TW201219514A - Composition for heat-curable conductive coatings, optical film and protective film - Google Patents

Abstract

The purpose of the invention is to provide a composition for heat-curable conductive coatings that is able to form, at low temperature and in short times, conductive films that are simultaneously scratch resistant, solvent resistant, and printable and that adhere tightly to printed characters. This composition for heat-curable conductive coatings is characterized in comprising (a) a conductive polymer, (b) a melamine resin derivative, (c) a sulfonic acid curing catalyst, (d) a silicone with both ends modified with a polyether, (e) a conductivity-improving agent, and (f) a solvent or dispersion medium.

Description

[Technical Field] The present invention relates to a thermosetting conductive coating composition, an optical film and a protective film obtained by using the thermosetting conductive coating composition. 0 [Prior Art] An optical film constituting a flat panel of a liquid crystal television, a plasma television, an electroluminescence display, a solar cell, or the like may be provided with an antistatic function coating (antistatic layer) in order to eliminate malfunction such as electrostatic damage. . For example, in the manufacturing step or the transporting step of the flat panel display, in order to prevent damage to the surface of the earthproof panel, adhesion of dirt or dust, the surface of the flat panel is bonded to a protective film of the film. The protective film is provided with an adhesive layer on one side of a resin substrate such as ρΕτ, and the adhesive layer is attached to the display, and the user is prevented from being damaged by static electricity caused by peeling off the film. Electrical product, resin substrate -, adhesive: an antistatic layer is formed on the opposite side of the layer side. For the antistatic layer, in addition to the antistatic function, it is also resistant to scratches, and it is used to prevent adhesiveness during tailoring. When it is used, it is used to wipe off the adhered adhesive. The required solvent resistance λΐ b _# special & in order to print the batch number on the protective film. Further, "4, also requires the printing adhesiveness of the oily ink, etc.: the cost requirement is also improved, A coating of a coating that satisfies the above characteristics. A material coating material that forms such an antistatic layer. A conductive polymer-containing conductor 3 5 201219514

^ j % | not 53⁄4 sufficiency, one layer of coating is not required to satisfy the above. Patent Document 1 discloses a conductive polymer composition for forming an antistatic layer. The conductive polymer composition contains a composition of a polythiophene-based conductive polymer and a polyester binder, and can form an adhesive fatigue s々4 on a resin substrate by drying at about 10 minutes (r i minutes).士雨雨 a Because it is a solvent-drying type composition, scratch resistance and solvent resistance are insufficient, and an overcoat layer is laminated on the antistatic layer to have properties. Patent Document 2 discloses a conductive polymerization. And the water-soluble polyether is modified to take the composition of the oxygen, and it is revealed that the film having excellent lubricity can be formed by adding the polyether modified by the polyether in the side chain, but the scratch resistance and the resistance are not mentioned. Printability, conductive composition of polyfluorene modified with polyether modified by side chains

Patent Document 3 discloses that a composition composed of a resin having active hydrogen and a polyfluorene resin containing polyphosphoric acid, polyisocyanuric acid, and an antistatic agent can be used to form a coating layer. An antistatic layer having surface resistivity, solvent resistance, and scratch resistance 'printability. However, this composition is insufficient in terms of printing adhesion, and it is required to form an antistatic layer at 4 (TC ageing). 48 hours, the productivity is low, and it is not suitable for mass production. Patent Document 4 discloses a composition containing an organic siloxane having a reactive B group such as a hydroxyl group at the terminal, and reveals that a film formed using the composition is simultaneously realized. The antifouling property (higher contact angle to water) is compatible with the printing of a specific ink. However, the hardening of the composition needs to be 14 〇 <t 2 201219514 minutes, so the productivity is low, and it is not suitable. Mass production. Patent Document 1 discloses a composition containing a conductive polymer, a melamine resin, and an acid catalyst, and discloses that it can be used by using this composition. The film having an antistatic function, scratch resistance, solvent resistance, and antifouling property is formed at a low temperature of about 1 minute. However, the medium formed by using the δ metamaterial cannot simultaneously achieve printability and print adhesion. [Patent Document 1] Japanese Laid-Open Patent Publication No. JP-A No. Hei. [Patent Document 4] JP-A-2009-107804 [Patent Document 5] JP-A-2009- 138042 SUMMARY OF THE INVENTION As described above, the conductive composition previously proposed When a conductive film is formed by a ruthenium layer coating, it is not possible to form a conductive film having excellent scratch resistance, solvent resistance, printability, and print adhesion when formed under a low-temperature curing condition for a short period of time. Scratch, printing, and printing adhesion usually have a trade-off relationship, and it is difficult to satisfy both of them at the same time. The present inventors have devoted themselves to solving the problems of Shangcheng 4® as-r- and -jr, and found that they have been studied. : Contains conductive polymer (a), r: ¥羞松姓+ , —\虱amine resin derivative (b), sulfonic acid hardening catalyst (C), both ends of the poly-shocking modified poly-negative emulsion (d), conductivity enhancer (e), and Thermally hardening the solvent or the dispersion medium (f) to form a scratch-resistant conductive composition by a conductive film which is excellent in low-temperature properties, solvent resistance, printability, and printing density, and is excellent in printability. In the present invention, the thermosetting conductive coating composition of the present invention comprises: (a) a conductive polymer, (b) a melamine resin derivative, and (c) a sulfonic acid hardening catalyst, ( d) a two-end polyether modified polyfluorene oxide, (e) a conductivity enhancer, and (f) a solvent or dispersion medium. Further, in the heat-curable bud-forming composition of the present invention, it is preferable that the conductive polymer (a) has a repeating structure of the following formula (1). a compound of a polyoxynene or a poly (3,4-external dioxy porphin) and a dopant (dopant),

(wherein R1 and R2 independently of each other represent a hydrogen atom or an alkyl group of CM, or a substituted alkyl group of C _4 which may be substituted). Further, in the thermosetting conductive coating composition, the content of the melamine resin derivative (b) is preferably 150 to 750 parts by weight based on 100 parts by weight of the conductive polymer. Further, in the thermosetting conductive coating composition, it is preferred that the sulfonic acid curing catalyst (c) is an aromatic sulfonic acid, and the content thereof is 8 to 1 part by weight based on 1 part by weight of the melamine resin derivative. 40 parts by weight. 6 201219514 Further, in the thermosetting conductive coating composition, it is preferred that the content of the two-end polyether modified polyfluorene (d) is 10 to 60 parts by weight based on 100 parts by weight of the melamine resin derivative. Share. Further, in the above-mentioned thermosetting conductive coating composition, the conductive reinforcing agent (e;) is preferably a compound having at least one substituent selected from the group consisting of a mercapto group, a sulfo group and a hydroxyl group. It is preferable that the thermosetting conductive coating composition further contains (g) a water-soluble antioxidant, and the water-soluble antioxidant (g) is preferably ascorbic acid or erythorbic acid. It is preferable that the thermosetting conductive coating composition further contains (h) a frost wetness improving agent. It is preferable that the thermosetting conductive coating composition further contains (1) an antifoaming agent, and the antifoaming agent (i) is preferably a polyoxymethylene emulsion. The optical film of the present invention is composed of a substrate and a conductive film laminated on the substrate, and the conductive film is formed using the thermosetting conductive coating composition of the present invention. In the above-mentioned optical film, it is preferable that the conductive film is applied to the substrate by the thermosetting conductive coating composition, and dried and thermally cured at a temperature of 130 ° C or lower. And formed. Further, it is preferable that the calculated film thickness of the conductive film is less than 45 nm. The protective oxime of the present invention is composed of the optical film of the present invention. According to the thermosetting conductive coating composition of the present invention, it can be formed by heat treatment (drying, heat curing) at a low temperature for a short period of time.

S 7 201219514 Conductive film for printing and printing adhesion to trace and solvent resistance. In addition, by using the above-mentioned thermosetting conductive coating composition, it is possible to form a conductive film which satisfies both excellent scratch resistance and excellent printability and printing adhesion. Further, the optical film of the present invention is provided with a conductive film which is obtained by applying the thermosetting conductive coating composition of the present invention to a substrate and curing the conductive film, thereby having excellent conductivity. Moreover, it is excellent in scratch resistance, solvent resistance, printability, and printing adhesiveness. Further, the optical film of the present invention is extremely suitable as a protective film, and the protective film composed of the above optical film is also one of the inventions. [Embodiment] First, the thermosetting conductive coating composition of the present invention will be described. The thermosetting conductive coating composition (hereinafter also referred to simply as a conductive composition) of the present invention contains (a) a conductive polymer, (b) a melamine resin derivative, and (c) a sulfonic acid hardening catalyst. (d) a polyether modified polyfluorene at both ends, (e) a conductivity enhancer, and (f) a solvent or dispersion medium. Hereinafter, each formulation will be described in order. 1. Conductive polymer (a) The conductive polymer (a) is a formulation for imparting conductivity to a formed conductive film (coating layer). The conductive polymer may, for example, be a polystyrene, a polymer, a polyamine, a polyacetylene, a polystyrene, a polynaphthalene or the like, and a composite of the above and the like. 8 201219514 Among these, the car exchange # is a polythiophene-based conductive polymer composed of a polyphenol and a #hybrid < complex, as a polythiophene-based conductive polymer, more preferably poly (3, 4) a complex of a di-oxo-oxysole or a poly(3,4-extension dioxy porphin) and a dopant. The above poly(3,4-disalkoxythiophene) or poly(3,4-desanedioxythiophene)' is preferably a repeat represented by the following 戎Λ 4 + W Λ 心 式 Q) a cationic form of polythiophene composed of structural units,

(I 〇 , R R R R R R R R R R R 与 与 与 与 与 与 与 R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R Examples of the alkyl group include a methyl group, an ethyl group, a propyl group, an isopropyl group, a n-butyl group, an isobutyl group, a second butyl group, a third butyl group, etc. Further, R1 and R2 are formed by The substituted alkyl group of Ci 4 may, for example, be a methylene group, an ethyl group, a propyl group, a m-butylene group, a methyl group, a methyl group, a methyl group, a 1 Gan 1-methylethyl 1-ethyl ~ 1,2-extended ethyl, i-methyl, 3-propyl, 2-methyl-13-propyl, etc. Preferably, = base, ... Ethyl, ... extended propyl 'is especially good for ... extended ethyl. - There is a sufficiency of the base (four) pheno- especially good for poly (3,4-ethylene dioxy porphin). = poly (3,4 - The composite composed of acetyl dioxane and phenanthrene is excellent in addition to conductivity and transparency, and is excellent in chemical stability, and makes conductivity of 201219514 using the composite as a conductive polymer. The film has extremely stable conductivity independent of humidity and is extremely high Transparency. In addition, since the conductive tortoise containing the composite as a conductive polymer can form a film at a low temperature for a short period of time, it is also highly productive for producing an optical film such as a protective film which is mass-produced. The dopant constituting the above-mentioned polyphenylene-based conductive polymer is a polymer which forms a complex by escaping an epitaxial ion on a disk to form an ion, and which can stably disperse the polyphenanthrene in water. Examples of the dopant include a carboxylic acid polymer, such as 'polypropylene polybutadiac diacid, polymethyl methic acid, etc., and a continuous acid polymer (for example, m acid, polyethylene, Polyisoprene, etc.). The phthalic acid polymers and sulfonic acid polymers, Q cheeks, may also be ethylene carboxylic acid members and ethylene wheels and other polymerizable monomers, such as acrylic acid styrene, styrene, ethylene A copolymer of an aromatic acetyl compound such as naphthalene. Among them, polystyrenesulfonic acid is especially preferred. The above polystyrene sulfonic acid is preferably heavy and is 5 Å or less. More preferably, 4 〇〇〇〇 thousand knives ^ greater than, and live in the horse 400 〇〇 ~ 200000. If polystyrene is used outside this range, there is a polyporphyrin-based conductive compound: the dispersion stability in water is lowered. Further, the average molecular weight of the above poly σ is measured by gel permeation 3 ϋ γ ^ 蚀 喂 〜 ~ edge chromatography (GPC). . The content of the above conductive polymer is preferably used in the measurement. The weight of the conductive polymer is preferably 〇.01 to h2% by weight relative to the total conductivity group. More preferably 0.03~0.5 weight 10 201219514

2. Melamine resin derivative (b)

The above melamine resin derivative is represented by, for example, the following formula (I): 〇3 r.4

(wherein R3 to R8 represent H or CH2?r9, and r9 represents H or a burnt group). The melamine resin derivative in which the substituents R3 to R8 are each a hydrogen atom is an imide type melamine resin derivative; the melamine resin derivative in which the substituents R3 to rS are both CH2OH is a methyl type melamine resin derivative. The substituents R to R8 are all CH2〇R9, and R9 is a C1-alkyl substituted one, and one of the melamine resin derivatives is a fluorene-type melamine resin derivative. In addition, the two of the above three substituents are mixed in the structure of the molecule. 201219514 The melamine resin derivative is classified into an imidomethylol type, a methylol ether type and an imino ether type, all of which are mixed with the melamine resin. The derivative is an imidohydroxymethyl ether type. In the case where R3 to R8 represent CH2〇R9 and R9 is an alkyl group of Ci_4, the alkyl group of Ci-4 has a mercapto group, an ethyl group, a propyl group, a butyl group or the like, and in view of low-temperature curability, it is preferably methyl. The above melamine resin derivative may also be a polymer having a basic skeleton of the formula (II) and self-condensing. These melamine resin derivatives may be used singly or in combination of two or more. Among the melamine resin derivatives having the above structure, from the viewpoint of the stability of the conductive composition and the curability at low temperature, it is more preferably a perether-type trimeric oleylamine, and particularly preferably a sulphonic melamine in which R9 is a methyl group. . Further, in the case where the triazamine resin derivative is an oligomer, it is preferable to consider the pot life of the conductive composition (pot Hfe) to have a lower average degree of polymerization, and more preferably more than 1 · Not up to 1.8. _ Further, in the present specification, the application period of the so-called conductive composition is the appearance of the electrode 4, the appearance of the composition (coating solution), the appearance of the formed conductive I* film, Transparency, electrical conductivity, adhesion to the substrate f to the mark|±, only/mixture property, printability, printability, and the like can be sufficiently maintained after the preparation of the conductive composition (coating liquid) . In order to make the conductive film which is cured at a low temperature, the melamine resin (b) having the appearance of the film, the adhesion of the conductive permeable sub-substrate, and the solvent resistance is preferably 3 to the conductive polymer (a) The solid part by weight is 150 to 75 parts by weight. More preferably, it is 25 〇 to 45 〇 weight 12 201219514 parts 0 When the content exceeds 750 parts by weight, the conductivity of the film may be lowered, or the film may be whitened and the transparency may be lowered. Conversely, less than Μ. In the case of a weight fraction, it is difficult to impart sufficient solvent property to the film. 3. Sulfonic acid hardening catalyst (^) The above-mentioned acid-hardening catalyst (7) has a function of promoting crosslinking of the melamine resin derivative (b) on a substrate upon drying and hardening. Since the acid continued to exhibit acidity in the conductive composition, crosslinking of the trimeric amine resin derivative in the conductive composition is promoted, and the pot life of the coating liquid is shortened. Further, the rhein hardening catalyst also has a function of leveling the k-conductive composition on the substrate. Therefore, the above-mentioned acid-hardening catalyst is preferably a structure which promotes hard 2 on the substrate and maintains the leveling property of the conductive composition on the substrate and the pot life of the conductive composition. Examples of such a sulfonic acid hardening catalyst include sulphide or aromatic sulphonic acid = aliphatic acid, and examples thereof include: f acid, trimethyl benzoic acid, isovalerone acid, camphor 驮 驮Benzene, octanesulfonic acid, sulfonium sulfonate, hydrazine, hexadecyl sulfonic acid, and the like. Further, # Further, the above-mentioned aromatic sulfonic acid may, for example, be an acid-increasing, p-toluene (tetra)-isopropylbenzene (tetra), ten: silk phthalic acid, naphthonic acid, decylnaphthalenesulfonic acid or the like. Point and the application period of H (four) liquid and the view of the hardening property of low temperature and ^ is preferably the fang (four) rhyme, especially the ten: benzene continued acid. The content of the above-mentioned acid-hardening catalyst is preferably an upper limit relative to the trimerization

S 13 201219514 : The amine resin 4 is not 100 parts by weight of 4 parts by weight, more preferably 33 parts by weight. Further, the lower limit is preferably 8 parts by weight relative to the melamine resin derivative 100. The reason for the pot m is that if it is for this range, the melamine resin derivative can be hardened in a short period of time, and can be sufficiently maintained. The pot life of the cloth. On the other hand, when the content is more than 40 parts by weight on the right side, the application period of the coating liquid is likely to be maintained. On the other hand, if it is less than 8 parts by weight, the film formed by the deterioration of the conductivity of the conductive composition may be formed. The case of shrinkage can be seen in the case where there is a decrease in the solvent resistance of the film. 4. Both ends of the poly-modified poly (oxygen) (d) The two-end polyether modified polyfluorene (d) has a scratch resistance, a solvent, a printability, and a printing adhesion to the conductive film. effect. In particular, in the thermosetting conductive coating composition of the present invention, the both-end polyether modified polyfluorene oxide and other components are used in combination, and the conductive film formed can be simultaneously provided with scratch resistance and Printability and print adhesion. α * · π Κ ϊ ϊ , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , This effect cannot be enjoyed even with the use of side chain polyfluorene modified polychlorite. Moreover, 'this kind of insight is the newly discovered opinion of the inventor of the present case^> Further, the reason for using the two-end polyether to modify polyfluorene can enjoy the effect of the effect> can be considered as: (1) due to the change质聚石夕氧": The orientation of the surface of the film is improved, and the smoothness is excellent. As a result, the resistance is improved to 14 201219514, and (2) the adhesion of the ink is improved by the polyether chain at both ends. The printing property and the printing adhesion can be imparted to a high degree. Further, the solvent resistance is maintained even when the polyether is modified by the two-end polyether. The reason is considered to be that the polyether is modified by the two ends. Since the oxygen is uniformly oriented on the surface, the cross-linking of the melamine resin derivative is not hindered, so that the crosslinking density of the film is not lowered. The above-mentioned two-end polyether-modified polyfluorene oxide can be, for example, the following formula (III). Representation, R_CH3 'Si-ΟΙ ch3 CHg · Si-〇-in3 „ ch3 -Si—R10I ch3 (ID) (wherein R1G is a poly-base, which represents R (C2H4〇) aR12 composed of ethylene oxide, R11 (C3H6(7)bRl2 consisting of propylene oxide or such a mixture RM(C2H40)a(C3H60)bRi2. R" and R 2 in the polyether group independently represent an alkyl group or an alkylene group. Further, the polyether groups R10 at both ends of the above formula (ΠΙ) may be the same Further, the degree of polymerization (η) of the polyoxyalkylene is preferably 38 Å or less, preferably 45 to 23 Å. By formulating the polyoxy siloxane having the above polymerization degree, the formed conductive film can be imparted more. Further, in the above-mentioned conductive composition, the polymerization of the ether group contained in the r1〇 is maintained as long as the solubility of the both-end polyether-modified polyfluorene is maintained and the performance is required. The degree (a and b) is not particularly limited. 15 201219514 The skeleton of the above-mentioned polymerization group is oxidized ethylene oxide, propylene oxide, or a copolymer of ethylene oxide and propylene oxide. Among these, from the viewpoint of water solubility, Preferably, it is ethylene oxide, and in view of printability and printing adhesion, it is preferably propylene oxide or a copolymer of ethylene oxide and propylene oxide. As described above, polyether modified polyoxane is selected by selecting an optimum structure. , can reliably make the resistance to traces in the formed conductive film Both the printing property and the adhesiveness are coexisting. The two-end polyether modified polyfluorene-based oxygen contained in the conductive composition can provide scratch resistance and print and print density without losing solvent resistance. The excellent conductive film is preferably the above formula (called the one shown: the two ends of the structure are combined with the modified money. The above formula (ιπ) is expressed by the two ends of the poly-bonded polysulfide oxide alone. The use of 1#, can also be used together with two or more kinds of two ends of the polyether modified polyfluorene. The content of the polyphosphonium at the end of the 3rd and 2nd polycondensate is preferably the upper limit of the relative weight: 100 parts by weight of the amine resin derivative is parts by weight, more preferably 33 parts by weight! Further, the lower limit is preferably 1 part by weight relative to the melamine resin derivative (10). The reason for this is that, in the case of the film, scratch resistance, printability, and printing adhesion are obtained: the film formed at the same time has a content of more than 6 at the end of the polycondensation. In the case of serious injury, the solvent resistance of the formed film deteriorates. (5) Conductivity enhancer (e) The conductivity of the conductive film formed by the ^ ^ ^ ^ ^ ^ contained in the above conductive composition. K liter agent (〇 can improve shape 16 201219514 The above conductivity enhancer (e), for example, N-methyl amide, N, N-dimethylformamide, r-butyrolactone, n- Alkalamine compounds such as methyl oxabromone, ethylene glycol, -ethyl-d-glycol, propylene glycol, 1,3-ethylene glycol, M-butanediol, 15 pentylene glycol, 16-hexane Yeast, neopentyl glycol, catechol, cyclohexanediol, m-hexane dimethanol, glycerol, diethylene glycol monoethyl, internal glycol monomethyl (tetra) containing trans-based compounds; isophorone, Propylene carbonate, cyclohexanone, acetophenone, acetic acid, ethyl acetate, methyl 〇nh〇acetate, ethyi 〇nh〇f〇rmate, etc. a compound containing a group of compounds, a compound having a thiol group such as dimethyl sulfene, etc., etc., in the case of Hai et al., the pot life of the coating liquid or the hardening property at a low temperature, and the formation of a conductive film (four), ❹ From the viewpoints of properties, oxime, etc., it is preferably a stilbene compound, a thiol-containing compound, a thiol-containing compound, and more preferably N-methylpyrrolidone, dimethyl Further, the content of the above-mentioned conductivity improving agent is not particularly limited, but it is usually preferably contained in an amount of 〇.丨6〇% by weight in the conductive composition. 6. Solvent or dispersion The medium (f) is not particularly limited as long as it dissolves or disperses each component contained in the conductive composition, and examples thereof include water, an organic solvent, and the like. In the present invention, when a solvent or a component other than the solvent contained in the conductive composition is dissolved, it is called a solvent, and when at least one component constituting the composition is uniformly dispersed, it is called Is a dispersion medium. In the above conductive composition, the above melamine resin is derived

S 17 201219514 The shape of water insoluble in water ^ shape. In this case, when the solvent or water and the organic solvent are used in the case where the medium can be used, the mixture of the right m κ and the organic solvent, preferably an organic solvent containing at least the organic solvent, as long as Containing one kind of organic solvent containing water mixed with water, it can also be a mixture of low-hydrogen alcohols, and it is also used by alcohols with lower boiling points. The mixture of the solvent and the water is improved in volatility and is used for the inspection of the medium in the age of inspection, and it is advantageous to use the resin substrate in the case of dryness and heat hardening. ^11 organic solvent can help to improve the conditioning (4) 'so-called water-based thermosetting conductive coating composition, the solvent or dispersion of the right Μ knife-like" quality is only water or water and with A thermosetting conductive coating composition for a mixture of water mixtures; a thermosetting conductive coating composition for a bismuth-based thermosetting conductive coating, a thermosetting conductive coating for a solvent or a dispersion medium 3, a water-insoluble organic solvent The composition of the cloth. 6 - 1 · Organic solvent The organic solvent may be one which dissolves or disperses a component such as a melamine resin derivative which is dissolved in water. Examples of the organic solvent to be mixed with water include alcohols such as methanol, ethanol, 2-propanol and propanol; ethylene glycols such as ethylene glycol tetraethylene glycol; and ethyl alcohol monomethyl and hydrazine; a division of early methyl ether, diethylene glycol monomethyl ether diethylene glycol diethyl ether, diethylene glycol dimethyl ether and other glycol ethers; ethylene glycol monoethyl phthalic acid from the purpose, [B Glycol ether acetate such as diol monoethyl succinic acid S, diethylene glycol monobutyl ether acetate; propylene glycol such as propylene glycol, dipropylene glycol, tripropylene glycol; diol monomethyl (tetra), propylene glycol Ethyl ether, 201219514 monopropanol, ketone, dipropylene glycol monoethyl hydrazine, propylene glycol, dipropylene glycol, di-f-butyl ether, propylene glycol diethyl ether, dipropylene and other propylene glycol ethers; propylene glycol monomethyl methacrylate Known monoethyl ether acetate, dipropanol mouth, propylene glycol monoethyl hydrazine - propyl methacrylate, dipropylene glycol vinegar, etc. Mixtures, etc. acetonitrile, and the = as a hydrophobic organic solvent, for example, ethyl acetate, acetaminophen, ethyl lactate and the like, 2; fAr propyl propyl ether, diisobutyl ether and other cores, T-ethyl ethyl, methyl diisobutyl ketone and other oils such as aliphatic cigarettes; a mixture of 疋辛虎, etc. * - A special-purpose aromatic tobacco; and the organic solvent may be used singly or in combination of two or more. = The electrical component of the wire is a water-based conductive wire. The content of the organic solvent is preferably a portion. Preferably, it is 20 parts by weight with respect to water (10) parts by weight. The right side is less than 20 parts by weight, and the target household + one sugar component is dissolved and 戋 is not smeared in the form of a melamine resin derivative. When the film property is deteriorated and the performance is not exhibited (Jf^04), when the electrical composition is a solvent-based conductive composition, the content of the solvent is not limited. 6 - 2. Water-based conductive composition For example, distilled water, parent water exchange, and ion exchange distilled water can be used. Further, Ψ ^ AL· X The water also contains water contained in the water dispersion of the conductive material I and other components. The content is preferably greater than or equal to the total conductivity.

S 19 201219514 In the case of the above-mentioned conductive composition Λ# feng water-based conductive composition, the enthalpy of the conductive composition is preferably in the range of 〜 /L , 14 , and is preferably considered in consideration of low-temperature hardenability. For 〗 〖7, Yuu #丄佳 is 1.5~3. The pH value of the conductive composition may be adjusted by a positive value adjusting agent such as alkali. The pH adjusting agent may, for example, be an alkanolamine such as ammonia or an amine. Here, it is considered that the acid and salt are sometimes formed to reduce the hardening promoting effect of the trimeric amine resin derivative, and the higher the pH of the conductive composition is, the lower the hardening resistance of the low temperature is. However, since the stability or the pot life of the solution is improved by the self-crosslinking in the solution of the melamine (tetra) derivative, the addition amount of the pH adjuster may be appropriately determined. Further, the pH adjusting agent is an optional component of the conductive composition. Further, the conductive composition containing the components (a) to (7) as described above is particularly preferably used in the case where the pot life of the conductive composition is remarkably improved in the following cases. 15〇~75〇Replacement of the full ether type melamine resin derivative amine (IV) derivative 丨. . The parts by weight contain a part of aryl 2 = a % acid hardening catalyst (c), and 10 to 60 parts by weight of the melamine resin derivative ι 〇〇 contains 10 to 60 parts by weight of the two-end polyether modified polyfluorene (d), containing One or more compounds having a mercapto group, a trans group, and a confirming group are used as the conductivity enhancer (e). The components (a) to (f) described above are essential components in the thermosetting conductive coating composition of the present invention. Further, the thermosetting conductive coating composition of the present invention may contain a water-soluble antioxidant foaming agent (i) or the like as required by 20 201219514. (g), moisturizing enhancer (h), elimination 7. Water-soluble antioxidant (g) The conductive composition of the upper trace may also be combined with the right water-soluble antioxidant (g). j The water-soluble antioxidant (g) has a function of uniformly exhibiting a conductive property in the film when the conductive port is formed, and suppressing the exposure by exposure. The resistance caused by air rises. Further, the fat-soluble antioxidant cannot be uniformly present in the film, and the increase in electric resistance caused by exposure to air cannot be effectively suppressed. The water-soluble antioxidant may, for example, be a reducing or non-reducing water-soluble antioxidant. Examples of the above-mentioned water-soluble antioxidant having a reducing property include L-sputum I, sodium L-ascorbate, L-ascorbate, erythorbic acid, sodium ascorbate, and potassium gluconate. a compound in which hydroxy group is substituted with 酉曰%; monosaccharide or disaccharide such as maltose, lactose, cellobiose, xylose 'arabinose, grape#, fructose, galactose, mannose; catechin, rutin, arbutus Flavonoids, quercetin, flavonoids such as kaempferol; curcumin, rosmarinic acid, bleaching acid, 2,4,5-trihydroxybenzoic acid, etc. A compound having a phenolic hydroxyl group; a compound having a thiol group such as cysteine, glutathione, or pentaerythritol tetrakis(3-mercaptobutyrate). Examples of the non-reducing water-soluble antioxidant include a phenyl group, an acid, a streptozoic acid, a 2-basic biting, a phenyl salicylate, and a 2-hydroxy group. Dimethyl ketone -5 - continuous sodium sulphate absorption becomes oxidative

S 21 201219514 The ultraviolet compound of the reason ^ ^ . J # can be used alone or in combination of two or more. Among the water-cooling antioxidants such as Xuan, it is preferable that ascorbic acid and erythorbic acid are more preferably ascorbic acid. The reason is that the effect of suppressing the electric power caused by exposure to air and the transparency of the formed conductive film are excellent. The content of the above water-soluble antioxidant is not particularly limited, but the upper limit thereof is preferably 6 parts by weight', more preferably 40 parts by weight, based on the melamine resin-derived (9) parts by weight. On the other hand, the lower limit is preferably 9 parts by weight, more preferably 20 parts by weight. When the content exceeds 60 parts by weight, the solvent resistance of the formed conductive film is lowered. Conversely, if it is less than 9 parts by weight, the SR rise rate is sometimes increased by exposure to air. 8·Frost Humidity Enhancer (h) The above conductive composition may also contain a Confucian enhancer (1). The above-mentioned pan wetness improving agent (h) can improve the pan wetness of the substrate of the conductive composition and can improve the uniformity of the formed conductive film. " The above-mentioned wetness improving agent may, for example, be an acrylic copolymer or a polyoxyethylene fatty acid ester compound. Among these, an acrylic copolymer is preferred. The reason for this is that the conductive film is excellent in transparency, scratch resistance, and solvent resistance. The content of the solid content of the above-mentioned moisture-reducing agent is not particularly limited, but the upper limit thereof is preferably 70% by weight and more preferably 40 parts by weight based on 100 parts by weight of the melamine resin derivative. On the other hand, the lower limit thereof is preferably relative to 22 201219514 on the second: the amount of the murine amine resin derivative is 4 parts by weight. The above-mentioned cross-linked dense sound having a content of more than 70% by weight on the right side is degraded in the case where the melamine resin is degraded and the solvent resistance is deteriorated. If the knife is not knives, the film formability is not improved (υ 〒 职 职 不 不 不The above conductive composition may also contain an antifoaming agent for defoaming 杳丨 ", - Τ · hunting by the package: (:), which can effectively defoam and inhibit the blistering of the conductive composition. Examples of the agent include g. υ, etc. m... alcohol (p°lyaeetylene organically modified poly-stone oxy-oxygenation, etc.): the polydimethylene (four) house is dispersed in water by an emulsifier Among the emulsion methyl groups, the emulsion of the oxime is excellent in the defoaming property. The content of the terminal foaming agent is not particularly limited, but is preferably relative to the two masses. Oxygen (10) parts by weight is 30 parts by weight. When it exceeds η, the crosslinking density of the melamine resin derivative decreases and the agent property deteriorates. If it is not part by weight, the defoaming property is not caught and the foam is present. The case of the thermosetting conductive coating composition of the present invention, in addition to the above Other components may be contained as needed. 10 Other components - 1 - Adhesive resin The conductive composition may contain a binder resin in order to improve the film formability or printability of the formed conductive film. 201219514 In the conductive composition of the present invention, the self-crosslinking film of the melamine resin derivative has a binder function, but by adding a binder resin, there is a stepwise improvement in film formability, flexibility and adhesion of the film. In the case of the above-mentioned adhesive resin, for example, polyacetal, poly(methyl)acrylic acid s曰 polyamine oxime, polyacetic acid ethoxylate, and polypyrenequinone a homopolymer of ethylene ethoxide, polyamine, polyimine, polyvinyl alcohol, polyglycolic acid polyol, polyhydric alcohol, etc.; selected from styrene's vinylidene chloride, chloroethene and (a) The compound of the group consisting of alkyl acetophenate is a copolymer of a copolymerization component, etc. The content of the binder resin is not particularly limited, but is preferably 2 parts by weight based on 100 parts by weight of the melamine resin derivative. Weight by weight More preferably, it is 40 parts by weight or less. When the amount of the binder resin exceeds 2 parts by weight, the solvent resistance of the conductive film formed by the decrease in the crosslinking density of the melamine resin derivative may be deteriorated. The thermal hardening of the melamine resin derivative in the conductive composition is preferably a self-crosslinking reaction of the melamine resin derivative, because the conductive film formed is excellent in scratch resistance or solvent resistance, and the melamine resin is considered to be considered. The reason why the film formed by self-crosslinking of the derivative is excellent in scratch resistance or solvent resistance is that the crosslinking density is high. On the other hand, the melamine resin derivative may be reduced by the binder resin or (4) When the functional group reacts, it functions as a crosslinking agent for the binder = resin, but the melamine resin derivative functions as a crosslinking agent for the binder resin, and the film is resistant to scratch or resistance/valley. The self-crosslinking of the agent with the melamine resin derivative is lower than that of the 2012 20121414. The above conductive composition may also contain an interface activity 1 2. ~ 2. Surfactant In order to improve the leveling property, the agent. The above surfactants may, for example, be exemplified by a fluorenyl carboxylic acid, a perfluoroxanyl ethoxylated oxime oxime, a cerium surfactant, a polyoxyethylene alkyl benzoquinone, or a propylene oxide. Polyether compound such as 1w hole 1 匕 ethylene polymer; coconut oil fatty acid amine salt, rosin gum, etc. (4); t sesame oil sulfur type, dish vinegar, hospital ether sulfate, &; linoleic fatty acid g|, continuous acid vinegar, broken acid vinegar and other I compounds; alkyl aryl sulfonate amine salt, sulfosyl sulfonate sodium octanoate sodium sulfonate compounds; sodium lauryl phosphate, etc. Phosphate compound; decylamine compound such as coconut oil fatty acid ethanol decylamine; anionic surfactant, cationic surfactant, nonionic surfactant, hydrazine modified acrylic compound, and the like. The content of the surfactant is not particularly limited, but is preferably 1 part by weight or less based on 1 part by weight of the melamine resin derivative. When the amount is more than 100 parts by weight, the crosslinking property of the melamine resin derivative is lowered to deteriorate the solvent resistance of the conductive film formed. Further, 〇 - 3. decane coupling agent The conductive composition may contain a decane coupling agent in order to improve solvent resistance, printability, and printability of the conductive film. Examples of the above decane coupling agent include 3-glycidoxypropyltrimethoxydecane, 3-glycidoxypropylmercaptodimethoxydecane, and 2__(3,4-oxycyclohexyl). Ethyltrimethoxydecane, 3_mercaptotrimethoxysilane

25 S 201219514 and so on. 3 rye black is particularly limited, but if it is more than 1 〇〇 by weight based on the melamine resin derivative, there is one 〇〇 by weight or less. If the sub-linkage of the poly-moleamine resin derivative is reduced, the conductivity is formed by the conductive adenine + w and the electricity is kept! - The case where the solvent resistance of the green film deteriorates. 1 0 — 4 · Tackifier In order to increase the viscosity of the above-mentioned conductive composition, the top material may also contain a tackifier β electro-xistence to form the above-mentioned tackifier, for example, can be listed as a salt of alginic acid. Water-soluble: a saccharide such as a derivative, a bacterium, a carrageenan or a cellulose; the content of the above-mentioned tackifier is not particularly limited, but is preferably 100 parts by weight of a cyanoamine resin derivative. 100 parts by weight or less. In the case of 1 part by weight, a trimeric amine tree is present; the cross-linking density of the Japanese organism is lowered, and the solvent resistance of the conductive film formed is deteriorated. 1) - 5. Fine particle material In order to improve the smoothness or printability of the conductive film and to print the dense film, the conductive composition may also contain colloidal bismuth oxide, fluororesin fine particles, and two t mustard. Song A work a material. The content of the fine particle material such as the titanium oxide cerium fine metal particles is not particularly limited, but it is preferably 10,000 parts by weight or less based on the weight of the melamine resin derivative. When 婪 = (10) parts by weight, the solvent resistance of the conductive film formed by the decrease of the trimeric amine resin derivative may be deteriorated. - 26 201219514 1 6. 6. Organic carboxylic acid compound The electroconductive composition may contain an organic carboxylic acid having a carboxyl group in order to improve printability and print adhesion of the conductive film. Κ Organic carboxylic acids contain aliphatic and aromatic valences, polyvalent carboxy hydrazines, and functional groups such as hydroxyl groups or vinyl groups in the molecule. Examples of the above aliphatic acid include acetic acid, butyric acid, hexasic acid, simazine, acetoacetic acid, malonic acid, succinic acid, glutaric acid, adipic acid, butyl succinic acid, and cis. Butyric acid, malic acid, tartaric acid, citric acid, and the like. Further, examples of the above-mentioned "fragrance acid" include benzoic acid, salicylic acid, gallic acid: acid, phthalic acid, trimellitic acid, and tetrabenzoic acid. Next, the optical film of the present invention will be described. The optical film of the present invention is composed of a substrate and a film which is laminated on the substrate, and the conductive film is formed by using the composition for a thermosetting conductive coating of the present invention. The optical film is composed of a substrate and a conductive film laminated on the substrate. Examples of the substrate include a resin substrate and a glass substrate. Examples of the material resin of the above-mentioned secret fat base material include polyolefin resins such as polyethylene, polypropylene ethylene-vinyl acetate copolymer, ethylene monoacrylate copolymer, ion poly-sigma copolymer, and cycloolefin resin; Phenyl phthalate, polybutylene terephthalate, polycarbonate, polyoxyethylene, modified polystyrene, polyphenylene sulfide, etc.; nylon 6, nylon 6,6,

At ^, . 务 "Aromatic polyamine 0T6, semi-aromatic polyamine 6T66, semi-aromatic

S 27 201219514 Aromatic polyamide resin such as polyamide 9T; acrylic resin, polystyrene, acrylonitrile steareth copolymer, acrylonitrile butadiene copolymer, stupid ethylene copolymer, gas vinyl resin, triethyl Cellulose and the like. Further, the above substrate is preferably transparent (having a high light transmittance). Further, in the case of using the optical film as a protective film, it is preferable to use polyethylene terephthalate or triethylene terbene fiber from the viewpoint of processing and workability. Prime. The shape of the substrate is not particularly limited, and may be selected depending on the shape of the optical film. The film shape, the plate shape, and other desired shapes may be mentioned. Therefore, various substrates such as a film and a plate or a molded article can be used for the above substrate. Further, physical treatment such as corona treatment, flame treatment, or electro-hydraulic treatment may be applied to the surface of the substrate. The coating property of the conductive composition can be improved by applying such treatment. The conductive film is formed by using the conductive composition of the present invention, and is formed by applying the conductive composition to a substrate, drying it, and thermally curing the conductive composition. The method of applying the above-mentioned conductive composition to the above-mentioned substrate is not particularly limited, and can be appropriately selected from methods common in the field, and examples thereof include spin coating, gravure coating, bar coating, and dip coating. Coating methods such as curtain coating, die coating, and spray coating. Further, the conductive composition may be applied by a printing method such as screen printing or inkjet printing, letterpress printing, gravure printing or lithography. Further, when the conductive composition is applied, a coating liquid in which the conductive composition is previously diluted with an alcohol or the like may be prepared, and the coating liquid may be applied. 28 201219514 The thickness of the above-mentioned conductive film 1 is not particularly limited, and may be appropriately selected depending on the purpose. From the viewpoint of coating cost, it is preferred that the calculated film thickness after heat drying is 45 nm or less, more preferably 10 to 20 nm. Further, the right weight of the coating liquid and the specific gravity of the film after drying may be approximately 1 Å, and the calculated film thickness can be calculated according to the following calculation formula. Film thickness - concentration of coating liquid (%) + theoretical coating amount of 100X wire rod (β m) "System" Since the coating amount of the wire bar is less than the theoretical value, the actual film thickness is thinner than the calculated value. The conductive film has conductivity because it contains a conductive polymer, and its surface resistivity is preferably 104 to 1 ϋ 11 Ω/□. The reason for this is that if it has the surface resistivity in this range, the shell sufficiently satisfies the required characteristics as an antistatic layer. The conductive film is formed by heating the conductive composition applied to the substrate and evaporating the solvent or the dispersion medium while thermally hardening (drying, hardening). Here, the heating condition is preferably a condition of heating at a temperature of 13 or less (about 8 Torr to 13 (rc) for about 1 minute (3 Torr to 9 sec). The reason is: ^ The conductive composition of the invention The conductive film can be sufficiently formed under the above conditions, and the above conditions are conditions of low temperature and short time in the technical field of the present invention, so that productivity is also excellent. ^ Those who are insufficiently hardened under the conditions are coated with a roll. After the state of ... in 25 ° C ~ 60. Drying machine or storage after the curing ^ small g 29 201219514 hours ~ weeks. : Evaporation solvent or dispersion medium drying and thermal hardening using the usual air drying machine, Hot air dryer, infrared dryer, etc.: When drying and heating, it is necessary to use a dry method with a heating means: ::air dryer, infrared dryer, etc.) Also, as a heating means, in addition to the above dryers, It can also be used to take a & tooth 'JJ using a heating and pressing roller with a heating function, a press machine, etc.. As described above, the t conductive composition of the present invention is electrically polymerized 2, a melamine resin derivative, Sulfonic acid hardening catalyst, two ends : Polyoxane, conductivity enhancer, and solvent or dispersion medium as a must-- and further optionally contain water-soluble antioxidant 1 wetness enhancer, defoamer, binder resin, surfactant, decane coupling agent, Viscosity: Microparticle material, etc. - A composition composed of such a composition is usually separated from an acidic component by a melamine resin in order to prevent self-crosslinking in a solution of a melamine resin derivative. In addition, supply (herein, a component which shows an acidity may be a conductive polymer, a sulfonic acid hardening catalyst, etc.). Moreover, each component mentioned above is mix|blended at a predetermined ratio before use, and it is used by mixing all components. Further, when an acidic component is neutralized with an alkali or the like, even if all the components are supplied in a mixed state, storage stability can be maintained. Usually, the composition period and storage stability of the composition are used for the wounding. The coating liquid of the above-mentioned conductive composition is supplied in a state of 2 to 3 liquids in which the melamine resin derivative and the severe component are separated. From the viewpoint of cost 30 2012195 14 The components of the coating liquids may be sufficiently concentrated. The method for preparing the above-mentioned conductive composition (coating liquid) is omitted: each component is taught by a mechanical mixer or a magnetic mixer: clock face mixing Preparation. Here, the above-mentioned grant preferably lasts for about two: or the acid-hardening touch, so it is desirable to pre-recend the mixture to avoid the conductive polymer medium and the melamine resin derivative at a high concentration. First, a diluent such as an alcohol is added. The cookware contains a water-soluble conductive material, and the solution containing the organic solvent in the solution tray of the spun polymer is mixed at a high concentration, and the dispersion stability is lowered to agglomerate, and the pot life is reduced. In the case of directly mixing a melamine resin derivative with an acidic component, 'the self-crosslinking of melamine is easily carried out in a solution, so that the pot life of the conductive composition is shortened. Further, since the conductivity composition is also dependent on the temperature of the composition, it is preferably prepared by keeping the liquid temperature below 30t. The liquid temperature is preferably ～5°C~1 (TC. The above conductive composition of the fox is stable at room temperature of about 25t, but in the case of containing an inert component, sometimes the melamine resin derivative is self-crosslinked to the solution. The application period is deteriorated. Since the pot life depends on the temperature of the coating liquid, the application period can be improved by maintaining the temperature at a temperature of 20 C to 20 C. It can be preferably maintained at 5 〇C. ~10. (: The temperature is applied to the substrate. The lower the temperature is, the higher the pot life is, the more the water-based conductive composition

S 31 201219514 The composition of the temperature below -20 c may freeze. Preferably, the conductive composition is prepared by maintaining the temperature below 3 (TC) from the time of preparation, and more preferably at a temperature of from 5 ° C to 10 ° C. The optical film composed of the composition is used as the optical film. It is preferable to use an optical film having an antistatic layer for a liquid crystal display, a polarizing light, an electroluminescence display, a plasma display, an electronic color display, a solar cell, etc. The above optical film is particularly preferable as a film, and the present invention is The protective film composed of the optical film is also one of the inventions. Further, in the case of the protective film, the substrate is preferably polyethylene terephthalate in terms of workability, hardness or transparency. [Examples] Hereinafter, the present invention will be described by way of examples, but the present invention is not limited to the examples. (Examples 1 to 27 and Comparative Examples 1 to 9) The components shown in Table 1 ( The raw materials are added to the solvent or the dispersion medium one by one while stirring. It is confirmed that the added components are dissolved or uniformly dispersed, and then the next component is added, and all the components are added, followed by stirring for 5 minutes to prepare a solution or dispersion state heat. Hardened type A composition for electrical coating. Thereafter, the composition was diluted to 6 times (1:5 by weight) with 80% ethanol to prepare a coating liquid. Immediately after preparation of the coating liquid, No. 4 The wire rod (wet film thickness 9 v claw) was applied to a substrate composed of a polyethylene terephthalate film (Lumirror T_60 (trade name) manufactured by T〇ray Co., Ltd.), and a hot air dryer was used. The film was dried and thermally cured at 130 ° C for 1 minute to form a conductive film. 32 201219514 Further, in the evaluation of the pot life, conductivity was prepared in the same manner after 24 hours from preparation of the thermosetting conductive coating composition. (Example 28) In the same manner as in Examples 1 to 27, each component (using raw material) shown in Table 2 was added while stirring on the surface to prepare a thermosetting conductive coating composition. Thereafter, the composition was prepared by diluting the composition to 4 times (1:3, by weight) with 80% ethanol. Immediately after the preparation of the coating liquid, a wire rod of No. 4 (wet film thickness of 9 μm) was used. ) coated with a polyethylene terephthalate film (Lumirror T-60 (trade name) manufactured by T〇ray Co., Ltd.) On the material, the hot air dryer was used for drying at 130 ° C for 1 minute to form a conductive film. The evaluation of the pot life was carried out 24 hours after the preparation of the thermosetting conductive coating composition. A conductive film was produced in the same manner. Further, the conductive film was cut and observed, and the results are shown in Fig. 1. Fig. 1 shows the conductive film produced in Example 28 at a magnification of 10,000 times. After the filming, the image is observed. In the figure, 1 is a conductive film, 2 is a PET film, and a scale of 115 nm in length is shown in the lower right corner of the figure.

Ll conductive polymer (a) An aqueous dispersion containing a conductive material, and an aqueous dispersion of a conductive polymer composed of a composite of poly(3,4-ethylenedioxythiophene) and polystyrene. That is, Clevios P (trade name) manufactured by H.c. Starck Co., Ltd. (1_3 wt% poly(3,4-ethylenedioxythiophene)/polystyrenesulfonic acid (weight average)

S 33 201219514 sub-quant = 15000) The composite dispersion aqueous solution, water 98.7 wt. /. ). 1.2 Melamine resin derivative (b) Melamine resin derivative using NIKALAC MW-390 manufactured by NIPPON CARBIDE Industrial Co., Ltd. (per ether type, R9 in formula (π) is methyl 'degree of polymerization: 1.00), NIKALAC MS - 11 (After the sulfhydryl type, 6〇% by weight of the product 'R9 in the formula (II) is a hydrogen atom, the degree of polymerization: 18 〇) and Cymel 300 manufactured by Nippon Sytecs Industry Nihon Cytec Industries (all ether type, formula (II) R9 is a methyl group, a degree of polymerization: 1.35), Cymel 301 (a full ether type, R9 in the formula (η) is a methyl group, and a degree of polymerization: 1.40) (the above names are all trade names). 1.3 Sulfonic acid hardening catalyst (〇) Sulfonic acid hardening catalyst, Taycat® xT-5 (trade name) manufactured by Tayca Co., Ltd. (molecular weight 187_2; compound name: cumenesulfonic acid; the following Q is QS) NE〇pELEX GS (trade name) manufactured by Kao Corporation (molecular weight 326.8; compound name: dodecylbenzenesulfonic acid; hereinafter referred to as dbs). Further, in one of the comparative examples, nitric acid (molecular weight 63 〇 1 ; 6 〇 wt% product) manufactured by Wako Pure Chemical Industries Co., Ltd. was diluted to 2% by weight as an acid catalyst. 1.4 Polyether modified polyfluorene (d) Both ends of the polycondensate modified polysulfide oxygen, using T〇ray. D〇w匸 price to call the company's 8G29 additive (trade name), Yurongshe Chemicals #公司的聚流流 KL- 402 (trade name), or BYK 378 (trade name) manufactured by BYK. The σ 卩 ' 较 作为 作为 作为 作为 作为 作为 作为 作为 作为 作为 作为 作为 作为 作为 作为 作为 作为 作为 作为 作为 作为 作为 作为 作为 作为 作为 作为 作为 作为 作为 作为 作为 作为 作为 作为 作为 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 348 2012 2012 2012 348 — 307 (trade name), or YF-3842 (trade name) manufactured by Momentive Performance Materials. 1.5 Water-Soluble Antioxidant (g) Water-soluble antioxidant, using ascorbic acid or isoascorbic acid manufactured by Wako Pure Chemical Industries, Ltd. The organic/treat agent can be used as an anti-emulsifier for cereals, and DRYMIX FS-20 (trade name) (main component: vitamin E) manufactured by Riken Vitamin Co., Ltd. is also used. L6 conductivity enhancer (e) Conductivity enhancer, using the N-曱 base ratio manufactured by Wako Pure Chemical Industries, Ltd. Each of the ketones (hereinafter referred to as NMP), dimethyl sulfite (hereinafter referred to as DMSO), or ethylene glycol (hereinafter referred to as EG), and N-methylformamide (hereinafter referred to as NMF). Industrial 7 Organic Solvent (f) Organic 'Valley, using grade 1 ethanol manufactured by Wako Pure Chemical Industries, Ltd. Ι·8 Water (f) The majority of water K is a water-dispersion of conductive polymer Clevios P. 7 . The newly added water uses pure water treated by ion exchange. The newly added water in the water system described in 1 2 . 〉Humidity enhancer (h) σ name), “Life enhancer, BYK—38〇N (commercial name: acrylic copolymer) manufactured by BYK. ^10 defoamer (i)

S 35 201219514 Defoamer, using ANTIFOAM 013A (trade name) manufactured by Toray Corning Co., Ltd. (compound name: polydimethyl oxime emulsion, hereinafter referred to as 〇 13 A). I · 11 other additives Other additives 'Use Momentive as a decane coupling agent ·

SIRQUEST A - 189 (trade name) manufactured by Performance. Materials (Compound name: 3 - Mercaptopropyl triethoxy sulphur), Snowtex 〇xs (trade name) manufactured by 曰 化学 化工Name: Colloidal silica dioxide aqueous dispersion), Trimellitic Acid (trade name) manufactured by Mitsubishi Gas Chemical Co., Ltd., organic acid retardant. 36 201219514 φ peach: time 22.80 1 22.30 | | 22.40 | | 23.20 1 I 18.30 I | 22.22 I 1 22.22 1 1 22.22 1 ί 22.22 | • 22.22 I : 22.40 I | 22.40 | 1 22.22 I | 22.22 | 1 1 22.52 I | 21.78 | 1 21.30 I 1 20.72 I 1 22.25 I 1 22.00 1 I 22.10 1 1 22.15 1 I 22.25 II 22.22 II 22.37 I 1 22.22 I 1 22.02 II 22.12 II 22.32 II 22.22 II 22.22 II 22.72 II 22.22 I Ι 22.22 Ι | 22.21 | 1 Organic 剤 1 sss § s § § ss S 8 s 8 SS s SS s 8 ss S sgsss 8 SS 1 type | 1 Ethanol | ^ 1 1 Ethanol 1 1 Ethanol | 1 ^ 1 1 ^ 1 1 ^ 1 1 Ethanol 1 1 ^ 1 - Ethanol 1 Ethanol 1 ^ 1 1 ^ | 1 ^ | I Ethanol 1 ^ 1 ϋΙ 1 Ethanol 1 1 Ethanol l 1 ^ \ 1 Ethanol 1 1 ^ Ethanol 1 1 Ethanol 1 | Ethanol I ^ 1 Ethanol 1 Ethanol" ^ I 1 Ethyl 1 nl 1 Ethanol 1 - B-Alcohol 1 Ethanol 1 1 Ethanol I Defoamer 1 Μ 1 1 1 1 1 1 1 1 1 II 1 1 1 1 1 I 1 1 I 1 1 1 1 1 t 0.01 1 type | 1 1 1 1 1 t 1 1 1 1 1 * 1 1 1 I 1 1 I • 1 1 1 1 1 1 1 1 1 ί 1 1 I | 013A | 濡 性 剤 剤 | (Ν 〇cs o' rs o rs o fN O' <N o &l t;Ν Ο <N Ο <N 〇<N o O' 1 (N O' <N O' fN o <N 〇<N o (N o <N d fS o rs 〇<;N O' fN o fS 〇cs o fS o' fN 〇fS o fN O' fS o fS o CN 〇fN 〇<N 〇CN Ο fN 〇 kind | ΒΥΚ-380Ν I BYK-380N | BYK-380N | BYK-380N I | BYK-380N I 1 BYK-380N I 1 BYK-3S0N 1 1 BYK-380N 1 | BYK-380N I | BYK-380N I | BYK-380N I 1 | BYK-380N I | BYK-380N I | BYK-380N I 1 BYK-380N I | BYK-380N I | BYK-380N I | BYK-380N I 1 BYK-380N I | BYK-380N I | BYK-380N I | BYK-380N | | BYK-380N I BYK-380N I | BYK-380N I BYK-380N I | BYK-380N I 1 BYK-380N I 1 BYK-380N 1 | BYK-380N I Water-soluble anti-deuteration agent | <Ν 〇〇cs 6 <N 〇no <N 〇rs ο rs d (N 〇<N 〇<N d (N o' o' fN o' tN 〇«Ν o' ίΝ 〇<N 〇(N 〇<N o' <N 〇<N 〇rs O <N 〇<N 〇· o (N 〇 o' o iN o' fN d fN (N d ο rs o' species | . ascorbic acid | 丨 丨 壊 I i i | | Blood acid I | Ascorbic acid I | Ascorbic acid I 1 anti-ascorbate ι 1 anti-halophilic acid ι | Ascorbic acid 1 | Ascorbic acid 1 1 1 Anti-ascorbic acid ι l anti-blood Acid ι |Anti-Haltoic Acid ι lAnti-Haltic Acid ι 1 Anti-Haltaric Acid ι 1 Anti-Haltic Acid ι 1 Ascorbate ι l Anti-Haltaric Acid ι l Anti-Haltaric Acid ι 1 Anti-Haltic Acid ι l Anti-Aging Blood acid ι 1 anti-ascorbic acid ι 1 anti-ascorbic acid ι 1 anti-ascorbic acid ι l anti-ascorbic acid ι l anti-ascorbic acid ι 1 anti-ascorbic acid ι l anti-ascorbic acid ι l anti-ascorbic acid ι |Anti-ascorbic acid ι I anti-ascorbic acid ι | Ascorbate ι | Iso-anti-ascorbic acid] 1 Vitamin E 1 1 anti-ascorbic acid ι Conductive enhancer | 〇Ο ο 1 〇· ρ ο ρ ρ ρ p ρ ο ο ο ο ο ο ο ο ο ο ο ο ο ο ΝΜΡ 1 I ΝΜΡ 1 | ΝΜΡ II ΝΜΡ 1 1 ΝΜΡ 1 I ΝΜΡ 1 1 ΝΜΡ 1 1 ΝΜΡ II ΝΜΡ 1 1 ΝΜΡ 1 1 ΝΜΡ 1 1 ΝΜΡ 1 ι ΝΜΡ 1 1 ΝΜΡ 1 I ΝΜΡ 1 I ΝΜΡ 1 1 ΝΜΡ 1 I ΝΜΡ 1 I ΝΜΡ 1 I ΝΜΡ 1 I ΝΜΡ 1 I ΝΜΡ 1 1 DMSO 1 1 NMF ] 2 1 ΝΜΡ 1 I ΜΡ 1 | ΝΜΡ 1 Modified polyfluorene | ΦΙ 0.20 I 0.20 1 1 ! 0.20 1 1 0.20 1 1 0.20 1 1 0.20 1 1 0.20 1 1 0.20 1 1 0.20 1 | 0.20 II 0.20 1 1 0.20 1 1 0.20 1 1 0.20 1 1 0.20 I 1 0.20 1 1 0.20 1 I 0.20 1 I 0.20 1 1 0.20 1 1 0.20 1 I 0.20 1 1 0.20 1 1 0.20 1 LmJ 1 0.20 1 I 0.40 1 1 0.30 1 La>°JI 0.20 1 1 0.20 1 | 0.20 II 0.20 1 I 0.20 1 1 0.20 1 Type | i BYK-378 I 1 BYK-378 1 1 1 BYK-378 | 1 BYK-378 1 1 ΒΥΚ-348 1 1 YF-3842 1 I KF-355A 1 I ΒΥΚ-307 1 I BYK-378 1 | BYK-378 I 1 BYK-378 1 1 BYK-378 1 ι BYK-378 1 1 BYK-378 1 1 BYK-378 1 ι BYK-378 1 1 BYK-378 1 ι BYK-378 1 I BYK-378 1 ι BYK-378 1 ι BYK-378 1 I BYK-378 1 I BYK-378 ] 1 8029 additive | 1 Polyflow-KL-402 | I Polyflow-KL-402 | I BYK -378 ] I BYK-378 1 1 BYK-378 1 1 BYK-378 I 1 BYK-378 I | BYK-378 I 1 ΒΥΚ-378 1 I BYK-378 1 1 BYK-378 I Sulfonic acid catalyst | o. Io | 1 o.io 1 0.10 I 4.00 0.08 1 ! 0.08 1 1 0.08 1 : 0.08 1 1 0.08 1 o.io 1 1 0.08 1 1 0.08 1 ο.]. 1 1 0.08 IL〇j8j LmJ Lm〇J 1 0.20 1 Lml 1 0.08 1 | 0.08 II 0.08 1 1 0.08 1 1 0.08 1 1 0.08 1 | 0.08 I | 0.08 I | 0.08 1 1 0.08 1 1 0.08 1 | 0.08 I 1 Category | DB DBS 1 ί 1 DBS 1 | DBS I 1 2% nitric acid 1 1 DBS 1 1 DBS 1 1 DBS 1 1 DBS 1 1 DBS 1 | DBS 1 1 DBS I 1 DBS 1 1 DBS 1 1 DBS 1 1 DBS I 1 DBS I 1 DBS 1 1 DBS 1 CO 〇1 DBS | 1 DBS 1 1 DBS | 1 DBS I 1 DBS 1 | DBS I 1 DBS 1 1 DBS | 1 DBS 1 1 DBS | | DBS I | DBS 1 | DBS I 1 DBS 1 1 DBS 1 | DBS 1 Triazide Resin Derivative | ΦΙ 1 s〇O' Ό Ο s〇os〇〇· Ό Ο ο SO d Ό Ο SO os〇〇so o' o' \〇o SO oop W-) o fN Ό oo' so o Ό o' Ό o' \〇d Ό o' so o' Ό 〇s〇o' so o Ό d Ό o' d Ό Ο d Ό o' Category | 1 Cymel 300 | Cymel 300 | Cymel 300 | 1 Cymel 300 | 1 Cymel 300 | 1 Cymel 300 | 1 Cymel 300 | | Cymel 300 | | Cymel 300 | Cymel 300 | | Cymel 301 | 1 MW-390 IT ζΛ SI Cyme! 300 I | Cymel 300 | 1 Cymel 300 I | Cyme! 300 | | Cymel 300 | | Cymel 300 | | Cyme! 300 | | Cymel 300 | | Cymel 300 | Cymel 300 | | Cymel 300 | | Cymel 300 | | Cymel 300 | | Cymel 300 | | Cymel 300 | | Cymel 300 | | Cymel 300 | I Cymel 300 | 1 Cymel 300 | | Cymel 300 | Polymer | in vi VI wi •n »n in •rl w-» m V)' *r> «Π •Λ »n in in «τ» Ui ui kind | Clevios PI Clevios P | Clevios P | Clevios PI 1 Clevios PI Clevios Ρ 1 Clevios Ρ 1 Clevios P | 1 Clevios Ρ 1 I Clevios PI | Clevios P | | Clevios P | I Clevios PI | Clevios P | | Clevios PI Clevios PI | Clevios P | I Clevios PI | Clevios P | Clevios P | | Clevios P | | Clevios P | | Clevios P | | Clevios P | | Clevios P | | Clevios P | | Clevios P | Clevios P | Clevios P | Clevios P | Clevios P | Clevios P 1 Clevios | | Clevios P | Clevios P | | Comparative Example i | | Comparative Example 2 I | Comparative Example 3 1 | Comparative Example 4 I | Comparative Example 5 I 1 Comparative Example 6 1 1 Comparative Example 7 I | Comparative Example 8 I 1 Comparative Example 9 1 1 Example i | 1 Example 2 I 丨 Example 3 1 | Example 4 I Example 5 | Example 6 | Example 7丨Embodiment 8 ί |Example 9 ! |Example 丨〇1 I Example 丨1 ιExample 丨2 1 |Example 丨3 1 丨Example 14 | 丨Example 15 1 丨Example 16 1 | Example 17 1 | Example 18 ! 丨 Example 19 | Example 20 丨 Example 21 | Example 22 丨 Example 23 I Example 24 丨 Example 25 丨 Example 26 | Example 27 s 201219514 [Table 2 Unit: Heavy Example 28 (Use of raw materials) Type of conductive polymer Clevios P 10.5 Melamine resin derivative Cymel 300 0.6 Sulfonic acid catalyst DBS 0.05 Modified polyfluorene BYK-378 0.30 Conductivity enhancer NMP 2.0 Water Soluble Antioxidant Ascorbic Acid 0.1 Hydrating Lifting Agent BYK-380N 0.05 Additive 1 A-189 0.05 Additive 2 Snowtex OXS 0.05 Additive 3 Trimellitic Acid 0.10 Organic Solvent Ethanol 60 Water 26.20 II. Evaluation For Examples 1 to 28 and Comparative Examples The appearance of the liquid of the coating liquid prepared in 1 to 9, the appearance of the film of the conductive film obtained by using the film, the scratch resistance, the solvent property, the printability, and the printing adhesion were evaluated in the following three grades. Further, the values of SR, Tt, and Haze were measured. The adhesion to the substrate was evaluated in accordance with JIS K 5400. The pot life is a coating liquid which has been subjected to 24 hours from the preparation of the solution and a film formed using the coating liquid. The application period of the coating liquid was evaluated in the same manner as the initial value in consideration of the appearance of the coating liquid, the appearance of the coating film, the adhesion, the scratch resistance, the solvent property, the printability, and the printing adhesion. On the other hand, the change in the measured values of SR ' Tt and Haze of the film from the initial value was evaluated in the following three levels. In addition, in the initial evaluation, even if there is one "X" evaluation example and comparative example, the evaluation period is not evaluated. The evaluation results are shown in Tables 3 and 4 below. 38 201219514 Appearance of π·1 conductive coating composition The appearance of the solution after the preparation of the composition was evaluated by visual observation on a grade of 3. The applicability period is also evaluated in the same way. ◎: no precipitate was produced 〇: a small amount of precipitate was produced χ: gelation ΙΙ. 2 Appearance of the film The appearance (uniformity) of the coated conductive film was evaluated by visual observation in the following three grades. The applicability period is also evaluated in the same manner. ◎: The film was uniformly coated, and no coating unevenness was observed: a slight uneven coating was observed: the film was not formed due to shrinkage. 3 Surface resistivity / Sr (Ω/〇) Surface resistivity was based on jIS Κ 7 194. A ua probe of HirestaUP (MCP-HT450 type, trade name) manufactured by Mitsubishi Chemical Corporation was used, and a voltage was measured at a frequency of 100 V, and the measured value was evaluated. The increase rate of the pot life relative to the initial value is evaluated in the following three levels. ◎ : 1 〇 or less 〇: more than 10 times less than 100 times χ : 100 times or more II.4 total light transmittance (Tt : % ) The total light transmittance is based on JIS K 7150 using Suga Test lnstruments Haze Computer HGM — 2B (trade name) was measured and the measured value was evaluated. Evaluate the pot life relative to the following 3 levels

S 39 201219514 The amount of change in the initial value. ◎: greater than a 0.5, less than +0.5 〇: a 1,0 ~ a 0.5 or +0.5 ~ +1. 〇 x * not up to 1.0 or greater than + 1.0 II.5 Haze ( % )

Haze was measured according to jis K 7150 using Haze Computer HGM-2B (trade name) manufactured by Suga Test Instruments, and the measured values were evaluated. The amount of change in the pot life relative to the initial value was evaluated in the following three grades. ◎: greater than a 0.5, less than +0.5 〇: a 1.0 ~ a 0.5 or + 0.5 ~ +1. 〇 x. less than a 1.0 or greater than 1. 〇Η · 6 pairs of substrate adhesion conductive film The adhesion to the substrate was evaluated in accordance with the grid peel test of JIS κ 54〇〇, and evaluated by a predetermined score. The pot life is evaluated at the following 3 levels. ◎: Since the initial value has not changed 〇. The initial value has decreased by less than 2 points χ: The initial value has decreased by 2 points or more. 7. 7 Scratch resistance test 2 〇〇g of negative formation and powder The conductive film formed on the substrate was rubbed by the length of the claw c load by 10 Cm, and the damage was evaluated in the following three grades. The applicability period is also evaluated in the same manner. ◎: No scars were formed 40 201219514 〇: Lighter friction marks were observed, but no powder was produced. X: Scar formation, powder II.8 Solvent resistance test The conductive film formed on the substrate was subjected to an ethanol wiping test. Ethyl acetate wiping test, mercaptoethyl ketone (hereinafter referred to as ΜΕκ) rub test, hexane wiping test. Specifically, the appearance of the film after the test was evaluated by using a dust-free paper (BEMCOT) infiltrated with each solvent with a load of about 200 g and a length of 15 cm under a load of 15 cm. The same applies to the evaluation. ◎: No change in the film. 微小 Visible traces of friction x: Peeling off by 臈. 9 Printability test mark The printability test of the ink film is made using oil produced by Mitsubishi Pencil Co., Ltd. ( Pi: S, fine character), the shrinkage at the time of printing on the guide surface was evaluated in the following three grades. ◎: The printed characters are completely uncontracted. The printed characters are slightly shrinked and uneven. X. The shrinkage is large, and it is impossible to print the oily marking oil of the Π10 printing adhesion test. After 1 minute, the following 3 ratios are used. Flashing you... A sigh of relief, ink (Pl.S, fine words) printed on the conductive film ^ U about 5QGg load friction, level ° parity at this time the printing state. ,

S 41 201219514 ◎: No peeling of printing 〇: traces of friction left on printing X: complete peeling of printing 11.11 Air resistance test Air exposure test system attaches conductive film to the wall, and evaluates SR after 1 week as follows: . The applicability period is also evaluated in the same manner. ◎: less than 1χ101()Ω/〇〇:1χ1010Ω/□ or more, less than 1χ10"Ω/〇X : 1χ10ηΩ/□ or more 11.12 Defoaming test Defoaming test system oscillates the coating liquid 5 times as follows The rating is evaluated until the time when the larger bubbles are all gone. The applicability period is also evaluated in the same manner. ◎: Defoaming within 20 seconds: Defoaming within 20 minutes and over 20 minutes △: Defoaming within 1 hour over 20 minutes X: Not defoaming even after 1 hour or more 42 201219514 [ε < μ & 〇 ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ J UJ 2 XX ◎ ◎ I ◎ ◎ 〇〇 ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇 ◎ ◎ 〇 〇 I I I ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ & 基 基 ◎ ◎ ◎ ◎ 1 〇 ◎ 〇〇 ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ t. 4μ Silver 〇 6 U Ο ο ο ο ο ο ο ο ο ο ο ο ο ο ο ο ο ο ο ο ο ο ο ο ο ο ο O'· <N Ο <Ν Ο ΓΜ ο <Ν 〇\ (Ν σ\ Ον ο fS ο fs Ν (Ν ο is σ; ο ΓΜ ο (Ν <Ν ri ο <Ν ΟΝ O' 〇Ν· 〇Ν· S (Ν ri σ\ Η口· ο <Ν 90 ε g〇£ Μ £ 09 ε 1 00 £ 00 ε r- £ 0C ε 00 Μ ε βο ε 00 £ Γ- ε 00 £ 00 £ O' ε 00 £ 00 £ 〇Ν ε 〇Ν £ 00 £ 00 £ 00 £ 〇 00 £ Ρ» £ Μ ε 00 00 ε 00 ε r- £ βο ε ββ ν〇£ b X r**' "ο ΓΛ ο X οΰ 1 ~°〇X ΙΛ V0 : \ Η ΓΛ "ο X «Λ rS ·°ο X "ο Π' •b 1= νο "ο -3⁄4 «Λ ·°ο 〇\ •Λ "ο X 00 "ο σ; 00 X Γ4 "ο X 00 «Λ "ο X Γ- •b 1 •b X "ο X 00 ό' ri X 3< XX pg "ο 00 "ο X κ ~k 瑶 ◎ 〇 ◎ ◎ 1 ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇〇 ◎ 〇 1 〇 ◎ 〇〇〇〇〇〇〇〇〇〇〇 〇〇〇〇〇〇〇〇〇〇〇Ο 〇〇〇〇〇 〇 〇 〇〇Ο 〇〇Ο ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇 ◎ ◎ jj (NA} cn 耷rr A3 m 〇τ 耷jj id 00 σ\ 〇J 4κ (Ν m *Κ «η省NO 卜*κ 00 嫜V © «Κ 4κ Γ* Ί VV «/ϊ Ό Γ>» V: 00 Marry V: 〇\ *« 婼fN <Ν V ί*1 <Ν ν «Λ <Ν 鸯V VC ΓΊ Ρ; 00 <Ν s 201219514 〔 Inch<] /* ί e 1 4 Μ m 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 * 1 1 1 1 1 1 ( 1 1 ο t ΐτ d 〇\ 00 v〇耷od 00 O' «Λ 00 〇V» 〇ΓΊ 〇00 00 CM νο «£>0< ή <Ν m 1 Building 4 Correction 1 1 1 1 1 1 1 1 t ◎ 〇 ◎ ◎ ◎ 〇〇 ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ 鸯 1 1 1 1 1 1 1 1 ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇 ◎ 〇瘅 〇 〇 〇 1 1 1 1 1 1 1 1 ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ § 1 1 1 1 1 1 1 1 1 1 ◎ ◎ ◎ ◎ ◎ 〇 〇 ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ο lt lt 0 0 0 0 0 0 0 ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ti 1 1 1 1 \ 1 1 1 1 1 ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ · · · 〇 Silver 1 1 1 1 1 1 1 I 1 ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ 1 X 1 1 1 1 1 1 1 1 1 ◎ ◎ ◎ 〇〇〇 〇〇〇 ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ Female thin 1 1 1 1 1 1 1 1 1 ◎ ◎ ◎ ◎ ◎ 〇 ◎ ◎ 〇〇 ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇 〇 ◎ ◎ Μ Μ m 1 1 1 1 1 \ 1 1 1 〇〇〇〇〇〇〇〇〇〇〇〇〇〇〇〇〇〇〇〇〇〇〇〇〇〇 ◎ prostitute 1 1 1 1 t 1 1 1 1 ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ΓΊ 5 S « Jj m 5 s SO s s ! > · Xuan A} 00 Jj 〇\ IK ΓΊ m 鸯Tf *n NO r- 00 <3\ % 〇ί 'Τ •Λ NO Γ- 1«: 00 On Γ'ί fS Sea Μ 堤 201219514 According to Comparative Examples 1 to 4 and implementation In Examples 1 to 3, it is obvious that gg is obvious, even if it lacks one of the trimeric amine resin derivative, the acid-hardening catalyst, the two-end polymerization modified polyoxane, and the conductivity enhancer,臈 appearance, conductivity, total light transmittance, Haze, adhesion to substrates, resistance to traces, solvent resistance,

Printability and print adhesion cannot be satisfied at the same time. If there is no conductive polyA and conductivity enhancer, then SR is not exhibited. If there is no melamine resin derivative and the acid-curing catalyst, the film is not cured. The two-end poly-bonded polysulfate system is used to make the trace resistance and printability and print adhesion coexist. According to Examples i and 4 to 6, it is obvious that the melamine tree is derived. The coating liquid of the all-ether type is excellent in stability, and the physical properties of the coating film after 24 hours are not lowered. According to the examples U7 to 10, it is apparent that the application period is deteriorated if the content of the melamine resin derivative is increased, and if it is less than 15 parts by weight relative to 100 parts by weight of the conductive polymer solid content, it is resistant from the initial stage. Low solvent. According to Comparative Example 5 and Example 8, it is apparent that the hardening catalyst is preferably acid. Further, according to Example U, it is apparent that the application period of the coating liquid is slightly deteriorated due to the use of Qs, and the characteristic property is deteriorated after 24 hours. Therefore, as a hardening catalyst, it is especially good for DB S. Further, according to Examples i and 12 to 15, it is apparent that the content is preferably 4 parts by weight or less based on 100 parts by weight of the melamine resin derivative, which is preferable in terms of maintenance of the pot life. According to Examples 1 and 16 to 18, it is apparent that in order to satisfy both scratch resistance and printability and print adhesion, it is necessary to use a two-end polyether modified polyfluorene.

45 S 201219514 Oxygen As the side chain polyether modified polyfluorene was used as in Comparative Examples 6 to 9, the scratch resistance, printability, and printing adhesion could not be satisfied at the same time. Further, in the first embodiment and the comparative example 9, the polyether modified polyfluorene oxide was used to have substantially the same molecular weight as that of the polydimethylsiloxane, and the modified portion had a different structure. Further, Example 1 is a polyether modified polyfluorene at both ends, which satisfies both scratch resistance, solvent resistance, printability, and printing adhesion. On the other hand, the side chain polyether of Comparative Example 9 is modified. Polyoxyl cannot be satisfied at the same time. From the results, it is apparent that the effects of the present invention are specifically achieved by using the two-end polyether modified polyfluorene as a polyether modified polyfluorene. Further, according to Examples 1 and 19 to 21, it is apparent that the content of the polyether modified polyfluorene at both ends is preferably 60 parts by weight or less relative to the melamine resin derivative by weight of 60 parts by weight or less. . According to Examples 1 and 22 to 24, it is apparent that the conductivity of the conductive film is further improved by using a compound having a mercapto group, a hydroxyl group or a sulfo group as a conductivity improving agent. ♦ Comparing Examples 1, 25 with Example 2, it is apparent that the addition of ascorbic acid or isoascorbic acid of a water-soluble antioxidant can suppress the SR rise of exposure to air. Further, such an effect was not observed in the oil-soluble antioxidant as in Example 26. - Again, a slight shrinkage was confirmed in Example 3. If compared with other examples, it is obvious that the wettability is improved. Further, according to Example 27, it is apparent that the antifoaming agent is effectively added. The bubble is defoamed. In addition, according to (4) Example 28 and Figure i 'reported', the film with a calculated film thickness of 46 201219514 and about 3 〇 nm was analyzed by TEM, and the actual measurement was about the composition known as 'film formation under these conditions. The film thickness is much thinner than that of B yia η. The conductive composition of the present invention can be formed at a low temperature for a short period of time while satisfying the scratch resistance, solvent resistance, printability, and print adhesion. It is preferably used to form, for example, a conductive film (antistatic layer) or the like which constitutes various photonic films such as a protective film. [Simple diagram of the diagram] Conductivity produced in Fig. 1 is an example of an image taken at an altitude of 100,000 times. [Main component symbol description] 1 conductive film 2 ρΕΤ film

47 S

Claims (1)

201219514 VII. Patent application scope: 1. A thermosetting conductive coating composition comprising: (a) a conductive polymer, (b) a melamine resin derivative, (c) a sulfonic acid hardening catalyst, (d a two-end polyether modified polyfluorene oxide, (e) a conductivity enhancer, and (f) a solvent or dispersion medium. 2. The thermosetting conductive coating composition 'in which' the conductive polymer (a) is a poly(3,4-disalkoxy group having a repeating structure of the following formula (1), as claimed in the ninth aspect of the invention. a complex of thiophene) or poly(3,4-desalkyldioxythiophene) with a dopant, (wherein R1 and R2 independently of each other represent a hydrogen atom or an alkyl group of Cl-*, or a combination thereof may be substituted (: a 4-alkyl group of the group 4), as in the first or second aspect of the patent application. The composition for a thermosetting conductive coating composition, wherein the content of the melamine resin derivative (b) is 〜75 重量重量份 based on 100 parts by weight of the conductive polymer. 4. The scope of claims 1 to 3 The thermosetting conductive coating composition according to any one of the preceding claims, wherein the sulfonic acid hardening catalyst (c) is an aromatic acid, 48 201219514, the content of which is 8 to 4 parts by weight relative to the melamine resin street organism (10) by weight. The heat-curable conductive coating composition according to any one of the above-mentioned items of the present invention, wherein the two ends are aggregated and modified to contain oxygen (4) The composition of the thermosetting conductive coating composition of the melamine resin derivative 1 (9) is 〇 量 重量 重量 重量 重量 重量 重量 重量 重量 重量 重量 重量 重量 重量 重量 重量 重量 重量 重量 重量 重量 重量 重量 重量 重量 重量 重量 重量 重量The enhancer (1) is a substituent having at least one of a mercapto group, a sulfo group and a hydroxyl group. 7. The thermosetting conductive coating composition 'in any one of the above-mentioned items to claim 6' further contains (g) a water-soluble antioxidant. ^ Patent Application No. 7 A composition for thermosetting conductive coating, wherein t, the water-soluble antioxidant (g) is ascorbic acid or isoascorbic acid. 9. If the patent application (4) is applied to the thermosetting conductive coating of the item The composition for the fabric of the present invention further comprises (1) a composition for the thermosetting conductive coating according to any one of the above claims, further comprising (i) a consumer. U. The thermosetting conductive coating composition of claim 10, wherein the antifoaming agent (i) is a polyoxymethylene emulsion. I2. An optical film is made of a substrate. The conductive film is formed of a conductive film laminated on the substrate. The conductive film is formed by using a thermosetting conductive coating composition according to any one of the above claims. 49 1 201219514 13. Optical film as in claim 12 In the conductive film, the thermosetting conductive coating composition is applied to the substrate, and dried at a temperature of TC or lower and thermally cured. The optical film of item 12 or 13, wherein the conductive film has a calculated film thickness of less than 45 nm. The seed δ vine film is an optical of any one of claim 12 to 14 Membrane composition. 50