TW201232176A

TW201232176A - Coloring photosensitive resin composition for touch panel, touch panel and display device

Info

Publication number: TW201232176A
Application number: TW100148673A
Authority: TW
Inventors: Shigeru Suzuki; Naoto Yamaguchi; Dai Shiota
Original assignee: Tokyo Ohka Kogyo Co Ltd
Priority date: 2011-01-11
Filing date: 2011-12-26
Publication date: 2012-08-01
Also published as: KR20120081557A; TWI578104B; CN102591148A; KR101840055B1; JP2012145699A; JP5744528B2; CN102591148B

Abstract

The present invention provides a coloring photosensitive resin composition for touch panels, and a touch panel and display device formed using the same; the chemical resistance and weatherability of the coloring photosensitive resin composition for touch panel is outstanding, and the present invention is applicable to touch control use. The coloring photosensitive resin composition of the present invention includes: (A) an adhesive compound, (B) a photopolymerization monomer, (C) a photopolymerization initiator, and (D) a coloring agent, wherein (A) the adhesive compound includes an epoxy compound. The epoxy compound is preferably one represented by Formula (A1). In Formula (A1), Ra1 is a residue remained upon removing active hydrogen groups from an organic compound containing k active hydrogen groups; n1 to nk represent integers of 0-100 and their sum is 1-100; k represents an integer of 1-100; A is an oxy-cyclohexane skeleton or oxy-norcamphene skeleton having substitutes such as epoxides.

Description

201232176 六、發明說明：【發明所屬之技術領域】本發明是關於一種觸控面板用著色感光性樹脂組成物、觸控面板及顯示裝置。【先前技術】目前，觸控面板被廣泛使用作為具有液晶顯示器等的顯示裝置中的輸入手段。其中，基於光學上較明亮、結構上較簡單等理由，靜電容方式觸控面板較受到喝目。靜電容方式觸控面板，係具有：電介質；以及以不同圖案分別形成於電介質兩側的第丄導電體與第2導電體。此第1導電體與第2導電體，是通過形成於主動區域外之區域的引出線，而連接於外部的控制電路。若以這樣的靜電容方式觸控面板，則可以基於外部導體（典型而言是手扣）接觸或接近觸控面板之際所產生的電磁性變化或靜電容變化’而檢測出外部導體的位置。 [先前技術文獻] (專利文獻）專利文獻1 :日本特開2010-198615號公報【發明内容】 [發明所欲解決之問題] 然而，在此種觸控面板中’因為能夠使用金屬作為第 3 201232176 1導電體與第2導電體，所以有文獻提出將第1導電體與導電體隱藏在黑色矩陣的後面（參照專利文且，也已探討以無法從使用者側辨識出的方式將引出線隱[Technical Field] The present invention relates to a coloring photosensitive resin composition for a touch panel, a touch panel, and a display device. [Prior Art] Currently, a touch panel is widely used as an input means in a display device having a liquid crystal display or the like. Among them, the capacitive touch panel is more attractive for reasons such as being optically brighter and simpler in structure. The capacitive touch panel has a dielectric material and a second conductive body and a second conductive body which are respectively formed on the two sides of the dielectric in different patterns. The first conductor and the second conductor are connected to an external control circuit through lead wires formed in a region outside the active region. If the touch panel is touched in such a capacitive manner, the position of the outer conductor can be detected based on an electromagnetic change or a change in electrostatic capacitance generated when the outer conductor (typically a buckle) contacts or approaches the touch panel. . [Prior Art Document] (Patent Document) Patent Document 1: JP-A-2010-198615 SUMMARY OF INVENTION [Problems to be Solved by the Invention] However, in such a touch panel, 'because metal can be used as the third 201232176 1 conductor and second conductor, so it is proposed in the literature to hide the first conductor and the conductor behind the black matrix (refer to the patent document, it has also been discussed that the lead wire can not be recognized from the user side) hidden

藏在黑色矩陣的後面。此情形中’因為形成了黑色矩陣I 後必須將金屬膜進行㈣等，所以作為黑色矩陣的材料而言，耐藥品性很重要。又，當將具備觸控面板的顯示裝置使用於衛星導航系統之類的車載用料，作為黑色料的材料^，耐候性报重要。但是，當將遽色片之黑色矩陣用的著色感光性樹脂組成物轉用於觸控面板用途時，有著在耐藥品性或財候性方面無法滿足所要求之水準的問題。本發明係鑑於上述課題而完成，其目的係提供一種觸控面板用著色感光性樹脂組成物、具有使用該觸控面板用著色感光性樹脂組成物而形成之硬化樹脂圖案的觸控面板、以及具備該觸控面板的顯示裝置，該觸控面板用著色感光性樹脂組成物的耐藥品性、耐候性優異，且適合用於觸控用途。 [解決問題之技術手段] 本發明人為了達成上述目的而專心研究。結果發現藉由3有環氧化合物來作為著色感光性樹脂組成物的黏合劑匕。物則能解決上述課題，而完成了本發明。具體而言，本發明提供下述發明。本發明的第一態樣是一種觸控面板用著色感光性樹脂 201232176 組成物，其含有（A)黏合劑化合物、⑻光聚合性單體、 (c)光聚合起始劑、及（D)著色劑，且前述（a)黏合劑化合物包含環氧化合物。本發明的第二態樣是一種觸控面板，其具有硬化樹脂圖案’該硬化樹脂圖案是使用第-態樣中的觸控面板用著色感光性樹脂組成物所形成。本發明的第二態樣是一種顯示裝置，其具備第二態樣中的觸控面板。 [功效] 根據本發明，能夠提供一種觸控面板用著色感光性樹脂組成物、具有使用該觸控面㈣著色感光性樹脂組成物而形成之硬化樹脂圖案的觸控面板、以及具備該觸控面板的顯示裝置，該觸控面板用著色感光性樹脂組成物的耐藥品性 '耐候性優異，且適合用於觸控用途。【實施方式】《觸控面板用著色感光性樹脂組成物》本發明之觸控面板用著色感光性樹脂組成物（以下僅簡單稱為「著色感光性樹脂組成物」），係含有（A)黏合劑化合物、（B)光聚合性單體、（c)光聚合起始劑、及（d) 著色劑。以下針對著色感光性樹脂組成物所含有的各成分加以說明。 < (A )黏合劑化合物> 201232176 本發明之著色感光性樹脂組成物，係含有環氧化合物來作為（A)黏合劑化合物（以下又稱為「(A)成分小環氧化合物並無特別限定，可以使用會發揮作為黏人劑的功能之以往習知的環氧化合物，纟中從财藥品性、耐候性的觀點而言，以下述式（A」）所示之環氧化合 (Α)η1-ΗHidden behind the black matrix. In this case, since the metal film must be subjected to (four) or the like after the black matrix I is formed, chemical resistance is important as a material of the black matrix. Further, when a display device including a touch panel is used for an in-vehicle material such as a satellite navigation system, as a material of a black material, weather resistance is important. However, when the colored photosensitive resin composition for the black matrix of the enamel sheet is used for a touch panel, there is a problem that the required level cannot be satisfied in terms of chemical resistance or financial property. The present invention has been made in view of the above-described problems, and an object of the invention is to provide a coloring photosensitive resin composition for a touch panel, a touch panel having a cured resin pattern formed using the colored photosensitive resin composition for a touch panel, and A display device including the touch panel, which is excellent in chemical resistance and weather resistance of the colored photosensitive resin composition for a touch panel, and is suitable for use in touch applications. [Technical means for solving the problem] The present inventors focused on research in order to achieve the above object. As a result, it was found that an epoxy compound was used as a binder for coloring the photosensitive resin composition. The present invention can be solved by solving the above problems. Specifically, the present invention provides the following invention. A first aspect of the present invention is a composition of a colored photosensitive resin 201232176 for a touch panel, comprising (A) a binder compound, (8) a photopolymerizable monomer, (c) a photopolymerization initiator, and (D) A colorant, and the aforementioned (a) binder compound contains an epoxy compound. A second aspect of the present invention is a touch panel having a cured resin pattern. The cured resin pattern is formed using a photosensitive resin composition of a touch panel in the first aspect. A second aspect of the present invention is a display device having a touch panel in a second aspect. [Effect] According to the present invention, it is possible to provide a colored photosensitive resin composition for a touch panel, a touch panel having a cured resin pattern formed by using the touch surface (4) colored photosensitive resin composition, and the touch panel The panel display device is excellent in weather resistance of the coloring photosensitive resin composition for a touch panel, and is suitable for use in touch applications. [Embodiment] "Coloring photosensitive resin composition for a touch panel" The coloring photosensitive resin composition for a touch panel of the present invention (hereinafter simply referred to as "colored photosensitive resin composition") contains (A) a binder compound, (B) a photopolymerizable monomer, (c) a photopolymerization initiator, and (d) a colorant. Hereinafter, each component contained in the colored photosensitive resin composition will be described. < (A) Binder Compound> 201232176 The colored photosensitive resin composition of the present invention contains an epoxy compound as the (A) binder compound (hereinafter referred to as "(A) component small epoxy compound In particular, it is possible to use a conventionally known epoxy compound which exhibits a function as an adhesive, and an epoxidation represented by the following formula (A)) from the viewpoint of chemical properties and weather resistance ( Α)η1-Η

Ra1^-(A)n2-η (Α-1) '(A)nk-Η [式中，Ral是從具有k個活性氫基之有機化合物中除去活性氫基之後餘留的殘基；nl、心、…、吡分別獨立表示’〇 100之整數，其總和為 A是具有取代基B之氧基環己烷骨架、或具有取代基8之氧基降莰烯骨架 •0— v 〇是以下述式（A-2)或（a-3)表示Ra1^-(A)n2-η(Α-1) '(A)nk-Η [wherein, Ral is a residue remaining after removing an active hydrogen group from an organic compound having k active hydrogen groups; nl , heart, ..., pyridine each independently represent an integer of '〇100, the sum of which is A is an oxycyclohexane skeleton having a substituent B, or an oxynordecene skeleton having a substituent 8 is 0-v 〇 Expressed by the following formula (A-2) or (a-3)

B (A-3) (式中，B是分別獨立以下述式（A_4)、式（A_5)或式（α·6) 表示之基團， C义 /CH2 CH==CH2 —CH—CH2 0 OH 0Ra2 (Α·4) (A-5) (A-6) 惟，該環氧化合物中含有1個以上的前述式（A_4 )所示之基團，Ra2表示烷基、烷基羰基、或芳基羰基）]。上述式（A-1)中，是從具有活性氫基之有機化合 201232176 物中除去活,咕_ # > % 古性虱基之後餘留的殘基，其前驅物，也就是具有活丨生氫基之有機化合物，可以舉出：醇類、酚類、羧酸類、胺類、硫醇（thiol)類等。上述醇類’可以是1元醇也可以是多元醇。具體而言，可以皐屮· m f .甲醇、乙醇、丙醇、丁醇、戊酵、己醇、辛醇等脂肪族醇；$曱醇等芳香族醇；乙二醇、〕乙二醇、三知 1乙一醇、丙二醇、二丙二醇、1，3-丁二醇、1，4_ 丁一醇、戊二醇、1，6-己二醇、新戊二醇、新戊二醇羥基三甲基乙酸酯、環己烷二甲醇、甘油、二甘油、聚甘油、三經甲基丙烧、三羥曱基乙烷、季戊四醇、二季戊四醇等多元醇等。上述盼類’可以舉出：苯紛、甲驗、兒茶盼、五倍子齡、對苯二酚、對苯二酚單曱基醚、雙酚A、雙酚F、4,4’· 二經基二苯曱酮、雙酚S、酚樹脂、甲酚酚醛清漆樹脂等。上述羧酸類’可以舉出：曱酸、乙酸、丙酸、丁酸、動植物油之脂肪酸、反丁浠二酸、順丁稀二酸、己二酸、十一燒二酸、偏苯三甲酸、苯均四酸、聚丙稀酸、鄰笨二曱酸、間苯二甲酸、對苯二甲酸等。又，也可以舉出：乳酸、檸檬酸、羥基己酸等同時具有羥基與羧基的化合物。上述胺類’可以舉出··單曱胺、二甲胺、單乙胺、二乙胺、丙胺、單丁胺、二丁胺、戊胺、己胺、環己胺、辛扣、十·一炫胺、4,4 _ _胺基二苯曱烧、異佛明二胺、曱笨二胺、六亞曱基二胺、二甲笨二胺、二伸乙三胺、三伸乙四胺 '乙醇胺等。 7 201232176 上述硫醇類，可以舉出：甲硭 ^ ^ 喻_、乙硫醇、丙硫醇、本基硫醇等硫醇；_ 醇二酼基丙酸酯、三經曱基丙烷三巯基丙酸酯、季戊、叹四知四巯基丙酸酯等巯基丙酸或疏基丙酸的多元醇酯等。並且，具有活性氫基之有機化合物，也可以舉出：聚乙烯醇1乙酸乙烯醋部分水解物、殿粉、纖維素、乙酸纖維素、乙酸丁酸纖維素1乙基纖維素、丙稀酸多元醇樹脂、苯乙烯-烯丙醇共聚樹脂、本乙婦-順丁稀二酸共聚樹脂、醇酸樹脂、聚酯多元醇满夕兀知槠月日、聚酯羧酸樹脂、聚己内酯多元醇樹脂、聚丙烯多元外夕兀畔聚四亞甲基二醇等。此具有活性氫基之有機化合 »切’亦可在其骨架中具不飽和雙鍵。具體例可舉出：嫌琊丙醇、丙烯酸、甲基酸、3-%己烯甲醇、四氫鄰苯二甲酸等。以上的具有活性氫基土之有機化合物’可以單獨使用或組合2種以上來使用。上述式（A-1)中，, Λ .........分別獨立表示〇B (A-3) (wherein B is a group independently represented by the following formula (A_4), formula (A_5) or formula (α·6), C meaning /CH2 CH==CH2 —CH—CH2 0 OH 0Ra2 (Α·4) (A-5) (A-6) However, the epoxy compound contains one or more groups represented by the above formula (A-4), and Ra2 represents an alkyl group, an alkylcarbonyl group, or Arylcarbonyl)]. In the above formula (A-1), the residue remaining after removing the living, 咕_# >% ancient sulfhydryl group from the organic compound 201232176 having an active hydrogen group, the precursor thereof, that is, having an active hydrazine Examples of the hydrogen-generating organic compound include alcohols, phenols, carboxylic acids, amines, and thiols. The above alcohols ' may be a monohydric alcohol or a polyhydric alcohol. Specifically, it may be an aliphatic alcohol such as methanol, ethanol, propanol, butanol, valer, hexanol or octanol; an aromatic alcohol such as decyl alcohol; ethylene glycol; Sanzhi 1 ethyl alcohol, propylene glycol, dipropylene glycol, 1,3-butanediol, 1,4-butanol, pentanediol, 1,6-hexanediol, neopentyl glycol, neopentyl glycol hydroxy trimethyl Polyols such as acetoxylate, cyclohexanedimethanol, glycerin, diglycerin, polyglycerol, trimethyl methacrylate, trihydroxy decyl ethane, pentaerythritol, dipentaerythritol, and the like. The above-mentioned hopes can be cited as: benzene, test, tea, five times old, hydroquinone, hydroquinone monodecyl ether, bisphenol A, bisphenol F, 4, 4'· Dibenzophenone, bisphenol S, phenol resin, cresol novolak resin, and the like. The above carboxylic acid 'supplements include: citric acid, acetic acid, propionic acid, butyric acid, fatty acids of animal and vegetable oils, butyl bromide, cis-succinic acid, adipic acid, undecanedioic acid, trimellitic acid , pyromellitic acid, polyacrylic acid, o-arsic acid, isophthalic acid, terephthalic acid, and the like. Further, a compound having a hydroxyl group and a carboxyl group, such as lactic acid, citric acid or hydroxycaproic acid, may also be mentioned. The above amines may be exemplified by monoamine, dimethylamine, monoethylamine, diethylamine, propylamine, monobutylamine, dibutylamine, pentylamine, hexylamine, cyclohexylamine, octane, and ten. A serotonin, 4,4 _ _ amino benzophenone, isophorhedimide, hydrazine diamine, hexamethylenediamine, dimethyldiamine, diamethylenetriamine, triamethylene Amine 'ethanolamine and the like. 7 201232176 The above-mentioned mercaptans include mercaptan such as methyl hydrazine, ethanethiol, propane thiol, and mercapto thiol; _ an alcohol dimercapto propionate, a tris-propyl propane trimethyl sulfonate A polyhydric alcohol ester of mercaptopropionic acid or thioglycolic acid, such as propionate, pentaerythritol, and tetradecylpropionate. Further, the organic compound having an active hydrogen group may also be a polyvinyl alcohol 1 vinyl acetate partial hydrolyzate, a temple powder, cellulose, cellulose acetate, cellulose acetate butyrate 1 ethyl cellulose, acrylic acid Polyol resin, styrene-allyl alcohol copolymer resin, this maternal-cis-succinic acid copolymer resin, alkyd resin, polyester polyol, full moon, polyester carboxylic acid resin, poly-caprol An ester polyol resin, a polypropylene multi-element, a polytetramethylene glycol, and the like. The organic compound having an active hydrogen group can also have an unsaturated double bond in its skeleton. Specific examples thereof include stilbene, acrylic acid, methyl acid, 3-% hexene methanol, and tetrahydrophthalic acid. The above organic compound having an active hydrogen-based soil may be used singly or in combination of two or more. In the above formula (A-1), Λ ......... respectively represent 〇

〜100之整數’其總和為MOO 又 k表不1〜1〇〇之整數。、n2、···、nV，ι\» 、乂 /刀別獨立為2〜10之整數為佳，較佳為3〜6之整數。又 1 n2、…、nk的總和，以4 〜30為佳’較佳為4〜2〇。益山收，一 20藉由將上述總和設為4以上，可以提高硬化後的交聯密声 P在度、棱向硬度。又，藉由將上述總和設為3 0以下，可以描古机，々愈丨、對溶劑之溶解性、提高處理性。上述式（A-1)中，A县且：甘η 疋具有取代基Β之氧基環己烷骨 201232176 架、或具有取代基B之氧基降莰烯骨架，是以上述式（a_2) 或（A-3)表示。A以上述式（a_2)所示結構為佳。另外，所具有的k個A，可以是分別相同或不同。上述式（A-1 )所示之環氧化合物中，必須含有1個以上的上述式（A-4)所示之基團，越多越好。另一方面，上述式（A-6 )所示之基團則是越少越好。上述式（A-1 )所示之環氧化合物，是如日本特公平 7-119270號公報中所述，以具有活性氫基之有機化合物作為起始劑，以過乙酸或過氧化氫等來使下述聚醚樹脂進行環氧化而製造：4_乙烯基環己烯_丨_氧化物 (4411^1(^〇1〇}1以61^_卜0?^(^)或 5_ 乙烯基雙環[2 2^庚 _2_ 烯-2-氧化物（5-vinylbicycl〇[2 2 1]hept_2_ene 2 〇xide)、與具肴1個環氧基之化合物所構成的混合物進行開環聚合而獲得的聚醚樹脂，亦即，將具有乙烯基側鏈及環己烷骨架、或疋具有乙烯基側鏈及降莰烯骨架的聚醚樹脂。市售〇口了舉出Dai cel化學工業公司製造的EHPE3 150 (nl〜nk之總和的平均數是15)為較合適的化合物。又’環氧化合物也可以使用脂環式環氧化合物。脂環式環氧化合物，可以舉出：3，，4，_環氧環己院缓酸 3,4·環氧環己基甲酯、2-( 3,4_環氧環己基_5,5_螺_3,4_環氧） % 己院-間二n萼院（2_(3,4_epoxycycl〇hexyl 5,5 咖⑺_3，心 ep〇xy)cyclohexane_m_di〇xane)、己二酸雙（3 4 環氧環己基 :基）酯、己二酸雙（3,4_環氧-6_曱基環己基甲基）酿、3，,4，_ 環氧-6’-甲基環己烷羧酸3,4_環氧_6_甲基環己酯、己内 201232176 醋改質3，,4，-環氧環己院㈣3,4_環氧環己基甲醋、三子基己内醋改質3’，4，-環氧環己烷羧酸3,4_環氧環己基甲酯、点 -甲基-5-戊内酯改質3，，4，_環氧環己烷羧酸3,4_環氧環己基甲酯、亞曱基雙（M-環氧環己烷）、乙二醇二（3,4_環氧壤己基曱基）i|、伸乙基雙（3,4_環氧環己烧缓酸醋）、環氧環六氫鄰苯二曱酸二辛酯、環氧環六氫鄰苯二甲酸二 -2-乙基己酯等。較合適的市售品可以舉出：Daicel化學工業公司製造的 Cell〇xide 202 卜 2021P、2081、2083、2085 以及 Epolead GT-300、GT-301、GT_3〇2、GT_4〇〇、4〇1、4〇3 等；新日化環氧製造公司（NSCC Epoxy Manufacturing Co.，Ltd.)製造的 SUN TOHTO ST-3000、ST-4000、ST-5080、ST-5100 等。並且’環氧化合物也可以使用：酚酸清漆型環氧化合物、雙紛A型環氧化合物、曱酚酚醛清漆型環氧化合物、聯苯型環氧化合物等。上述盼路清漆型環氧化合物，以環氧當量為200〜220 的化合物為佳。市售品可舉出大日本油墨公司製造的 EPICLON N-660、N-665、N-670、N-673、N-680、N-690、 N-695、N-685-EXP、N-672-EXP、N-655-EXP-S、N-865、 N-865-80M、YDCN-701、YDCN-702、YDCN-703、 YDCN-704、YDCN-704L 等。上述雙酚A型環氧化合物的市售品，可以舉出新曰化環氧製造公司製造的EPO TOHTO YD-115、YD-118T、 YD-127、YD-128、YD-134、YD-8 125、YD-7011R、ZX-1059、 10 201232176 YDF-8170、YDF-170 等；Nagase ChemteX 公司製造的 DENACOL EX-1101、EX-1102、EX-1103 等；Daicel 化學工業公司製造的 PLACCEL GL-61、GL-62、G101、G102 等。上述甲酌酴搭清漆型環氧化合物的市售品，可以舉出：新日化環氧製造公司製造的EPO TOHTO YDPN-638、 YDPN-7(n、YDPN-702、YDPN-703、YDPN-704 等；或 Nagase ChemteX 公司製造的 DENACOL EM-125 等。上述聯苯型環氧化合物，可以舉出：3，5,3’，5，-四甲基 -4,4’-二縮水甘油基聯苯等。本發明之著色感光性樹脂組成物，以除了上述環氧化合物以外進而含有其他黏合劑化合物為佳。這樣的其他黏合劑化合物’可以舉出：由（曱基）丙烯酸、反丁烯二酸、順丁烯二酸、反丁烯二酸單甲酯、反丁烯二酸單乙酯、（甲基）丙烯酸2-羥基乙酯、乙二醇單甲基醚（甲基）丙烯酸酉日、乙一醇卓乙基醚（甲基）丙稀酸醋、丙三醇（甲基）丙烯酸酯、（曱基）丙烯醯胺、丙烯腈、甲基丙烯腈、（甲基）丙烯酸甲酯、（曱基）丙烯酸乙酯、（曱基）丙烯酸異丁酯、（甲基）丙烯酸2-乙基己酯、（甲基）丙烯酸苯甲酯、乙二醇二（甲基）丙烯酸酯、二乙二醇二丙烯酸酯、三乙二醇二（甲基）丙烯酸酯、四乙二醇二（甲基）丙烯酸酯、丁二醇二甲基丙烯酸酯、丙二醇二（甲基）丙烯酸酯、三經曱基丙院二（甲基）丙烯酸酯、四經甲基丙烧四（甲基）丙烯酸酯、季戊四醇三（甲基）丙烯酸酯、季戊四醇四（甲 201232176 基）丙烯酸酯、二季戊四醇五（甲基）丙烯酸酯、二季戊四醇六（曱基）丙締酸酯、1，6 -己二醇二（曱基）丙烯酸酯、 D卡°木％氧一丙稀酸醋（Cardoepoxy diacrylate)等所聚合而成的寡聚物類；使由多元醇與一元酸或多元酸所縮合而得的聚S旨預聚物’與（曱基）丙烯酸反應而得的聚酯（甲基）丙烯酸在多元醇與具有2個異氰酸基的化合物進行反應後’使（甲基）丙烯酸與其反應而獲得的聚胺酯 (polyurethane)(甲基）丙烯酸酯；由雙酚a型環氧樹脂、雙酚F型環氧樹脂、雙酚s型環氧樹脂、苯酚或甲酚酚醛 /月漆型環氧樹脂、甲階酚醛（res〇1)型環氧樹脂、三酚甲烷型裱氧樹脂、聚羧酸聚縮水甘油酯、多元醇聚縮水甘油酯、脂肪族或脂環式環氧樹脂、胺型環氧樹脂、二經基苯型環氧樹舳等環氧樹脂，與（甲基）丙烯酸反應而得的環氧（甲基）丙烯酸酯樹脂等。並且，較合適的可以使用·使多元酉夂酐與環& (曱基）丙烯酸酯樹脂反應而成的樹脂。八他的舶兮劑化合物，也適合使用使由環氧化^ 物與含不飽和基的羧酸化合物反應而得之反應物進而盥《 -酸酐反應而得之樹脂。其中，從其本身之硬化性高㈣點而言，以下述4 (Α·7)所示之化合物為佳 Γ (ρ〇ΟΗ - HO〇C-Y~q〇_q.The integer of ~100' is the sum of MOO and k is not an integer of 1~1〇〇. , n2, ···, nV, ι\», 乂/knife are preferably integers of 2 to 10, preferably 3 to 6 integers. Further, the sum of 1 n2, ..., nk is preferably 4 to 30', preferably 4 to 2 inches. By using the above sum to be 4 or more, it is possible to improve the degree of cross-linking and the hardness of the ribs after hardening. Further, by setting the above total to 30 or less, the machine can be used to improve the solubility in a solvent and improve the handleability. In the above formula (A-1), the oxycyclohexane bone 201232176 or the oxynorthene skeleton having the substituent B in the A county and the ηη疋 has the substituent ,, and is the above formula (a_2) Or (A-3) indicates. A is preferably a structure represented by the above formula (a_2). In addition, the k As that are present may be the same or different. In the epoxy compound represented by the above formula (A-1), it is necessary to contain one or more groups represented by the above formula (A-4) as much as possible. On the other hand, the group represented by the above formula (A-6) is as small as possible. The epoxy compound represented by the above formula (A-1) is an organic compound having an active hydrogen group as a starting agent and peracetic acid or hydrogen peroxide as described in Japanese Patent Publication No. 7-119270. Manufactured by epoxidizing the following polyether resin: 4_vinylcyclohexene_丨_oxide (4411^1(^〇1〇}1 to 61^_卜0?^(^) or 5_vinyl A ring-opening polymerization of a mixture of a bicyclo[2 2^hept-2-ene-2-oxide (5-vinylbicycl〇[2 2 1]hept_2_ene 2 〇xide) and a compound having an epoxy group A polyether resin, that is, a polyether resin having a vinyl side chain and a cyclohexane skeleton, or a fluorene having a vinyl side chain and a norbornene skeleton. The commercially available product is manufactured by Dai cel Chemical Industry Co., Ltd. EHPE3 150 (the average of the sum of nl~nk is 15) is a suitable compound. Further, an epoxy compound may also be used as the epoxy compound. The alicyclic epoxy compound may be exemplified by 3, 4,_epoxy ring hexanes acid 3,4·epoxycyclohexyl methyl ester, 2-( 3,4_epoxycyclohexyl_5,5_spiro_3,4_epoxy) % 院院- Between the two n hospitals (2_(3,4) _epoxycycl〇hexyl 5,5 coffee (7)_3, heart ep〇xy)cyclohexane_m_di〇xane), adipic acid bis(3 4 epoxycyclohexyl:yl) ester, adipic acid bis(3,4_epoxy-6_曱Cyclohexylmethyl), 3,4,_epoxy-6'-methylcyclohexanecarboxylic acid 3,4_epoxy_6_methylcyclohexyl ester, hexene 201232176 vinegar modified 3, , 4,-epoxy ring hexaxy (4) 3,4_epoxy cyclohexyl ketone, triterpenyl vinegar modified 3',4,-epoxycyclohexanecarboxylic acid 3,4_epoxycyclohexyl Ester, dot-methyl-5-valerolactone modified 3,4,_epoxycyclohexanecarboxylic acid 3,4-epoxycyclohexylmethyl ester, fluorenylene bis (M-epoxycyclohexane) ), ethylene glycol bis(3,4_epoxy hexyl fluorenyl)i|, ethyl bis(3,4_epoxycyclohexyl sulphuric acid vinegar), epoxy ring hexahydrophthalic acid Dioctyl ester, epoxide ring di-2-ethylhexyl hexahydrophthalate, etc. Suitable commercial products include: Cell〇xide 202, 2021P, 2081, 2083, manufactured by Daicel Chemical Industry Co., Ltd. 2085 and Epolead GT-300, GT-301, GT_3〇2, GT_4〇〇, 4〇1, 4〇3, etc.; NSCC Epoxy Manufacturing C o., Ltd.) manufactured by SUN TOHTO ST-3000, ST-4000, ST-5080, ST-5100, etc. and 'epoxy compounds can also be used: phenolic acid varnish type epoxy compounds, double A type epoxy A compound, an anthraquinone novolac type epoxy compound, a biphenyl type epoxy compound, or the like. The above-mentioned lacquer-type epoxy compound is preferably a compound having an epoxy equivalent of 200 to 220. Commercially available products include EPICLON N-660, N-665, N-670, N-673, N-680, N-690, N-695, N-685-EXP, and N-672 manufactured by Dainippon Ink Co., Ltd. -EXP, N-655-EXP-S, N-865, N-865-80M, YDCN-701, YDCN-702, YDCN-703, YDCN-704, YDCN-704L, etc. As a commercial item of the above bisphenol A type epoxy compound, EPO TOHTO YD-115, YD-118T, YD-127, YD-128, YD-134, YD-8 manufactured by Shin Seng Epoxy Manufacturing Co., Ltd. may be mentioned. 125, YD-7011R, ZX-1059, 10 201232176 YDF-8170, YDF-170, etc.; DENACOL EX-1101, EX-1102, EX-1103, etc. manufactured by Nagase ChemteX; PLACCEL GL-61 manufactured by Daicel Chemical Industry Co., Ltd. , GL-62, G101, G102, etc. As a commercial item of the above-mentioned varnish-type epoxy compound, EPO TOHTO YDPN-638, YDPN-7 (n, YDPN-702, YDPN-703, YDPN- manufactured by Shin-Nippon Epoxy Manufacturing Co., Ltd.) can be cited. 704, etc.; or DENACOL EM-125 manufactured by Nagase ChemteX, etc. The above biphenyl type epoxy compound can be exemplified by 3,5,3',5,-tetramethyl-4,4'-diglycidyl. Biphenyl or the like. The colored photosensitive resin composition of the present invention preferably contains other binder compounds in addition to the above epoxy compound. Such other binder compounds may be exemplified by (mercapto)acrylic acid and counter-butylate. Aenedioic acid, maleic acid, monomethyl fumarate, monoethyl fumarate, 2-hydroxyethyl (meth)acrylate, ethylene glycol monomethyl ether (methyl) Acrylic acid, ethyl ketone ethyl ether (methyl) acrylate vinegar, glycerol (meth) acrylate, (mercapto) acrylamide, acrylonitrile, methacrylonitrile, (meth)acrylic acid Methyl ester, ethyl (meth) acrylate, isobutyl (meth) acrylate, 2-(meth) acrylate Hexyl hexyl ester, benzyl (meth) acrylate, ethylene glycol di (meth) acrylate, diethylene glycol di acrylate, triethylene glycol di (meth) acrylate, tetraethylene glycol bis ( Methyl) acrylate, butanediol dimethacrylate, propylene glycol di(meth) acrylate, tri-propyl propyl propylene di(meth) acrylate, tetra-methyl propyl hydride tetra(methyl) acrylate Ester, pentaerythritol tri(meth)acrylate, pentaerythritol tetra(methyl 201232176) acrylate, dipentaerythritol penta (meth) acrylate, dipentaerythritol hexa(indenyl) propionate, 1,6-hexanediol An oligomer obtained by polymerizing bis(indenyl) acrylate, Cardoepoxy diacrylate, or the like; a polycondensation obtained by condensing a polyhydric alcohol with a monobasic acid or a polybasic acid The polyester (meth)acrylic acid obtained by reacting a prepolymer with a (meth)acrylic acid is obtained by reacting a polyhydric alcohol with a compound having two isocyanato groups to obtain (meth)acrylic acid. Polyurethane (meth) propylene Ester; bisphenol a type epoxy resin, bisphenol F type epoxy resin, bisphenol s type epoxy resin, phenol or cresol novolac / moon paint type epoxy resin, resol phenolic (res〇1) type ring Oxygen resin, trisphenol methane type epoxy resin, polycarboxylic acid polyglycidyl ester, polyol polyglycidyl ester, aliphatic or alicyclic epoxy resin, amine type epoxy resin, dipyl benzoic epoxy tree An epoxy resin such as hydrazine, an epoxy (meth) acrylate resin obtained by reacting with (meth)acrylic acid, etc., and more suitably used, a polyphthalic anhydride and a ring & Resin-reacted resin. It is also suitable to use a resin obtained by reacting an epoxidized product with an unsaturated group-containing carboxylic acid compound and then reacting with an acid anhydride. Among them, from the high (4) point of its own hardening property, the compound represented by the following 4 (Α·7) is preferred (ρ〇ΟΗ - HO〇C-Y~q〇_q.

-Z-CO-C-Z-CO-C

X—0-CO-Z-CO-O-COOH -X-〇—CO-γ—Q〇〇H m /A (A-7) A-8 )所示之基團。上述式（A-7)中，X表示下述式 12 201232176X—0-CO-Z-CO-O-COOH-X-〇-CO-γ-Q〇〇H m /A (A-7) A-8). In the above formula (A-7), X represents the following formula 12 201232176

上述式（A-8 )中，Ra3分別獨立表示氫原子、碳數工〜6的烴基、或_素原子，IT4分別獨立表示氫原子或甲基， W則表示單鍵或下述式（A-9)所示之基團。In the above formula (A-8), Ra3 independently represents a hydrogen atom, a hydrocarbon group of carbon number -6, or a _ atom, and IT4 independently represents a hydrogen atom or a methyl group, and W represents a single bond or a formula (A) -9) The group shown.

(A-9) 又，上述式（A-7)中，γ表示從二羧酸酐除去酸酐基 (-C0-0-C0-)之後餘留的殘基。二羧酸酐的具體例，可以舉出.順丁稀二酸酐、琥珀酸酐、伊康酸酐、鄰苯二甲酸酐、四氫鄰苯二曱酸酐、六氫鄰苯二甲酸酐、甲基内亞曱基四氫鄰本一甲酸舒、氣橋酸軒、甲基四氫鄰苯二甲酸酐、戊二酸酐等。又，上述式（A-7 )中，Z表示從四羧酸二酐除去2個酸野基之後餘留的殘基。四羧酸二酐的例示，可以舉出·· 苯均四酸酐、二苯曱酮四羧酸二酐、聯苯四羧酸二酐、二苯醚四幾酸二酐等。又’上述式（A-7 )中，m表示〇〜20之整數。上述式（A-7 )所示之化合物的酸價，以樹脂固形分計算時是以10〜150 mgKOH/g為佳，較佳為70〜11〇 mgK0H/g。藉由將酸價設為10 mgKOH/g以上，可以獲得充分的顯影性。又，藉由將酸價設為丨50 mgKOH/g以下，可以獲得充分的硬化性，且能使表面性良好。 13 201232176 又，上述式（A-7) m- ~所不之化合物的質量平均分子晋以1000〜40000為佳，阜 $ q丨王孕乂佳為2000〜30000。藉由將質景平均分子量設為1000以μ 負1 上’能夠使耐熱性、膜強度提升。又’藉由將質量平均分不旦μ 1 1刀子罝堍為4〇〇〇〇以下，能夠獲得對於顯影液之充分的溶解性。 (Α)成分的含量，以相對於本發明之著色感光性樹脂 ':成物的固形分為30〜9〇質量％為佳，較佳為50〜70質量％。又，相對於（A)成分之總量的環氧化合物之比例，以30〜70質量％為佳，車交佳為4〇〜6〇質量％。藉由將環氧化合物的比例設為30質量％以上，能夠使耐藥品性、耐候性提升。又，藉由將環氧化合物的比例設為7〇質量％以下，能夠抑制感度與顯影性之降低。 < (B)光聚合性單體> (B )光聚合性單體（以下又稱為「（ b )成分」），並無特別限定’可以使用以往習知的單官能單體或多官能單體。上述單官能單體，可以舉出：（曱基）丙烯醯胺、羥曱基（甲基）丙烯酿胺、曱氧基曱基（曱基）丙烯醯胺、乙氧基曱基（曱基）丙烯醯胺、丙氧基甲基（甲基）丙烯醯胺、丁氧基曱氧基曱基（甲基）丙烯醯胺、N-羥甲基（甲基）丙烯醞胺、N-羥基曱基（甲基）丙烯醯胺、（曱基）丙稀酸、反丁烯二酸、順丁烯二酸、順丁稀二酸Sf、伊康酸、伊康酸酐、檸康酸、檸康酸酐、巴豆酸、2-丙烯醢胺基-2-曱基丙磺酸、三級丁基丙烯醞胺磺酸、（甲基）丙烯酸甲酯、 14 201232176 (曱基）丙烯酸乙酯、（甲基）丙烯酸丁酯、（甲基）丙烯酸2-乙基己酯、（甲基）丙烯酸環己酯、（甲基）丙烯酸2_ 經基乙_、（曱基）丙烯酸2-羥基丙酯、（曱基）丙烯酸2-經基丁醋、（甲基）丙烯酸2_苯氧基_2羥基丙酯、鄰苯二甲酸2-(甲基）丙烯醯氧基_2_羥基丙酯、甘油單（甲基）丙烯酸醋、（曱基）丙烯酸四氫糠酯、（甲基）丙烯酸二甲基胺基醋、（甲基）丙烯酸縮水甘油酯、（甲基）丙烯酸2,2,2_ 二氟*乙醋、（甲基）丙烯酸2,2,3,3-四氟丙酯、鄰苯二甲酸衍生物的（甲基）丙稀酸半酯等。這些單官能單體，可以單獨使用或組合2種以上來使用。另一方面’上述多官能單體，可以舉出：乙二醇二（曱基）丙缔酸酯、二乙二醇二（甲基）丙烯酸酯、四乙二醇二（曱基）丙烯酸酯、丙二醇二（曱基）丙烯酸酯、聚丙二醇二（甲基）丙烯酸酯、丁二醇二（甲基）丙烯酸酯、新戊一醇二（曱基）丙烯酸酯、1，6-己二醇二（曱基）丙烯 IS曰、二經甲基丙烧三（甲基）丙稀酸酯、甘油二（甲基）丙烯酸酯、季戊四醇三丙烯酸酯、李戊四醇四丙烯酸酯、二季戊四醇五丙烯酸酯、二季戊四醇六丙烯酸酯、季戊四醇二（甲基）丙烯酸酯、季戊四醇三（甲基）丙烯酸酯、季戊四醇四（甲基）丙烯酸酯、二季戊四醇五（甲基）丙烯酸酯、二季戊四醇六（曱基）丙烯酸酯、2,2_雙（4·(甲基）丙烯醯氧基二乙氧基苯基）丙烧、2，2_雙（‘（甲基）丙烯醯氧基聚乙氧基苯基）丙烷、（曱基）丙烯酸2_羥基_3_ (曱基）丙稀酿氧基丙g旨、乙一醇二縮水甘油基喊二（甲 15 201232176 基）丙稀酸酯、二乙二醇二縮水甘油基醚二（甲基）丙烯酸醋、鄰苯二曱酸二縮水甘油酯二（甲基）丙烯酸酯、甘油三丙烯酸酯、甘油聚縮水甘油基醚聚（甲基）丙烯酸酯、胺醋（甲基）丙烯酸酯（亦即，曱苯二異氰酸酯）、由三甲基六亞甲基二異氰酸酯與六亞甲基二異氰酸酯等與（甲基）丙烯酸2-羥基乙酯反應而得之反應物、亞甲基雙（曱基）丙烯醯胺、（曱基）丙烯醯胺基亞曱基醚、由多元醇與N-羥甲基（甲基）丙烯醯胺縮合而成之縮合物等多官能單體，或疋1，3,5-二丙浠酿基六虱_ι，3,5-三啡（triacryif〇rmai)等。这些多官能單體，可單獨使用或組合2種以上來使用。 (B)成分的含量，以相對於（A)成分為2〇〜6〇質量％為佳，較佳為30〜50質量％。藉由設於上述範圍内，而能夠提升硬化性，並使圖案形成較為容易。 < (C)光聚合起始劑> (C)光聚合起始劑，並無特別限定，可以使用以往習知的光聚合起始劑。這樣的光聚合起始劑，可以舉出：苯乙酮、二乙氧基苯乙酮、對二甲基苯乙酮、對二甲基胺基苯丙_、二氣苯乙酮、三氯苯乙綱、對三級丁基苯乙_ 等苯乙酮類；三苯甲晒、2-氯二笨甲綱、p，p，_雙（二甲其胺基）二苯甲酮等二苯甲，類；笨偶姻甲基趟、笨偶姻；丙基峻、苯偶姻異丁基趟等苯偶姻喊類；^塞嘲 (如__叫、2_氯嘆嘲、2,4 —二乙基，、2_甲基^頓、 2-異丙基㈣等硫化物；2-乙基:1|昆、八甲基葱酿、& 苯并葱藏、2,3-二苯基葱酿等葱過氧化苯甲醯、過氧 16 201232176 化異丙笨等有機過氧化物；2-疏基苯并咪嗤、2-魏基苯并曙嗤(2-mercaptobenzoxazole) 、2-疏基苯并嘴吐 (2-mercaptobenzothiazole)等硫醇化合物；2_ (鄰氣苯基） -4,5-二（間曱氧基苯基）咪唑基二聚物等咪唑基化合物；對甲氧基三哄（p-methoxytriazine)等三哄化合物；2,4,6-參 (三氯曱基）-S·三哄、2-曱基-4,6-雙（三氯曱基）_5_三畊、 2-[2- ( 5-曱基呋喃-2-基）乙烯基]-4,6-雙（三氯甲基）_s_ 三畊、2-[2-(呋喃-2-基）乙烯基]-4,6-雙（三氯甲基）_s_ 三畊' 2-[2-( 4-二乙基胺基_2_曱基苯基）乙烯基]_4,6_雙（三氣甲基）-s-三畊、2-[2- ( 3,4-二曱氧基苯基）乙烯基]_4 6_ 雙（三氯曱基）-s-三哄、2- ( 4-甲氧基苯基）_4,6_雙（三氯甲基）-s-三畊、2- ( 4-乙氧基苯乙烯基）_4,6_雙（三氣曱基）-s-三哄、2- ( 4-正丁氧基苯基）_4,6-雙（三氣甲基） -s-二畊等具有_曱基的三哄化合物；2_笨曱基_2二曱基胺基-1- ( 4- ( N-嗎啉基）苯基）-丁-丨_酮 (2-benzyi-2-dimethylamino-l-(4-morpholinophenyl)-butane _l-one)等胺基酮化合物；乙酮^ 乙基_6_ ( 2曱基苯甲醯基）-9H-咔唑_3-基]-1- ( 〇_乙醯肟）等肟酯化合物等。這些化合物中，從能充分保持著色感光性樹脂組成物之感度、提升圖案之直線性的觀點而言，以肟酯化合物為佳。這樣的肟酯化合物以下述式（（>1)所示化合物為佳。 17 201232176(A-9) Further, in the above formula (A-7), γ represents a residue remaining after the acid anhydride group (-C0-0-C0-) is removed from the dicarboxylic anhydride. Specific examples of the dicarboxylic acid anhydride include cis-succinic anhydride, succinic anhydride, itaconic anhydride, phthalic anhydride, tetrahydrophthalic anhydride, hexahydrophthalic anhydride, and methylene. Mercaptotetrahydro-o-benzamide, gas bridge acid, methyl tetrahydrophthalic anhydride, glutaric anhydride, and the like. Further, in the above formula (A-7), Z represents a residue remaining after removing two acid field groups from the tetracarboxylic dianhydride. Examples of the tetracarboxylic dianhydride include pyromellitic anhydride, benzophenone tetracarboxylic dianhydride, biphenyltetracarboxylic dianhydride, and diphenyl ether tetraacid dianhydride. Further, in the above formula (A-7), m represents an integer of 〇 20-20. The acid value of the compound represented by the above formula (A-7) is preferably 10 to 150 mgKOH/g, more preferably 70 to 11 mgK0H/g, based on the solid content of the resin. By setting the acid value to 10 mgKOH/g or more, sufficient developability can be obtained. Moreover, by setting the acid value to 丨50 mgKOH/g or less, sufficient hardenability can be obtained, and surface properties can be improved. 13 201232176 Further, the mass average molecular weight of the compound of the above formula (A-7) m-~ is preferably 1000 to 40,000, and 阜 $ q丨王孕乂 is preferably 2000 to 30000. The heat resistance and film strength can be improved by setting the average molecular weight of the texture to 1000 by μ minus 1 Å. Further, by setting the mass average to be less than 1 1 and the knives are 4 Å or less, sufficient solubility for the developer can be obtained. The content of the (Α) component is preferably from 30 to 9 % by mass, preferably from 50 to 70% by mass, based on the solid content of the colored photosensitive resin of the present invention. Further, the ratio of the epoxy compound to the total amount of the component (A) is preferably from 30 to 70% by mass, and the car is preferably from 4 to 6 % by mass. By setting the ratio of the epoxy compound to 30% by mass or more, chemical resistance and weather resistance can be improved. In addition, by setting the ratio of the epoxy compound to 7 〇 mass% or less, it is possible to suppress a decrease in sensitivity and developability. < (B) Photopolymerizable monomer> (B) Photopolymerizable monomer (hereinafter also referred to as "(b) component)" is not particularly limited. "It is possible to use a conventional monofunctional monomer or more. Functional monomer. Examples of the above monofunctional monomer include (mercapto) acrylamide, hydroxymethyl (meth) acrylamide, decyl fluorenyl (decyl) acrylamide, ethoxy fluorenyl (fluorenyl) Acrylamide, propoxymethyl (meth) acrylamide, butoxy methoxy methoxy (meth) acrylamide, N-methylol (meth) acrylamide, N-hydroxyl Mercapto (meth) acrylamide, (mercapto) acrylic acid, fumaric acid, maleic acid, cis-succinic acid Sf, itaconic acid, itaconic anhydride, citraconic acid, lemon Coconic anhydride, crotonic acid, 2-propenyl guanidino-2-mercaptopropanesulfonic acid, tert-butyl butyl methacrylate sulfonic acid, methyl (meth) acrylate, 14 201232176 (decyl) ethyl acrylate, ( Butyl methyl methacrylate, 2-ethylhexyl (meth) acrylate, cyclohexyl (meth) acrylate, 2-hydroxyethyl 2-(hydroxy) acrylate, 2-hydroxypropyl (meth) acrylate, (Mercapto) acrylic acid 2- butyl vinegar, 2-phenoxy 2-hydroxypropyl (meth) acrylate, 2-(methyl) propylene oxy 2- hydroxypropyl phthalate, glycerin Single (methyl) Acrylic vinegar, (indenyl) tetrahydrofurfuryl acrylate, (meth)acrylic acid dimethylamino vinegar, (meth)acrylic acid glycidyl ester, (meth)acrylic acid 2,2,2-difluoroacetic acid, 2,2,3,3-tetrafluoropropyl (meth)acrylate, (meth)acrylic acid half ester of a phthalic acid derivative, and the like. These monofunctional monomers may be used singly or in combination of two or more. On the other hand, the above polyfunctional monomer may, for example, be ethylene glycol bis(indenyl)propionate, diethylene glycol di(meth)acrylate or tetraethylene glycol bis(indenyl)acrylate. , propylene glycol di(mercapto) acrylate, polypropylene glycol di(meth) acrylate, butanediol di(meth) acrylate, neopentyl bis(indenyl) acrylate, 1,6-hexanediol Di(indenyl)propene IS曰, dimethicone tris(meth)acrylate, glycerol di(meth)acrylate, pentaerythritol triacrylate, pentaerythritol tetraacrylate, dipentaerythritol Acrylate, dipentaerythritol hexaacrylate, pentaerythritol di(meth) acrylate, pentaerythritol tri(meth) acrylate, pentaerythritol tetra (meth) acrylate, dipentaerythritol penta (meth) acrylate, dipentaerythritol hexa Mercapto) acrylate, 2,2_bis(4.(methyl)propenyloxydiethoxyphenyl)propane, 2,2_bis('(meth)acryloxypolyoxyethylene) Phenyl)propane, (mercapto)acrylic acid 2_hydroxy_3_ (曱Acetyloxypropyl ketone, ethylene glycol diglycidyl sulfonate (A 15 201232176 base) acrylate, diethylene glycol diglycidyl ether di(meth)acrylate vinegar, phthalic acid Acid diglycidyl di(meth) acrylate, glycerin triacrylate, glycerol polyglycidyl ether poly(meth) acrylate, amine vinegar (meth) acrylate (ie, decyl diisocyanate), a reaction product obtained by reacting trimethylhexamethylene diisocyanate with hexamethylene diisocyanate or the like with 2-hydroxyethyl (meth)acrylate, methylene bis(indenyl) acrylamide, (曱a polyfunctional monomer such as a propylene hydrazino-mercaptoether or a condensate obtained by condensing a polyol with N-methylol (meth) acrylamide, or hydrazine 1,3,5-dipropionate Stuffed 虱, ι, 3,5-trimorphine (triacryif〇rmai) and the like. These polyfunctional monomers can be used singly or in combination of two or more. The content of the component (B) is preferably 2 〇 to 6 〇 by mass based on the component (A), and is preferably 30 to 50% by mass. By being provided in the above range, the hardenability can be improved and pattern formation can be facilitated. <(C) Photopolymerization initiator> (C) The photopolymerization initiator is not particularly limited, and a conventional photopolymerization initiator can be used. Examples of such a photopolymerization initiator include acetophenone, diethoxyacetophenone, p-dimethylacetophenone, p-dimethylaminophenylpropanoid, diacetophenone, and trichlorochloride. Acetophenone, p-tert-butyl butyl benzene, and other acetophenones; triphenylmethyl, 2-chlorodiphenyl, p, p, bis (dimethylamino) benzophenone, etc. Benzene, class; stupid mate methyl 趟, stupidity; propyl sulphur, benzoin isobutyl hydrazine and other benzoin shouting class; ^ sneer (such as __ call, 2_ chlorine sneer, 2 , 4-diethyl, 2-methyl-methyl, 2-isopropyl (tetra), etc.; 2-ethyl: 1|Kun, octamethyl onion, & benzoate, 2,3 -2-Phenyl onion and other organic peroxides such as onion peroxide, peroxybenzoic acid; 201232176 isopropylidene; 2-mercaptobenzoxazole a thiol compound such as 2-mercaptobenzothiazole; an imidazolyl compound such as 2_(o-phenyl)-4,5-di(metamethoxyphenyl)imidazolyl dimer; a triterpene compound such as p-methoxytriazine; 2,4,6-gin(trichloroindenyl)-S·santhanum, 2-anthracene -4,6-bis(trichloroindenyl)_5_three tillage, 2-[2-(5-mercaptofuran-2-yl)vinyl]-4,6-bis(trichloromethyl)_s_ Tillage, 2-[2-(furan-2-yl)vinyl]-4,6-bis(trichloromethyl)_s_ 三耕' 2-[2-( 4-diethylamino)_2_曱Phenyl)vinyl]_4,6_bis(trimethylmethyl)-s-three tillage, 2-[2-(3,4-dimethoxyphenyl)vinyl]_4 6_ bis (trichloro) Indenyl)-s-triterpene, 2-(4-methoxyphenyl)_4,6-bis(trichloromethyl)-s-trin, 2-(4-ethoxystyryl)_4 , 6_bis(triseofluorenyl)-s-triterpene, 2-(4-n-butoxyphenyl)_4,6-bis(trimethylmethyl)-s-second tillage, etc. Triterpenoid compound; 2_ azainyl-2-didecylamino-1-(4-(N-morpholinyl)phenyl)-butan-indole (2-benzyi-2-dimethylamino-l-( 4-morpholinophenyl)-butane _l-one) aminoketone compound; ethyl ketone ^ ethyl _6_ ( 2 benzyl benzoguanidino)-9H-carbazole _3-yl]-1- ( 〇 _ 醯肟), such as an oxime ester compound, etc. Among these compounds, an oxime ester is obtained from the viewpoint of sufficiently maintaining the sensitivity of the coloring photosensitive resin composition and improving the linearity of the pattern. The compound is preferred. Such an oxime ester compound is preferably a compound represented by the following formula ((>1). 17 201232176

上述式（c-i)中，RCi 表示_N〇2 或_(：〇]^5。又，rc5 表示可具有取代基的雜環基、縮合環式芳香族基、1或芳香族基。Re2〜Rc4分別獨立表示一價的有機基。In the above formula (ci), RCI represents _N〇2 or _(:〇)^5. Further, rc5 represents a heterocyclic group which may have a substituent, a condensed cyclic aromatic group, or an aromatic group. Rc4 independently represents a monovalent organic group.

Rc5所示之雜環基，可以舉出：含有氮原子、硫原子、及氧原子中的至少1個原子之5員環以上的雜環基，且以 5員環或6員環為佳。雜環基的例示可以舉出：吡咯基、咪唑基、吼唑基等含氮5員環基；n比啶基、吡阱基 (pyrazinyl)、嘧啶基、嗒啡基（pyridaziny丨）等含氮6員環基. 噻唑基（thiazolyl)、異噻唑基等含氮含硫基；噚唆"基 (oxazolyl)、異噚唑基等含氮含氣篡：成&且“」、The heterocyclic group represented by Rc5 may, for example, be a 5-membered or more heterocyclic group containing at least one of a nitrogen atom, a sulfur atom and an oxygen atom, and preferably a 5-membered ring or a 6-membered ring. Examples of the heterocyclic group include a nitrogen-containing 5-membered ring group such as a pyrrolyl group, an imidazolyl group or a carbazolyl group; n is a pyridyl group, a pyridinyl group, a pyrimidinyl group, a pyridaziny group or the like. Nitrogen 6-membered ring group. Nitrogen-containing sulfur-containing group such as thiazolyl or isothiazolyl; nitrogen-containing gas-containing gas such as oxazolyl and isoxazolyl: into & and "",

菲基等。又，Rel所示之芳香族基，可以舉出：萘基、蒽基、，可以舉出苯基。或方香族基，也可以具 ;基時，以具有取代基為 :_N02、_CN、_S〇2Rc6、 •〇-Rcl°-〇_Rcii 等。雜環基、縮合環式芳香族基、或芳有取代基《特別是當Rc5是芳香族基時佳。作為這樣的取代基，可以舉出： -C0Rc6、_NRc7Rc8、-Rc9、_〇 201232176 R刀別獨立表示院基，這些烧基可以經齒素原子取代’也可以被ϋ鍵、硫賴、自旨鍵所中斷。Re6中的院基，以碳數1〜5為佳’例如可以舉出：甲基、乙基、丙基、異丙基、丁基、異丁基等。 R R /刀別獨立表示氫原子、烷基、或烷氧基這些基團可以經i素原子取代，這些基團中，減及院氧基的伸炫基部分可以被賴、硫醚鍵或g旨鍵所中斷。又，rc7 與β也可以鍵結而形成環狀結構„rc7、rc8中的院基或烧氧基，以碳數1〜5為佳，例如可以舉出：曱基、乙基、丙基、異丙基、丁基、異丁基、甲氧基、乙氧基、丙氧基等。Fickey and so on. Further, examples of the aromatic group represented by Rel include a naphthyl group and an anthracenyl group, and a phenyl group is exemplified. Or a scented group, which may also have a base; the substituents are: _N02, _CN, _S〇2Rc6, • 〇-Rcl°-〇_Rcii, and the like. The heterocyclic group, the fused cyclic aromatic group, or the aryl substituent is particularly preferable when Rc5 is an aromatic group. Examples of such a substituent include: -C0Rc6, _NRc7Rc8, -Rc9, _〇201232176 R, which independently represent a hospital base, and these alkyl groups may be substituted by a fang atom, or may be a ruthenium or a ruthenium. The key is interrupted. The base of Re6 is preferably a carbon number of 1 to 5, and examples thereof include a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, and an isobutyl group. RR / Knife independently means that a hydrogen atom, an alkyl group, or an alkoxy group may be substituted by an i atom, and in these groups, the pendant moiety of the alkoxy group may be reduced by a thiol bond or a g bond. The key is interrupted. Further, rc7 and β may be bonded to each other to form a group or a group of alkoxy groups in the ring structure „rc7 and rc8, and preferably have a carbon number of 1 to 5, and examples thereof include a mercapto group, an ethyl group, and a propyl group. Isopropyl, butyl, isobutyl, methoxy, ethoxy, propoxy and the like.

Rc7與Re8所能鍵結而形成的環狀結構，可以舉出雜環。此雜環，舉出：至少含有氮原子之5員環以上的雜環，且以5〜7員環為佳。此雜環令亦可包含縮合環，雜環的例示可以舉L定環、嗎琳（m〇rph〇line)環硫代嗎啉（thiomorpholine)環等。其中又以嗎啉環為佳。A ring structure formed by bonding Rc7 and Re8 may be a hetero ring. The heterocyclic ring is a heterocyclic ring containing at least a 5-membered ring of a nitrogen atom, and preferably a 5- to 7-membered ring. The heterocyclic ring may also contain a condensed ring, and examples of the heterocyclic ring include an L-ring ring, a m〇rph〇line ring thiomorpholine ring, and the like. Among them, a morpholine ring is preferred.

Rc9表示部分或全部的氫原子可㈣素原子取代的烧基。R-中的烷基’以碳數卜5為佳，例如可以舉出：甲基、乙基、丙基、異丙基、丁基、異丁基等。 RCl〇、Re11分別獨立表示烧基’這些^基可以經函素原子取代，也可以被賴、硫_、s旨鍵所巾^較佳的碳數或具體例，係與上述Rc6的說明相同。其中可以舉出下述作為較佳的例示、比洛基、。比啶基、噻吩基、噻喃基、苯并噻吩基、蔡基、具有取代基之苯基。 19 201232176 上述式（C-1)中，Rc2表示一價的有機基。此有機基以下述為佳：-Rcl2、-〇Rc12、_C〇Rc12、_SRc12、_NRcl2RCl3 所示之基團。R 、R分別獨立表示烧基、婦基、芳基、芳烷基、或雜環基，這些基團可以經_素原子、烷基、或雜環基取代，其中，烷基及芳烷基的伸烷基部分，也可以被不飽和鍵、醚鍵、硫醚鍵、酯鍵所中斷。又，RCl2與RCl 3 也可以鍵結而與氮原子一起形成環狀結構。Rc9 represents a part or all of a hydrogen atom which may be substituted by a (tetra) atom. The alkyl group in R- is preferably a carbon number of 5, and examples thereof include a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, and an isobutyl group. RCl〇 and Re11 each independently represent a base group. These groups may be substituted by a functional atom, or may be replaced by a lysine, a sulfur _, or a s-key. The preferred carbon number or specific example is the same as the above description of Rc6. . Among them, the following is a preferable example, and it is exemplified. A pyridyl group, a thienyl group, a thiopyranyl group, a benzothienyl group, a decyl group, a phenyl group having a substituent. 19 201232176 In the above formula (C-1), Rc2 represents a monovalent organic group. The organic group is preferably a group represented by -Rcl2, -〇Rc12, _C〇Rc12, _SRc12, _NRcl2RCl3. R and R each independently represent an alkyl group, a aryl group, an aryl group, an arylalkyl group or a heterocyclic group, and these groups may be substituted by a silane atom, an alkyl group or a heterocyclic group, wherein an alkyl group and an aralkyl group are used. The alkyl moiety can also be interrupted by unsaturated bonds, ether bonds, thioether bonds, and ester bonds. Further, RCl2 and RCl 3 may be bonded to form a cyclic structure together with a nitrogen atom.

Rel2、Ren所示之烷基，以碳數為佳，較佳為碳數1〜5。烷基之例示，可以舉出下述直鏈狀或支鏈狀的基團.甲基、乙基、正丙基、異丙基、正丁基、異丁基、二級丁基、二級丁基、正戊基、異戊基、二級戊基、三級戊基、正己基、正庚基、正辛基、異辛基、二級辛基、三級辛基、正壬基、異壬基、正癸基、異癸基等。又，這些烷基也可以具有取代基。具有取代基之烷基的例示，可以舉出：甲氧基乙氧基乙基、乙氧基乙氧基乙基、丙氧基乙氧基乙基、曱氧基丙基等。 R 、R所示之烯基，以碳數1〜20為佳，較佳為碳數1〜5。烯基之例示，可以舉出下述直鏈狀或支鏈狀的基團：己烯基（vinyl)、烯丙基、丁烯基、乙烯基卜化印…）、丙烯基等。又，這些烯基也可以具有取代基。具有取代基之烯基的例示，可以舉出：2_(苯并噚唑_2•基）乙烯基等。The alkyl group represented by Rel2 and Ren is preferably a carbon number, preferably a carbon number of 1 to 5. The alkyl group is exemplified by the following linear or branched group. Methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, secondary butyl, secondary Butyl, n-pentyl, isopentyl, secondary pentyl, tertiary pentyl, n-hexyl, n-heptyl, n-octyl, isooctyl, dioctyl, trioctyl, n-decyl, Isoindolyl, n-decyl, isodecyl, and the like. Further, these alkyl groups may have a substituent. Examples of the alkyl group having a substituent include a methoxyethoxyethyl group, an ethoxyethoxyethyl group, a propoxyethoxyethyl group, a decyloxypropyl group and the like. The alkenyl group represented by R and R is preferably a carbon number of from 1 to 20, more preferably a carbon number of from 1 to 5. Examples of the alkenyl group include the following linear or branched groups: hexenyl (vinyl), allyl, butenyl, vinyl (...), acryl, and the like. Further, these alkenyl groups may have a substituent. Examples of the alkenyl group having a substituent include a 2_(benzoxazole-2-yl)vinyl group.

Rcl2、ReI3所示之芳基，以碳數6〜2〇為佳，較佳為碳數6〜10。芳基之例示，可以舉出：苯基、甲苯基、二甲苯基、乙基苯基、萘基、蒽基、菲基等。 20 201232176 κ Κ' 所示之芳炫基，以碳數7〜20為佳，較佳為芳烷基之例示，可以舉出：苯甲基…甲基苯甲基、广心二甲基苯甲基、苯基乙基、苯基乙烯基等二The aryl group represented by RCl2 and ReI3 is preferably a carbon number of 6 to 2 Å, more preferably a carbon number of 6 to 10. Examples of the aryl group include a phenyl group, a tolyl group, a xylyl group, an ethylphenyl group, a naphthyl group, an anthracenyl group, and a phenanthryl group. 20 201232176 κ Κ ' The aromatic group represented by carbon, preferably having a carbon number of 7 to 20, preferably an aralkyl group, may be exemplified by benzyl...methylbenzyl, broad-hearted dimethylbenzene Methyl, phenylethyl, phenyl vinyl, etc.

Rcl2、Ο cl 3 私 _ 所不之雜環基，可以舉出··含有氮原子、硫 ”子、及氧原子中至少1個原子之5員環以上且以5員環 ^員環為佳的雜環基。此雜環中亦可包含縮合環。雜環基的例示可以舉出：料基…比咬基、㈣基、噻吩基等。 t一 R 、R之中，烷基及芳烷基的伸烷基部分，也可以被不=和鍵、醚鍵、硫喊鍵、醋鍵所中斷。 R與R所能鍵結而形成的環狀結構，可以舉出雜環。此雜環，可以舉出：至少含有氮原子之5員環以上且以5〜7員環為佳的雜環。此雜γ 衣此雜％中亦可包含縮合環，雜ί哀的例示可以舉出：哌啶衣、嗎啉環、硫代嗎啉環等。上述之中，R。2最佳為. ,、取住马.甲基、乙基、丙基、苯基。上述式（C-1)中，RC3主一 . 表不一價的有機基。此有機基以下述為佳：碳數1〜5之烷其_ Β ^ 朴暴可具有取代基的碳數6〜 12之方基、下述式（c_2) ^ ^ ^ L 厅不之基、或是可具有取代基之雜環基。取代基可舉出蛊〜D + — β /、 4R中同樣的基團。碳數όRcl2, Ο cl 3 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ The heterocyclic group may further contain a condensed ring. Examples of the heterocyclic group include a base group, a thiol group, a (tetra) group, a thienyl group, etc. t-R, R, an alkyl group and an aromatic group. The alkyl group of the alkyl group may also be interrupted by a bond, an ether bond, a sulfur bond, or a vinegar bond. The ring structure formed by the bond of R and R may be a hetero ring. The ring may be a heterocyclic ring containing at least a 5-membered ring of a nitrogen atom and preferably a 5- to 7-membered ring. The hetero-γ clothes may also contain a condensed ring in the % of impurities, and examples of the impurities may be exemplified. : piperidine, morpholine ring, thiomorpholine ring, etc. Among the above, R. 2 is preferably ., and is taken from the horse methyl group, ethyl group, propyl group, phenyl group. 1), RC3 main one. The non-monovalent organic group. The organic group is preferably as follows: alkane having a carbon number of 1 to 5, _ Β ^ 暴可 can have a substituent of a carbon number of 6 to 12 , the following formula (c_2) ^ ^ ^ L Or a heterocyclic group which may have a substituent. The substituent may be the same group as 蛊~D + - β /, 4R. Carbon number ό

丄2之方基，可以舉出：笼I c14 土、萘基、蒽基、菲基等。 —R〇14_rc15 (C_2) 上述式（C-2 )中，RC丨4类_ 衣不可被氧原子中斷的碳數1 〜5之伸烷基。這樣的伸烷美，絲壯沾I " 可以舉出下述直鏈狀或支鏈狀的基團：亞甲基、伸？评乙基、伸正丙基、伸異丙基、伸 21 201232176 正丁基、伸異丁基、伸一級丁基、伸正戍基、伸異戊基、伸二級戊基等。其中，Rcl4最佳為伸異丙基。The square base of 丄2 can be exemplified by cage I c14 soil, naphthyl group, fluorenyl group, phenanthryl group and the like. —R〇14_rc15 (C_2) In the above formula (C-2), the RC丨4 type _ clothes are an alkylene group having 1 to 5 carbon atoms which are not interrupted by an oxygen atom. Such an alkylene oxide, silky strong I " can be cited as the following linear or branched group: methylene, stretch? Ethyl, n-propyl, isopropyl, and extension 21 201232176 n-butyl, isobutyl, butyl, fluorenyl, isoamyl, and pentyl. Among them, Rcl4 is preferably an isopropyl group.

上述式（C-2)中’ Rcl5表示-NRcl6Rc17所示之—價的有機基（Rc 16、Rc 17分別獨立表示一價的有機基）。這樣的有機基之中’若Rcl5的結構是下述式（C-3 )所示之結構，則從能提升$聚合起始劑之溶解性的觀點而言，係為較佳。上述式（C-3)中’ Rcl8、Rcl9分別獨立表示碳數之院基。這樣的烷基，可以舉出：曱基、乙基、正丙基、異丙基、正丁基、異丁基、二級丁基、三級丁基、正戊基、異戊基、一級戊基、三級戊基等。其中，Rc 18、Rc 19最佳為甲基。 ~In the above formula (C-2), 'Rcl5' represents a valence organic group represented by -NRcl6Rc17 (Rc 16 and Rc 17 each independently represent a monovalent organic group). Among the above-mentioned organic groups, when the structure of RCl5 is a structure represented by the following formula (C-3), it is preferable from the viewpoint of improving the solubility of the polymerization initiator. In the above formula (C-3), "Rcl8 and Rcl9" independently represent the number of carbon atoms. Examples of such an alkyl group include mercapto, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, dibutyl, tert-butyl, n-pentyl, isopentyl, and Amyl, tertiary amyl and the like. Among them, Rc 18 and Rc 19 are most preferably a methyl group. ~

Re3所示之雜環基，可以舉出：含有氮原子、硫原子、及氧原子中的至少1個原子之5員環以上的雜環基，且以 5員環或6員環為佳。雜環基的例示可以舉出：吡咯基、米唾基、°比唾基等含氮5員環基；°比咬基、°比D井基、。密咬基、嗒畊基等含氮6員環基；噻唑基、異噻唑基等含氮含 &基，Pf唑基、異卩萼唑基等含氮含氧基；噻吩基、噻喃基等含硫基；吱喃基、派喃基等含氧基等。其中’以含有丄 =氮原子或硫原子的雜環基為佳。此雜環中亦可包含縮合展°包含縮合環之雜環基的例示，可以舉出笨并嘆吩基。又，雜壤基也可以具有取代基。取代基可舉出與 K 中同樣的基團。 22 201232176 上述式（c-i)中，R。4表示一價的有機基。其中，以反數1 5之烧基為佳。這樣的烧基，可以舉出：甲基、乙基、正丙基、異丙基、正丁基、異丁基、二級丁基、三級丁基、正戊基、異戊基、二級戊基、三級戊基等。其中， Re4最佳為曱基。 (C )成分的含量，以相對於本發明之著色感光性樹脂組成物的固形分而言是化丨〜％質量％為佳，較佳為1〜45 質|%。藉由將（c)成分的含量設於上述範圍内，能夠獲得充分的耐熱性、耐藥品性，並且能抑制硬化不良的情形。〈（D)著色劑> (D )著色劑（以下又稱為「（ D )成分」），並無特別限定’可以使用以往習知的著色劑。著色劑’例如可以舉出：在色彩索引（CU.; The society of Dyers and Colourists公司發行）中被分類為顏料 (Pigment)之化合物，具體而言，可以舉出附有如下述般的色彩索引.（C.I.)編號的化合物。 C.I·顏料黃1 (以下同樣是「C.I.顏料黃」，僅記載編號）、3、11、12、13、14、15、16、17、20、24、31、53、 55、60、61、65、7卜 73、74、81、83、86、93、95、97、 98、99、100、1(H、1〇4、106、108、109、11〇、in、114、 116 、 117 、 119 、 120 、 125 、 126 、 127 、 128 、 129 、 137 、 138 、 139 、 147 、 148 、 150 、 151 、 152 、 153 、 154 、 155 、 156 、 166 、 167 、 168 ' 175 、 180 、 185 ; C.I.顏料橙1 (以下同樣是「C.I·顏料橙」，僅記載編 23 201232176 號）、5' 13、14、16、17、24、34、36、38、40、43、46、 49 、 51 、 55 、 59 、 61 、 63 、 64 、 71 、 73 ; C.I.顏料紫1 (以下同樣是「C.I.顏料紫」’僅記載編號）、19、23、29、30、32、36、37' 38、39、40' 50; C.I.顏料紅1 (以下同樣是「C.I·顏料紅」’僅記載編號）、2、3、4、5、6、7、8、9、10、11、12、14、15、16、 17、18、19、21、22、23、30、31、32、37、38、40、41、 42、48 : 1 ' 48 : 2 ' 48 : 3、48 : 4、49 : 1、49 : 2、50 : 1、 52 ： 1 ' 53 ： 1、57、57: 1、57:2、58:2、58:4、60: 1、 63 : 1 、 63 : 2 、 64 : 1 、 81 : 1 、 83 、 88 、 90 : 1 、 97 、 101 、 102 、 104 、 105 、 106 、 108 、 112 、 113 、 114 、 122 、 123 、 144 ' 146 、 149 、 150 、 151 、 155 、 166 、 168 、 170 、 171 、 172 、 174 、 175 、 176 、 177 、 178 、 179 、 180 、 185 、 187 、 188 、 190 ' 192 ' 193 、 194 、 202 、 206 、 207 、 208 、 209 ' 215 、 216 、 217 、 220 、 223 、 224 ' 226 、 227 、 228 ' 240 ' 242 、 243 、 245 、 254 、 255 、 264 、 265 ; C.I.顏料藍1 (以下同樣是「C.I.顏料藍」，僅記載編號）、2、15、15 : 3、15 : 4、15 : 6 ' 16、22、60、64、66 ; C.I.顏料綠7、C.I.顏料綠36、C.I.顏料綠37 ; C.I.顏料棕23、C.I.顏料棕25、C.I.顏料棕26、C.I.顏料栋2 8， C.I.顏料黑1、C.I.顏料黑7。又’著色劑以使用黑色顏料為佳。黑色顏料，可以舉出不論是有機物或無機物的各種顏料：碳黑、鈦黑；銅、 24 201232176 鐵、猛、姑、絡、錄、辞、複合氧化物、金屬破化物、碳酸鹽等。其中較佳為使用碳黑，可以使用：槽黑知的碳黑，以使用槽黑或爐舞、銀、錫等的金屬氧化物、金屬硫酸鹽、金屬合金或金屬具有高遮光性的碳黑。、爐黑、熱裂碳黑、燈黑等習黑為佳。 (D)成分的含量，以相相對於本發明之著色感光性樹脂組成物的固形分為5〜7〇貝里/〇為佳，較佳為25〜55質量 %，更佳為30〜50質量。/〇。 < (S )有機溶劑> 本發明之著色感光性樹脂組成物，以含有用以稀釋的有機溶，為佳。此有機溶劑，可以舉出：乙二醇單甲基酸、醇單乙基㈣、乙二醇單正丙基趟、乙：醇單正丁基趟、 :乙二醇單甲基驗、二乙二醇翠乙基輕、二乙二醇單正丙 π 哔早止丁基醚、三乙二醇單甲基醚、三乙二醇早乙基鱗、丙-酿g田甘。。内一％早甲基醚、丙二醇單乙基醚、丙二醇早正丙基驗、丙二醇單正丁基鍵、二丙二醇單f基喊、二丙二醇單乙基、二丙二醇單正丙基醚、二丙二醇單正丁基鍵、三丙二醇單甲基趟、三丙二醇單乙基趟等（聚）院二醇單烧基乙二醇單甲㈣乙酸§旨、乙二醇單乙: :乙酸醋、二乙二醇單甲基驗乙酸醋、二乙二醇單乙基二暖醋、丙二醇單甲基趟乙酸酷、丙二醇單乙基喊乙酸醋 _ (聚）烧二醇單貌基趟乙酸酷類；^乙二醇二甲基喊、他n 土、二乙二醇二乙基驗、四氫咳喃等其 ’曱基乙基_、環己酮、2'㈣、3·庚鲷等酮類； 25 201232176 2- 挺基丙酸曱酿、2_羥基丙酸乙酯等乳酸烷基酯類；2_羥基 -2-甲基丙酸乙g旨、3_甲氧基丙酸甲酯、3甲氧基丙酸乙酯、 3- 乙氡基丙酸甲酯、3_乙氧基丙酸乙酯、乙氧基乙酸乙酯、羥基乙酸乙酯、2-羥基-3-甲基丁酸f酯、乙酸3-甲基-3-曱氧基丁酯、丙酸3-曱基-3-甲氧基丁酯、乙酸乙酯、乙酸正丙酯、乙酸異丙酯、乙酸正丁酯、乙酸異丁酯、曱酸正戊酯、乙酸異戊酯、丙酸正丁酯、丁酸乙酯、丁酸正丙酯、丁異丙6曰、丁酸正丁酯、丙酮酸曱酯、丙酮酸乙酯、丙酮酸正丙酯、乙醯乙酸甲酯、乙醯乙酸乙酯、2-酮基丁酸乙醋等其他S旨甲苯、二甲苯等芳香族烴類；N曱基他各定酮、N，N_二甲基曱醯胺、n，n-二甲基乙醯胺等醯胺類等這些有機溶劑可以單獨使用或組合2種以上來使用。這些有機溶劑中，因為對於（A)成分、（B)成分、（C) 成刀顯不出優異的溶解性，並且可以使黑色顏料等不溶性成刀的分散性較為良好，所以又以下述為佳：丙二醇單甲基醚乙一醇單甲基醚乙酸酯、丙二醇單甲基醚乙酸酯、丙一醇單乙基醚乙酸酯、二乙二醇二甲基醚、〔乙二醇曱基乙基醚、環己酮、乙酸3_曱氧基丁酯。 (S)成分的含量，以使本發明之著色感光性樹脂組成物的固形分濃度成為5〜3〇質量％的量為佳。 <其他成分> 八本發月之著色感光性樹脂組成物中，也可以視需要而 ^ '、劑。添加劑，可以舉出：敏化劑、硬化促進劑、交聯劑、分散助劑、填充劑、密著促進劑、抗氧化劑、紫 26 201232176 外線吸收劑、解凝劑、熱聚合抑制劑、消泡劑、界面活性劑等。 <著色感光性樹脂組成物之調製方法> 本發明之著色感光性樹脂組成物，可以藉由將上述各成分全部以授拌機混合而獲得。另外，也可以使用薄膜過濾器，以使所獲得的組成物成為均勻的組成物。《觸控面板及顯示裝置》本發明之觸控面板具有硬化樹脂圖案，該硬化樹脂圖案疋使用本發明之著色感光性樹脂組成物而形成。又，本發明之顯示裝置具備本發明之觸控面板。為了在觸控面板上形成硬化樹脂圖案，首先是使用輥塗佈盗、反輥塗佈器、棒塗佈器等接觸轉印型塗佈裝置或方疋轉器（旋轉式塗佈裝置）、簾流式塗布機（curtain flow coater)等非接觸型塗佈裝置，在基板上塗佈本發明之著色感光性樹脂組成物。接著，使所塗佈的著色感光性樹脂組成物乾燥而形成塗膜。乾燥方法並無特別限定，例如可以使用下述任一種 / 、1)以加熱板在80〜12(rc、較佳為90〜10(rc的溫度使其乾燥60〜120秒的方法，（2 )在室溫放置數小時〜數Θ 的大、土 r v 3 )放在溫風加熱器或紅外線加熱器中數十分鐘〜數小時以去除溶劑的方法。接著’隔著負型遮罩，對此塗膜照射紫外線' 準分子雷射光等活性能量線’以使其部分曝光。所照射的能量線蓋疋因著色感光性樹脂組成物的組成而異，例如以2 0〜 27 201232176 200 mJ/cm2左右為佳。接著’將曝光後的塗膜藉肤稭由顯衫液而顯影，藉此成形為所期望的形狀。顯寻彡古土、，’·、’V 並…、特別限定，可以使用浸潰法、喷霧法等》顯影液，可舉一 ▲ 芈出.早乙醇胺、二乙醇胺、二乙醇胺#有機系的物質，痞异急备几〜 A疋氲氧化納、氫氧化卸、碳酸鈉、氨水、四級銨鹽等的水溶液。 "接著，對於顯影後的圖案，以〜25代左右進行曝光後烤（post bake)。此時，以將所形成的圖案全面曝光為佳。除了如上述般藉由部分曝光及顯影而形成硬化樹脂圖㈣方法以外，例如也可以使用喷墨印表機來形成硬化樹脂圖案。此時，在基板上使本發明之著色感光性樹脂組成物喷出並形成所期望的圖案形狀，接著經過乾燥、曝光及曝光後烤，而形成硬化樹脂圖案。將如同上述般進行而形成有硬化樹脂圖案的觸控面板，依照規定方法組合於顯示裝置中，藉此而可以製造本發明之顯示裝置。 [實施例] 以下說明本發明之實施例’但本發明的範圍並不限定於這些實施例。另外，以下的記載中，r份」、「％」分別是質量基準。〈合成例1 > 首先’在500ml之四口燒瓶中，填入雙紛芴型環氧樹 28 201232176 脂（環氧當量為235 ) 235 g、氣化四甲銨u〇mg、2,6二_ 三級丁基-4-曱基苯酚1〇〇 mg、及丙烯酸72 .〇g，_邊於其中以25 1111/分鐘的速度喷入空氣、一邊以9〇〜1〇〇。(：加熱溶解。接著’在溶劑呈白濁狀態下緩緩升溫，加熱至12〇它而使其完全溶解。此時溶液會逐漸變成透明黏稠狀，但仍繼續攪拌。期間，測定酸價，並持續加熱攪拌至酸價小於小時。下述式 1.0 mgKOH/g為止。至酸價達到目標值為止需要12 然後’冷卻至室溫，而獲得無色透明且固體狀的 (A-10)所示之雙酚芴型環氧丙烯酸酯。The heterocyclic group represented by Re3 may, for example, be a 5-membered or more heterocyclic group containing at least one of a nitrogen atom, a sulfur atom and an oxygen atom, and preferably a 5-membered ring or a 6-membered ring. Examples of the heterocyclic group include a pyrrolyl group, a mastyl group, a nitrogen-containing 5-membered ring group such as a thiol group, and a ratio of a bite base to a ratio D. a nitrogen-containing 6-membered ring group such as a thief base or a hydrazine base; a nitrogen-containing aryl group such as a thiazolyl group or an isothiazolyl group; a nitrogen-containing oxy group such as a Pf azole group or an isoxazolyl group; a thienyl group and a thiopyran a sulfur-containing group such as a thiol group; an oxy group such as a fluorenyl group or a phenyl group; Among them, a heterocyclic group containing a ruthenium = nitrogen atom or a sulfur atom is preferred. The heterocyclic ring may also contain an exemplified condensed heterocyclic group containing a condensed ring, and may be exemplified. Further, the heterobasic group may have a substituent. The substituents may be the same as those in K. 22 201232176 In the above formula (c-i), R. 4 represents a monovalent organic group. Among them, the base of the inverse number of 15 is preferred. Such a base can be exemplified by methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, secondary butyl, tert-butyl, n-pentyl, isopentyl, and Grade pentyl, tertiary pentyl and the like. Among them, Re4 is preferably a sulfhydryl group. The content of the component (C) is preferably from 5% to 5% by mass, more preferably from 1 to 45% by mass, based on the solid content of the colored photosensitive resin composition of the present invention. By setting the content of the component (c) within the above range, sufficient heat resistance and chemical resistance can be obtained, and curing failure can be suppressed. <(D) Colorant> (D) The colorant (hereinafter also referred to as "(D) component)" is not particularly limited. A conventionally known coloring agent can be used. The coloring agent 'is, for example, a compound classified as a pigment in a color index (CU.; issued by The Society of Dyers and Colourists), and specifically, a color index attached as follows (CI) numbered compound. CI·Pigment Yellow 1 (hereinafter, “CI Pigment Yellow”, only number), 3, 11, 12, 13, 14, 15, 16, 17, 20, 24, 31, 53, 55, 60, 61, 65, 7 卜 73, 74, 81, 83, 86, 93, 95, 97, 98, 99, 100, 1 (H, 1 〇 4, 106, 108, 109, 11 〇, in, 114, 116, 117 , 119 , 120 , 125 , 126 , 127 , 128 , 129 , 137 , 138 , 139 , 147 , 148 , 150 , 151 , 152 , 153 , 154 , 155 , 156 , 166 , 167 , 168 ' 175 , 180 , 185 CI Pigment Orange 1 (the same applies to "CI·Pigment Orange", only 23, 201232176), 5' 13, 14, 16, 17, 24, 34, 36, 38, 40, 43, 46, 49 51, 55, 59, 61, 63, 64, 71, 73; CI Pigment Violet 1 (the same is also "CI Pigment Violet" 'only numbered), 19, 23, 29, 30, 32, 36, 37' 38 , 39, 40' 50; CI Pigment Red 1 (hereinafter, "CI·Pigment Red" is only the number), 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 14 , 15, 16, 17, 18, 19, 21, 22, 23, 30, 31, 32 37, 38, 40, 41, 42, 48: 1 ' 48 : 2 ' 48 : 3, 48 : 4, 49 : 1, 49 : 2, 50 : 1, 52 : 1 ' 53 : 1, 57, 57: 1, 57:2, 58:2, 58:4, 60: 1, 63: 1, 63: 2, 64: 1, 81: 1, 83, 88, 90: 1, 97, 101, 102, 104, 105, 106, 108, 112, 113, 114, 122, 123, 144 '146, 149, 150, 151, 155, 166, 168, 170, 171, 172, 174, 175, 176, 177, 178, 179, 180, 185, 187, 188, 190 '192' 193, 194, 202, 206, 207, 208, 209 '215, 216, 217, 220, 223, 224 '226, 227, 228 '240' 242, 243, 245, 254, 255, 264, 265; CI Pigment Blue 1 (the same is "CI Pigment Blue", only the number is described), 2, 15, 15: 3, 15: 4, 15: 6 ' 16, 22, 60 , 64, 66; CI Pigment Green 7, CI Pigment Green 36, CI Pigment Green 37; CI Pigment Brown 23, CI Pigment Brown 25, CI Pigment Brown 26, CI Pigment Building 2 8, CI Pigment Black 1, CI Pigment Black 7 . Further, the coloring agent is preferably a black pigment. Examples of the black pigment include various pigments of organic or inorganic substances: carbon black, titanium black; copper, 24 201232176 iron, fierce, agglomerate, complex, recorded, compound oxide, metal oxide, carbonate, and the like. Among them, it is preferable to use carbon black, and it is possible to use carbon black which is known as black in the tank to use metal black oxides of furnace black, furnace, silver, tin, etc., metal sulfates, metal alloys or carbon blacks having high light-shielding properties. . Black, hot black, black, black, etc. are preferred. The content of the component (D) is preferably 5 to 7 μm / 〇, more preferably 25 to 55% by mass, still more preferably 30 to 50, based on the solid content of the coloring photosensitive resin composition of the present invention. quality. /〇. < (S) Organic solvent> The colored photosensitive resin composition of the present invention preferably contains an organic solvent for dilution. The organic solvent may, for example, be ethylene glycol monomethyl acid, alcohol monoethyl (tetra), ethylene glycol mono-n-propyl fluorene, ethylene: alcohol mono-n-butyl fluorene, ethylene glycol monomethyl test, Ethylene glycol chloroethyl, diethylene glycol mono-n-propion π 哔 early butyl ether, triethylene glycol monomethyl ether, triethylene glycol early ethyl scale, C - brewing g Tiangan. . Internal one% early methyl ether, propylene glycol monoethyl ether, propylene glycol early positive propyl test, propylene glycol mono-n-butyl bond, dipropylene glycol single f-group shout, dipropylene glycol monoethyl, dipropylene glycol mono-n-propyl ether, dipropylene glycol single n-Butyl bond, tripropylene glycol monomethyl hydrazine, tripropylene glycol monoethyl hydrazine, etc. (poly) diol monoalkyl glycol monomethyl (tetra) acetic acid §, ethylene glycol monoethyl: : acetic acid vinegar, diethylene glycol Monomethyl acetate acetate, diethylene glycol monoethyl di warm vinegar, propylene glycol monomethyl hydrazine acetic acid, propylene glycol monoethyl acetal vinegar _ (poly) glycerol monomorphic hydrazine acetic acid cool class; ^ B a ketone such as diol dimethyl ketone, t-n, diethylene glycol diethyl, tetrahydroc-butyl or the like; ketones such as 'mercaptoethyl _, cyclohexanone, 2' (tetra), and 3 · hydrazine; 201232176 2-Acrylic acid alkyl esters such as terpenyl propionate, 2_hydroxypropionate, etc.; 2-hydroxy-2-methylpropionic acid, ethylene glycol, methyl 3-methoxypropionate, 3 Ethyl oxypropionate, methyl 3-ethylmercaptopropionate, ethyl 3-ethoxypropionate, ethyl ethoxyacetate, ethyl hydroxyacetate, 2-hydroxy-3-methylbutyric acid Ester, acetic acid 3-methyl-3-oxime Butyl ester, 3-mercapto-3-methoxybutyl propionate, ethyl acetate, n-propyl acetate, isopropyl acetate, n-butyl acetate, isobutyl acetate, n-amyl citrate, acetic acid Isoamyl ester, n-butyl propionate, ethyl butyrate, n-propyl butyrate, isopropyl isopropanol, n-butyl butyrate, decyl pyruvate, ethyl pyruvate, n-propyl pyruvate, B Other products such as methyl acetate, ethyl acetate, ethyl 2-ketobutyrate, etc., such as aromatic hydrocarbons such as toluene and xylene; N-mercapitadine, N,N-dimethylhydrazine These organic solvents, such as an amine and a guanamine, such as n-n-dimethyl acetamide, can be used individually or in combination of 2 or more types. Among these organic solvents, since the (A) component, the (B) component, and the (C) forming process do not exhibit excellent solubility, and the dispersibility of insoluble knives such as a black pigment can be improved, the following is Good: propylene glycol monomethyl ether ethyl alcohol monomethyl ether acetate, propylene glycol monomethyl ether acetate, propanol monoethyl ether acetate, diethylene glycol dimethyl ether, [ethylene glycol Mercaptoethyl ether, cyclohexanone, 3-butoxybutyl acetate. The content of the component (S) is preferably such that the solid content concentration of the colored photosensitive resin composition of the present invention is 5 to 3 % by mass. <Other components> The colored photosensitive resin composition of the eight moons may also be used as needed. Examples of the additives include a sensitizer, a hardening accelerator, a crosslinking agent, a dispersing aid, a filler, a adhesion promoter, an antioxidant, and a violet 26 201232176 external absorbent, a deagglomerating agent, a thermal polymerization inhibitor, and a consumer. A foaming agent, a surfactant, and the like. <Preparation method of coloring photosensitive resin composition> The colored photosensitive resin composition of the present invention can be obtained by mixing all of the above components with a mixer. Alternatively, a membrane filter may be used to make the obtained composition a uniform composition. <<Touch Panel and Display Device>> The touch panel of the present invention has a cured resin pattern which is formed using the colored photosensitive resin composition of the present invention. Further, the display device of the present invention includes the touch panel of the present invention. In order to form a hardened resin pattern on the touch panel, first, a contact transfer type coating device or a square transfer device (rotary coating device) using a roll coating thief, a reverse roll coater, a bar coater, or the like is used. A non-contact type coating device such as a curtain flow coater is applied to the substrate to apply the colored photosensitive resin composition of the present invention. Next, the applied colored photosensitive resin composition is dried to form a coating film. The drying method is not particularly limited. For example, any one of the following methods can be used, and the heating plate is heated at 80 to 12 (rc, preferably 90 to 10 (the temperature of rc is dried for 60 to 120 seconds, (2). ) Place at room temperature for several hours ~ several Θ large, soil rv 3) Place in a warm air heater or infrared heater for tens of minutes ~ several hours to remove the solvent. Then 'via a negative mask, right The coating film is irradiated with ultraviolet light [active energy ray such as excimer laser light to partially expose it. The energy ray cap to be irradiated varies depending on the composition of the coloring photosensitive resin composition, for example, 20 to 27 201232176 200 mJ/ It is preferable that it is about cm2. Then, the exposed film coating straw is developed from the scented liquid to form a desired shape. The sacred earth, '·, 'V and ... are particularly limited. You can use the dipping method, the spray method, etc., to develop a solution. Early ethanolamine, diethanolamine, diethanolamine #organic substances, different kinds of sputum ~ A 疋氲疋氲、, An aqueous solution of sodium carbonate, ammonia, or a quaternary ammonium salt. For the developed pattern, post bake is performed in about ~25 generations. At this time, it is preferable to fully expose the formed pattern. In addition to forming a hardened resin pattern by partial exposure and development as described above (4) In addition to the method, for example, an inkjet printer can be used to form the cured resin pattern. At this time, the colored photosensitive resin composition of the present invention is sprayed on the substrate to form a desired pattern shape, followed by drying, exposure, and After exposure and baking, a cured resin pattern is formed. The touch panel formed with the cured resin pattern as described above is combined with a display device according to a predetermined method, whereby the display device of the present invention can be manufactured. The embodiment of the present invention will be described below, but the scope of the present invention is not limited to these examples. In the following description, r parts and "%" are mass standards. <Synthesis Example 1 > First 'in 500 ml In the four-necked flask, filled with double-dip-type epoxy tree 28 201232176 grease (epoxy equivalent of 235) 235 g, vaporized tetramethylammonium u〇mg, 2,6 di-tertiary -4-mercaptophenol 1 〇〇 mg, and acrylic acid 72. 〇g, _ while blowing air at a rate of 25 1111/min, while 9〇~1〇〇. (: heating to dissolve. Then 'in The solvent is slowly warmed up in a white turbid state, heated to 12 〇 to completely dissolve it. At this point, the solution will gradually become transparent and viscous, but stirring will continue. During this period, the acid value is measured and the heating is continued until the acid value is less than the hour. The following formula is 1.0 mg KOH/g. It is necessary to 12 after the acid value reaches the target value, and then 'cooled to room temperature to obtain a bisphenol oxime type epoxy acrylate represented by (A-10) which is colorless and transparent. .

OH -g=CH2 (A-10) 接著，在如上述般進行而獲得的上述雙酚苟型環氧丙烯酸酯307.0 g中加入乙酸3_甲氧基丁酯6〇〇g而使其溶解之後’再混合二笨甲酮四m酸二酐8Q 5 g及漠化四乙録i g’緩緩升溫而以110〜U5t反應4小時。確認酸酐基消失之後，混合1，2,3,6-四氫鄰苯二曱酸酐38 〇g，在9〇t>c反應 6小時’而獲得樹脂A1。酸酐基之消失是藉由紅外線光譜 (infrared(IR) Spectrum)來確認。此樹脂A1 ’相當於上述式（A_7)所示之化合物。 <實施例1 > 將下述所示之各成分溶解於乙酸3_曱氧基丁酯/環己銅/丙二醇單曱基喊乙酸§旨=60/20/20 (質量比）的混合溶 29 201232176 劑中’並使固形h》辰度成為1 5質量％，以授拌機混合2小時之後，以孔徑為5 μιη的薄膜過濾器進行過濾，而調製著色感光性樹脂組成物。 *黏合劑化合物於合成例1所獲得之樹脂A1 ··· 95份苯乙烯/曱基丙烯酸=80/20 (質量比）之共聚物（樹脂 A2，質量平均分子量13000) · · · 60份「EHPE3150」（Daicel化學工業公司製造；2,2-雙（羥基曱基）-1-丁醇的1，2-環氧基-4- ( 2-環氧乙烷基）環己烷 (l，2-epoxy-4-(2-oxiranyl)cyclohexane)加成物；參照下述式 (1 )) . · · 155 份鲁光聚合性單體二季戊四醇六丙烯酸酯（曰本化藥公司製造）··· Π5份癱光聚合起始劑「OXE-02」（BASF公司製造；乙酮-l-[9-乙基-6- ( 2-曱基苯甲醯基）-9H-咔唑-3-基]-卜（0-乙醯肟））· · · 100 份 *著色劑碳黑（御國色素公司製造）··· 450份 (1) 201232176OH -g=CH2 (A-10) Next, after dissolving 6 〇〇g of acetic acid 3-methoxybutyl acrylate in 307.0 g of the above bisphenol fluorene type epoxy acrylate obtained as described above 'Remix two ketones of tetrakis acid dianhydride 8Q 5 g and desertification tetrahedron i g' slowly warmed up and reacted at 110~U5t for 4 hours. After confirming the disappearance of the acid anhydride group, 38 〇g of 1,2,3,6-tetrahydrophthalic anhydride was mixed and reacted at 9 〇t > c for 6 hours to obtain a resin A1. The disappearance of the acid anhydride group is confirmed by infrared spectrum (infrared (IR) Spectrum). This resin A1' corresponds to the compound represented by the above formula (A-7). <Example 1 > The components shown below were dissolved in a mixture of 3-methoxybutyrate acetate/cyclohexyl copper/propylene glycol monodecyl-acetic acid §=60/20/20 (mass ratio) In the solution of 201232176, the solid content h was changed to 15 mass%, and the mixture was mixed by a mixer for 2 hours, and then filtered through a membrane filter having a pore size of 5 μm to prepare a colored photosensitive resin composition. *Binder compound A1 ··· 95 parts of styrene/mercaptoacrylic acid=80/20 (mass ratio) copolymer (resin A2, mass average molecular weight 13000) · · · 60 parts EHPE3150" (manufactured by Daicel Chemical Industry Co., Ltd.; 1,2-epoxy-4-(2-oxiranyl)cyclohexane of 2,2-bis(hydroxyindenyl)-1-butanol (l, 2-epoxy-4-(2-oxiranyl)cyclohexane) adduct; refer to the following formula (1)). · · 155 parts of Luguang polymerizable monomer dipentaerythritol hexaacrylate (manufactured by Sakamoto Chemical Co., Ltd.) ·· 5 parts of osmium polymerization initiator “OXE-02” (manufactured by BASF Corporation; ethyl ketone-l-[9-ethyl-6-(2-mercaptobenzylidene)-9H-carbazole-3 -基]-Bu (0-Ethyl))·· · 100 parts*Colorant carbon black (manufactured by Royal Chinese Pigment Co., Ltd.)··· 450 parts (1) 201232176

n1+n2+n3=15 <實施例2〜5 > 除了將黏合劑化合物的組成變更如表j 物相對於黏合劑化合物之總量的比例設為 2〇°/。、10%以外，其餘與實施例1同樣地進行光性樹脂組成物。另外，表1中的數值是表 <實施例6 > 除了如表1所示，使用下述式（2 )所示 202iP」（Daicel化學工業公司製造）來取代以外，其餘與實施例丨同樣地進行而調製著乡且成物。 ’將環氧化合 40% ' 3 0% ' 而調製著色感々質量份。之「Celloxide 「EHPE3150」色感光性樹脂〇N1 + n2 + n3 = 15 <Examples 2 to 5 > The ratio of the composition of the binder compound was changed to 2 〇 / / with respect to the total amount of the binder compound. The photosensitive resin composition was carried out in the same manner as in Example 1 except for 10%. In addition, the numerical value in Table 1 is a table <Example 6 > Except as shown in Table 1, except for 202iP" (manufactured by Daicel Chemical Industry Co., Ltd.) represented by the following formula (2), the remainder and the examples 丨The same is done to modulate the township and the object. 'The oxidized 40% '30%' is prepared to modulate the coloring sensation by mass. "Celloxide "EHPE3150" color photosensitive resin 〇

，將環氧化合 40% > 3 0% ' 31 201232176 20%、1 〇%以外，其餘與實摊光性樹脂組成物。另外，表其餘與實施例6同樣地進行而調製著色感。另外’表1中的數值是表示質量份。 <實施例11 > 除了如表1所示，使用下述式（3)所示之「CeU〇xide 2081」（DaiCel化學工業公司製造）來取代「EHpE3i5〇」以外，其餘與實施例1同樣地進行而調製著色感光性樹脂組成物。The epoxidized 40% > 30% ' 31 201232176 20%, 1 〇%, and the other light-retardant resin composition. Further, the rest of the table was carried out in the same manner as in Example 6 to prepare a coloring feeling. Further, the numerical values in Table 1 indicate the parts by mass. <Example 11> Except that as shown in Table 1, "CeU〇xide 2081" (manufactured by DaiCel Chemical Industry Co., Ltd.) represented by the following formula (3) was used instead of "EHpE3i5", and the same as Example 1 The colored photosensitive resin composition was prepared in the same manner.

<實施例12〜15> 除了將黏合劑化合物的組成變更如表1，將環氧化合物相對於黏合劑化合物之總量的比例設為4〇%、3〇%、 20%、1 〇%以外，其餘與實施例1丨同樣地進行而調製著色感光性樹脂組成物。另外’表1中的數值是表示質量份。〈實施例16〉除了如表2所示’使用下述式（4)所示之「CeU〇xide 2000」（Daicel化學工業公司製造）來取代γΕΗΡΕ315〇」以外’其餘與實施例1同樣地進行而調製著色感光性樹脂組成物。<Examples 12 to 15> The ratio of the epoxy compound to the total amount of the binder compound was set to 4%, 3%, 20%, 1%, except that the composition of the binder compound was changed as shown in Table 1. In the same manner as in Example 1 except that the coloring photosensitive resin composition was prepared. Further, the numerical values in Table 1 indicate the parts by mass. (Example 16) The same procedure as in Example 1 was carried out except that "CeU〇xide 2000" (manufactured by Daicel Chemical Industry Co., Ltd.) shown in the following formula (4) was used instead of γΕΗΡΕ315〇. Further, a coloring photosensitive resin composition was prepared.

32 201232176 〈實施例1 7〜2 0 > 除了將黏合劑化合物的組成變更如纟2，冑環氧化合物相對於黏合劑化合物之總量的比例設為4〇%、“％、 20 /〇、1 〇 /〇以外，其餘與實施例丨6同樣地進行而調製著色感光性樹脂組成物。另外，表2中的數值是表示質量份。〈實施例2 1 > 除了如表2所示，使用下述式（5)所示之「Cell〇xide 3_」（Daieel化學工業公司製造）來取代「EHpE3i5〇」以外’其餘與實施们同樣地進行而調製著色感光性樹脂組成物。32 201232176 <Example 1 7 to 2 0 > In addition to changing the composition of the binder compound such as 纟2, the ratio of the oxime epoxy compound to the total amount of the binder compound was set to 4% by weight, "%, 20 / 〇 In the same manner as in Example 丨6, the coloring photosensitive resin composition was prepared in the same manner as in Example 丨6. The numerical values in Table 2 indicate the parts by mass. <Example 2 1 > In the same manner as in the "EHpE3i5", the "Cell〇xide 3_" (manufactured by Daieel Chemical Industry Co., Ltd.), which is represented by the following formula (5), was used to prepare a colored photosensitive resin composition.

<貫施例2 2〜2 5 > 除了將黏合劑化合物的組成變更如表2，將環氧化合物相對於黏合劑化合物之總量的比例設為4〇%、3〇〇/。、 2〇°/°、1 〇%以外，其餘與實施例2 1同樣地進行而調製著色感光性樹脂組成物。另外，表2中的數值是表示質量份。 <比較例1 > 除了將黏合劑化合物的組成變更如表2，在黏合劑化 σ干不含環氧化合物以外，其餘與實施例1同樣地進行而調製著色感光性樹脂組成物。另外’表2中的數值是表 33 201232176 示質量份。 <評估> [耐藥品性之評估] 使用旋轉塗佈器（TR2 5000 :東京應化工業公司製造）將實施例1〜25、比較例1中所調製的著色感光性樹脂組成物塗佈於玻璃基板（Corning公司製造，Ε2Κ玻璃）上，以90C乾無120秒’而形成膜厚為1·8μιη的塗膜。接著，使用鏡投射對準裝置（Mirror Projection Alignei·) (TME-150RTO : TOPCON公司製造），對此塗膜照射紫外線（波長365 nm ’照射量50 mJ )。然後，以循環式烤箱在 230°C進行曝光後烤20分鐘，而獲得硬化膜。將形成有此硬化膜的玻璃基板在40 〇c之蝕刻液 (H3P04/CH3C00H/HN03/H20= 65/3/12/22 )中浸潰 1 分鐘，經水洗之後’藉由空氣吹洗（air bi〇w)來進行除水。並且，將形成有硬化膜的玻璃基板在6(rc之剝離液（DMS〇/ 單乙醇胺= 30/70 )中浸潰i分鐘，經水洗之後，藉由空氣吹洗來進行除水。<Example 2 2 to 2 5 > The ratio of the epoxide compound to the total amount of the binder compound was set to 4% by weight, 3 〇〇/, except that the composition of the binder compound was changed as shown in Table 2. In the same manner as in Example 21, except that 2 〇 ° / ° and 1 〇%, the coloring photosensitive resin composition was prepared. In addition, the numerical value in Table 2 is a mass part. <Comparative Example 1> The coloring photosensitive resin composition was prepared in the same manner as in Example 1 except that the composition of the binder compound was changed as shown in Table 2, and the epoxy resin was not contained in the binder σ dry. In addition, the values in Table 2 are the mass parts shown in Table 33 201232176. <Evaluation> [Evaluation of Chemical Resistance] Using a spin coater (TR2 5000: manufactured by Tokyo Ohka Kogyo Co., Ltd.) The colored photosensitive resin compositions prepared in Examples 1 to 25 and Comparative Example 1 were coated. A coating film having a film thickness of 1.8 μm was formed on a glass substrate (manufactured by Corning Co., Ltd., Ε2 Κ glass) at 90 C for 120 seconds. Next, using a mirror projection alignment device (Mirror Projection Alignei) (TME-150RTO: manufactured by TOPCON Co., Ltd.), the coating film was irradiated with ultraviolet rays (wavelength 365 nm' irradiation amount: 50 mJ). Then, it was baked in a circulating oven at 230 ° C for 20 minutes to obtain a cured film. The glass substrate on which the cured film was formed was immersed in an etching solution (H3P04/CH3C00H/HN03/H20=65/3/12/22) of 40 〇c for 1 minute, and after being washed with water, 'air was purged (air) Bi〇w) to remove water. Further, the glass substrate on which the cured film was formed was immersed in 6 (rMS 〇/monoethanolamine = 30/70) for 1 minute, washed with water, and then deaerated by air purge.

之後，為了評估硬化膜的耐藥品性，而進行了十字切割試驗（cross hatch test)。具體而言，是依照IS〇24〇9( ASTM 〇-3359 )’以2.〇11^之間隔，將硬化膜交叉切割（(^〇^(^) 成100格（縱松各切割u次），將黏著膠帶強力地黏貼於交叉切割處，之後急速地剝去黏著膠帶，並調查有無硬化膜之剝離，以等級GB至等級5B為止的6階段來評估。將 34 201232176 結果顯示於下述表1、2。 [耐候性之評估] 使用實施例1〜25、比較例1 =, 脂組成物，與上述[耐藥品性之*所調製的著色感光性樹基板上形成硬化膜。子估]同樣地進行而在玻璃試驗機公司製造）來實施耐候 ‘（Xe_ X75: Suh 射試驗1次與黑暗試驗 '驗。具體而t ’是將照循環（20。小時)，上驗二環（8小時)，進行25 丨。〇_、有uv，…Γ 條件是溫度⑽、濕度 ⑽刪、無UV。〜暗試驗的條件是溫度抓、濕度而與上述[耐藥品性果顯示於下述表1、馮了怦估硬化膜之耐候之評估]同樣地進行十字切割試驗。表2 〇 35 201232176 [表i]Thereafter, in order to evaluate the chemical resistance of the cured film, a cross hatch test was performed. Specifically, according to IS〇24〇9 ( ASTM 〇-3359 )', the hardened film is cross-cut at intervals of 2.〇11^ ((^〇^(^) into 100 grids) ), the adhesive tape is strongly adhered to the cross-cutting place, and then the adhesive tape is quickly peeled off, and the peeling of the cured film is investigated, and the evaluation is performed in six stages from the grade GB to the grade 5B. The results of 34 201232176 are shown below. Tables 1 and 2. [Evaluation of weather resistance] Using Examples 1 to 25, Comparative Example 1 =, a lipid composition, and a cured film formed on the colored photosensitive tree substrate prepared by the above [Chemical Resistance*]. In the same manner, it was carried out in Glass Testing Machine Co., Ltd. to carry out weather resistance '(Xe_ X75: Suh shot test 1 time and dark test). Specifically, t ' is the cycle (20 hours), and the second ring ( 8 hours), carry out 25 丨. 〇 _, uv, ... Γ conditions are temperature (10), humidity (10) deleted, no UV. ~ dark test conditions are temperature scratch, humidity and the above [resistance of drug resistance is shown below Table 1. Feng's evaluation of the weathering resistance of the cured film] The same cross-cut test was carried out. Table 2 〇 35 201232176 [Table i]

黏合劑化合物環氧化合物之比例十字切割試驗耐藥品性耐候性實施例1 樹脂A1 『951 樹脂A2 『601 EHPE3150 [155] 50% 5B 5B 實施例2 樹脂A1 『1261 樹脂A2 [601 EHPE3150 [124] 40% 5B 5B 實施例3 樹脂A1 『1571 樹脂A2 _ EHPE3150 [93] 30% 5B 3B 實施例4 樹脂A1 『1881 樹脂A2 [601 EHPE3150 [62] 20% 5B 1B 實施例5 樹脂A1 「2191 樹脂A2 _ EHPE3150 [31] 10% 3B 0B 實施例6 樹脂A1 [951 樹脂A2 Γ601 Celloxide2021P [155] 50% 5B 5B 實施例7 樹脂A1 Π261 樹脂A2 [601 Celloxide 202 IP [124] 40% 5B 3B 實施例8 樹脂A1 『1571 樹脂A2 『601 Celloxide 202 IP [93] 30% 5B 1B 實施例9 樹脂A1 Γ1Β81 樹脂A2 『601 Celloxide 202 IP [62] 20% 3B 0B 實施例10 樹脂A1 『2191 樹脂A2 _ Celloxide 202 IP [31] 10% 0B 0B 實施例11 樹脂A1 『951 樹脂A2 『601 Celloxide 2081 [155] 50% 5B 5B 實施例12 樹脂A1 『1261 樹脂A2 _ Celloxide 2081 [124] 40% 5B 3B 實施例13 樹脂A1 [1571 樹脂A2 [601 Celloxide 2081 [93] 30% 5B 1B 實施例14 樹脂A1 『關樹脂A2 F601 Celloxide 2081 [62] 20% 3B 0B 實施例15 樹脂A1 P191 樹脂A2 『601 Celloxide 2081 [31] 10% 0B 0B 36 201232176 [表2]Adhesive compound epoxy compound ratio Cross-cut test Chemical resistance Weatherability Example 1 Resin A1 "951 Resin A2 "601 EHPE3150 [155] 50% 5B 5B Example 2 Resin A1 "1261 Resin A2 [601 EHPE3150 [124] 40% 5B 5B Example 3 Resin A1 "1571 Resin A2_EHPE3150 [93] 30% 5B 3B Example 4 Resin A1 "1881 Resin A2 [601 EHPE3150 [62] 20% 5B 1B Example 5 Resin A1 "2191 Resin A2 _ EHPE3150 [31] 10% 3B 0B Example 6 Resin A1 [951 Resin A2 Γ 601 Celloxide 2021P [155] 50% 5B 5B Example 7 Resin A1 Π261 Resin A2 [601 Celloxide 202 IP [124] 40% 5B 3B Example 8 Resin A1 "1571 Resin A2 "601 Celloxide 202 IP [93] 30% 5B 1B Example 9 Resin A1 Γ1Β81 Resin A2 "601 Celloxide 202 IP [62] 20% 3B 0B Example 10 Resin A1 "2191 Resin A2 _ Celloxide 202 IP [31] 10% 0B 0B Example 11 Resin A1 "951 Resin A2 "601 Celloxide 2081 [155] 50% 5B 5B Example 12 Resin A1 "1261 Resin A2 _ Celloxide 2081 [124] 40% 5B 3B Example 13 Resin A1 [1571 Resin A2 [601 Celloxide 2081 [9] 3] 30% 5B 1B Example 14 Resin A1 "Resin A2 F601 Celloxide 2081 [62] 20% 3B 0B Example 15 Resin A1 P191 Resin A2 "601 Celloxide 2081 [31] 10% 0B 0B 36 201232176 [Table 2]

黏合劑化合物環氧化合物之比例十字切割試驗耐藥品性财候性實施例16 樹脂A1 Γ951 樹脂A2 _ Celloxide 2000 [155] 50% 5B 5B 實施例17 樹脂A1 『1261 樹脂A2 _ Celloxide 2000 [124] 40% 5B 3B 實施例18 樹脂A1 『1571 樹脂A2 _ Celloxide 2000 [93] 30% 5B 1B 實施例19 樹脂A1 Γ1881 樹脂A2 [6〇1 Celloxide 2000 [62] 20% 3B 0B 實施例20 樹脂A1 『2191 樹脂A2 _ Celloxide 2000 [31] 10% 0B 0B 實施例21 樹脂A1 『951 樹脂A2 『601 Celloxide 3000 [155] 50% 5B 5B 實施例22 樹脂A1 「1261 樹脂A2 Γ601 Celloxide 3000 [124] 40% 5B 3B 實施例23 樹脂A1 『1571 樹脂A2 『601 Celloxide 3000 [93] 30% 5B 1B 實施例24 樹脂A1 [1881 樹脂A2 [6〇1 Celloxide 3000 [62] 20% 3B 0B 實施例25 樹脂A1 [2191 樹脂A2 [601 Celloxide 3000 pi] 10% 0B 0B 比較例1 樹脂A1 「2501 樹脂A2 [601 — 0% 無法評估 0B 由表1、表2可知，當使用含有環氧化合物來作為黏合劑化合物之實施例1〜25的著色感光性樹脂組成物時，在耐藥品性試驗後的十字切割試驗及耐候性試驗後的十字切割試驗中，均顯示了等級0B以上的密著性。其中，當環氧化合物相對於黏合劑化合物之總量的比例是4 0〜5 0 % 時，在耐藥品性試驗後的十字切割試驗中顯示等級5B以上的密著性，且在耐候性試驗後的十字切割試驗中顯示等級 3B以上的密著性，特別是使用EHPE3 1 50作為環氧化合物的實施例1、2，在耐藥品性試驗後的十字切割試驗及耐候性試驗後的十字切割試驗中，均顯示了等級5B的密著性。相對於此，當使用不含有環氧化合物來作為黏合劑化 37 201232176 合物的比較例1的著色感光性樹脂組成物時，在耐候性試驗後的十字切割試驗中雖然顯示等級〇B的密著性，彳曰a耐藥品性顯著低劣’因此塗膜在蝕刻處理中或剝離處理中發生制離’而無法實施耐藥品性試驗後的+ 町十予切割試驗。【圖式簡單說明】無【主要元件符號說明】無 38Adhesive Compound Epoxy Compound Ratio Cross Cutting Test Chemical Resistance Financial Example 16 Resin A1 Γ951 Resin A2 _ Celloxide 2000 [155] 50% 5B 5B Example 17 Resin A1 "1261 Resin A2 _ Celloxide 2000 [124] 40% 5B 3B Example 18 Resin A1 "1571 Resin A2_ Celloxide 2000 [93] 30% 5B 1B Example 19 Resin A1 Γ 1881 Resin A2 [6〇1 Celloxide 2000 [62] 20% 3B 0B Example 20 Resin A1 " 2191 Resin A2 _ Celloxide 2000 [31] 10% 0B 0B Example 21 Resin A1 "951 Resin A2 "601 Celloxide 3000 [155] 50% 5B 5B Example 22 Resin A1 "1261 Resin A2 Γ 601 Celloxide 3000 [124] 40% 5B 3B Example 23 Resin A1 "1571 Resin A2 "601 Celloxide 3000 [93] 30% 5B 1B Example 24 Resin A1 [1881 Resin A2 [6〇1 Celloxide 3000 [62] 20% 3B 0B Example 25 Resin A1 [ 2191 Resin A2 [601 Celloxide 3000 pi] 10% 0B 0B Comparative Example 1 Resin A1 "2501 Resin A2 [601 - 0% Unevaluable 0B As can be seen from Tables 1 and 2, when an epoxy compound is used as a binder compound Color sensitization of Examples 1 to 25 In the case of the resin composition, in the cross-cut test after the chemical resistance test and the cross-cut test after the weather resistance test, the adhesion of the grade 0B or more was exhibited. Among them, when the epoxy compound is relative to the binder compound When the ratio of the total amount is 40 to 50%, the adhesion of the grade 5B or more is shown in the cross-cut test after the chemical resistance test, and the density of the grade 3B or more is displayed in the cross-cut test after the weather resistance test. In particular, in Examples 1 and 2 in which EHPE 3 150 was used as the epoxy compound, the adhesion of the grade 5B was exhibited in the cross-cut test after the chemical resistance test and the cross-cut test after the weather resistance test. On the other hand, when the colored photosensitive resin composition of Comparative Example 1 containing no epoxy compound as the adhesive agent 37 201232176 was used, the grade 〇B was displayed in the cross-cut test after the weather resistance test. Adhesion, 彳曰a chemical resistance is significantly inferior 'so the coating film is detached during etching or peeling treatment' and can not be subjected to the chemical resistance test Experience. [Simple diagram description] None [Main component symbol description] None 38

Claims

201232176 VII. Patent application scope: 1. A coloring photosensitive resin composition for a touch panel, which comprises (Α) a binder compound, (Β) a photopolymerizable monomer, (c) a photopolymerization initiator, and D) A colorant, and the aforementioned (A) binder compound contains an epoxy compound. 2. The coloring photosensitive resin composition for a touch panel according to the invention, wherein the epoxy compound is an epoxy compound represented by the following formula (A), (A) ni-Η Ral '(A)n2 Η (Α-1) -Η, (8) nk_ [wherein Ral is the residue remaining after removing the active hydrogen group from the organic compound having k active ϋ 11 &11; .....nk respectively represent an integer of 〇~100, the sum of which is 10 u 'k represents an integer of 1 to 1〇〇; A is an oxy ring having a substituent B, a hexane skeleton, or The oxetene skeleton of the substituent B is a formula

Β (Α-2)

Β (Α-3) \ Ρ— , .0—fly 1 Α-2) or (Α-3) means, where Β is a group independently represented, C^~7CH2 —CH==CH2 Μ$ formula (Α~4), formula (Α-5) or formula (Α-6) ο (Α-4) (Α-5) CHlOH 2 2 a HR CIO -6) (A- 39 201232176 only, The epoxy compound contains one or more groups represented by the above formula (A-4); and Ra2 represents an alkyl group, an alkylcarbonyl group, or an arylcarbonyl group)]. 3. The coloring photosensitive tree θ composition for a touch panel according to the first aspect of the invention, wherein the ratio of the epoxy compound is 40 to 60 mass with respect to the total amount of the component (A). %. 4. The colored photosensitive resin composition for a touch panel according to claim 1, wherein the (D) colorant is a black pigment. A touch panel formed of a colored photosensitive resin composition for a touch panel according to any one of claims 1 to 4, wherein the touch panel is provided with a hardened resin pattern. A display device comprising the touch panel of claim 5 of the patent application. 40 201232176 IV. Designated representative map: (1) The representative representative of the case is: None. (2) A brief description of the symbol of the representative figure: None. 5. If there is a chemical formula in this case, please disclose the chemical formula that best shows the characteristics of the invention: None 2