TW200914476A - Crosslinkable blends of polyolefin elastomers and silane copolymers for increased flexibility cable insulation - Google Patents
Crosslinkable blends of polyolefin elastomers and silane copolymers for increased flexibility cable insulation Download PDFInfo
- Publication number
- TW200914476A TW200914476A TW097123891A TW97123891A TW200914476A TW 200914476 A TW200914476 A TW 200914476A TW 097123891 A TW097123891 A TW 097123891A TW 97123891 A TW97123891 A TW 97123891A TW 200914476 A TW200914476 A TW 200914476A
- Authority
- TW
- Taiwan
- Prior art keywords
- polyolefin polymer
- resin
- elastomer resin
- polymer
- composition
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 40
- 229920001577 copolymer Polymers 0.000 title claims description 15
- 229920006124 polyolefin elastomer Polymers 0.000 title abstract description 9
- 229910000077 silane Inorganic materials 0.000 title abstract 3
- 238000009413 insulation Methods 0.000 title 1
- 229920000642 polymer Polymers 0.000 claims abstract description 48
- 229920001971 elastomer Polymers 0.000 claims abstract description 37
- 239000000806 elastomer Substances 0.000 claims abstract description 37
- 229920005989 resin Polymers 0.000 claims abstract description 36
- 239000011347 resin Substances 0.000 claims abstract description 36
- 229920000098 polyolefin Polymers 0.000 claims abstract description 30
- 239000002952 polymeric resin Substances 0.000 claims abstract description 17
- 229920003002 synthetic resin Polymers 0.000 claims abstract description 17
- 239000000155 melt Substances 0.000 claims abstract description 10
- 239000012968 metallocene catalyst Substances 0.000 claims abstract description 8
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 claims description 38
- 239000003054 catalyst Substances 0.000 claims description 14
- 239000000126 substance Substances 0.000 claims description 7
- 239000000945 filler Substances 0.000 claims description 5
- 239000003063 flame retardant Substances 0.000 claims description 5
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 4
- 239000005977 Ethylene Substances 0.000 claims description 4
- 239000011810 insulating material Substances 0.000 claims description 4
- 239000000049 pigment Substances 0.000 claims description 4
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 3
- 239000003963 antioxidant agent Substances 0.000 claims description 3
- 230000003078 antioxidant effect Effects 0.000 claims description 3
- 239000000178 monomer Substances 0.000 claims description 2
- AMXXSQQEBVAIEH-UHFFFAOYSA-N C(=C)C(C(OC)(OC)OC)CCCCCCCC.C=C Chemical compound C(=C)C(C(OC)(OC)OC)CCCCCCCC.C=C AMXXSQQEBVAIEH-UHFFFAOYSA-N 0.000 claims 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 abstract 2
- 229920005672 polyolefin resin Polymers 0.000 abstract 1
- -1 polyethylene Polymers 0.000 description 12
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 8
- 230000005070 ripening Effects 0.000 description 8
- 229920000573 polyethylene Polymers 0.000 description 7
- 239000004698 Polyethylene Substances 0.000 description 6
- 239000000654 additive Substances 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 5
- 238000001125 extrusion Methods 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 239000012212 insulator Substances 0.000 description 4
- 238000013008 moisture curing Methods 0.000 description 4
- 239000004594 Masterbatch (MB) Substances 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 150000003254 radicals Chemical class 0.000 description 3
- 229920001187 thermosetting polymer Polymers 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 2
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 238000000071 blow moulding Methods 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 238000001723 curing Methods 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 235000005985 organic acids Nutrition 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- BZQKBFHEWDPQHD-UHFFFAOYSA-N 1,2,3,4,5-pentabromo-6-[2-(2,3,4,5,6-pentabromophenyl)ethyl]benzene Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1CCC1=C(Br)C(Br)=C(Br)C(Br)=C1Br BZQKBFHEWDPQHD-UHFFFAOYSA-N 0.000 description 1
- OZHJEQVYCBTHJT-UHFFFAOYSA-N 1,2,3,4,5-pentabromo-6-methylbenzene Chemical compound CC1=C(Br)C(Br)=C(Br)C(Br)=C1Br OZHJEQVYCBTHJT-UHFFFAOYSA-N 0.000 description 1
- CRSBERNSMYQZNG-UHFFFAOYSA-N 1-dodecene Chemical compound CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 description 1
- BMVXCPBXGZKUPN-UHFFFAOYSA-N 1-hexanamine Chemical compound CCCCCCN BMVXCPBXGZKUPN-UHFFFAOYSA-N 0.000 description 1
- DYIZJUDNMOIZQO-UHFFFAOYSA-N 4,5,6,7-tetrabromo-2-[2-(4,5,6,7-tetrabromo-1,3-dioxoisoindol-2-yl)ethyl]isoindole-1,3-dione Chemical compound O=C1C(C(=C(Br)C(Br)=C2Br)Br)=C2C(=O)N1CCN1C(=O)C2=C(Br)C(Br)=C(Br)C(Br)=C2C1=O DYIZJUDNMOIZQO-UHFFFAOYSA-N 0.000 description 1
- ZUGAOYSWHHGDJY-UHFFFAOYSA-K 5-hydroxy-2,8,9-trioxa-1-aluminabicyclo[3.3.2]decane-3,7,10-trione Chemical compound [Al+3].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O ZUGAOYSWHHGDJY-UHFFFAOYSA-K 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 239000004971 Cross linker Substances 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- VCUFZILGIRCDQQ-KRWDZBQOSA-N N-[[(5S)-2-oxo-3-(2-oxo-3H-1,3-benzoxazol-6-yl)-1,3-oxazolidin-5-yl]methyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C1O[C@H](CN1C1=CC2=C(NC(O2)=O)C=C1)CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F VCUFZILGIRCDQQ-KRWDZBQOSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- HDVDLQFPDLTOSI-UHFFFAOYSA-L O[AlH]O Chemical compound O[AlH]O HDVDLQFPDLTOSI-UHFFFAOYSA-L 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000012963 UV stabilizer Substances 0.000 description 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 229910001570 bauxite Inorganic materials 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- FNAQSUUGMSOBHW-UHFFFAOYSA-H calcium citrate Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O FNAQSUUGMSOBHW-UHFFFAOYSA-H 0.000 description 1
- 239000001354 calcium citrate Substances 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- WHHGLZMJPXIBIX-UHFFFAOYSA-N decabromodiphenyl ether Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1OC1=C(Br)C(Br)=C(Br)C(Br)=C1Br WHHGLZMJPXIBIX-UHFFFAOYSA-N 0.000 description 1
- DIOQZVSQGTUSAI-NJFSPNSNSA-N decane Chemical class CCCCCCCCC[14CH3] DIOQZVSQGTUSAI-NJFSPNSNSA-N 0.000 description 1
- UGQQAJOWXNCOPY-UHFFFAOYSA-N dechlorane plus Chemical compound C12CCC3C(C4(Cl)Cl)(Cl)C(Cl)=C(Cl)C4(Cl)C3CCC2C2(Cl)C(Cl)=C(Cl)C1(Cl)C2(Cl)Cl UGQQAJOWXNCOPY-UHFFFAOYSA-N 0.000 description 1
- AYOHIQLKSOJJQH-UHFFFAOYSA-N dibutyltin Chemical compound CCCC[Sn]CCCC AYOHIQLKSOJJQH-UHFFFAOYSA-N 0.000 description 1
- 239000012975 dibutyltin dilaurate Substances 0.000 description 1
- ZXDVQYBUEVYUCG-UHFFFAOYSA-N dibutyltin(2+);methanolate Chemical compound CCCC[Sn](OC)(OC)CCCC ZXDVQYBUEVYUCG-UHFFFAOYSA-N 0.000 description 1
- 238000004512 die casting Methods 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000010433 feldspar Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- YLQWCDOCJODRMT-UHFFFAOYSA-N fluoren-9-one Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3C2=C1 YLQWCDOCJODRMT-UHFFFAOYSA-N 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- GIWKOZXJDKMGQC-UHFFFAOYSA-L lead(2+);naphthalene-2-carboxylate Chemical compound [Pb+2].C1=CC=CC2=CC(C(=O)[O-])=CC=C21.C1=CC=CC2=CC(C(=O)[O-])=CC=C21 GIWKOZXJDKMGQC-UHFFFAOYSA-L 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000011806 microball Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 229960002446 octanoic acid Drugs 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 229920006285 olefinic elastomer Polymers 0.000 description 1
- 150000007530 organic bases Chemical class 0.000 description 1
- 150000002896 organic halogen compounds Chemical class 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 229920005653 propylene-ethylene copolymer Polymers 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 230000007928 solubilization Effects 0.000 description 1
- 238000005063 solubilization Methods 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000003017 thermal stabilizer Substances 0.000 description 1
- 239000012974 tin catalyst Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- YJGJRYWNNHUESM-UHFFFAOYSA-J triacetyloxystannyl acetate Chemical compound [Sn+4].CC([O-])=O.CC([O-])=O.CC([O-])=O.CC([O-])=O YJGJRYWNNHUESM-UHFFFAOYSA-J 0.000 description 1
- 235000013337 tricalcium citrate Nutrition 0.000 description 1
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 210000003462 vein Anatomy 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen
- C08L23/0892—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen with monomers containing atoms other than carbon, hydrogen or oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L43/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium or a metal; Compositions of derivatives of such polymers
- C08L43/04—Homopolymers or copolymers of monomers containing silicon
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/28—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances natural or synthetic rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
- C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/14—Copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2312/00—Crosslinking
- C08L2312/08—Crosslinking by silane
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- Chemical & Material Sciences (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Physics & Mathematics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Insulating Materials (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Insulated Conductors (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US94645807P | 2007-06-27 | 2007-06-27 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW200914476A true TW200914476A (en) | 2009-04-01 |
Family
ID=39689078
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW097123891A TW200914476A (en) | 2007-06-27 | 2008-06-26 | Crosslinkable blends of polyolefin elastomers and silane copolymers for increased flexibility cable insulation |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US8445786B2 (enExample) |
| EP (1) | EP2164900B1 (enExample) |
| JP (2) | JP6097001B2 (enExample) |
| KR (1) | KR101500779B1 (enExample) |
| CN (2) | CN103122096B (enExample) |
| BR (1) | BRPI0811795A2 (enExample) |
| CA (1) | CA2691206C (enExample) |
| MX (1) | MX2009014239A (enExample) |
| TW (1) | TW200914476A (enExample) |
| WO (1) | WO2009002845A1 (enExample) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2765339A1 (en) * | 2009-07-08 | 2011-01-13 | Queen's University At Kingston | Silane-coupled propylene-based polymer and method |
| JP5526951B2 (ja) * | 2010-04-05 | 2014-06-18 | 株式会社オートネットワーク技術研究所 | 電線被覆材用組成物、絶縁電線及びワイヤーハーネス |
| KR20180107291A (ko) * | 2011-02-04 | 2018-10-01 | 다우 글로벌 테크놀로지스 엘엘씨 | 성형된 텍스쳐화된 스킨 제품용 가교결합성 폴리올레핀 조성물 |
| ES2468817T3 (es) * | 2011-08-26 | 2014-06-17 | Borealis Ag | Cable que comprende una composición polim�rica de silano apta para reticulación |
| CN104575747A (zh) * | 2013-10-13 | 2015-04-29 | 宁夏海洋线缆有限公司 | 一种高防火性能电缆 |
| EP2910595A1 (en) | 2014-02-21 | 2015-08-26 | Borealis AG | Polymer Blends |
| JP6569129B2 (ja) * | 2016-03-22 | 2019-09-04 | 株式会社オートネットワーク技術研究所 | 電線被覆材組成物、絶縁電線およびワイヤーハーネス |
| JP2020513430A (ja) * | 2016-12-02 | 2020-05-14 | ボレアリス エージー | 接着剤用途のためのポリマー組成物 |
| JP7256169B2 (ja) | 2017-07-25 | 2023-04-11 | ダウ シリコーンズ コーポレーション | ポリオレフィン主鎖とポリオルガノシロキサンペンダント基とを有する、グラフトコポリマーを調製するための方法 |
| US12037462B2 (en) | 2018-03-19 | 2024-07-16 | Dow Global Technologies Llc | Polyolefin-polydiorganosiloxane block copolymer and method for the synthesis thereof |
| CA3093558A1 (en) | 2018-03-19 | 2019-09-26 | Dow Silicones Corporation | Polyorganosiloxane hot melt adhesive compositions containing polyolefin - polydiorganoosiloxane copolymers and methods for the preparation and use thereof |
| WO2019182718A1 (en) | 2018-03-19 | 2019-09-26 | Dow Silicones Corporation | Hot melt adhesive composition containing a polyolefin - polydiorganosiloxane copolymer and methods for the preparation and use thereof |
| JP7378411B2 (ja) | 2018-03-19 | 2023-11-13 | ダウ シリコーンズ コーポレーション | ポリオレフィン－ポリジオルガノシロキサンブロックコポリマーおよびその合成のための加水分解反応方法 |
| CN111886288A (zh) * | 2018-04-03 | 2020-11-03 | 伊奎斯塔化学有限公司 | 含液体的聚烯烃母料和方法 |
| BR112020020675B1 (pt) * | 2018-04-27 | 2023-11-28 | Dow Global Technologies Llc | Composição mesclada por fusão, composição reticulada, bainha de fio ou cabo e fio ou cabo |
| JP7334195B2 (ja) | 2018-07-17 | 2023-08-28 | ダウ シリコーンズ コーポレーション | ポリシロキサン樹脂－ポリオレフィンコポリマー並びにその調製方法及び使用方法 |
| MX2021006322A (es) * | 2018-12-27 | 2021-08-11 | Dow Global Technologies Llc | Composiciones de poliolefina reticulada solida para el recubrimiento de alambres y cables. |
| US11837383B2 (en) * | 2020-03-27 | 2023-12-05 | Prysmian S.P.A. | Cables with improved coverings to reduce shrinkback and methods of forming the same |
| EP4172256A1 (en) * | 2020-06-24 | 2023-05-03 | Dow Global Technologies LLC | Cure and functionalization of olefin/silane interpolymers |
| JP7491149B2 (ja) * | 2020-09-03 | 2024-05-28 | 株式会社オートネットワーク技術研究所 | 難燃性樹脂組成物、絶縁電線、ワイヤーハーネス |
| EP4095195A1 (en) | 2021-05-25 | 2022-11-30 | Borealis AG | Crosslinkable polyolefin compositions for wire and cable applications |
Family Cites Families (40)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3225018A (en) * | 1961-12-15 | 1965-12-21 | Union Carbide Corp | Heat curing of ethylene/vinylsilane copolymers |
| BE794718Q (fr) * | 1968-12-20 | 1973-05-16 | Dow Corning Ltd | Procede de reticulation d'olefines |
| JPS5476648A (en) | 1977-11-30 | 1979-06-19 | Hitachi Cable Ltd | Crosslinking of polyolefin and preparation of electrical wire insulated with crosslinked polyolefin |
| JPS54148044A (en) | 1978-04-17 | 1979-11-19 | Mitsui Polychemicals Ltd | Preparation of crosslinked polyethylene |
| JPS60189114A (ja) * | 1984-03-07 | 1985-09-26 | 株式会社フジクラ | 難燃性ケ−ブル |
| US4549041A (en) * | 1983-11-07 | 1985-10-22 | Fujikura Ltd. | Flame-retardant cross-linked composition and flame-retardant cable using same |
| GB8400149D0 (en) | 1984-01-05 | 1984-02-08 | Bp Chem Int Ltd | Polymer composition |
| GB2156825B (en) * | 1984-03-07 | 1987-10-14 | Fujikura Ltd | Flame-retardant cross-linked composition and flame-retardant cable using same |
| JPH0615644B2 (ja) * | 1985-02-25 | 1994-03-02 | 三菱油化株式会社 | シラン架橋性共重合体組成物 |
| CA1280528C (en) * | 1986-06-16 | 1991-02-19 | Barry Topcik | Elastomer polyolefin blends |
| PT90516A (pt) | 1988-05-10 | 1989-11-30 | Union Carbide Corp | Processo para a preparacao de composicoes isoladoras electricas resistentes a arborescencia de agua |
| EP0365289A3 (en) | 1988-10-21 | 1991-10-09 | Neste Oy | Method for producing a filled water-crosslinkable silane copolymer composition |
| GB8927174D0 (en) | 1989-12-01 | 1990-01-31 | Exxon Chemical Patents Inc | Cross-linkable polymer blends |
| US5272236A (en) * | 1991-10-15 | 1993-12-21 | The Dow Chemical Company | Elastic substantially linear olefin polymers |
| FR2668159B1 (fr) | 1990-10-19 | 1993-01-22 | Inst Francais Du Petrole | Compositions reticulables a base de polyethylene et les materiaux qui en derivent. |
| CA2061465A1 (en) * | 1991-02-25 | 1992-08-26 | Craig C. Meverden | Filled hydrolyzable copolymer compositions resistant to premature crosslinking |
| US5278272A (en) * | 1991-10-15 | 1994-01-11 | The Dow Chemical Company | Elastic substantialy linear olefin polymers |
| WO1995009426A1 (en) * | 1993-09-29 | 1995-04-06 | University Of Connecticut | An improved insulated electric cable |
| US5492760A (en) * | 1994-12-05 | 1996-02-20 | At Plastics Inc. | Water tree resistant, moisture curable insulation composition for power cables |
| JP3602704B2 (ja) * | 1997-03-07 | 2004-12-15 | 株式会社クラレ | 樹脂組成物およびそれを用いた多層構造体 |
| US6207754B1 (en) * | 1997-05-29 | 2001-03-27 | Exxon Chemical Patents, Inc. | Low modulus thermoplastic olefin compositions |
| WO2000060615A1 (en) * | 1999-04-01 | 2000-10-12 | At Plastics Inc. | Semiconductive polyolefin compositions and cables covered with the same |
| SE515726C2 (sv) * | 1999-05-05 | 2001-10-01 | Borealis As | Elektrisk kabel |
| JP3069093B1 (ja) | 1999-06-10 | 2000-07-24 | 住友ベークライト株式会社 | シラン架橋ポリオレフィン樹脂組成物及び絶縁ケ―ブル |
| US6331597B1 (en) * | 1999-08-09 | 2001-12-18 | The Dow Chemical Company | Azidosilane-modified, moisture-curable polyolefin polymers, process for making, and articles obtained therefrom |
| CA2290317A1 (en) * | 1999-11-24 | 2001-05-24 | Peter Jackson | Tracking resistant electrical insulating material suitable for high voltage applications |
| US6441097B1 (en) * | 2000-08-03 | 2002-08-27 | King Industries, Inc. | Alkylaryl and arylalkyl monosulfonic acid catalysts for crosslinking polyethylene |
| US6420485B1 (en) * | 2000-08-14 | 2002-07-16 | Dow Corning Corporation | Siloxane-grafted hydrocarbon copolymers |
| US6864429B2 (en) * | 2001-12-17 | 2005-03-08 | General Cable Technologies Corporation | Semiconductive compositions and cable shields employing same |
| EP1524294B1 (en) * | 2002-06-14 | 2008-05-28 | Mitsui Chemicals, Inc. | Thermoplastic resin composition, polymer composition, and molded object obtained from the composition |
| CA2530600A1 (en) * | 2003-06-25 | 2005-01-13 | Union Carbide Chemicals & Plastics Technology Corporation | Moisture crosslinkable polymeric composition containing special antioxidants |
| CN1813006B (zh) * | 2003-06-25 | 2013-03-27 | 陶氏环球技术有限责任公司 | 聚合物组合物--缓蚀剂 |
| US6936655B2 (en) * | 2003-09-02 | 2005-08-30 | Equistar Chemicals, Lp | Crosslinkable flame retardant wire and cable compositions having improved abrasion resistance |
| DE60305928T2 (de) * | 2003-10-24 | 2006-10-12 | Borealis Technology Oy | Niedrigspannungsenergiekabel mit Isolierschicht aus Polyolefin mit polaren Gruppen |
| JP2005213480A (ja) * | 2004-02-02 | 2005-08-11 | Nippon Polyethylene Kk | 難燃性樹脂組成物及びそれを用いた電線・ケーブル |
| CA2574515A1 (en) * | 2004-08-05 | 2006-02-16 | Dow Global Technologies Inc. | Moisture-curable, silane crosslinkable composition |
| CN101142270A (zh) * | 2005-03-18 | 2008-03-12 | 陶氏环球技术公司 | 改进热老化性能的湿可交联聚合组合物 |
| JP2006290961A (ja) * | 2005-04-07 | 2006-10-26 | Nippon Polyethylene Kk | ポリオレフィン樹脂組成物及びそれを用いた成形体 |
| US7232604B2 (en) * | 2005-07-28 | 2007-06-19 | Equistar Chemicals, Lp | Flame retardant crosslinkable compositions and articles |
| JP2007177189A (ja) * | 2005-12-28 | 2007-07-12 | Nippon Polyethylene Kk | エチレン系グラフト変性物及びグラフト変性組成物 |
-
2008
- 2008-06-20 BR BRPI0811795-0A2A patent/BRPI0811795A2/pt not_active Application Discontinuation
- 2008-06-20 EP EP08771595.9A patent/EP2164900B1/en active Active
- 2008-06-20 CN CN201310006852.7A patent/CN103122096B/zh active Active
- 2008-06-20 KR KR1020107001737A patent/KR101500779B1/ko active Active
- 2008-06-20 CA CA2691206A patent/CA2691206C/en active Active
- 2008-06-20 CN CN200880025477.8A patent/CN101755007B/zh active Active
- 2008-06-20 JP JP2010514998A patent/JP6097001B2/ja active Active
- 2008-06-20 MX MX2009014239A patent/MX2009014239A/es active IP Right Grant
- 2008-06-20 WO PCT/US2008/067672 patent/WO2009002845A1/en not_active Ceased
- 2008-06-20 US US12/664,703 patent/US8445786B2/en active Active
- 2008-06-26 TW TW097123891A patent/TW200914476A/zh unknown
-
2014
- 2014-11-17 JP JP2014232606A patent/JP6261490B2/ja active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN103122096B (zh) | 2017-04-12 |
| EP2164900B1 (en) | 2013-05-08 |
| CN101755007B (zh) | 2016-03-09 |
| US20100181092A1 (en) | 2010-07-22 |
| CN103122096A (zh) | 2013-05-29 |
| CN101755007A (zh) | 2010-06-23 |
| BRPI0811795A2 (pt) | 2014-11-11 |
| WO2009002845A1 (en) | 2008-12-31 |
| JP6261490B2 (ja) | 2018-01-17 |
| JP2010531918A (ja) | 2010-09-30 |
| EP2164900A1 (en) | 2010-03-24 |
| JP6097001B2 (ja) | 2017-03-15 |
| KR20100050486A (ko) | 2010-05-13 |
| CA2691206A1 (en) | 2008-12-31 |
| MX2009014239A (es) | 2010-03-04 |
| US8445786B2 (en) | 2013-05-21 |
| KR101500779B1 (ko) | 2015-03-09 |
| CA2691206C (en) | 2016-04-05 |
| JP2015071776A (ja) | 2015-04-16 |
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