顏色或只有單一顏色沒有顏色的深淺變化、不美觀、手感差,缺乏質感。
有鑑於此,吾等發明人乃潛心進一步研究,並著手進行研發及改良,期以一較佳設作以解決上述問題,且在經過不斷試驗及修改後而有本發明之問世。
本發明目的在於解決市面上的自黏結成型的液體矽橡膠對基材(如玻璃、金屬、塑料等)的黏附力較差,如需要黏結力強,需要作基材表面處理,製作方法繁瑣;對基材表面進行複雜處理後再噴塗的矽膠層沒有顏色或只有單一顏色沒有顏色的深淺變化、不美觀、手感差,缺乏質感的不足而提供的一種新型玻璃容器矽膠塗層的製作方法。
本發明是通過以下技術方案來實現的:一種玻璃容器矽膠塗層的製作方法,在玻璃容器外表面噴塗一層液體矽膠,通過液體矽膠的黏附力,保護玻璃、防止玻璃破碎時,玻璃渣飛濺;包括如下步驟:
(1)準備玻璃容器,且將玻璃容器外表面進行清潔處理;
(2)在玻璃容器外表面噴塗一層黏結層,且在黏結層的外表面噴塗一層液體矽膠層或直接在玻璃容器外表面噴塗一層自黏結的液體矽膠層;液體矽膠為有色或無色液體矽膠,所述自黏結的液體矽膠層黏度為1000-2000cst;
(3)烘乾30分鐘-100分鐘,烘乾溫度為180-220℃,使矽橡膠硫化成型。
進一步地,所述步驟(2)中將有色液體矽膠層用有機溶劑稀釋,並自玻璃容器一端到另一端從厚到薄或從薄到厚噴塗在黏結層的外表面,靜置一段時間或將有色自黏結液體矽膠用有機溶劑稀釋,並自玻璃容器一端到另一端從厚到薄或從薄到厚直接噴塗在玻璃容器外表面,靜置一段時間。
進一步地,所述步驟(2)中將有色液體矽膠層用有機溶劑稀釋,並自玻璃容器一端到另一端從厚到薄或從薄到厚噴塗在黏結層的外表面,靜置一段時間或將有色自黏結液體矽膠用有機溶劑稀釋,並自玻璃容器一端到另一端從厚到薄或從薄到厚直接噴塗在玻璃容器外表面,靜置一段時間後;在有色液體矽膠層外層再用另外的機器自玻璃容器一端到另一端從薄到厚或從厚到薄噴塗無色液體矽膠。
進一步地,所述步驟(3)後在硫化成型的矽膠外表面再增加一層矽膠手感油;為了增強矽膠層手感和去除矽膠靜電,在矽油中加入矽膠手感油,在150-180℃條件下烘烤,使得表層在鉑金催化作用下硫化結網;為了增強產品預示功能,豐富產品色彩,將感溫或不感溫色粉添加劑加入到液體矽橡膠中,高速分散,使其與液體矽橡膠混合,使液體矽橡膠達到隨溫度的變化變色或不變色;所述矽膠手感油為聚乙烯微臘,在矽油中混合比例一般不超過10%。
進一步地,所述步驟(2)中在玻璃容器外表面噴塗一層黏結層,所述黏結層成分為:
聚矽氧烷,含量為65%;
氣相法白炭黑SiO2 ,含量為15%;以及
甲基矽樹脂,含量為20%。
進一步地,所述步驟(2)中在玻璃容器外表面噴塗一層黏結層,噴塗時間為1-5秒,厚度範圍為0.1-1絲。
進一步地,所述步驟(2)中將有色液體矽膠層用有機溶劑稀釋,並自玻璃容器一端到另一端從厚到薄或從薄到厚噴塗在黏結層的外表面,靜置一段時間或將有色自黏結液體矽膠用有機溶劑稀釋,並自玻璃容器一端到另一端從厚到薄或從薄到厚直接噴塗在玻璃容器外表面,靜置一段時間;噴塗時間為5-10秒;靜置時間為5-10秒;厚度範圍為200-2絲。
進一步地,在有色液體矽膠層外層再用另外的機器自玻璃容器一端到另一端從薄到厚或從厚到薄噴塗無色液體矽膠,噴塗時間為5-10秒;厚度範圍為2-200絲。
進一步地,所述自黏結的液體矽膠製備方法,包括如下步驟:
(1)準備氣相白炭黑SiO2 ,並混合帶有極性基團的矽氧烷處理劑;所述帶有極性基團為環氧基、甲基丙烯酸丙基;
(2)將處理好的氣相白炭黑SiO2 與帶極性基團的矽烷或矽油混合;
(3)將混合好的材料分成A、B組合;A組含有鉑金硫化劑,B組含有抑制劑,所述抑制劑通常為炔醇類物質,如甲基丁炔醇;以及
將A、B組分按1:1混合,使用有機溶劑將液體矽橡膠稀釋,黏度為1000-2000cst。
進一步地,所述自黏結的液體矽膠主要組分及質量百分比為:
氣相法白炭黑SiO2 ,含量為20%-40%;
乙烯基矽油含量為60%-75%;其分子結構式為:CH2=CH-Si(CH3)2O[(CH3)2SiO]n(CH3)2Si-CH=CH2 ;以及
含氫矽油含量為2%-10%;其分子結構式為:C3 H9 OSi·(CH4 OSi)n·C3 H9 Si;
使矽膠黏度500(Pas,23℃),拉伸強度大於9 Mpa。
本發明的有益效果在於:
(1)製作方法簡單,無需對基材表面進行特殊處理,即可將液體矽膠噴塗在玻璃容器表面;
(2)玻璃容器表面的矽膠層會有明顯的自淺到深或自深到淺的顏色變化;
(3)玻璃容器表面的矽膠外表面的矽膠層整體厚度一致,非常漂亮美觀,
(4)在硫化成型的矽膠外表面再增加一層矽膠手感油;為了增強矽膠層手感和去除矽膠靜電,在矽油中加入矽膠手感油,在150-180℃條件下烘烤,使得表層在鉑金催化作用下硫化結網;手感舒適,富有質感;
(5)為了增強產品預示功能,豐富產品色彩,將感溫或不感溫色粉添加劑加入到液體矽橡膠中,高速分散,使其與液體矽橡膠混合,使液體矽橡膠達到隨溫度的變化變色或不變色。
關於吾等發明人之技術手段,茲舉數種較佳實施例配合圖式於下文進行詳細說明,俾供 鈞上深入瞭解並認同本發明。
下面結合圖式及具體實施方式對本發明做進一步描述:
如第1圖所示:一種玻璃容器矽膠塗層的製作方法,在玻璃容器1外表面噴塗一層液體矽膠,通過液體矽膠的黏附力,保護玻璃、防止玻璃破碎時,玻璃渣飛濺;包括如下步驟:
(1)準備玻璃容器1,且將玻璃容器外表面進行清潔處理;
(2)在玻璃容器1外表面噴塗一層黏結層,且在黏結層的外表面噴塗一層液體矽膠層或直接在玻璃容器外表面噴塗一層自黏結的液體矽膠層;液體矽膠為有色或無色液體矽膠,所述自黏結的液體矽膠層黏度為1000-2000cst;
(3)烘乾30分鐘-100分鐘,烘乾溫度為180-220℃,使矽橡膠硫化成型。
進一步地,所述步驟(2)中將有色液體矽膠層2用有機溶劑稀釋,並自玻璃容器1一端到另一端從厚到薄或從薄到厚噴塗在黏結層的外表面,靜置一段時間或將有色自黏結液體矽膠用有機溶劑稀釋,並自玻璃容器1一端到另一端從厚到薄或從薄到厚直接噴塗在玻璃容器1外表面,靜置一段時間。
進一步地,所述步驟(2)中將有色液體矽膠層2用有機溶劑稀釋,並自玻璃容器1一端到另一端從厚到薄或從薄到厚噴塗在黏結層的外表面,靜置一段時間或將有色自黏結液體矽膠用有機溶劑稀釋,並自玻璃容器1一端到另一端從厚到薄或從薄到厚直接噴塗在玻璃容器1外表面,靜置一段時間後;在有色液體矽膠層外層2再用另外的機器自玻璃容器1一端到另一端從薄到厚或從厚到薄噴塗無色液體矽膠層3。
進一步地,所述步驟(3)後在硫化成型的矽膠外表面再增加一層矽膠手感油;為了增強矽膠層手感和去除矽膠靜電,在矽油中加入矽膠手感油,在150-180℃條件下烘烤,使得表層在鉑金催化作用下硫化結網;為了增強產品預示功能,豐富產品色彩,將感溫或不感溫色粉添加劑加入到液體矽橡膠中,高速分散,使其與液體矽橡膠混合,使液體矽橡膠達到隨溫度的變化變色或不變色;所述矽膠手感油為聚乙烯微臘,在矽油中混合比例一般不超過10%。
進一步地,所述步驟(2)中在玻璃容器1外表面噴塗一層黏結層,所述黏結層成分為:
聚矽氧烷,含量為65%;
氣相法白炭黑SiO2 ,含量為15%;以及
甲基矽樹脂,含量為20%;
進一步地,所述步驟(2)中在玻璃容器1外表面噴塗一層黏結層,噴塗時間為1-5秒,厚度範圍為0.1-1絲。
進一步地,所述步驟(2)中將有色液體矽膠層2用有機溶劑稀釋,並自玻璃容器1一端到另一端從厚到薄或從薄到厚噴塗在黏結層的外表面,靜置一段時間或將有色自黏結液體矽膠用有機溶劑稀釋,並自玻璃容器1一端到另一端從厚到薄或從薄到厚直接噴塗在玻璃容器1外表面,靜置一段時間;噴塗時間為5-10秒;靜置時間為5-10秒;厚度範圍為200-2絲。
進一步地,在有色液體矽膠層外層2再用另外的機器自玻璃容器1一端到另一端從薄到厚或從厚到薄噴塗無色液體矽膠層3,噴塗時間為5-10秒;厚度範圍為2-200絲。
進一步地,所述自黏結的液體矽膠製備方法,包括如下步驟:
(1)準備氣相白炭黑SiO2 ,並混合帶有極性基團的矽氧烷處理劑;所述帶有極性基團為環氧基、甲基丙烯酸丙基;
(2)將處理好的氣相白炭黑SiO2 與帶極性基團的矽烷或矽油混合;
(3)將混合好的材料分成A、B組合;A組含有鉑金硫化劑,B組含有抑制劑,所述抑制劑通常為炔醇類物質,如甲基丁炔醇;
(4)將A、B組分按1:1混合,使用有機溶劑將液體矽橡膠稀釋,黏度為1000-2000cst。
進一步地,所述自黏結的液體矽膠主要組分及質量百分比為:
氣相法白炭黑SiO2 ,含量為20%-40%;
乙烯基矽油含量為60%-75%;其分子結構式為:CH2=CH-Si(CH3)2O[(CH3)2SiO]n(CH3)2Si-CH=CH2 ;
含氫矽油含量為2%-10%;其分子結構式為:C3 H9 OSi·(CH4 OSi)n·C3 H9 Si;
使矽膠黏度500(Pas,23℃),拉伸強度大於9 Mpa。
綜上所述,本發明所揭露之技術手段確能有效解決習知等問題,並達致預期之目的與功效,且申請前未見諸於刊物、未曾公開使用且具長遠進步性,誠屬專利法所稱之發明無誤,爰依法提出申請,懇祈 鈞上惠予詳審並賜准發明專利,至感德馨。
惟以上所述者,僅為本發明之數種較佳實施例,當不能以此限定本發明實施之範圍,即大凡依本發明申請專利範圍及發明說明書內容所作之等效變化與修飾,皆應仍屬本發明專利涵蓋之範圍內。
〔本發明〕
1‧‧‧玻璃容器
2‧‧‧從厚到薄或從薄到厚的有色液體矽膠層
3‧‧‧從薄到厚或從厚到薄的無色液體矽膠層
第1圖係本發明在玻璃容器外表面噴塗液體矽膠層的結構示意圖。

Claims (10)

  1. 一種玻璃容器矽膠塗層的製作方法,其特徵在於,在玻璃容器外表面噴塗一層液體矽膠,通過液體矽膠的黏附力,保護玻璃、防止玻璃破碎時,玻璃渣飛濺;包括如下步驟: (1)準備玻璃容器,且將玻璃容器外表面進行清潔處理; (2)在玻璃容器外表面噴塗一層黏結層,且在黏結層的外表面噴塗一層液體矽膠層或直接在玻璃容器外表面噴塗一層自黏結的液體矽膠層;液體矽膠為有色或無色液體矽膠,所述自黏結的液體矽膠層黏度為1000-2000cst;以及 (3)烘乾30分鐘-100分鐘,烘乾溫度為180-220℃,使矽橡膠硫化成型。
  2. 如申請專利範圍第1項所述之玻璃瓶矽膠塗層的製作方法,其中,所述步驟(2)中將有色液體矽膠層用有機溶劑稀釋,並自玻璃容器一端到另一端從厚到薄或從薄到厚噴塗在黏結層的外表面,靜置一段時間或將有色自黏結液體矽膠用有機溶劑稀釋,並自玻璃容器一端到另一端從厚到薄或從薄到厚直接噴塗在玻璃容器外表面,靜置一段時間。
  3. 如申請專利範圍第2項所述之玻璃瓶矽膠塗層的製作方法,其中, 所述步驟(2)中將有色液體矽膠層用有機溶劑稀釋,並自玻璃容器一端到另一端從厚到薄或從薄到厚噴塗在黏結層的外表面,靜置一段時間或將有色自黏結液體矽膠用有機溶劑稀釋,並自玻璃容器一端到另一端從厚到薄或從薄到厚直接噴塗在玻璃容器外表面,靜置一段時間後;在有色液體矽膠層外層再用另外的機器自玻璃容器一端到另一端從薄到厚或從厚到薄噴塗無色液體矽膠層。
  4. 如申請專利範圍第1項所述之玻璃瓶矽膠塗層的製作方法,其中,所述步驟(3)後在硫化成型的矽膠外表面再增加一層矽膠手感油;為了增強矽膠層手感和去除矽膠靜電,在矽油中加入矽膠手感油,在150-180℃條件下烘烤,使得表層在鉑金催化作用下硫化結網;為了增強產品預示功能,豐富產品色彩,將感溫或不感溫色粉添加劑加入到液體矽橡膠中,高速分散,使其與液體矽橡膠混合,使液體矽橡膠達到隨溫度的變化變色或不變色;所述矽膠手感油為聚乙烯微臘,在矽油中混合比例一般不超過10%。
  5. 如申請專利範圍第1項所述之玻璃瓶矽膠塗層的製作方法,其中,所述步驟(2)中在玻璃容器外表面噴塗一層黏結層,所述黏結層成分為: 聚矽氧烷,含量為65%; 氣相法白炭黑SiO2 ,含量為15%;以及 甲基矽樹脂,含量為20%。
  6. 如申請專利範圍第1項所述之玻璃瓶矽膠塗層的製作方法,其中,所述步驟(2)中在玻璃容器外表面噴塗一層黏結層,噴塗時間為1-5秒,厚度範圍為0.1-1絲。
  7. 如申請專利範圍第2項所述之玻璃瓶矽膠塗層的製作方法,其中,所述步驟(2)中將有色液體矽膠層用有機溶劑稀釋,並自玻璃容器一端到另一端從厚到薄或從薄到厚噴塗在黏結層的外表面,靜置一段時間或將有色自黏結液體矽膠用有機溶劑稀釋,並自玻璃容器一端到另一端從厚到薄或從薄到厚直接噴塗在玻璃容器外表面,靜置一段時間;噴塗時間為5-10秒;靜置時間為5-10秒;厚度範圍為200-2絲。
  8. 如申請專利範圍第2項所述之玻璃瓶矽膠塗層的製作方法,其中,在有色液體矽膠層外層再用另外的機器自玻璃容器一端到另一端從薄到厚或從厚到薄噴塗無色液體矽膠層,噴塗時間為5-10秒;厚度範圍為2-200絲。
  9. 如申請專利範圍第1項所述之玻璃瓶矽膠塗層的製作方法,其中,所述自黏結的液體矽膠製備方法,包括如下步驟: (1)準備氣相白炭黑SiO2 ,並混合帶有極性基團的矽氧烷處理劑;所述帶有極性基團為環氧基、甲基丙烯酸丙基; (2)將處理好的氣相白炭黑SiO2 與帶極性基團的矽烷或矽油混合; (3)將混合好的材料分成A、B組合;A組含有鉑金硫化劑,B組含有抑制 劑,所述抑制劑通常為炔醇類物質,如甲基丁炔醇;以及 (4)將A、B組分按1:1混合,使用有機溶劑將液體矽橡膠稀釋,黏度為 1000-2000cst。
  10. 如申請專利範圍第1或9項所述之玻璃瓶矽膠塗層的製作方法,其中,所述自黏結的液體矽膠主要組分及質量百分比為: 氣相法白炭黑SiO2 ,含量為20%-40%; 乙烯基矽油含量為60%-75%;其分子結構式為:CH2=CH-Si(CH3)2O[(CH3)2SiO]n(CH3)2Si-CH=CH2 ;以及 含氫矽油含量為2%-10%;其分子結構式為:C3 H9 OSi·(CH4 OSi)n·C3 H9 Si; 使矽膠黏度500(Pas,23℃),拉伸強度大於9 Mpa。
TW107100184A 2016-07-22 2018-01-03 一種玻璃容器矽膠塗層的製作方法 TWI658020B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CN201610591220.5A CN106431002A (zh) 2016-07-22 2016-07-22 一种高透明液体硅胶保护玻璃容器的制备方法
CN201710128180.5A CN106915904A (zh) 2016-07-22 2017-03-06 一种玻璃容器硅胶涂层的制作工艺及方法
??201710128180.5 2017-03-06

Publications (2)

Publication Number Publication Date
TW201833053A true TW201833053A (zh) 2018-09-16
TWI658020B TWI658020B (zh) 2019-05-01

Family

ID=58184216

Family Applications (1)

Application Number Title Priority Date Filing Date
TW107100184A TWI658020B (zh) 2016-07-22 2018-01-03 一種玻璃容器矽膠塗層的製作方法

Country Status (6)

Country Link
US (1) US20190010355A1 (zh)
EP (1) EP3489203A4 (zh)
JP (1) JP2019503975A (zh)
CN (2) CN106431002A (zh)
TW (1) TWI658020B (zh)
WO (1) WO2018014603A1 (zh)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106431002A (zh) * 2016-07-22 2017-02-22 深圳市邦嘉实业有限公司 一种高透明液体硅胶保护玻璃容器的制备方法
CN107793920B8 (zh) * 2017-11-10 2020-06-16 梅州市诺华实业有限公司 玻璃、陶瓷容器及其制备方法
WO2019095468A1 (zh) * 2017-11-16 2019-05-23 刘展标 玻璃、陶瓷容器及其制备方法
CN109180013A (zh) * 2018-08-31 2019-01-11 深圳市力达创新科技有限公司 一种液态硅胶及其用于玻璃瓶表面喷胶的工艺方法
CN109452820A (zh) * 2018-09-17 2019-03-12 佛山市顺德区捷威不锈钢制品有限公司 一种具有防滑功能的沙拉碗及其制作方法
CN112826340A (zh) * 2020-11-04 2021-05-25 浙江绍兴苏泊尔生活电器有限公司 料理杯、料理机及在料理杯上形成橡胶层的方法
CN113698913B (zh) * 2021-10-15 2022-05-20 东莞天绘新材料有限公司 一种丝印用哑光硅橡胶及其制备方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59143984A (ja) * 1983-02-07 1984-08-17 Seiko Instr & Electronics Ltd 腕時計用カバ−ガラス
JP2002360667A (ja) * 2001-06-06 2002-12-17 Jex Inc 哺乳びんおよび哺乳びんの製造方法
US7531242B2 (en) * 2005-09-30 2009-05-12 Industrial Control Development, Inc. Silicone-coated architectural glass
JP2011104806A (ja) * 2009-11-13 2011-06-02 Fuji Kasei Kk 化粧品用ガラス製容器及び化粧品用ガラス製容器の製造方法
CN201793488U (zh) * 2010-09-08 2011-04-13 新李英玻璃工艺(深圳)有限公司 一种彩膜玻璃
FR2964646B1 (fr) * 2010-09-13 2014-06-13 Sgd Sa Recipient en verre et procede de fabrication correspondant
CN105153995B (zh) * 2015-07-28 2017-11-28 深圳市安品有机硅材料有限公司 导热硅橡胶粘接组合物、导热硅橡胶粘接片材及其应用
CN105439460B (zh) * 2015-12-02 2019-05-14 深圳市邦嘉实业有限公司 一种在玻璃表面喷涂液体硅胶防止玻璃碎裂的方法
CN106431002A (zh) * 2016-07-22 2017-02-22 深圳市邦嘉实业有限公司 一种高透明液体硅胶保护玻璃容器的制备方法

Also Published As

Publication number Publication date
CN106431002A (zh) 2017-02-22
US20190010355A1 (en) 2019-01-10
EP3489203A1 (en) 2019-05-29
EP3489203A4 (en) 2020-04-08
TWI658020B (zh) 2019-05-01
CN106915904A (zh) 2017-07-04
JP2019503975A (ja) 2019-02-14
WO2018014603A1 (zh) 2018-01-25

Similar Documents

Publication Publication Date Title
TWI658020B (zh) 一種玻璃容器矽膠塗層的製作方法
CN105439460B (zh) 一种在玻璃表面喷涂液体硅胶防止玻璃碎裂的方法
CN108219671A (zh) 一种双组分加成型液体硅橡胶及其制备方法
US4267297A (en) Room temperature curable silicone resins
CN100386398C (zh) 单组分表面可修饰性有机硅密封材料及其制备方法和用途
CN108192102A (zh) 一种非质子性溶剂型脱醇室温硫化硅橡胶及其制备方法
GB922828A (en) Process for treating paper with silicones
TWI698493B (zh) 緻密二氧化矽質膜形成用組成物
JPH01236282A (ja) プライマー組成物
CN110193982A (zh) 高温阻胶膜及其制造方法
CN109180013A (zh) 一种液态硅胶及其用于玻璃瓶表面喷胶的工艺方法
CN110078387A (zh) 超疏水性耐磨透明涂层及其制备方法
CN103753741A (zh) 一种文化石聚氨酯橡胶模具用脱模剂及使用方法
TWI835919B (zh) 接著性聚有機矽氧烷組成物
CN118421194A (zh) 一种不锈钢硅胶涂层及其制作工艺
CN112519005B (zh) 一种石材表面的仿皮革处理工艺
JPS6014970A (ja) ハ−ドコ−ト層への着色塗膜形成方法
US3445265A (en) Coating wood or metal with organopolysiloxane resin
JPS63110263A (ja) 表面処理方法
CN107721157A (zh) 彩釉玻璃的生产方法
CN107793920B (zh) 玻璃、陶瓷容器及其制备方法
CN104891826B (zh) 一种车辆用疏水玻璃及其制备方法
JPS63143978A (ja) 皮膜形成方法
SU1740182A1 (ru) Способ антиадгезионной обработки пресс-форм дл формовани изделий из полиуретанов
JP2013227577A (ja) ハウジング及びその製造方法