TR201903045T4 - Dimetil disülfür preparasyon yöntemi. - Google Patents
Dimetil disülfür preparasyon yöntemi. Download PDFInfo
- Publication number
- TR201903045T4 TR201903045T4 TR2019/03045T TR201903045T TR201903045T4 TR 201903045 T4 TR201903045 T4 TR 201903045T4 TR 2019/03045 T TR2019/03045 T TR 2019/03045T TR 201903045 T TR201903045 T TR 201903045T TR 201903045 T4 TR201903045 T4 TR 201903045T4
- Authority
- TR
- Turkey
- Prior art keywords
- hydrogen sulfide
- hydrogen
- dimethyl disulfide
- optionally
- reaction
- Prior art date
Links
- WQOXQRCZOLPYPM-UHFFFAOYSA-N dimethyl disulfide Chemical compound CSSC WQOXQRCZOLPYPM-UHFFFAOYSA-N 0.000 title abstract 8
- 238000002360 preparation method Methods 0.000 title abstract 2
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 abstract 12
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 abstract 6
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 abstract 5
- 150000002431 hydrogen Chemical class 0.000 abstract 3
- 229910052739 hydrogen Inorganic materials 0.000 abstract 3
- 239000001257 hydrogen Substances 0.000 abstract 3
- 229910000037 hydrogen sulfide Inorganic materials 0.000 abstract 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- 238000004064 recycling Methods 0.000 abstract 2
- 229910052717 sulfur Inorganic materials 0.000 abstract 2
- 239000011593 sulfur Substances 0.000 abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 238000005984 hydrogenation reaction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
- C07C319/22—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of hydropolysulfides or polysulfides
- C07C319/24—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of hydropolysulfides or polysulfides by reactions involving the formation of sulfur-to-sulfur bonds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/70—Compounds containing carbon and sulfur, e.g. thiophosgene
- C01B32/72—Carbon disulfide
- C01B32/75—Preparation by reacting sulfur or sulfur compounds with hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
- C07C319/02—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of thiols
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
- C07C319/02—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of thiols
- C07C319/06—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of thiols from sulfides, hydropolysulfides or polysulfides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C321/00—Thiols, sulfides, hydropolysulfides or polysulfides
- C07C321/02—Thiols having mercapto groups bound to acyclic carbon atoms
- C07C321/04—Thiols having mercapto groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C321/00—Thiols, sulfides, hydropolysulfides or polysulfides
- C07C321/12—Sulfides, hydropolysulfides, or polysulfides having thio groups bound to acyclic carbon atoms
- C07C321/14—Sulfides, hydropolysulfides, or polysulfides having thio groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00002—Chemical plants
- B01J2219/00027—Process aspects
- B01J2219/00029—Batch processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00002—Chemical plants
- B01J2219/00027—Process aspects
- B01J2219/00033—Continuous processes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Mevcut buluş, dimetil disülfürün preparasyonuna yönelik, kesintili veya kesintisiz, tercihen kesintili yöntem ile ilgili olup, söz konusu yöntem en az aşağıdaki aşamaları içermektedir: a) karbon disülfür (CS2) ve hidrojenin (H2) oluşturulması için hidrojen sülfür (H2S) ve isteğe bağlı olarak kükürt (S) varlığında en az bir hidrokarbonlu dolgunun reaksiyonu, b) metilmerkaptanın (CH3SH), hidrojen sülfürün (H2S) ve isteğe bağlı olarak hidrojenin (H2) oluşturulması için, aşama a)?da elde edilen söz konusu hidrojen (H2) varlığında söz konusu karbon disülfürün (CS2) hidrojenasyon reaksiyonu, c) isteğe bağlı olarak ancak tercihen, aşama b)?de oluşturulan söz konusu hidrojen sülfürün (H2S) aşama a)?ya geri dönüştürülmesi, d) dimetil disülfür ve hidrojen sülfürün oluşturulması için kükürt ile aşama b)?de oluşturulan metilmerkaptanın reaksiyonu, e) isteğe bağlı olarak aşama d)?de oluşturulan hidrojen sülfürün aşama a)?da geri dönüştürülmesi, ve f) dimetil disülfürün geri kazanılması.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1456440A FR3023288B1 (fr) | 2014-07-04 | 2014-07-04 | Procede de preparation de disulfure de dimethyle |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TR201903045T4 true TR201903045T4 (tr) | 2019-03-21 |
Family
ID=53191729
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TR2019/03045T TR201903045T4 (tr) | 2014-07-04 | 2015-06-29 | Dimetil disülfür preparasyon yöntemi. |
Country Status (21)
| Country | Link |
|---|---|
| US (1) | US10550077B2 (tr) |
| EP (1) | EP3164382B1 (tr) |
| JP (2) | JP6698557B2 (tr) |
| KR (2) | KR102174870B1 (tr) |
| CN (1) | CN107074758B (tr) |
| AU (1) | AU2015282544B2 (tr) |
| BR (1) | BR112016030334B1 (tr) |
| CA (1) | CA2952754C (tr) |
| EA (1) | EA031103B1 (tr) |
| ES (1) | ES2714904T3 (tr) |
| FR (1) | FR3023288B1 (tr) |
| MX (1) | MX2016016716A (tr) |
| MY (1) | MY181193A (tr) |
| NZ (1) | NZ727771A (tr) |
| PH (1) | PH12016502484A1 (tr) |
| PL (1) | PL3164382T3 (tr) |
| SG (1) | SG11201610786TA (tr) |
| TR (1) | TR201903045T4 (tr) |
| UA (1) | UA119780C2 (tr) |
| WO (1) | WO2016001554A1 (tr) |
| ZA (1) | ZA201608778B (tr) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR3023288B1 (fr) * | 2014-07-04 | 2016-07-15 | Arkema France | Procede de preparation de disulfure de dimethyle |
| WO2022023365A1 (en) | 2020-07-28 | 2022-02-03 | Totalenergies Se | Process to conduct an endothermic thio-reforming reaction of hydrocarbons in an installation comprising electrified fluidized bed reactor |
| FR3122876B1 (fr) | 2021-05-11 | 2024-03-08 | Arkema France | Procédé de co-production d’alkylmercaptan et de dialkyldisulfure à partir d’alcool |
| EP4101815A1 (en) | 2021-06-10 | 2022-12-14 | Evonik Operations GmbH | Hydrogen sulfide reforming of hydrocarbons |
| EP4169895A1 (en) * | 2021-10-21 | 2023-04-26 | TotalEnergies OneTech | Process and catalyst for conversion of carbon disulphide into c2-c3 olefins |
Family Cites Families (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2668752A (en) * | 1949-11-09 | 1954-02-09 | Fmc Corp | Process for the production of carbon disulfide |
| US2788262A (en) * | 1953-05-01 | 1957-04-09 | Pan American Petroleum Corp | Process for preparation of carbon disulfide |
| FR1412376A (fr) | 1963-09-23 | 1965-10-01 | Aquitaine Petrole | Nouveau procédé pour la fabrication de mercaptans |
| GB1126465A (en) | 1964-09-14 | 1968-09-05 | Ivor Gray Nixon | Manufacture of hydrogen and carbon disulphide |
| FR2130985A5 (tr) * | 1971-03-29 | 1972-11-10 | Aquitaine Petrole | |
| US3880933A (en) * | 1973-05-02 | 1975-04-29 | Phillips Petroleum Co | Hydrogenation of carbon disulfide to methyl mercaptan in presence of hydrogen sulfide |
| US4481181A (en) * | 1982-02-08 | 1984-11-06 | Ga Technologies Inc. | Hydrogen production from in situ partial burning of H2 S |
| ATE59634T1 (de) * | 1985-05-13 | 1991-01-15 | Atochem North America | Verfahren zur herstellung von dialkyldisulfiden. |
| DE68900007D1 (de) | 1988-04-14 | 1990-10-04 | Elf Aquitaine | Verfahren zur herstellung von organischen di- und polysulfiden. |
| US4822938A (en) | 1988-05-03 | 1989-04-18 | Mobil Oil Corporation | Processes for converting methane to higher molecular weight hydrocarbons via sulfur-containing intermediates |
| FR2659079A1 (fr) * | 1990-03-05 | 1991-09-06 | Elf Aquitaine | Procede pour la fabrication de disulfures organiques. |
| FR2781795B1 (fr) | 1998-07-31 | 2000-09-08 | Atochem Elf Sa | Compositions a base de dimethyldisulfure a odeur masquee |
| DE19854427A1 (de) * | 1998-11-25 | 2000-05-31 | Basf Ag | Verfahren zur Herstellung von organischen Disulfiden |
| CA2412057A1 (en) | 2000-06-14 | 2001-12-20 | University Of Wyoming | Apparatus and method for production of methanethiol |
| FR2844208B1 (fr) | 2002-09-06 | 2004-10-15 | Atofina | Purification du h2s par supports poreux |
| WO2004043883A2 (en) | 2002-11-06 | 2004-05-27 | Georgia-Pacific Resins, Inc. | Conversion of carbon disulfide and hydrogen to methyl mercaptans |
| DE10319739A1 (de) | 2003-04-30 | 2004-11-18 | Basf Ag | Katalysator zur Herstellung von Methylmercaptan aus Methanol und Schwefelwasserstoff |
| RU2394023C2 (ru) | 2003-10-10 | 2010-07-10 | Эвоник Дегусса Гмбх | Способ получения метилмеркаптана |
| US7455828B2 (en) * | 2004-03-01 | 2008-11-25 | H2S Technologies, Ltd. | Process and apparatus for converting hydrogen sulfide into hydrogen and sulfur |
| DE102004037739A1 (de) | 2004-08-04 | 2006-03-16 | Degussa Ag | Wolframat enthaltende Katalysatoren zur Synthese von Alkylmercaptan und Verfahren zu ihrer Herstellung |
| JP4666985B2 (ja) * | 2004-09-28 | 2011-04-06 | 国立大学法人北見工業大学 | 低級炭化水素の直接分解装置 |
| US7897292B2 (en) * | 2005-05-18 | 2011-03-01 | Lilliputian Systems, Inc. | Fuel cell apparatus and methods |
| DE102005043151A1 (de) | 2005-09-10 | 2007-03-22 | Degussa Ag | Verfahren zur Herstellung von Methylmercaptan |
| CN101143329A (zh) | 2006-09-11 | 2008-03-19 | 德古萨股份公司 | Mo-O-K基催化剂、其制备方法及其在甲硫醇合成中的应用 |
| US7645906B2 (en) | 2007-03-27 | 2010-01-12 | Chevron Phillips Chemical Company Lp | Graded catalyst bed for methyl mercaptan synthesis |
| DE102007024576A1 (de) | 2007-05-25 | 2009-05-20 | Evonik Degussa Gmbh | Verfahren zur kontinuierlichen Herstellung von Methylmercaptan aus kohlenstoff- und wasserstoffhaltigen Verbindungen |
| CN101468310B (zh) | 2007-12-28 | 2016-11-16 | 赢创德固赛有限责任公司 | 用于从高H2S合成气合成甲硫醇的负载型Mo-O-K-MexOy催化剂 |
| FR2937566B1 (fr) * | 2008-10-24 | 2014-07-18 | Arkema France | Catalyseur d'hydrogenation, notamment de sulfure de carbone |
| WO2010102653A1 (en) * | 2009-03-13 | 2010-09-16 | Eni S.P.A. | Process for the abatement of hydrogen sulphide from compositions containing it with simultaneous production of hydrogen |
| DE102009027837A1 (de) * | 2009-07-20 | 2011-01-27 | Evonik Degussa Gmbh | Verfahren zur kontinuierlichen Herstellung von Methylmercaptan aus kohlenstoffhaltigen Verbindungen, Schwefel und Wasserstoff |
| EP2751276B1 (en) | 2011-09-02 | 2023-01-25 | Arkema France | Preparation process of l-methionine |
| EP2606967A1 (de) | 2011-12-19 | 2013-06-26 | Evonik Degussa GmbH | Katalysator zur Synthese von Alkylmercaptanen und Verfahren zu seiner Herstellung |
| FR3023288B1 (fr) * | 2014-07-04 | 2016-07-15 | Arkema France | Procede de preparation de disulfure de dimethyle |
-
2014
- 2014-07-04 FR FR1456440A patent/FR3023288B1/fr active Active
-
2015
- 2015-06-29 MX MX2016016716A patent/MX2016016716A/es unknown
- 2015-06-29 MY MYPI2016704898A patent/MY181193A/en unknown
- 2015-06-29 WO PCT/FR2015/051761 patent/WO2016001554A1/fr active Application Filing
- 2015-06-29 US US15/323,564 patent/US10550077B2/en active Active
- 2015-06-29 TR TR2019/03045T patent/TR201903045T4/tr unknown
- 2015-06-29 EA EA201692500A patent/EA031103B1/ru not_active IP Right Cessation
- 2015-06-29 UA UAA201700970A patent/UA119780C2/uk unknown
- 2015-06-29 PL PL15736579T patent/PL3164382T3/pl unknown
- 2015-06-29 NZ NZ727771A patent/NZ727771A/en unknown
- 2015-06-29 CN CN201580036343.6A patent/CN107074758B/zh active Active
- 2015-06-29 KR KR1020197002401A patent/KR102174870B1/ko active IP Right Grant
- 2015-06-29 EP EP15736579.2A patent/EP3164382B1/fr active Active
- 2015-06-29 AU AU2015282544A patent/AU2015282544B2/en active Active
- 2015-06-29 CA CA2952754A patent/CA2952754C/fr active Active
- 2015-06-29 KR KR1020177001995A patent/KR20170021863A/ko not_active Application Discontinuation
- 2015-06-29 ES ES15736579T patent/ES2714904T3/es active Active
- 2015-06-29 BR BR112016030334-2A patent/BR112016030334B1/pt active IP Right Grant
- 2015-06-29 SG SG11201610786TA patent/SG11201610786TA/en unknown
- 2015-06-29 JP JP2016575828A patent/JP6698557B2/ja active Active
-
2016
- 2016-12-13 PH PH12016502484A patent/PH12016502484A1/en unknown
- 2016-12-20 ZA ZA2016/08778A patent/ZA201608778B/en unknown
-
2018
- 2018-11-02 JP JP2018207105A patent/JP2019048840A/ja not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| KR20170021863A (ko) | 2017-02-28 |
| UA119780C2 (uk) | 2019-08-12 |
| FR3023288B1 (fr) | 2016-07-15 |
| US10550077B2 (en) | 2020-02-04 |
| CA2952754A1 (fr) | 2016-01-07 |
| WO2016001554A1 (fr) | 2016-01-07 |
| EA201692500A1 (ru) | 2017-04-28 |
| JP2017519790A (ja) | 2017-07-20 |
| CN107074758A (zh) | 2017-08-18 |
| MY181193A (en) | 2020-12-21 |
| PL3164382T3 (pl) | 2019-07-31 |
| KR20190011334A (ko) | 2019-02-01 |
| EA031103B1 (ru) | 2018-11-30 |
| NZ727771A (en) | 2020-08-28 |
| AU2015282544A1 (en) | 2017-01-12 |
| ZA201608778B (en) | 2018-05-30 |
| AU2015282544B2 (en) | 2017-09-14 |
| SG11201610786TA (en) | 2017-01-27 |
| MX2016016716A (es) | 2017-04-13 |
| EP3164382A1 (fr) | 2017-05-10 |
| JP6698557B2 (ja) | 2020-05-27 |
| FR3023288A1 (fr) | 2016-01-08 |
| PH12016502484B1 (en) | 2017-04-10 |
| JP2019048840A (ja) | 2019-03-28 |
| CA2952754C (fr) | 2018-11-06 |
| BR112016030334B1 (pt) | 2021-03-23 |
| KR102174870B1 (ko) | 2020-11-05 |
| ES2714904T3 (es) | 2019-05-30 |
| EP3164382B1 (fr) | 2019-01-16 |
| US20170144966A1 (en) | 2017-05-25 |
| PH12016502484A1 (en) | 2017-04-10 |
| CN107074758B (zh) | 2021-02-26 |
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