TWI321578B - Anti-static polyester film - Google Patents

Description

1321578 IX. Description of the Invention: [Technical Field] [Invention] The invention relates to an antistatic polysulating film, and more particularly, to a selective electrostatic polycondensation film, which comprises at least a surface coating of a shaped film. And ^ W 曰 (A), binder resin (B), cross-linking I (C) with ruthenium dioxide dispersed composition 苴 苴 U extract CD) to improve the coating / , substrate adhesion, water resistance, dialing and transparency. U-solvent and anti-static properties [Prior technology] In recent years, with the progress of industrialization, from a wide range of fields, from electronics and electrical equipment, to the field of communication, to general life, to the use of tongue, The increase in disasters caused by power generation has become an extremely important issue in the prevention of static electricity in these U, /, etc. and industrial sites. The so-called anti-static of Μ w τ month is to discharge the charge accumulated on the surface of the insulator in an appropriate manner. In order to prevent static electricity, it is only necessary to form an antistatic layer which can discharge the electric charge accumulated on the surface of the product. In particular, a thin tantalum process in which impurities or dust adhere may occur, and since an electric discharge occurs in the process of processing the film, there is a risk of fire if an organic solvent is used in the process. Further, when such a film is used as a material such as an electric or electronic component, it causes a cause of static electricity damage, and therefore it is an essential requirement to impart antistatic performance when the film is used. In (4) Electrotechnical (4), the method of using an organic compound such as Urganie kiss hGnate and an organic compound such as organic phosphate, a method of vapor deposition of a metal compound, and coating of conductive inorganic particles have been used. The method, the method of coating a low molecular type anionic or cationic compound, the method of coating a conductive polymer, and the like. The internal addition method of anionic compounds such as organic sulfonate esters and organic phosphate esters has the advantages of being narrow, low cost, excellent in time-dependent change and safety, but there is an obstacle to the film's inherent properties. Disadvantages, the limit of anti-static fruit, due to whitening (bl〇〇ming) and the accumulation of layers between the film: the problem of reduced sag. Further, the method of steaming ore metal compounds has been made for a certain period of time, and has been widely used for conductive films in recent years, but it is too high and is limited to specific uses. Moreover, the coating method using a low molecular weight j or a cationic compound has a good antistatic effect, and is advantageous in terms of manufacturing cost and is suitable for a wide range of applications, but it is impossible to obtain about 1 by the limit of antistatic.表面9Q/□ below surface resistance, = the combination of moisture in the atmosphere exhibits anti-static properties, so when the moisture content in the atmosphere is low, anti-static, & I ”

Ml·Life will be greatly reduced. The solvent resistance is very poor, and it is possible to transfer to other areas. The shortcomings of the above, the applicability is severely affected by the polyaniline and the poly-portion as the anti-static material, and the coating is applied to the mechanical property including the hardness and the hardness. With the development of conductive polymers dissolved in water or organic solvents, or poly-phenesis, electropolymerized films have been increasingly used as applications for imparting applications to other polymer surfaces. One of them is a method in which a conductive polymer is produced and then dissolved in a suitable solvent to form various polymer surfaces such as vinegar. At this time, the binder is also used to promote the adhesion or surface quality of the coating. The development of the middle is an example. In U.S. Patent No. 4,959,43,13215,78, a conductive polymer monomer, 3,4-ethylenedioxythiophene, and an oxidizing agent of iron toluenesulfonate ( Ir〇n (羾) p-toluenesulfonate) and the conductive polymer synthesized from these substances, 3,4-polydioxythiophene, 34-ethylenedioxythiophene and toluene The acid iron is mixed at a normal temperature and heated to produce a blue conductive polymer 3,4-polyethylenedioxy porphin. In another aspect, 3,4-polyethylenedioxythiophene is commercially available in the form of dispersion in water, but if 3,4-ethylenedioxythiophene is mixed with toluene acid ferrite, it is left at room temperature for a long time. Sometimes a polymerization reaction occurs, based on the prevention of the occurrence of the polymerization reaction. (4) 'Immediately add a small amount of the reaction inhibitor to the imidazole. In Japan, the poly(3,4-dialkyloxy warm-glow plate) is disclosed in Japan. The compound can be obtained by the conductive polydecyloxy group composed of 3,4-di-di-polymer = in the presence of a polyanion, because of high conductivity, high chemical safety, and film formation. The coating film is highly transparent and attracts attention. It is applied to a plastic substrate from a coating liquid with a conductive polymer: Case: the content can satisfy the adhesion, transparency, water resistance of the substrate at the same time. A coating film having properties such as conductivity is not the purpose of sexuality and sexuality, and has been tasted by a water-repellent method based on a soaking coating film. § 4 Cross-linking of a binder resin as a crosslinking agent Ping Guang is promoted by Ju (3,4 a "=Special Kaiping) 6_73271坑 乳 thiophene thiophene) and polyanion constituting 4 7 (1) The recombining agent is selected from the group consisting of isocyanate, carbodiimide, oxazoline, and amine-based compounds. The above is preferred. The oxidized hair is divided into a ruthenium net, and the wy knives composition is preferably obtained by reacting a fluorine-based decane coupling agent with a oxidized granule a and a quinone in a cerium catalyst, preferably, month, J The fluorine-based decane coupling agent is a compound represented by the following chemical formula: <R)p |

-iCHj>n —sHiYK

CF3—CF2—, CF CF CF where X is selected from CF, (CF3)2-CFO—or cf3—(c—2: a positive number of 1 8 'R is an alkyl group of Ci~C4, Y series a methoxy group, an ethoxy group, a methoxyethoxy group or a gas atom, an integer ρ of the formula M2 is an integer of 〜2, „ is an integer of i to 3, and η+ is 3. The effect of the invention is Polyester film, when the helmet is used, the protective film of the display is used to remove the static electricity, which can suppress the foreign matter π. ^ ^ Depending on the surface, the effect of easily removing the foreign matter on the surface can be achieved. In the present invention, since the antistatic coating composition applied is mixed with an appropriate amount of the antibacterial and functional fluorine-based cerium oxide dispersed composition, no water or alcohol is used as the main component. Anti-static agent layer when the cheek claws wash foreign matter

The antistatic agent is detached or dissolved. IA 斛 争 争 可 可 可 可 可 可 可 可 可 可 可 可 可 可 IA IA IA IA IA IA IA 与 与 与 与 与 与 与 与 与 与 与 与 与 与 与 与 与 与 与 与Poly (four), and is a very useful invention. [Embodiment] 9 The present invention will be described in detail with reference to 578 and S. The present invention relates to a polyester crucible obtained by coating an antistatic coating composition on at least one side of a polyester film, the antistatic coating composition comprising a binder resin 200 to 2000 with respect to 100 parts by weight of the conductive polymer cabinet fat. Parts by weight, cross-linked J 40 1 〇〇 heavy parts, and fluorine-based cerium oxide dispersion composition - parts by weight. The type of the polyester film used in the present invention is not limited, and any one known as an antistatic coating substrate film can be used. In the present invention, the polyester resin such as polyethylene terephthalate, polybutylene terephthalate or polyethylene naphthalate is mainly described. The substrate of the antistatic coating composition of the invention is not limited to the related polyester sheet or film. The polyester constituting the film refers to a polyester obtained by polycondensing an aromatic dicarboxylic acid with a fatty sterol. Examples of the aromatic dicarboxylic acid include p-dicarboxylic acid and 2,6-naphthalene dicarboxylic acid, and examples of the aliphatic diol include ethylene glycol, diethylene glycol, and M-cyclohexanediol. As the representative of the polyester, there are polyethylene terephthalate (PET), polyethylene-2,6-naphthalened dicarboxylate (PEN) and the like. It is also possible for the polyester to be a copolymer containing the third component. Examples of the dicarboxylic acid component of the copolymer polyester include isophthalic acid, phthalic acid, terephthalic acid, 2,6-naphthalenedicarboxylic acid, adipic acid, sebacic acid, and oxycarboxylic acid. Oxycarb〇xylic acid (for example, p-hydroxybenzoic acid), and examples of the diol component include ethylene glycol, diethylene glycol, propylene glycol, butylene glycol, M-cyclohexanediol, and neopentyl Alcohol, etc. These dicarboxylic acid components and the diol component may be used in combination of two or more kinds. The film of the present invention is a uniaxial or biaxially oriented ruthenium which has high transparency and is excellent in productivity and workability. The conductive polymer resin of the present invention is preferably provided with antistatic property.

Words, can be mixed or mixed,

[Formula 1J]

In the formula, Ri and R2 each independently represent a hydrogen atom, an aliphatic hydrocarbon group of Cl 12 , an alicyclic group or an aromatic group, and specifically, a methyl group, an ethyl group, a propyl group, an isopropyl group, and a butyl group. Base, phenyl, etc. [Formula 2]

In the formula, η is an integer of 1 to 4. The polyanion is an acidic polymer, and is a high molecular carboxylic acid or a high molecular sulfonic acid or a polyvinyl sulfonic acid. Examples of the polymer carboxylic acid include polyacrylic acid, polyacrylic acid, and polymaleic acid. In the case of a polymer sulfonic acid, polystyrene sulfonic acid or the like is used. On the other hand, in the present invention, a layer composition containing poly(3,4-ethylenedioxythiophene) and 0.5% by weight of polystyrene (molecular weight Μη = 150,000) is used to contain a fluorine-based cerium oxide dispersion composition. The fluorine-based cerium oxide dispersion composition is obtained by using a fluorine-based decane coupling agent, cerium oxide particles, water or an organic granule in the presence of an acid catalyst at 25 to 6 (rc reaction for 5 minutes to 5 hours). More preferably, the fluorine-based decane coupling agent has a structure of the following formula 3. [Formula 3] β7)ρ |

X—tCHiV» —si—" (in YV, X is selected from CF3—, CF3—CF2—, d—ch—eF2__ (CF3)2—CF0—or *CF3—(CF2) Guang CH Factory— In the group 2, y is an integer of i~8, R is an alkyl group of c丨~G, γ is a methoxyethoxy group, a methoxyethyl group or a chlorine atom, and m is 0 to 12 An integer, Ρ if' is an integer of 0 to 2, an integer of η is i~3, n+p = 3. A fluorine-based decane coupling agent represented by the above formula 3 is specifically selected from difluoropropyltrimethyl Oxydecane, trifluoropropyltriethoxydecane, trifluoropropyldioxane, hexafluoropropyltrimethoxyoxydecane, hexafluoropropyltriethoxydecane, hexafluoropropylmethyldifluorene Oxydecane, hexafluoropropyltrichloromethane, = fluoroisopropoxypropyltrimethoxy, I's hexaisopropoxypropyltriethoxylate, "fluoroisopropoxypropyltrichloride" Shi Xixuan, hexadecafluorooctyloxypropyltrimethoxydecane constitutes a compound of 1 or more in the group. The size of the cerium oxide particles used is preferably corresponding to "claws, and is used in organic solvents. Alkane, cyclohexane, heptane, octane, alpha % Hexyl appearance, toluene, benzene, methanol, ethanol, isopropanol, butanol, Shu alcohol, hexyl alcohol%, Yue cyclohexanol, phenol, diethyl ether, dipropyl ether, tetrahydrofuran, 13

Acetone, cyclohexyl, methyl ethyl, acetic acid methyl acetate, ethyl acetate, acetic acid, lyophilic acid, cellosolve, cellosolve acetate, hydrocarbon, alcohol, (iv), vinegar, complex acid, and Replace the smoke system and so on. It is preferable to use isopropyl alcohol, butanol, and xylene toluene. These organic solvents may be used alone or in combination of two or more. The catalyst can be used alone or in combination with hydrochloric acid, acid, acetic acid, and the like. The I-type silica dispersion composition produced by the above method contains 1 () to fine parts by weight of the H 糸-emulsified stone dispersion composition less than 10 parts by weight with respect to the conductive high score + (10) parts by weight, Then, the water-repellent effect of the coating layer will be lowered. If it exceeds 500, it will be γ for 8 days, and it will hinder the performance of the transparent fish antistatic agent of the film.聚 The polyester film which is the base film described above can be produced by a conventional method. That is, the polyester resin is vacuum-dried, then smelted in an extruder, and formed into a sheet shape by a τ mold, and the sheet is cooled and solidified by a static printing method on a chill roll. An unstretched polyzide tablet was obtained. The granules were subjected to a longitudinal stretching of 25 to 4 - 5 times by the difference in the ratio of the turnover speed between the rolls and the light, which was heated to a temperature higher than the glass transition temperature of the poly-resin. The transverse stretching device (the thin medium that is continuously sandwiched by the clip is made ::: stretched) is inserted into the 彳3·. ~ 7.0 times stretching and heat setting to obtain the stretched alignment film. The coating method to be carried out between the longitudinal stretching and the transverse stretching is not particularly limited. It is preferable to use a Meyer bar method, a gravure method, etc., to apply a film surface before coating. The polar group is introduced to perform a corona (C touch) discharge treatment in such a manner that the adhesion of the coating to the film and the coating property are improved. In order to improve the safety, wetting and coating flatness of the antistatic coating liquid, 14 1321578 (]eveling) 'Alcohol, isopropanol and other alcohols, ethyl cellosolve, A vinegar such as tributyl cellosolve, a ketone such as acetamidine or acetone, an amine such as dimercaptoethanolamine or an ionic/nonionic surfactant; The above is used in combination. The thickness of the polyester film is usually 5 to 3 Å #m, preferably 1 0 to 250 #m. The antistatic layer formed on the substrate film is coated on the base (four) u-surface-coated antistatic coating composition (with respect to 1 part by weight of the conductive polymer resin, the binder layer is included) It is formed by adding 〇2 to 2 parts by weight, 4 to 100 parts by weight of a crosslinking agent, and 10 to 500 parts by weight of a fluorine-based dioxide dispersion composition. The coating method of the coating composition can be utilized: a method using a gravure roll (grass e roll) or a reverse gravure light k (10) gravure roU), a coating method using a Meyer bar, and an air knife C Air knife) coating method, etc. - 舯^ θ, a general method, before the coating - electric discharge treatment is introduced on the surface of the film. ^ f base and edge lift surface tension, so that the coating composition of the composition The adhesion of the favorable gland (tetra) antimony composition to the poly-resin resin is promoted by Ma Jia. At the time of manufacture, the content of the antistatic coating liquid is 〇.5~1〇.〇% by weight, and more preferably 4 i.0~5·〇% by weight. If the solid Ψ μ , ^ is difficult to fully exhibit the coating film formation and antistatic function of the coating, if the Μ: ϋ, ϋ, 〇 〇 〇 〇 , , , , , , , , , 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 . The protective film of the present invention is anti-static formed by the main layer liquid due to the prevention of the dispersion of the fluorine-containing emulsified enamel composition on the early or double-sided coating of the soil material. The presence of the layer is in addition to the advantages of water-repellent function, alcohol resistance, and ease of removal of the adhesive. Therefore, + eight foreign objects are not easy to adhere to the outer layer of the protective film, the special angle is 90 households, and the surface protective film of the bright surface has the antistatic layer to contact with water (it is preferably the contact angle of the temperature to Qn # ) Water-repellent. If it is 90 degrees to the water, it is easy to produce speckle on the surface due to the κ attached by removing the surface decoration material for the water I + θ 勹1 cloud. The antistatic property of the surface protective film of the present invention is 1xl 〇 12Q/ after the solvent is rubbed. It is difficult to control the stripping of static electricity. The value of the surface resistance is described in more detail by way of examples, which are intended to be within the scope of the invention. The examples in this month are not intended to limit the present invention. <Preparation Example 1 &gt; The polyester film substrate is manufactured to have an ultimate viscosity of amorphous spherical spheroidal dioxide particles of 20 ppm | 625.625 dl / g of polyethylene terephthalate granules (Pellet) in a vacuum dryer at 16 Torr. . After sufficiently drying for 7 hours, it was melted: an amorphous unstretched sheet was produced by extruding a T die and then electrostatically applied to a cooling roll, and it was again heated at 9 rc to be stretched 3.5 times in the film traveling direction. Next, a corona discharge treatment is applied to the film surface to be coated to produce a polyester film. &lt;Synthesis Example 2&gt; Preparation of fluorine-based cerium oxide dispersion composition The fluorine-based cerium oxide dispersion composition of the present invention is fluoroethoxysilane (CF3(CF2)7CH2CH2Si(OC2H5)3)0.i ~2〇16 丄321578 Dispersion Dispersion in Isopropanol (iS0_pr0pyl alC〇h〇l) l~50 Weight Guangling *Hai Dispersion 'Addition of Dioxide Fragments 1~5 in the presence of hydrochloric acid as acid catalyst After the weight fraction is 25 to 6 (TC treatment for 5 minutes to 5 hours, a cerium-based cerium oxide dispersion composition is produced.) &lt;Example 1&gt; Corona treatment surface of the polyester film produced in the above Synthesis Example 1 Use #5 7 耶棒 to coat anti-static coating liquid 'This anti-static coating liquid system will be conductive Luhe knife resin (Bayer 公司, Baytr〇np) parts by weight, acryl oxime binder resin (Japan Calcium carbide company, γ8〇〇3Β) 4 parts by weight, melamine cross-linking agent (Sittik's CYMEL385) 1 〇〇 ^ 份, 2, and fluorinated silica dioxide dispersion composition 165G parts by weight It is prepared by diluting and preparing a solid as a whole solid of X to a content of 2% by weight. Thereafter, the applied coating liquid was dried in the range of (10) to 12 (r ((4) (4)). Thereafter, the coating was stretched 3.5 times in the direction perpendicular to the traveling direction of the film. A biaxially stretched film having a thickness of 5 〇 m. &lt;Example 2&gt; The antistatic coating liquid is excited by Λ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ (Bai Ai Lu company, mouth, mouth, J, Baytron P) 1 〇〇 by weight, urethane binder resin (Da Ri Tai, eight W ink chemistry, AP-40F) 500 heavy injury, dimerization A chaotic amine cross-linking agent (Cold-bearing ancient eight ^ ah d, ridge gram company, CYMEL385) 150 parts by weight, and fluorine-based cerium oxide male gongzhishan &amp; hole G / knife powder composition 〇〇 〇〇 weight mixture A biaxially stretched film was produced in the same manner as in the above Example 1 except that the total solid content was 25 times. /6/1 士.. Trang %. The film was produced in the same manner as in the above Example 1. 17 1321578 <Example 3> In the manufacturing stage of antistatic coating liquid, in addition to the solid component benchmark, conductive southern molecular resin (Bailulu Company) Bay tron P) 1 part by weight, polyester resin (Nippon Synthetic, W0030) 400 parts by weight, melamine crosslinking agent (Cytic, CYMEL385) 100 parts by weight, and i-type oxidized stone dispersion composition 5 A biaxially stretched film was produced in the same manner as in Example 1 except that the mixture was diluted and prepared so that the total solid content was 2,5 wt%. &lt;Example 4&gt; In the production stage of the antistatic coating liquid, in addition to the solid content standard, 100 parts by weight of a conductive resin (Baytron P), poly resin (high pine oil, A-215GE) 500 parts by weight, melamine

150 parts by weight of a cross-linking agent (CYCEL385), and a fluorine-based cerium oxide-dispersed composition, 1 part by weight, mixed, and diluted and prepared so that the total solid content is 3.0% by weight. Example 1 was also to produce a biaxially stretched film. &lt;Comparative Example 1 &gt; In the production stage of the antistatic coating liquid, the fluorine-free cerium oxide-dispersed composition was not used, and the conductive polymer resin (Bayer P) was used as a solid component. 〇 by weight, acrylic binder resin (Sakamoto calcium carbide company, Y8003B) 400 parts by weight, and melamine cross-linking agent (Sittik's CYMEL385) 1 〇〇 part by weight, and the whole solid knives containing S into 2.0 The biaxially stretched film was produced in the same manner as in the above Example 1 except that it was diluted in a weight % manner. 18 1321578 &lt;Comparative Example 2&gt; In the production stage of the antistatic coating liquid, the gas-based and sulphur dioxide dispersed composition is not contained, and the conductive polymer tree is used as the basis of the m-body component (Bai Ai Lu Company) 'Baytron P ) i 00 parts by weight, poly-resin resin (Japanese synthetic, w〇〇3〇). 400 parts by weight, and melamine cross-linking agent (Settik, MEL385) 1 〇〇 1 part mixed, and The total solid content was 2. 〇 weight 〇 /. The mode was diluted, except that the other biaxially stretched film was produced in the same manner as in the above Example i. • &lt;Comparative Example 3&gt; In the manufacturing stage of the antistatic coating liquid, the conductive I&quot; 冋 冋 molecular resin (Bayer 〇np, Baytr〇np) 丨〇〇 by weight, poly resin (Gaosong) 40 parts by weight of a fat, A_215GE), a triazamine crosslinking agent (CYMEL385) 150 parts by weight, and a fluorine-based oxidized powder dispersion composition of 800 parts by weight, and the total solid content is 3.0 weight. A biaxially stretched film was produced in the same manner as in Example 1 except that the preparation was diluted in %. ^ &lt;Experimental Example&gt; The physical property evaluation of the biaxially stretched film produced in the above Examples 1 to 4 and Comparative Example U was carried out by the following method. The electric __-water contact angle is carried out using a contact angle measuring machine (Kyowa Interface Science Co Ltd. model name Dropmaster 300) by ion-exchanged water by steaming the obtained sessile drop method, at different positions, Then take the average after 5 times. 2L. Anti-static anti-static anti-static measuring machine (Mitsubishi (share), model name; Mcp_T6〇〇) After setting the sample under the environment of temperature hunger and humidity 5G%RH, the surface resistance was measured according to JIS Κ7194. 3. Water-resistance The surface-coated film was placed in running tap water for 1 minute, and dried at 50 C for 1 minute. Then, the antistatic property and appearance were evaluated as follows.

〇Δ X has no white turbidity phenomenon, and there is no slight anti-static property. It shows some slight white turbidity phenomenon. When the antistatic property is reduced, the white turbidity phenomenon appears clearly, and the antistatic property disappears. 4. The acetaminophen is dampened with ethanol. Maintain the angle of the cotton swab at 45. In the case where the coated film surface was transferred to the length of 5 cm at a speed of 1 Torr and 5 cm/sec for 10 times, the state of the coating layer was evaluated on the basis of the following criteria. 〇 乎 / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / A sample of 1 〇cmx 1 〇cm sample was placed vertically in a turbidity measuring machine (AUTOMATIC DIGITAL HAZEMETER, manufactured by Nippon Electric Co., Ltd.), and the vertically placed sample was placed at a right angle of 400 to 700. The value at which the light of the m wavelength penetrates. At this time, the turbidity (Haze) 20 1321578 value is obtained by the following mathematical formula 1, and is shown in the turbidity measuring machine. [Formula 1] Turbidity (%) = ( l-DF/TT) X 1〇〇 DF : amount of scattered light TT : total penetration of light [Table 1] Example 1 Example 2 Example 3 Implementation Example 4 Comparative Example 1 Comparative Example 2 Comparative Example 3 Surface resistance 105 106 105 107 10s 105 1014 Water contact angle 104 112 102 110 55 61 109 Water resistance 〇〇〇〇〇〇〇 Ethanol resistance is wide 〇〇 〇3.5 3.2 2.9 3.0 a 3.2 2.8 where the unit of surface resistance is ', Ω / , and the unit of water contact angle is degree (.), '.

From the results of Table 1, it is possible to carry out the process of W丨~4, which is produced by W电~4, and exhibits: maintenance, solvent resistance and surface resistance. lxl012Q/□ The following physical properties can greatly improve the water-repellent demanding contact angle of 1〇〇. The above properties, but once the Dunhuang dioxide is also y P „ ^ ^ ^ 夕 knife government composition added more than a certain amount will lead to a decrease in transparency and anti-static properties. [Simple diagram] No [ Main component symbol description] Benefit 21

Claims (1)

Patent Application No. 095121843, Patent Application Revision/Replacement This 'application patent scope: 2009.11月Μ3%#》[Replacement page!------------------------------------------------------------------------------------------ : 'Aibu antistatic coating composition; the antistatic coating composition, the phase material conductive polymer resin 〇〇 〇〇, 3,,, ° D agent resin 200~2000 parts by weight, cross-linking agent 40 to 100 parts by weight and a fluorine-based cerium oxide dispersion composition of 1 〇 to 5 〇〇 by weight. 2 Anti-static (4) film of the patent (4) of the patent, wherein the carrier is a resin produced by polymerizing polybenzazole or a derivative thereof in the presence of a polyanion. Mixtures Please refer to the anti-static polyester film of the first item of the patent range, in which 'the base of the base is selected from a few groups, a trans-group, an acrylic group, an amino carboxylic acid sulfonate, a sulfonamide group, a quinone imine group. And a functional group of at least one of the group consisting of a carboxylic acid, a maleic acid, and a maleic acid needle. The antistatic "film" of the first range of the crosslinking agent, wherein the mixture is composed of a mixture of ^ ' /, 虱 I from the lanthanide, carbonyl quinone, oxazoline, and trimeric (4) compounds! More than one species. (1) Anti-static poly-S film of the first item of the patent scope (7), wherein the emulsification sentence is 7 _ _ _ _ _ _, and the system is a fluorine-based decane coupling agent in the acid catalyst The next reaction with 6 dioxo prior particles. Review! The antistatic polyester film of the fifth aspect of the invention, wherein the fluorine: shixi coupling coupling agent is a compound represented by any one of the following Chemical Formulas 4 to 6. Chemical Formula 4 22 1321578 γ Year &quot;月曰修( More) is replacing the fiber! X—(CH 2) m — S i — YI γ Chemical Formula 5 RIX— (CH 2) m — S i — YI γ Chemical Formula 6 RIX—(CH 2]m — S i — RI γ In the chemical formulas 4 to 6, X is selected from CF 3 —, CF 3 —CF 2 —, CF 3 —CF 2 —CF 2 —, (CF 3) 2—CFO— Or CF3 — (CF2) y—CH 2 —O—is one of the groups, y is an integer from 1 to 8, R is an alkyl group of CcC*, and Y is a decyloxy group, an ethoxy group, a methoxyethoxy group. Or a gas atom, m is an integer from 0 to 12. XI. Schema: None 23