BR112018006044A2 - método de produção de mercaptanos por hidrogenólise enzimática de dissulfetos - Google Patents

método de produção de mercaptanos por hidrogenólise enzimática de dissulfetos

Info

Publication number
BR112018006044A2
BR112018006044A2 BR112018006044-5A BR112018006044A BR112018006044A2 BR 112018006044 A2 BR112018006044 A2 BR 112018006044A2 BR 112018006044 A BR112018006044 A BR 112018006044A BR 112018006044 A2 BR112018006044 A2 BR 112018006044A2
Authority
BR
Brazil
Prior art keywords
mercaptans
hydrogenolysis
production
disulfide
enzymatic
Prior art date
Application number
BR112018006044-5A
Other languages
English (en)
Other versions
BR112018006044B1 (pt
Inventor
Fremy Georges
Masselin Arnaud
Original Assignee
Arkema France
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Arkema France filed Critical Arkema France
Publication of BR112018006044A2 publication Critical patent/BR112018006044A2/pt
Publication of BR112018006044B1 publication Critical patent/BR112018006044B1/pt

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C319/00Preparation of thiols, sulfides, hydropolysulfides or polysulfides
    • C07C319/02Preparation of thiols, sulfides, hydropolysulfides or polysulfides of thiols
    • C07C319/06Preparation of thiols, sulfides, hydropolysulfides or polysulfides of thiols from sulfides, hydropolysulfides or polysulfides
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C321/00Thiols, sulfides, hydropolysulfides or polysulfides
    • C07C321/02Thiols having mercapto groups bound to acyclic carbon atoms
    • C07C321/04Thiols having mercapto groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12NMICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
    • C12N9/00Enzymes; Proenzymes; Compositions thereof; Processes for preparing, activating, inhibiting, separating or purifying enzymes
    • C12N9/0004Oxidoreductases (1.)
    • C12N9/0012Oxidoreductases (1.) acting on nitrogen containing compounds as donors (1.4, 1.5, 1.6, 1.7)
    • C12N9/0036Oxidoreductases (1.) acting on nitrogen containing compounds as donors (1.4, 1.5, 1.6, 1.7) acting on NADH or NADPH (1.6)
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12NMICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
    • C12N9/00Enzymes; Proenzymes; Compositions thereof; Processes for preparing, activating, inhibiting, separating or purifying enzymes
    • C12N9/0004Oxidoreductases (1.)
    • C12N9/0051Oxidoreductases (1.) acting on a sulfur group of donors (1.8)
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12PFERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P11/00Preparation of sulfur-containing organic compounds
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12YENZYMES
    • C12Y101/00Oxidoreductases acting on the CH-OH group of donors (1.1)
    • C12Y101/99Oxidoreductases acting on the CH-OH group of donors (1.1) with other acceptors (1.1.99)
    • C12Y101/9901Glucose dehydrogenase (acceptor) (1.1.99.10)
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12YENZYMES
    • C12Y108/00Oxidoreductases acting on sulfur groups as donors (1.8)

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Zoology (AREA)
  • Wood Science & Technology (AREA)
  • Genetics & Genomics (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • General Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • Microbiology (AREA)
  • Biotechnology (AREA)
  • Biomedical Technology (AREA)
  • Molecular Biology (AREA)
  • Medicinal Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)

Abstract

a invenção refere-se a um método de produção por catálise enzimática de mercaptanos a partir de dissulfetos, e em particular de mercaptano de metila a partir de dissulfeto de dimetila.
BR112018006044-5A 2015-09-30 2016-09-29 Método de preparação de um mercaptano de fórmula r-sh BR112018006044B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR1559257A FR3041635B1 (fr) 2015-09-30 2015-09-30 Procede de production de mercaptans par hydrogenolyse enzymatique de disulfures
FR1559257 2015-09-30
PCT/FR2016/052479 WO2017055752A1 (fr) 2015-09-30 2016-09-29 Procédé de production de mercaptans par hydrogénolyse enzymatique de disulfures

Publications (2)

Publication Number Publication Date
BR112018006044A2 true BR112018006044A2 (pt) 2018-10-09
BR112018006044B1 BR112018006044B1 (pt) 2021-12-07

Family

ID=54783825

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112018006044-5A BR112018006044B1 (pt) 2015-09-30 2016-09-29 Método de preparação de um mercaptano de fórmula r-sh

Country Status (16)

Country Link
US (2) US11434513B2 (pt)
EP (1) EP3356325B1 (pt)
JP (2) JP7036714B2 (pt)
KR (1) KR102078951B1 (pt)
CN (1) CN108137493B (pt)
BR (1) BR112018006044B1 (pt)
ES (1) ES2907616T3 (pt)
FR (1) FR3041635B1 (pt)
HU (1) HUE058022T2 (pt)
MY (1) MY196451A (pt)
PL (1) PL3356325T3 (pt)
RU (1) RU2709486C1 (pt)
SA (1) SA518391214B1 (pt)
SG (1) SG11201802687VA (pt)
SI (1) SI3356325T1 (pt)
WO (1) WO2017055752A1 (pt)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3041636B1 (fr) * 2015-09-30 2018-11-16 Arkema France Procede de production de mercaptans par hydrogenolyse enzymatique de disulfures a l'aide d'hydrogene
CN113058621B (zh) * 2019-12-12 2022-02-15 中国科学院大连化学物理研究所 还原型辅酶及其类似物再生催化剂以及制备方法、应用
US20230124898A1 (en) * 2020-04-03 2023-04-20 Wacker Chemie Ag Biocatalyst as a core component of an enzyme-catalyzed redox system for the biocatalytic reduction of cystine

Family Cites Families (28)

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DE2508709C2 (de) 1975-02-28 1985-02-07 Bayer Ag, 5090 Leverkusen Trisphenole
US4059636A (en) * 1976-05-04 1977-11-22 Phillips Petroleum Company Mercaptans by catalytic cleavage of organic sulfides
JPS6013668B2 (ja) 1980-09-25 1985-04-09 協和醗酵工業株式会社 グルタチオン・パ−オキシダ−ゼの製造法
JPS61247391A (ja) * 1985-04-24 1986-11-04 Ebara Res Co Ltd メチルメルカプタンの製造方法
FR2711366B1 (fr) 1993-10-20 1995-12-15 Elf Aquitaine Synthèse du méthylmercaptan à partir du diméthyldisulfure.
EP0770686A1 (fr) * 1995-10-25 1997-05-02 Societe Des Produits Nestle S.A. Procédé de préparation de thiols
BR0111690A (pt) 2000-06-14 2003-10-07 Univ Wyoming Equipamento e método para produção de metanotiol
DE10319739A1 (de) 2003-04-30 2004-11-18 Basf Ag Katalysator zur Herstellung von Methylmercaptan aus Methanol und Schwefelwasserstoff
EP1670754A2 (en) 2003-10-10 2006-06-21 Degussa AG Process for the manufacture of methylmercaptan
WO2005107723A2 (en) 2004-05-06 2005-11-17 Rashid Buttar Transdermal delivery systems and transdermal chelation preparations
WO2005115173A1 (en) * 2004-05-24 2005-12-08 Ott David M Medicinal products incorporating bound organosulfur groups
DE102004037739A1 (de) 2004-08-04 2006-03-16 Degussa Ag Wolframat enthaltende Katalysatoren zur Synthese von Alkylmercaptan und Verfahren zu ihrer Herstellung
DE102005043151A1 (de) 2005-09-10 2007-03-22 Degussa Ag Verfahren zur Herstellung von Methylmercaptan
CN101143329A (zh) 2006-09-11 2008-03-19 德古萨股份公司 Mo-O-K基催化剂、其制备方法及其在甲硫醇合成中的应用
US7645906B2 (en) 2007-03-27 2010-01-12 Chevron Phillips Chemical Company Lp Graded catalyst bed for methyl mercaptan synthesis
DE102007024576A1 (de) 2007-05-25 2009-05-20 Evonik Degussa Gmbh Verfahren zur kontinuierlichen Herstellung von Methylmercaptan aus kohlenstoff- und wasserstoffhaltigen Verbindungen
AT505436B1 (de) * 2007-07-10 2009-03-15 Univ Graz Enzymkatalysiertes verfahren zur oxidativen spaltung von ethylenischen doppelbindungen
WO2009060573A1 (ja) 2007-11-07 2009-05-14 Nippon Kayaku Kabushiki Kaisha 水溶性ナフタロシアニン色素及びこれを含有する水系インク
FR2937566B1 (fr) 2008-10-24 2014-07-18 Arkema France Catalyseur d'hydrogenation, notamment de sulfure de carbone
DE102009027837A1 (de) 2009-07-20 2011-01-27 Evonik Degussa Gmbh Verfahren zur kontinuierlichen Herstellung von Methylmercaptan aus kohlenstoffhaltigen Verbindungen, Schwefel und Wasserstoff
RU2673190C1 (ru) * 2010-12-29 2018-11-22 СиДжей ЧеилДжеданг Корпорейшн Способ получения L-метионина и органической кислоты
EP2606967A1 (de) 2011-12-19 2013-06-26 Evonik Degussa GmbH Katalysator zur Synthese von Alkylmercaptanen und Verfahren zu seiner Herstellung
FR2994974B1 (fr) 2012-08-30 2015-05-01 Arkema France Distillation reactive des dso
CN103053703B (zh) 2013-01-18 2014-06-04 岑溪市信畅坚果开发有限公司 澳洲坚果豆腐的制作方法
JP2015130808A (ja) * 2014-01-10 2015-07-23 株式会社ダイセル 発酵性基質から高い選択率でアルキルジオールを生成する組換え微生物及びその利用
FR3041659B1 (fr) * 2015-09-30 2017-10-20 Arkema France Procede de production de l-methionine
FR3041636B1 (fr) 2015-09-30 2018-11-16 Arkema France Procede de production de mercaptans par hydrogenolyse enzymatique de disulfures a l'aide d'hydrogene
JP7286980B2 (ja) * 2019-01-29 2023-06-06 富士フイルムビジネスイノベーション株式会社 多孔質ポリイミド膜、リチウムイオン二次電池用セパレータ、リチウムイオン二次電池、及び全固体電池

Also Published As

Publication number Publication date
RU2709486C1 (ru) 2019-12-18
JP2020188784A (ja) 2020-11-26
WO2017055752A1 (fr) 2017-04-06
SG11201802687VA (en) 2018-05-30
US20220372530A1 (en) 2022-11-24
KR102078951B1 (ko) 2020-02-19
ES2907616T3 (es) 2022-04-25
SA518391214B1 (ar) 2022-12-05
EP3356325A1 (fr) 2018-08-08
PL3356325T3 (pl) 2022-04-19
HUE058022T2 (hu) 2022-06-28
CN108137493A (zh) 2018-06-08
FR3041635B1 (fr) 2019-01-25
KR20180053754A (ko) 2018-05-23
FR3041635A1 (fr) 2017-03-31
US11434513B2 (en) 2022-09-06
SI3356325T1 (sl) 2022-04-29
CN108137493B (zh) 2020-09-29
EP3356325B1 (fr) 2022-01-26
JP2018529358A (ja) 2018-10-11
BR112018006044B1 (pt) 2021-12-07
JP7036714B2 (ja) 2022-03-15
MY196451A (en) 2023-04-12
US20190055586A1 (en) 2019-02-21

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Legal Events

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B06U Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 29/09/2016, OBSERVADAS AS CONDICOES LEGAIS.