TW200804435A - Halogen-free, flame-retardant wire-and-cable composition and related articles - Google Patents
Halogen-free, flame-retardant wire-and-cable composition and related articles Download PDFInfo
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- TW200804435A TW200804435A TW096115546A TW96115546A TW200804435A TW 200804435 A TW200804435 A TW 200804435A TW 096115546 A TW096115546 A TW 096115546A TW 96115546 A TW96115546 A TW 96115546A TW 200804435 A TW200804435 A TW 200804435A
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- composition
- free
- halogen
- copolymer
- coupling agent
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K21/00—Fireproofing materials
- C09K21/14—Macromolecular materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/016—Flame-proofing or flame-retarding additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
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200804435 九、發明說明: 【發明所屬之技術領域3 發明領域 本發明是關於一種不含iS素、财火的電線電纟覽組成 5物。特別地,本發明是關於適用於製備具有高的耐刮磨性 和柔韌性的一經包覆的汽車電線的一種耐火的組成物。 t先前技術3 發明背景 汽車電線必須通過嚴格要求,包括阻燃性和财到磨 10 性。諸如ISO 6722、LV 112以及J-1128的標準提出關於阻燃 性和财刮磨性的要求。 含有鹵化聚合物或鹵化阻燃劑的組成物已發現在[I且燃 應用中是有用的。但是,這些材料引起健康風險和其他關 注。對為得到汽車電線應用,用於製備一耐火塗層的一不 15 含鹵素的組成物有一需求。 含有高密度聚乙烯和乙烯與不飽和酯之共聚物的組成物 已發現在包覆汽車電線中的效用。遺憾的是,當製備該組成 物或該塗層時’使用南密度聚乙稀增加了加工事項。同樣, 乙烯與不飽和酯之共聚物不產生具有合適的耐刮磨性的塗 20 層。有一對提供極好的加工特徵並產生具有極好的财刮磨性 的塗層的一組成物的需要。同樣有一對為了產生具有高的斷 裂伸長度、機械強度和熔體強度的組成物的需要。 【發明内容3 發明概要 5 200804435 本發明是一種不含函素、而ί火的組成物,它包含一乙 烯/(X-烯烴共聚物、一不含鹵素的無機阻燃劑、用於使該無 機阻燃劑偶合到該共聚物的一偶合劑和一加工助劑。 在一較佳具體例中,本發明是一種經包覆的汽車電 5 線,其中該塗層是由該不含鹵素、耐火的組成物製備。 【實施方式3 較佳實施例之詳細說明 如本文所使用的“聚合物”,是指透過使相同類型或不 同類型的單體聚合而製備的一巨分子化合物。“聚合物”包 10 括均聚物、共聚物、三元共聚物、互聚物等等。該術語“互 聚物”是指透過至少兩種類型的單體或共聚單體的聚合而 製備的一共聚物。它包括但不限制在共聚物(通常是指由兩 種不同類型的單體或共聚單體製備的聚合物,然而它常常 與“互聚物”被交換使用來指由三種或多種不同類型的單體 15 或共聚單體製備的聚合物)、三元共聚物(通常是指由三種不 同類型的單體或共聚單體製備的聚合物)、四元共聚物(通常 是指由四種不同類型的單體或共聚單體製備的聚合物)等等。 該術語“單體”或“共聚單體”可被交換使用,並且它們 是指具有為了產生一聚合物被加入一反應器中的具有一可 20 聚合部分的任何化合物。在那些一聚合物被描述為包含一 個或多個單體的例子中,例如一聚合物包含丙烯和乙烯, 該聚合物當然包含從該等單體衍生的單元,例如 -CH2-CH2-,並且不包含該單體本身,例如CH2=CH2。 在一第一具體例中,本發明是一種不含鹵素、耐火的 6 200804435 組成物,該組成物包含一乙烯/心烯烴共聚物、一不含_素 的無機阻燃劑、用於使該無機阻燃劑偶合到該共聚物的一 偶合劑和一加工助劑。該組成物本質上不含乙烯與不飽和 s旨之共聚物並且本質上不含^化組分。較佳地,該組成物 5缺少乙稀與不飽和酯之任何共聚物並且缺少鹵化組分。 在本發明中有用的該等乙烯/〇1_烯烴共聚物是乙烯與具 有3至12個碳原子、並且較佳地具有4至8個碳原子的一個或 多個α-烯烴之共聚物,或者是這些共聚物的一混合物或摻 合物。該α-烯烴可以在約2%至約12%之間的量出現。當該 1〇共聚物是這些共聚物的一混合物或摻合物時,它可是一機 械摻合或一原位摻合。該等心烯烴的例子是丙烯、卜丁烯、 1-己烯、4-甲基-1_戊稀和1_辛稀。 該等共聚物通常具有一約大於5 〇的多分散性 (Mw/Mn),Mw被定義為重量平均分子量,以及Μη被定義 15 為數目平均分子量。 δ亥專聚合物具有一在約〇 86〇g/cm3至約0.960g/cm3的範 圍内的一密度’並且較佳地具有約〇 915g/cm3至約 〇.945g/cm3的範圍内的一密度。 它們也具有在約0.5g/l〇min至約5.0g/10minK圍内的 20 一熔態指數。溶態指數是按照ASTM D-1238條件E測量的, 並且在190°C和2160g下被測量。 適用於製備這些聚合物的催化劑系統包括但不限制在 金屬茂或限制幾何形狀的催化系統。 该乙烯/α-烯煙共聚物較佳地是以在約2〇wt%至約 7 200804435 80wt%之間的一量出現。 合適的不含i素的無機阻燃劑包括金屬氫氧化物、碳 酸辦和此等之混合物。特別有用的金屬氯氧化物是三氣氧 化銘(也被瞭解為ATH或三水合糾和氫氧傾(也被瞭解為 5二氫氧化鎂)。其他金屬氫氧化物是被在此技術中具有通常 知識者瞭解。較佳地,該金屬氫氧化物是氮氧化鎮。 该金屬氫氧化物的平均粒度可從小於〇1微米至5〇微 米。在一些情況中,希望的是使用具有一奈米級別粒度的 金屬氫氧化4勿。該金屬^氧化物可是自然存在或合成的, 10 被研磨或被沉澱的。 同樣,當該不含鹵素的無機阻燃劑是一金屬氫氧化物 時,希望的是該金屬氫氧化物被細微地分散或具有在約 5m2/g至約15m2/g的範圍内的一比表面,較佳地是在約9m2/g 至約11 m2/g的範圍内。 15 為加強該不含鹵素的無機阻燃劑對該乙烯/α-烯烴共聚 物的偶合,邊阻燃劑可用一偶合劑來表面處理,偶合劑包 括石夕烧、銥酸鹽、錯酸鹽、魏酸和經】嗅丁烯二酸針接枝的 聚合物。合適的塗層包括在美國專利第6,5〇〇,882號中被揭 露的塗層。較佳地,該塗層是以矽烷為主的或以油酸為主 20的。其他合適的偶合劑是被在此技術中具有通常知識者瞭 解。那些經表面處理的、不含鹵素的無機阻燃劑的用途是 在本發明的範圍内。 該不含鹵素的無機阻燃劑較佳地是以約2〇wt%至約 70wt%之間的一量出現。 8 200804435 一省不a i素、耐火組成物可含有其他耐火添加劑。其 他合適的非_化财火添加劑包括紅鱗、二氣切、氧化無、 二氧化鈦、碳奈米管、滑石、黏土、經有機改質的黏土、 $石:氧”聚合物、硼酸鋅、三氧化二銻、灰石、雲母、位阻胺 5女疋劑、八鋇酸銨、八銦酸蜜胺、玻璃料、空心破璃微球、 泡脹化合物、可膨脹石墨、乙二胺磷酸鹽、磷酸三聚氰胺、 焦磷酸二聚氰胺、聚磷酸三聚氰胺和聚磷酸銨。 °亥不合_素、耐火的組成物含有一偶合劑,用來改進 1〇 °亥無機阻燃劑和該共聚物之間的相容性。偶合劑的例子包 八。鈦^鹽、鍅酸鹽、各種經順丁稀二酸酐接枝的聚 ^物、接枝到該聚合物上的川員丁烯二酸酐和此等之混合 &佳地’該偶合劑是—均聚物,或以順Τ烯二酸酸酐 妾枝的共聚物聚乙稀,或以順丁烯二酸野接枝至共聚物的 15 2烯/(?烴共㈣。其他偶合技術對在此技術中具有通常 識者是㈣顯的並且在本發明的範圍内是被考量的。 該等經接枝的烯烴聚合物可透過任何傳統的方法而被 幕^備。 2〇 m 丁烯二_具有共_該等酸基的稀煙不 匕和位置’在相關技射是已知的。反丁稀二酸是順丁稀 :酸的-異構物’也是共耗的’當被加熱時產生水並且重 丁稀二酸肝’並且因此在本發明中是可操作的。 二體和聚合物的混合物被保持在高剪切和熱條件下時, ::空氣、氫過氧化物或其他自由基引發劑的存在下接 可被影響,或在本質缺少這師料下接枝可被影響。儘 9 200804435 管Brabender混合機或Banbury混合機、輥磨機等等也可被用 於形成該接枝聚合物,一種用於生產該接枝聚合物的方便 的方法是擠壓機。較佳的是使用雙嫘桿液化擠壓機(諸如一 Werner_Pfleiderer雙螺桿擠壓機),其中順丁烯二酸酐被混合 5並且在熔融溫度下與該烯烴聚合物反應而產生並擠壓該經 接枝的聚合物。 該經接枝的聚合物的該等酸酐基團大體上構成約 O.OOlwt%至約2.0〇wt%的該接枝聚合物,較佳地構成約 O.Olwt%至約i.〇〇wt%。該經接枝的聚合物的特徵在於沿著 10該聚合物鏈存在側接的酸酐基團。 該偶合劑較佳地是以從約2wt%至約I5wt%的一量存 在’更佳地是在約2wt%至約i3wt%之間。 該不含鹵素、耐火的組成物含有一加工助劑,該加工 助劑是選自由如下構成之群組:矽聚合物、硬脂酸、氟聚 15合物:硬脂酸鋅和此等之混合物。較佳地,該加工助劑是 取紗氣燒和硬脂酸之一組合。 该加工助劑較佳地是以在約〇2wt%至約5 w%的一量存在。 t外’該不含*素、耐火的組成物可含有其他添加劑、 (諸如,密度聚乙烯)、酸給與體、抗氧化劑、安定劑、發泡 20劑:碳黑、顏料、過氧化物和固化促進劑。當一高密度聚 乙稀子在日守匕疋以小於約1 Owt%的一量出現。此外,該 不a ΰ素耐火的組成物可是熱塑性的或經交聯的。 此外’该不含_素、耐火的組成物可含有奈米黏土。 較佳地,該奈米黏土具有一至少在〇·9至2〇〇奈米大小範圍 200804435 内的尺寸,更佳地是至少在〇·9至15〇奈米的尺寸内,又更 佳地是在〇·9至100奈米,以及最佳地是在〇9至3〇奈米。 較佳地,該等奈米黏土是層狀的,包括奈米黏土,諸 如蒙脫石、天然矽酸鈉、氟化合成雲母、皂石、氟鋰皂石、 5合成鋰皂石、海泡石、厄帖浦石、鋰膨潤石、鋁膨潤石、 蛭石、高嶺石、鐵膨潤石、滑鎂皂石、pyr〇she、鋅膨潤石 和斜水石夕鈉石。該等層狀的奈米黏土可是自然存在的或合 成的。 透過使用含有-有機陽離子的化合物處理該奈米黏 10 土 σ亥示米黏土的-些陽離子(例如,鈉離子)可與一有機陽 離子交換。選擇性地’該陽離子可包括一氫離子(質子)或被 一氫離子(質子)代替。較佳的交換陽離子是甲 烧基銨和多烧基銨。-合適的錢化合物的一例子是二甲基 敍二氫化牛油銨。較佳地,以層狀的奈米黏土加上陽離子 15塗層的王。p重里计,該陽離子塗層會以】5加%至術作❹存 在。在最佳的具體例中,以層狀的奈米黏土加上陽離子塗 層的王。P重里β十,s亥陽離子塗層會以大於勤以的存在。 另一較佳的銨塗層是十八烷基銨。 在-經選擇的具體例中,本發明是—種由該不含函 20素、耐火的組成物製造的物件。較佳地該物件是一汽車 電線,該汽車電線是被該組成物製備的一絕緣層所包覆。 其他物件包括用於建築和其他建造的電_和絕緣電線。 【圖式簡單說^明】 (無) 11 200804435 【主要元件符號說明】 (無) 12
Claims (1)
- 200804435 十、申請專利範圍: 1. 一種不含函素、财火的組成物,包含: a. 由一金屬茂或限制幾何催化劑製備的一乙烯/(X-烯烴共聚物,它具有在約2%至約12%範圍内的一cx-烯烴 5 共聚單體含量,大於約5.0的一多分散性指數,在約 0.5§/1〇111丨11至約5.0§/1〇111丨11範圍内的一嫁態指數,以及在 約0.860g/cm3至約0.960g/cm3範圍内的一密度,並且本質 上不含氧原子, b. —不含鹵素的無機阻燃劑, 10 c.一用於使該無機阻燃劑偶合到該共聚物的一偶合 劑,以及 d.—加工助劑, 其中該組成物本質上不含乙烯與不飽和酯之共聚 物並且本質上不含鹵化組分。 15 2.如申請專利範圍第1項所述之不含鹵素、财火的組成 物,其中該不含_素的無機阻燃劑是選自由金屬氫氧化 物、碳酸妈和此等之混合物構成之群組。 3. 如申請專利範圍第1項所述之不含函素、耐火的組成 物,其中該偶合劑是選自由如下構成之群組:矽烷、鈦 20 酸鹽、锆酸鹽、經順丁烯二酸酐接枝的聚合物、接枝到 該共聚合物上的順丁烯二酸酐以及此等之混合物。 4. 如申請專利範圍第3項所述之不含素、耐火的組成 物,其中該偶合劑是經順丁烯二酸酸酐接枝的一聚乙烯。 5. 如申請專利範圍第1項所述之不含函素、财火的組成 13 200804435 物,其中該加工助劑是選自由矽聚合物、硬脂酸、氟聚 合物、硬脂酸辞和此等之混合物構成之群組。 6.如申請專利範圍第5項所述之不含_素、耐火的組成 物,其中該加工助劑是一聚石夕氧烧。 5 7.如申請專利範圍第1項所述之不含鹵素、耐火的組成物 還包含高密度聚乙烯。 8. 如申請專利範圍第1項所述之不含i素、耐火的組成物 還包含一奈米黏土。 9. 一種汽車電線,是被一由申請專利範圍第1項至第8項中 10 任一項所述之不含函素、对火的組成物製備的絕緣層所 包覆。 14 200804435 七、指定代表圖: ' (一)本案指定代表圖為:第()圖。(無) (二)本代表圖之元件符號簡單說明: 八、本案若有化學式時,請揭示最能顯示發明特徵的化學式:
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TR199902072T2 (xx) * | 1997-02-28 | 1999-10-21 | The Dow Chemical Company | Dolgulu polietilen bile�imleri. |
JPH11106430A (ja) * | 1997-10-07 | 1999-04-20 | Asahi Chem Ind Co Ltd | 表面光沢性に優れたエチレン系樹脂 |
JP4181681B2 (ja) * | 1999-02-19 | 2008-11-19 | 日本ユニカー株式会社 | 難燃性エチレン系樹脂組成物及び電線・ケーブル |
JP3807587B2 (ja) * | 1999-07-12 | 2006-08-09 | 協和化学工業株式会社 | 難燃性熱可塑性樹脂組成物及びその成形品 |
JP5105706B2 (ja) * | 2002-06-14 | 2012-12-26 | 三井化学株式会社 | 熱可塑性樹脂組成物、重合体組成物、該組成物からなる成形体 |
CN1784464A (zh) * | 2003-05-05 | 2006-06-07 | 陶氏环球技术公司 | 填充的热塑性烯烃组合物 |
MXPA06002482A (es) * | 2003-09-05 | 2006-06-20 | Oration Union Carbide Chemical | Composicion retardante de flama con excelente procesabilidad. |
WO2006026256A1 (en) * | 2004-08-25 | 2006-03-09 | Dow Global Technologies Inc. | Improved crosslinked and flame retardant automotive wire |
JP2006307176A (ja) * | 2005-03-28 | 2006-11-09 | Sumitomo Chemical Co Ltd | エチレン−α−オレフィン共重合体 |
-
2007
- 2007-05-02 EP EP07776561A patent/EP2016131A1/en not_active Withdrawn
- 2007-05-02 JP JP2009509660A patent/JP2009535487A/ja active Pending
- 2007-05-02 TW TW096115546A patent/TW200804435A/zh unknown
- 2007-05-02 MX MX2008014081A patent/MX2008014081A/es unknown
- 2007-05-02 WO PCT/US2007/010545 patent/WO2007130407A1/en active Application Filing
- 2007-05-02 CA CA002652001A patent/CA2652001A1/en not_active Abandoned
- 2007-05-02 US US12/299,084 patent/US20090131568A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
WO2007130407A1 (en) | 2007-11-15 |
JP2009535487A (ja) | 2009-10-01 |
EP2016131A1 (en) | 2009-01-21 |
US20090131568A1 (en) | 2009-05-21 |
MX2008014081A (es) | 2008-11-14 |
CA2652001A1 (en) | 2007-11-15 |
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