KR101500779B1 - 증가된 가요성 케이블 절연을 위한 폴리올레핀 엘라스토머 및 실란 공중합체의 가교성 블렌드 - Google Patents
증가된 가요성 케이블 절연을 위한 폴리올레핀 엘라스토머 및 실란 공중합체의 가교성 블렌드 Download PDFInfo
- Publication number
- KR101500779B1 KR101500779B1 KR1020107001737A KR20107001737A KR101500779B1 KR 101500779 B1 KR101500779 B1 KR 101500779B1 KR 1020107001737 A KR1020107001737 A KR 1020107001737A KR 20107001737 A KR20107001737 A KR 20107001737A KR 101500779 B1 KR101500779 B1 KR 101500779B1
- Authority
- KR
- South Korea
- Prior art keywords
- resin
- polymer
- composition
- silane
- polymeric
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 33
- 229910000077 silane Inorganic materials 0.000 title claims abstract description 25
- 229920001577 copolymer Polymers 0.000 title claims description 11
- 229920006124 polyolefin elastomer Polymers 0.000 title abstract description 13
- 238000009413 insulation Methods 0.000 title description 4
- 229920005989 resin Polymers 0.000 claims abstract description 27
- 239000011347 resin Substances 0.000 claims abstract description 27
- 229920000642 polymer Polymers 0.000 claims abstract description 25
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims abstract description 21
- 229920001971 elastomer Polymers 0.000 claims abstract description 18
- 239000000806 elastomer Substances 0.000 claims abstract description 18
- 239000002952 polymeric resin Substances 0.000 claims abstract description 16
- 229920003002 synthetic resin Polymers 0.000 claims abstract description 16
- 229920000098 polyolefin Polymers 0.000 claims abstract description 11
- 239000012968 metallocene catalyst Substances 0.000 claims abstract description 8
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 7
- 239000000155 melt Substances 0.000 claims description 7
- 229920000573 polyethylene Polymers 0.000 claims description 7
- 239000005977 Ethylene Substances 0.000 claims description 5
- 239000011810 insulating material Substances 0.000 claims description 5
- UKRDPEFKFJNXQM-UHFFFAOYSA-N vinylsilane Chemical compound [SiH3]C=C UKRDPEFKFJNXQM-UHFFFAOYSA-N 0.000 claims description 3
- 239000011342 resin composition Substances 0.000 claims 1
- 229920005672 polyolefin resin Polymers 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 description 13
- 238000000034 method Methods 0.000 description 11
- -1 polyethylene Polymers 0.000 description 9
- 238000001723 curing Methods 0.000 description 8
- 239000004594 Masterbatch (MB) Substances 0.000 description 7
- 239000000654 additive Substances 0.000 description 6
- 238000013008 moisture curing Methods 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 239000004698 Polyethylene Substances 0.000 description 4
- 238000001125 extrusion Methods 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 150000002978 peroxides Chemical class 0.000 description 4
- 150000003254 radicals Chemical class 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 2
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000012975 dibutyltin dilaurate Substances 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 229920001684 low density polyethylene Polymers 0.000 description 2
- 239000004702 low-density polyethylene Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 description 2
- BZQKBFHEWDPQHD-UHFFFAOYSA-N 1,2,3,4,5-pentabromo-6-[2-(2,3,4,5,6-pentabromophenyl)ethyl]benzene Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1CCC1=C(Br)C(Br)=C(Br)C(Br)=C1Br BZQKBFHEWDPQHD-UHFFFAOYSA-N 0.000 description 1
- OZHJEQVYCBTHJT-UHFFFAOYSA-N 1,2,3,4,5-pentabromo-6-methylbenzene Chemical compound CC1=C(Br)C(Br)=C(Br)C(Br)=C1Br OZHJEQVYCBTHJT-UHFFFAOYSA-N 0.000 description 1
- BMVXCPBXGZKUPN-UHFFFAOYSA-N 1-hexanamine Chemical compound CCCCCCN BMVXCPBXGZKUPN-UHFFFAOYSA-N 0.000 description 1
- DYIZJUDNMOIZQO-UHFFFAOYSA-N 4,5,6,7-tetrabromo-2-[2-(4,5,6,7-tetrabromo-1,3-dioxoisoindol-2-yl)ethyl]isoindole-1,3-dione Chemical compound O=C1C(C(=C(Br)C(Br)=C2Br)Br)=C2C(=O)N1CCN1C(=O)C2=C(Br)C(Br)=C(Br)C(Br)=C2C1=O DYIZJUDNMOIZQO-UHFFFAOYSA-N 0.000 description 1
- IGZKXTGKGMPSTG-UHFFFAOYSA-N 4-[(5-bromo-4,6-dichloropyrimidin-2-yl)amino]benzonitrile Chemical compound ClC1=C(Br)C(Cl)=NC(NC=2C=CC(=CC=2)C#N)=N1 IGZKXTGKGMPSTG-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- MXRIRQGCELJRSN-UHFFFAOYSA-N O.O.O.[Al] Chemical compound O.O.O.[Al] MXRIRQGCELJRSN-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 239000012963 UV stabilizer Substances 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- SWLVFNYSXGMGBS-UHFFFAOYSA-N ammonium bromide Chemical compound [NH4+].[Br-] SWLVFNYSXGMGBS-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000000378 calcium silicate Substances 0.000 description 1
- 229910052918 calcium silicate Inorganic materials 0.000 description 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- WHHGLZMJPXIBIX-UHFFFAOYSA-N decabromodiphenyl ether Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1OC1=C(Br)C(Br)=C(Br)C(Br)=C1Br WHHGLZMJPXIBIX-UHFFFAOYSA-N 0.000 description 1
- ZXDVQYBUEVYUCG-UHFFFAOYSA-N dibutyltin(2+);methanolate Chemical compound CCCC[Sn](OC)(OC)CCCC ZXDVQYBUEVYUCG-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 239000010433 feldspar Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 229910021485 fumed silica Inorganic materials 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 230000002140 halogenating effect Effects 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- GIWKOZXJDKMGQC-UHFFFAOYSA-L lead(2+);naphthalene-2-carboxylate Chemical compound [Pb+2].C1=CC=CC2=CC(C(=O)[O-])=CC=C21.C1=CC=CC2=CC(C(=O)[O-])=CC=C21 GIWKOZXJDKMGQC-UHFFFAOYSA-L 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- 238000010128 melt processing Methods 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000004005 microsphere Substances 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 150000007530 organic bases Chemical class 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- 150000003018 phosphorus compounds Chemical class 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920005653 propylene-ethylene copolymer Polymers 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000003017 thermal stabilizer Substances 0.000 description 1
- 239000012974 tin catalyst Substances 0.000 description 1
- 150000003608 titanium Chemical class 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- YJGJRYWNNHUESM-UHFFFAOYSA-J triacetyloxystannyl acetate Chemical compound [Sn+4].CC([O-])=O.CC([O-])=O.CC([O-])=O.CC([O-])=O YJGJRYWNNHUESM-UHFFFAOYSA-J 0.000 description 1
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- CHJMFFKHPHCQIJ-UHFFFAOYSA-L zinc;octanoate Chemical compound [Zn+2].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O CHJMFFKHPHCQIJ-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen
- C08L23/0892—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen with monomers containing atoms other than carbon, hydrogen or oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L43/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium or a metal; Compositions of derivatives of such polymers
- C08L43/04—Homopolymers or copolymers of monomers containing silicon
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/28—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances natural or synthetic rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
- C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/14—Copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2312/00—Crosslinking
- C08L2312/08—Crosslinking by silane
Landscapes
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Insulating Materials (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Insulated Conductors (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US94645807P | 2007-06-27 | 2007-06-27 | |
| US60/946,458 | 2007-06-27 | ||
| PCT/US2008/067672 WO2009002845A1 (en) | 2007-06-27 | 2008-06-20 | Crosslinkable blends of polyolefin elastomers and silane copolymers for increased flexibility cable insulation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20100050486A KR20100050486A (ko) | 2010-05-13 |
| KR101500779B1 true KR101500779B1 (ko) | 2015-03-09 |
Family
ID=39689078
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020107001737A Active KR101500779B1 (ko) | 2007-06-27 | 2008-06-20 | 증가된 가요성 케이블 절연을 위한 폴리올레핀 엘라스토머 및 실란 공중합체의 가교성 블렌드 |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US8445786B2 (enExample) |
| EP (1) | EP2164900B1 (enExample) |
| JP (2) | JP6097001B2 (enExample) |
| KR (1) | KR101500779B1 (enExample) |
| CN (2) | CN101755007B (enExample) |
| BR (1) | BRPI0811795A2 (enExample) |
| CA (1) | CA2691206C (enExample) |
| MX (1) | MX2009014239A (enExample) |
| TW (1) | TW200914476A (enExample) |
| WO (1) | WO2009002845A1 (enExample) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20110009514A1 (en) * | 2009-07-08 | 2011-01-13 | Dow Global Technologies Inc. | Silane-Coupled Propylene-Based Polymer and Method |
| JP5526951B2 (ja) * | 2010-04-05 | 2014-06-18 | 株式会社オートネットワーク技術研究所 | 電線被覆材用組成物、絶縁電線及びワイヤーハーネス |
| US9115620B2 (en) * | 2011-02-04 | 2015-08-25 | Dow Global Technologies Llc | Cross-linkable polyolefin composition for formed textured skin applications |
| ES2468817T3 (es) * | 2011-08-26 | 2014-06-17 | Borealis Ag | Cable que comprende una composición polim�rica de silano apta para reticulación |
| CN104575747A (zh) * | 2013-10-13 | 2015-04-29 | 宁夏海洋线缆有限公司 | 一种高防火性能电缆 |
| EP2910595A1 (en) | 2014-02-21 | 2015-08-26 | Borealis AG | Polymer Blends |
| JP6569129B2 (ja) * | 2016-03-22 | 2019-09-04 | 株式会社オートネットワーク技術研究所 | 電線被覆材組成物、絶縁電線およびワイヤーハーネス |
| WO2018099816A1 (en) * | 2016-12-02 | 2018-06-07 | Borealis Ag | Polymer composition for adhesive applications |
| JP7256169B2 (ja) | 2017-07-25 | 2023-04-11 | ダウ シリコーンズ コーポレーション | ポリオレフィン主鎖とポリオルガノシロキサンペンダント基とを有する、グラフトコポリマーを調製するための方法 |
| US12037462B2 (en) | 2018-03-19 | 2024-07-16 | Dow Global Technologies Llc | Polyolefin-polydiorganosiloxane block copolymer and method for the synthesis thereof |
| EP3768765B1 (en) | 2018-03-19 | 2023-05-17 | Dow Silicones Corporation | Polyolefin-polydiorganosiloxane block copolymer and hydrosilylaton reaction method for the synthesis thereof |
| CA3101628A1 (en) | 2018-03-19 | 2019-09-26 | Dow Silicones Corporation | Hot melt adhesive composition containing a polyolefin - polydiorganoosiloxane copolymer and methods for the preparation and use thereof |
| US11814555B2 (en) | 2018-03-19 | 2023-11-14 | Dow Silicones Corporation | Hot melt adhesive compositions containing polyolefin-polydiorganosiloxane copolymers and methods for the preparation and use thereof |
| WO2019195418A1 (en) * | 2018-04-03 | 2019-10-10 | Equistar Chemicals, Lp | Liquid-containing polyolefin master batches and methods |
| CA3097377A1 (en) * | 2018-04-27 | 2019-10-31 | Dow Global Technologies Llc | Foamed polyolefin compositions for wire and cable coating |
| JP7334195B2 (ja) | 2018-07-17 | 2023-08-28 | ダウ シリコーンズ コーポレーション | ポリシロキサン樹脂-ポリオレフィンコポリマー並びにその調製方法及び使用方法 |
| US20210347968A1 (en) * | 2018-12-27 | 2021-11-11 | Dow Global Technologies Llc | Solid crosslinked polyolefin compositions for wire and cable coating |
| US11837383B2 (en) * | 2020-03-27 | 2023-12-05 | Prysmian S.P.A. | Cables with improved coverings to reduce shrinkback and methods of forming the same |
| US20230279165A1 (en) * | 2020-06-24 | 2023-09-07 | Dow Global Technologies Llc | Cure and functionalization of olefin/silane interpolymers |
| JP7491149B2 (ja) * | 2020-09-03 | 2024-05-28 | 株式会社オートネットワーク技術研究所 | 難燃性樹脂組成物、絶縁電線、ワイヤーハーネス |
| EP4095195A1 (en) | 2021-05-25 | 2022-11-30 | Borealis AG | Crosslinkable polyolefin compositions for wire and cable applications |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR930006208B1 (ko) * | 1984-03-07 | 1993-07-09 | 후지구라 덴센 가부시기 가이샤 | 방화염 교차연결 화합물과 그것을 사용하는 방화염 케이블 |
| US5492760A (en) * | 1994-12-05 | 1996-02-20 | At Plastics Inc. | Water tree resistant, moisture curable insulation composition for power cables |
| US20070027250A1 (en) * | 2005-07-28 | 2007-02-01 | Sebastian Joseph | Flame retardant crosslinkable compositions and articles |
Family Cites Families (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3225018A (en) * | 1961-12-15 | 1965-12-21 | Union Carbide Corp | Heat curing of ethylene/vinylsilane copolymers |
| BE794718Q (fr) * | 1968-12-20 | 1973-05-16 | Dow Corning Ltd | Procede de reticulation d'olefines |
| JPS5476648A (en) | 1977-11-30 | 1979-06-19 | Hitachi Cable Ltd | Crosslinking of polyolefin and preparation of electrical wire insulated with crosslinked polyolefin |
| JPS54148044A (en) | 1978-04-17 | 1979-11-19 | Mitsui Polychemicals Ltd | Preparation of crosslinked polyethylene |
| JPS60189114A (ja) * | 1984-03-07 | 1985-09-26 | 株式会社フジクラ | 難燃性ケ−ブル |
| US4549041A (en) * | 1983-11-07 | 1985-10-22 | Fujikura Ltd. | Flame-retardant cross-linked composition and flame-retardant cable using same |
| GB8400149D0 (en) | 1984-01-05 | 1984-02-08 | Bp Chem Int Ltd | Polymer composition |
| JPH0615644B2 (ja) * | 1985-02-25 | 1994-03-02 | 三菱油化株式会社 | シラン架橋性共重合体組成物 |
| CA1280528C (en) | 1986-06-16 | 1991-02-19 | Barry Topcik | Elastomer polyolefin blends |
| JPH0243244A (ja) | 1988-05-10 | 1990-02-13 | Union Carbide Corp | 耐トリー性組成物 |
| EP0365289A3 (en) | 1988-10-21 | 1991-10-09 | Neste Oy | Method for producing a filled water-crosslinkable silane copolymer composition |
| GB8927174D0 (en) | 1989-12-01 | 1990-01-31 | Exxon Chemical Patents Inc | Cross-linkable polymer blends |
| US5272236A (en) * | 1991-10-15 | 1993-12-21 | The Dow Chemical Company | Elastic substantially linear olefin polymers |
| FR2668159B1 (fr) | 1990-10-19 | 1993-01-22 | Inst Francais Du Petrole | Compositions reticulables a base de polyethylene et les materiaux qui en derivent. |
| CA2061465A1 (en) * | 1991-02-25 | 1992-08-26 | Craig C. Meverden | Filled hydrolyzable copolymer compositions resistant to premature crosslinking |
| US5278272A (en) * | 1991-10-15 | 1994-01-11 | The Dow Chemical Company | Elastic substantialy linear olefin polymers |
| WO1995009426A1 (en) * | 1993-09-29 | 1995-04-06 | University Of Connecticut | An improved insulated electric cable |
| JP3602704B2 (ja) * | 1997-03-07 | 2004-12-15 | 株式会社クラレ | 樹脂組成物およびそれを用いた多層構造体 |
| US6207754B1 (en) * | 1997-05-29 | 2001-03-27 | Exxon Chemical Patents, Inc. | Low modulus thermoplastic olefin compositions |
| WO2000060615A1 (en) * | 1999-04-01 | 2000-10-12 | At Plastics Inc. | Semiconductive polyolefin compositions and cables covered with the same |
| SE515726C2 (sv) * | 1999-05-05 | 2001-10-01 | Borealis As | Elektrisk kabel |
| JP3069093B1 (ja) | 1999-06-10 | 2000-07-24 | 住友ベークライト株式会社 | シラン架橋ポリオレフィン樹脂組成物及び絶縁ケ―ブル |
| US6331597B1 (en) * | 1999-08-09 | 2001-12-18 | The Dow Chemical Company | Azidosilane-modified, moisture-curable polyolefin polymers, process for making, and articles obtained therefrom |
| CA2290317A1 (en) * | 1999-11-24 | 2001-05-24 | Peter Jackson | Tracking resistant electrical insulating material suitable for high voltage applications |
| US6441097B1 (en) * | 2000-08-03 | 2002-08-27 | King Industries, Inc. | Alkylaryl and arylalkyl monosulfonic acid catalysts for crosslinking polyethylene |
| US6420485B1 (en) * | 2000-08-14 | 2002-07-16 | Dow Corning Corporation | Siloxane-grafted hydrocarbon copolymers |
| US6864429B2 (en) * | 2001-12-17 | 2005-03-08 | General Cable Technologies Corporation | Semiconductive compositions and cable shields employing same |
| CN100491456C (zh) * | 2002-06-14 | 2009-05-27 | 三井化学株式会社 | 热塑性树脂组合物、该组合物形成的成型体 |
| JP2007524723A (ja) * | 2003-06-25 | 2007-08-30 | ダウ グローバル テクノロジーズ インコーポレイティド | ポリマー組成物−腐食防止剤 |
| EP1641850A1 (en) * | 2003-06-25 | 2006-04-05 | Union Carbide Chemicals & Plastics Technology Corporation | Moisture crosslinkable polymeric composition containing special antioxidants |
| US6936655B2 (en) * | 2003-09-02 | 2005-08-30 | Equistar Chemicals, Lp | Crosslinkable flame retardant wire and cable compositions having improved abrasion resistance |
| EP1528574B1 (en) * | 2003-10-24 | 2006-06-07 | Borealis Technology Oy | Low voltage power cable with insulation layer comprising polyolefin having polar groups |
| JP2005213480A (ja) * | 2004-02-02 | 2005-08-11 | Nippon Polyethylene Kk | 難燃性樹脂組成物及びそれを用いた電線・ケーブル |
| CA2574515A1 (en) * | 2004-08-05 | 2006-02-16 | Dow Global Technologies Inc. | Moisture-curable, silane crosslinkable composition |
| EP1863873B1 (en) * | 2005-03-18 | 2017-05-17 | Dow Global Technologies LLC | Moisture crosslinkable polymeric composition having improved heat aging performance |
| JP2006290961A (ja) * | 2005-04-07 | 2006-10-26 | Nippon Polyethylene Kk | ポリオレフィン樹脂組成物及びそれを用いた成形体 |
| JP2007177189A (ja) * | 2005-12-28 | 2007-07-12 | Nippon Polyethylene Kk | エチレン系グラフト変性物及びグラフト変性組成物 |
-
2008
- 2008-06-20 CN CN200880025477.8A patent/CN101755007B/zh active Active
- 2008-06-20 CA CA2691206A patent/CA2691206C/en active Active
- 2008-06-20 EP EP08771595.9A patent/EP2164900B1/en active Active
- 2008-06-20 KR KR1020107001737A patent/KR101500779B1/ko active Active
- 2008-06-20 MX MX2009014239A patent/MX2009014239A/es active IP Right Grant
- 2008-06-20 BR BRPI0811795-0A2A patent/BRPI0811795A2/pt not_active Application Discontinuation
- 2008-06-20 US US12/664,703 patent/US8445786B2/en active Active
- 2008-06-20 CN CN201310006852.7A patent/CN103122096B/zh active Active
- 2008-06-20 JP JP2010514998A patent/JP6097001B2/ja active Active
- 2008-06-20 WO PCT/US2008/067672 patent/WO2009002845A1/en not_active Ceased
- 2008-06-26 TW TW097123891A patent/TW200914476A/zh unknown
-
2014
- 2014-11-17 JP JP2014232606A patent/JP6261490B2/ja active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR930006208B1 (ko) * | 1984-03-07 | 1993-07-09 | 후지구라 덴센 가부시기 가이샤 | 방화염 교차연결 화합물과 그것을 사용하는 방화염 케이블 |
| US5492760A (en) * | 1994-12-05 | 1996-02-20 | At Plastics Inc. | Water tree resistant, moisture curable insulation composition for power cables |
| US20070027250A1 (en) * | 2005-07-28 | 2007-02-01 | Sebastian Joseph | Flame retardant crosslinkable compositions and articles |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2010531918A (ja) | 2010-09-30 |
| BRPI0811795A2 (pt) | 2014-11-11 |
| KR20100050486A (ko) | 2010-05-13 |
| WO2009002845A1 (en) | 2008-12-31 |
| MX2009014239A (es) | 2010-03-04 |
| TW200914476A (en) | 2009-04-01 |
| CN101755007A (zh) | 2010-06-23 |
| CA2691206A1 (en) | 2008-12-31 |
| CN103122096A (zh) | 2013-05-29 |
| EP2164900A1 (en) | 2010-03-24 |
| EP2164900B1 (en) | 2013-05-08 |
| CN101755007B (zh) | 2016-03-09 |
| US8445786B2 (en) | 2013-05-21 |
| JP6261490B2 (ja) | 2018-01-17 |
| CA2691206C (en) | 2016-04-05 |
| CN103122096B (zh) | 2017-04-12 |
| US20100181092A1 (en) | 2010-07-22 |
| JP6097001B2 (ja) | 2017-03-15 |
| JP2015071776A (ja) | 2015-04-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR101500779B1 (ko) | 증가된 가요성 케이블 절연을 위한 폴리올레핀 엘라스토머 및 실란 공중합체의 가교성 블렌드 | |
| US10563022B2 (en) | Hydroxyl-terminated PDMS as cure control additive for the silane crosslinking of polyolefins | |
| ES2389622T3 (es) | Composiciones de poliolefina reticuladas por humedad | |
| CA2861113C (en) | Thermoplastic, semiconductive compositions | |
| JP7540949B2 (ja) | ワイヤおよびケーブルコーティング用発泡ポリオレフィン組成物 | |
| US11767419B2 (en) | Non-foam polyolefin compositions for wire and cable coating | |
| EP1170114A1 (de) | Feuchtigkeitsvernetzbare Schrumpfartikel aus Polyolefinelastomeren | |
| KR100843607B1 (ko) | 촉감이 우수한 표면특성을 갖는 올레핀계 열가소성엘라스토머 수지 조성물 및 그 제조방법 | |
| BR112020020688A2 (pt) | Composições de poliolefina não espumantes para revestimento de fios e cabos |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PA0105 | International application |
Patent event date: 20100126 Patent event code: PA01051R01D Comment text: International Patent Application |
|
| PG1501 | Laying open of application | ||
| A201 | Request for examination | ||
| PA0201 | Request for examination |
Patent event code: PA02012R01D Patent event date: 20130530 Comment text: Request for Examination of Application |
|
| E902 | Notification of reason for refusal | ||
| PE0902 | Notice of grounds for rejection |
Comment text: Notification of reason for refusal Patent event date: 20140724 Patent event code: PE09021S01D |
|
| E701 | Decision to grant or registration of patent right | ||
| PE0701 | Decision of registration |
Patent event code: PE07011S01D Comment text: Decision to Grant Registration Patent event date: 20150204 |
|
| GRNT | Written decision to grant | ||
| PR0701 | Registration of establishment |
Comment text: Registration of Establishment Patent event date: 20150303 Patent event code: PR07011E01D |
|
| PR1002 | Payment of registration fee |
Payment date: 20150303 End annual number: 3 Start annual number: 1 |
|
| PG1601 | Publication of registration | ||
| FPAY | Annual fee payment |
Payment date: 20180201 Year of fee payment: 4 |
|
| PR1001 | Payment of annual fee |
Payment date: 20180201 Start annual number: 4 End annual number: 4 |
|
| FPAY | Annual fee payment |
Payment date: 20190129 Year of fee payment: 5 |
|
| PR1001 | Payment of annual fee |
Payment date: 20190129 Start annual number: 5 End annual number: 5 |
|
| FPAY | Annual fee payment |
Payment date: 20200129 Year of fee payment: 6 |
|
| PR1001 | Payment of annual fee |
Payment date: 20200129 Start annual number: 6 End annual number: 6 |
|
| PR1001 | Payment of annual fee |
Payment date: 20210127 Start annual number: 7 End annual number: 7 |
|
| PR1001 | Payment of annual fee |
Payment date: 20220118 Start annual number: 8 End annual number: 8 |
|
| PR1001 | Payment of annual fee |
Payment date: 20230117 Start annual number: 9 End annual number: 9 |
|
| PR1001 | Payment of annual fee |
Payment date: 20240110 Start annual number: 10 End annual number: 10 |
|
| PR1001 | Payment of annual fee |
Payment date: 20250106 Start annual number: 11 End annual number: 11 |