EA201692500A1 - Способ получения диметилдисульфида - Google Patents
Способ получения диметилдисульфидаInfo
- Publication number
- EA201692500A1 EA201692500A1 EA201692500A EA201692500A EA201692500A1 EA 201692500 A1 EA201692500 A1 EA 201692500A1 EA 201692500 A EA201692500 A EA 201692500A EA 201692500 A EA201692500 A EA 201692500A EA 201692500 A1 EA201692500 A1 EA 201692500A1
- Authority
- EA
- Eurasian Patent Office
- Prior art keywords
- hydrogen
- optionally
- hydrogen sulfide
- disulfide
- producing
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
- C07C319/22—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of hydropolysulfides or polysulfides
- C07C319/24—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of hydropolysulfides or polysulfides by reactions involving the formation of sulfur-to-sulfur bonds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/70—Compounds containing carbon and sulfur, e.g. thiophosgene
- C01B32/72—Carbon disulfide
- C01B32/75—Preparation by reacting sulfur or sulfur compounds with hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
- C07C319/02—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of thiols
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
- C07C319/02—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of thiols
- C07C319/06—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of thiols from sulfides, hydropolysulfides or polysulfides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C321/00—Thiols, sulfides, hydropolysulfides or polysulfides
- C07C321/02—Thiols having mercapto groups bound to acyclic carbon atoms
- C07C321/04—Thiols having mercapto groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C321/00—Thiols, sulfides, hydropolysulfides or polysulfides
- C07C321/12—Sulfides, hydropolysulfides, or polysulfides having thio groups bound to acyclic carbon atoms
- C07C321/14—Sulfides, hydropolysulfides, or polysulfides having thio groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00002—Chemical plants
- B01J2219/00027—Process aspects
- B01J2219/00029—Batch processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00002—Chemical plants
- B01J2219/00027—Process aspects
- B01J2219/00033—Continuous processes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Настоящее изобретение относится к периодическому или непрерывному способу получения диметилдисульфида, предпочтительно непрерывному, где упомянутый способ включает, по меньшей мере, следующие стадии: а) взаимодействие, по меньшей мере, углеводородного сырья в присутствии сероводорода (HS) и необязательно серы (S), например, для образования дисульфида углерода (CS) и водорода (Н); b) взаимодействие упомянутого дисульфида углерода (CS) путем гидрирования с присутствующим упомянутым водородом (Н), полученным в стадии а), например, с образованием метилмеркаптана (CHSH), сероводорода (HS) и необязательно водорода (Н), с) необязательно, но предпочтительно рециркуляцию упомянутого сероводорода (HS), образованного в стадии b), в стадию a); d) взаимодействие метилмеркаптана, образованного в стадии b), с серой, например, с образованием диметилдисульфида и сероводорода; е) необязательно рециркуляцию сероводорода, образованного в стадии d), в стадию а) и f) выделение диметилдисульфида.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1456440A FR3023288B1 (fr) | 2014-07-04 | 2014-07-04 | Procede de preparation de disulfure de dimethyle |
| PCT/FR2015/051761 WO2016001554A1 (fr) | 2014-07-04 | 2015-06-29 | Procédé de préparation de disulfure de diméthyle |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EA201692500A1 true EA201692500A1 (ru) | 2017-04-28 |
| EA031103B1 EA031103B1 (ru) | 2018-11-30 |
Family
ID=53191729
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EA201692500A EA031103B1 (ru) | 2014-07-04 | 2015-06-29 | Способ получения диметилдисульфида |
Country Status (21)
| Country | Link |
|---|---|
| US (1) | US10550077B2 (ru) |
| EP (1) | EP3164382B1 (ru) |
| JP (2) | JP6698557B2 (ru) |
| KR (2) | KR102174870B1 (ru) |
| CN (1) | CN107074758B (ru) |
| AU (1) | AU2015282544B2 (ru) |
| BR (1) | BR112016030334B1 (ru) |
| CA (1) | CA2952754C (ru) |
| EA (1) | EA031103B1 (ru) |
| ES (1) | ES2714904T3 (ru) |
| FR (1) | FR3023288B1 (ru) |
| MX (1) | MX2016016716A (ru) |
| MY (1) | MY181193A (ru) |
| NZ (1) | NZ727771A (ru) |
| PH (1) | PH12016502484B1 (ru) |
| PL (1) | PL3164382T3 (ru) |
| SG (1) | SG11201610786TA (ru) |
| TR (1) | TR201903045T4 (ru) |
| UA (1) | UA119780C2 (ru) |
| WO (1) | WO2016001554A1 (ru) |
| ZA (1) | ZA201608778B (ru) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR3023288B1 (fr) * | 2014-07-04 | 2016-07-15 | Arkema France | Procede de preparation de disulfure de dimethyle |
| WO2022023365A1 (en) | 2020-07-28 | 2022-02-03 | Totalenergies Se | Process to conduct an endothermic thio-reforming reaction of hydrocarbons in an installation comprising electrified fluidized bed reactor |
| FR3122876B1 (fr) * | 2021-05-11 | 2024-03-08 | Arkema France | Procédé de co-production d’alkylmercaptan et de dialkyldisulfure à partir d’alcool |
| EP4101815A1 (en) | 2021-06-10 | 2022-12-14 | Evonik Operations GmbH | Hydrogen sulfide reforming of hydrocarbons |
| EP4169895A1 (en) * | 2021-10-21 | 2023-04-26 | TotalEnergies OneTech | Process and catalyst for conversion of carbon disulphide into c2-c3 olefins |
Family Cites Families (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2668752A (en) * | 1949-11-09 | 1954-02-09 | Fmc Corp | Process for the production of carbon disulfide |
| US2788262A (en) * | 1953-05-01 | 1957-04-09 | Pan American Petroleum Corp | Process for preparation of carbon disulfide |
| FR1412376A (fr) | 1963-09-23 | 1965-10-01 | Aquitaine Petrole | Nouveau procédé pour la fabrication de mercaptans |
| GB1126465A (en) | 1964-09-14 | 1968-09-05 | Ivor Gray Nixon | Manufacture of hydrogen and carbon disulphide |
| FR2130985A5 (ru) * | 1971-03-29 | 1972-11-10 | Aquitaine Petrole | |
| US3880933A (en) * | 1973-05-02 | 1975-04-29 | Phillips Petroleum Co | Hydrogenation of carbon disulfide to methyl mercaptan in presence of hydrogen sulfide |
| US4481181A (en) * | 1982-02-08 | 1984-11-06 | Ga Technologies Inc. | Hydrogen production from in situ partial burning of H2 S |
| EP0202420B1 (en) * | 1985-05-13 | 1991-01-02 | ATOCHEM NORTH AMERICA, INC. (a Pennsylvania corp.) | Process for the manufacture of dialkyl disulfides |
| DE68900007D1 (de) | 1988-04-14 | 1990-10-04 | Elf Aquitaine | Verfahren zur herstellung von organischen di- und polysulfiden. |
| US4822938A (en) | 1988-05-03 | 1989-04-18 | Mobil Oil Corporation | Processes for converting methane to higher molecular weight hydrocarbons via sulfur-containing intermediates |
| FR2659079A1 (fr) * | 1990-03-05 | 1991-09-06 | Elf Aquitaine | Procede pour la fabrication de disulfures organiques. |
| FR2781795B1 (fr) | 1998-07-31 | 2000-09-08 | Atochem Elf Sa | Compositions a base de dimethyldisulfure a odeur masquee |
| DE19854427A1 (de) * | 1998-11-25 | 2000-05-31 | Basf Ag | Verfahren zur Herstellung von organischen Disulfiden |
| BR0111690A (pt) | 2000-06-14 | 2003-10-07 | Univ Wyoming | Equipamento e método para produção de metanotiol |
| FR2844208B1 (fr) | 2002-09-06 | 2004-10-15 | Atofina | Purification du h2s par supports poreux |
| US20040152921A1 (en) | 2002-11-06 | 2004-08-05 | Georgia-Pacific Resins, Inc. | Conversion of carbon disulfide and hydrogen to methyl mercaptans |
| DE10319739A1 (de) | 2003-04-30 | 2004-11-18 | Basf Ag | Katalysator zur Herstellung von Methylmercaptan aus Methanol und Schwefelwasserstoff |
| EP1670754A2 (en) | 2003-10-10 | 2006-06-21 | Degussa AG | Process for the manufacture of methylmercaptan |
| US7455828B2 (en) * | 2004-03-01 | 2008-11-25 | H2S Technologies, Ltd. | Process and apparatus for converting hydrogen sulfide into hydrogen and sulfur |
| DE102004037739A1 (de) | 2004-08-04 | 2006-03-16 | Degussa Ag | Wolframat enthaltende Katalysatoren zur Synthese von Alkylmercaptan und Verfahren zu ihrer Herstellung |
| JP4666985B2 (ja) * | 2004-09-28 | 2011-04-06 | 国立大学法人北見工業大学 | 低級炭化水素の直接分解装置 |
| US7897292B2 (en) * | 2005-05-18 | 2011-03-01 | Lilliputian Systems, Inc. | Fuel cell apparatus and methods |
| DE102005043151A1 (de) | 2005-09-10 | 2007-03-22 | Degussa Ag | Verfahren zur Herstellung von Methylmercaptan |
| CN101143329A (zh) | 2006-09-11 | 2008-03-19 | 德古萨股份公司 | Mo-O-K基催化剂、其制备方法及其在甲硫醇合成中的应用 |
| US7645906B2 (en) | 2007-03-27 | 2010-01-12 | Chevron Phillips Chemical Company Lp | Graded catalyst bed for methyl mercaptan synthesis |
| DE102007024576A1 (de) | 2007-05-25 | 2009-05-20 | Evonik Degussa Gmbh | Verfahren zur kontinuierlichen Herstellung von Methylmercaptan aus kohlenstoff- und wasserstoffhaltigen Verbindungen |
| CN101468310B (zh) | 2007-12-28 | 2016-11-16 | 赢创德固赛有限责任公司 | 用于从高H2S合成气合成甲硫醇的负载型Mo-O-K-MexOy催化剂 |
| FR2937566B1 (fr) * | 2008-10-24 | 2014-07-18 | Arkema France | Catalyseur d'hydrogenation, notamment de sulfure de carbone |
| WO2010102653A1 (en) * | 2009-03-13 | 2010-09-16 | Eni S.P.A. | Process for the abatement of hydrogen sulphide from compositions containing it with simultaneous production of hydrogen |
| DE102009027837A1 (de) * | 2009-07-20 | 2011-01-27 | Evonik Degussa Gmbh | Verfahren zur kontinuierlichen Herstellung von Methylmercaptan aus kohlenstoffhaltigen Verbindungen, Schwefel und Wasserstoff |
| SG2014010441A (en) | 2011-09-02 | 2014-08-28 | Arkema France | Preparation process of l-methionine |
| EP2606967A1 (de) | 2011-12-19 | 2013-06-26 | Evonik Degussa GmbH | Katalysator zur Synthese von Alkylmercaptanen und Verfahren zu seiner Herstellung |
| FR3023288B1 (fr) * | 2014-07-04 | 2016-07-15 | Arkema France | Procede de preparation de disulfure de dimethyle |
-
2014
- 2014-07-04 FR FR1456440A patent/FR3023288B1/fr active Active
-
2015
- 2015-06-29 BR BR112016030334-2A patent/BR112016030334B1/pt active IP Right Grant
- 2015-06-29 JP JP2016575828A patent/JP6698557B2/ja active Active
- 2015-06-29 TR TR2019/03045T patent/TR201903045T4/tr unknown
- 2015-06-29 ES ES15736579T patent/ES2714904T3/es active Active
- 2015-06-29 CA CA2952754A patent/CA2952754C/fr active Active
- 2015-06-29 AU AU2015282544A patent/AU2015282544B2/en active Active
- 2015-06-29 EA EA201692500A patent/EA031103B1/ru not_active IP Right Cessation
- 2015-06-29 UA UAA201700970A patent/UA119780C2/uk unknown
- 2015-06-29 KR KR1020197002401A patent/KR102174870B1/ko active IP Right Grant
- 2015-06-29 KR KR1020177001995A patent/KR20170021863A/ko not_active Application Discontinuation
- 2015-06-29 PL PL15736579T patent/PL3164382T3/pl unknown
- 2015-06-29 US US15/323,564 patent/US10550077B2/en active Active
- 2015-06-29 SG SG11201610786TA patent/SG11201610786TA/en unknown
- 2015-06-29 NZ NZ727771A patent/NZ727771A/en unknown
- 2015-06-29 WO PCT/FR2015/051761 patent/WO2016001554A1/fr active Application Filing
- 2015-06-29 CN CN201580036343.6A patent/CN107074758B/zh active Active
- 2015-06-29 MY MYPI2016704898A patent/MY181193A/en unknown
- 2015-06-29 MX MX2016016716A patent/MX2016016716A/es unknown
- 2015-06-29 EP EP15736579.2A patent/EP3164382B1/fr active Active
-
2016
- 2016-12-13 PH PH12016502484A patent/PH12016502484B1/en unknown
- 2016-12-20 ZA ZA2016/08778A patent/ZA201608778B/en unknown
-
2018
- 2018-11-02 JP JP2018207105A patent/JP2019048840A/ja not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| EA031103B1 (ru) | 2018-11-30 |
| SG11201610786TA (en) | 2017-01-27 |
| JP6698557B2 (ja) | 2020-05-27 |
| PH12016502484A1 (en) | 2017-04-10 |
| NZ727771A (en) | 2020-08-28 |
| MX2016016716A (es) | 2017-04-13 |
| ES2714904T3 (es) | 2019-05-30 |
| JP2017519790A (ja) | 2017-07-20 |
| US10550077B2 (en) | 2020-02-04 |
| KR20170021863A (ko) | 2017-02-28 |
| AU2015282544B2 (en) | 2017-09-14 |
| AU2015282544A1 (en) | 2017-01-12 |
| CA2952754A1 (fr) | 2016-01-07 |
| EP3164382B1 (fr) | 2019-01-16 |
| EP3164382A1 (fr) | 2017-05-10 |
| MY181193A (en) | 2020-12-21 |
| US20170144966A1 (en) | 2017-05-25 |
| WO2016001554A1 (fr) | 2016-01-07 |
| KR102174870B1 (ko) | 2020-11-05 |
| TR201903045T4 (tr) | 2019-03-21 |
| CN107074758B (zh) | 2021-02-26 |
| CN107074758A (zh) | 2017-08-18 |
| ZA201608778B (en) | 2018-05-30 |
| JP2019048840A (ja) | 2019-03-28 |
| CA2952754C (fr) | 2018-11-06 |
| KR20190011334A (ko) | 2019-02-01 |
| PL3164382T3 (pl) | 2019-07-31 |
| FR3023288B1 (fr) | 2016-07-15 |
| BR112016030334B1 (pt) | 2021-03-23 |
| FR3023288A1 (fr) | 2016-01-08 |
| PH12016502484B1 (en) | 2017-04-10 |
| UA119780C2 (uk) | 2019-08-12 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s) |
Designated state(s): AM BY KG TJ |