TR200001681T2 - Palladyum, altın, bakır kapsayan vinil asetat katalizörü. - Google Patents
Palladyum, altın, bakır kapsayan vinil asetat katalizörü.Info
- Publication number
- TR200001681T2 TR200001681T2 TR2000/01681T TR200001681T TR200001681T2 TR 200001681 T2 TR200001681 T2 TR 200001681T2 TR 2000/01681 T TR2000/01681 T TR 2000/01681T TR 200001681 T TR200001681 T TR 200001681T TR 200001681 T2 TR200001681 T2 TR 200001681T2
- Authority
- TR
- Turkey
- Prior art keywords
- gold
- copper
- vinyl acetate
- catalyst including
- acetate catalyst
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8946—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali or alkaline earth metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/48—Silver or gold
- B01J23/52—Gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/8926—Copper and noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0201—Oxygen-containing compounds
- B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/16—Reducing
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
- C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
- C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Metalik palladyum ve altinin katalitik olarak etkin miktarlarinin, serbest metal olarak bakirin ya da bakir asetatin ve magnezyum, kalsiyum, baryum ve zirkonyumdan meydana gelen gruptan seçilen bir dördüncü metalin oksidi ya da oksit ve serbest metalin bir oksidi halinde biriktigi gözenekli yüzeyler üzerinde, gözenekli bir destegi kapsayan reaktanlar olarak, etilen, oksijen asetik asetik asidin reaksiyonu ile vinil asetatin üretilmesi için bir katalizör.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/989,886 US6072078A (en) | 1997-12-12 | 1997-12-12 | Vinyl acetate production using a catalyst comprising palladium, gold, copper and any of certain fourth metals |
Publications (1)
Publication Number | Publication Date |
---|---|
TR200001681T2 true TR200001681T2 (tr) | 2001-01-22 |
Family
ID=25535562
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
TR2000/01681T TR200001681T2 (tr) | 1997-12-12 | 1998-12-03 | Palladyum, altın, bakır kapsayan vinil asetat katalizörü. |
Country Status (26)
Country | Link |
---|---|
US (2) | US6072078A (tr) |
EP (1) | EP1037706A1 (tr) |
JP (1) | JP4287999B2 (tr) |
KR (1) | KR20010033066A (tr) |
CN (1) | CN1104281C (tr) |
AR (1) | AR017429A1 (tr) |
AU (1) | AU736524B2 (tr) |
BR (1) | BR9813466A (tr) |
CA (1) | CA2312351C (tr) |
CZ (1) | CZ295487B6 (tr) |
HU (1) | HUP0004462A3 (tr) |
ID (1) | ID24889A (tr) |
MX (1) | MXPA00005760A (tr) |
MY (1) | MY116306A (tr) |
NO (1) | NO323902B1 (tr) |
NZ (1) | NZ505647A (tr) |
PE (1) | PE65199A1 (tr) |
PL (1) | PL340765A1 (tr) |
RU (1) | RU2202411C2 (tr) |
SA (1) | SA98190906B1 (tr) |
TR (1) | TR200001681T2 (tr) |
TW (1) | TW516975B (tr) |
UA (1) | UA60349C2 (tr) |
WO (1) | WO1999030818A1 (tr) |
YU (1) | YU49231B (tr) |
ZA (1) | ZA9811383B (tr) |
Families Citing this family (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB9810928D0 (en) * | 1998-05-22 | 1998-07-22 | Bp Chem Int Ltd | Catalyst and process |
DE19843693A1 (de) * | 1998-09-24 | 2000-03-30 | Degussa | Trägerkatalysator für die Produktion von Vinylacetatmonomer |
US6303537B1 (en) * | 1999-11-17 | 2001-10-16 | Celanese International Corporation | Vinyl acetate catalyst comprising metallic palladium and gold and prepared utilizing sonication |
TWI255736B (en) * | 2002-02-05 | 2006-06-01 | Basf Ag | A catalyst composition for the oxychlorination of ethylene and its use |
CA2778784A1 (en) * | 2003-06-13 | 2005-01-20 | Chevron U.S.A. Inc. | Method for making hydrogen using a gold containing water-gas shift catalyst |
TW201236755A (en) * | 2003-12-19 | 2012-09-16 | Celanese Int Corp | Halide free precursors for catalysts |
CN100457257C (zh) * | 2003-12-19 | 2009-02-04 | 国际人造丝公司 | 催化剂用含氧化锆载体材料 |
US7468455B2 (en) | 2004-11-03 | 2008-12-23 | Velocys, Inc. | Process and apparatus for improved methods for making vinyl acetate monomer (VAM) |
EP2380661A3 (en) * | 2004-12-20 | 2012-02-01 | Celanese International Corporation | Modified support materials for catalysts |
US8227369B2 (en) * | 2005-05-25 | 2012-07-24 | Celanese International Corp. | Layered composition and processes for preparing and using the composition |
JP4963922B2 (ja) * | 2006-10-04 | 2012-06-27 | 昭和電工株式会社 | 酢酸アルケニル製造用触媒の製造方法 |
JP2008173629A (ja) * | 2006-12-20 | 2008-07-31 | Showa Denko Kk | アシルオキシ化反応用触媒およびその製造方法 |
DE102007025362A1 (de) * | 2007-05-31 | 2008-12-11 | Süd-Chemie AG | Dotierter Pd/Au-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung |
BRPI1004975A2 (pt) * | 2009-12-08 | 2013-04-02 | Haldor Topsoe A/S | processo integrado para a produÇço de Ácido acÉtico, etileno e monâmero de acetato de vinila |
WO2011104170A1 (en) | 2010-02-24 | 2011-09-01 | Evonik Degussa Gmbh | Thermally and mechanically stable precious metal-loaded catalysts |
US9248436B2 (en) * | 2010-08-26 | 2016-02-02 | Basf Se | Highly active shift catalysts |
US20120149939A1 (en) | 2010-12-10 | 2012-06-14 | Celanese International Corporation | Recovery of Acetic Acid from Heavy Ends in Vinyl Acetate Synthesis Process |
CN102671717B (zh) * | 2012-06-05 | 2015-06-10 | 四川材料与工艺研究所 | 贵金属碱性浑浊液及其制备催化板的方法 |
DE112015004756T5 (de) | 2014-10-20 | 2017-09-28 | Velocys Technologies Limited | Verfahren der Entfernung von Wärme |
TW202128605A (zh) | 2019-12-19 | 2021-08-01 | 美商瑟蘭斯國際股份有限公司 | 於乙酸乙烯酯製造期間監測各式流之可燃性之方法及系統 |
TW202204892A (zh) | 2020-06-29 | 2022-02-01 | 美商瑟蘭斯國際股份有限公司 | 於乙酸乙烯酯製造之金屬離子原位分析 |
Family Cites Families (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3190912A (en) * | 1962-05-02 | 1965-06-22 | Nat Distillers Chem Corp | Process for preparing esters |
DE1252662B (tr) * | 1965-06-25 | |||
DE1618391C3 (de) * | 1967-03-22 | 1975-08-14 | Hoechst Ag, 6000 Frankfurt | Verfahren zur Herstellung von Vinylacetat |
CH534005A (de) * | 1968-02-01 | 1973-02-28 | Bayer Ag | Verfahren zur Herstellung eines Palladium und Gold enthaltenden Katalysators |
JPS514118A (en) * | 1974-06-27 | 1976-01-14 | Kuraray Co | Sakusanbiniruno seizohoho |
DE2509251C3 (de) * | 1975-03-04 | 1978-07-13 | Hoechst Ag, 6000 Frankfurt | Verfahren zur Herstellung eines Palladiumkatalysators |
GB1571910A (en) * | 1975-12-18 | 1980-07-23 | Nat Distillers Chem Corp | Vinyl acetate process and catalyst therefor |
US4048096A (en) * | 1976-04-12 | 1977-09-13 | E. I. Du Pont De Nemours And Company | Surface impregnated catalyst |
US4158737A (en) * | 1976-12-14 | 1979-06-19 | National Distillers And Chemical Corp. | Vinyl acetate preparation |
DE3200483A1 (de) * | 1982-01-09 | 1983-07-21 | Bayer Ag, 5090 Leverkusen | Kieselsaeurehaltige formkoerper, verfahren zu ihrer herstellung und ihre verwendung |
JP2821033B2 (ja) * | 1991-01-07 | 1998-11-05 | 株式会社日本触媒 | ディーゼルエンジン排ガス浄化用触媒 |
TW213869B (tr) * | 1991-06-21 | 1993-10-01 | Hoechst Ag | |
DE4120492A1 (de) * | 1991-06-21 | 1992-12-24 | Hoechst Ag | Verfahren zur herstellung von vinylacetat |
US5314858A (en) * | 1992-10-14 | 1994-05-24 | Hoechst Celanese Corporation | Vinyl acetate catalyst preparation method |
US5332710A (en) * | 1992-10-14 | 1994-07-26 | Hoechst Celanese Corporation | Vinyl acetate catalyst preparation method |
US5347046A (en) * | 1993-05-25 | 1994-09-13 | Engelhard Corporation | Catalyst and process for using same for the preparation of unsaturated carboxylic acid esters |
DE4323981C1 (de) * | 1993-07-16 | 1995-03-09 | Hoechst Ag | Palladium und Kalium sowie Cadmium, Barium oder Gold enthaltender Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung zur Herstellung von Vinylacetat |
CA2135021A1 (en) * | 1993-11-19 | 1995-05-20 | David J. Gulliver | Process for the preparation of catalysts for use in the production of vinyl acetate |
US6265343B1 (en) * | 1994-03-07 | 2001-07-24 | Degussa Corporation | Catalyst and method for the synthesis of chlorine dioxide, and method of making catalyst for the synthesis of chlorine dioxide |
US5665667A (en) * | 1994-06-02 | 1997-09-09 | The Standard Oil Company | Process for the preparation of vinyl acetate catalyst |
EP0723811A1 (de) * | 1995-01-25 | 1996-07-31 | Degussa Aktiengesellschaft | Katalysator zur Entfernung von Wasserstoff und/oder Kohlenmonoxid aus feuchter Luft |
US5576457A (en) * | 1995-05-23 | 1996-11-19 | Hoechst Celanese Corporation | Catalyst and procedure for preparation of vinyl acetate |
IN188013B (tr) * | 1995-05-23 | 2002-08-10 | Hoechst Celanese Corp | |
US5688993A (en) * | 1995-12-22 | 1997-11-18 | E. I. Du Pont De Nemours And Company | Method for modifying catalyst performance during the gas phase synthesis of vinyl acetate |
US5731457A (en) * | 1997-06-03 | 1998-03-24 | Hoechst Celanese Corporation | Vinyl acetate process utilizing a palladium-gold-copper catalyst |
US5968869A (en) * | 1997-06-03 | 1999-10-19 | Celanese International Corporation | Vinyl acetate catalyst comprising palladium and gold deposited on a copper containing carrier |
US5948724A (en) * | 1997-10-28 | 1999-09-07 | Celanese International Corporation | Vinyl acetate catalyst comprising metallic palladium and gold and cupric acetate |
-
1997
- 1997-12-12 US US08/989,886 patent/US6072078A/en not_active Expired - Lifetime
-
1998
- 1998-03-12 UA UA2000063447A patent/UA60349C2/uk unknown
- 1998-12-03 KR KR1020007006427A patent/KR20010033066A/ko not_active Application Discontinuation
- 1998-12-03 ID IDW20000998A patent/ID24889A/id unknown
- 1998-12-03 TR TR2000/01681T patent/TR200001681T2/tr unknown
- 1998-12-03 NZ NZ505647A patent/NZ505647A/xx not_active IP Right Cessation
- 1998-12-03 WO PCT/US1998/025599 patent/WO1999030818A1/en not_active Application Discontinuation
- 1998-12-03 EP EP98960659A patent/EP1037706A1/en not_active Ceased
- 1998-12-03 CA CA002312351A patent/CA2312351C/en not_active Expired - Fee Related
- 1998-12-03 HU HU0004462A patent/HUP0004462A3/hu unknown
- 1998-12-03 CZ CZ20002174A patent/CZ295487B6/cs not_active IP Right Cessation
- 1998-12-03 CN CN98812118A patent/CN1104281C/zh not_active Expired - Fee Related
- 1998-12-03 JP JP2000538787A patent/JP4287999B2/ja not_active Expired - Fee Related
- 1998-12-03 MX MXPA00005760A patent/MXPA00005760A/es unknown
- 1998-12-03 PL PL98340765A patent/PL340765A1/xx not_active Application Discontinuation
- 1998-12-03 BR BR9813466-3A patent/BR9813466A/pt not_active Application Discontinuation
- 1998-12-03 RU RU2000119117/04A patent/RU2202411C2/ru not_active IP Right Cessation
- 1998-12-03 AU AU16207/99A patent/AU736524B2/en not_active Ceased
- 1998-12-07 TW TW087120259A patent/TW516975B/zh not_active IP Right Cessation
- 1998-12-07 PE PE1998001188A patent/PE65199A1/es not_active Application Discontinuation
- 1998-12-10 MY MYPI98005577A patent/MY116306A/en unknown
- 1998-12-11 AR ARP980106317A patent/AR017429A1/es active IP Right Grant
- 1998-12-11 ZA ZA9811383A patent/ZA9811383B/xx unknown
- 1998-12-11 YU YU57298A patent/YU49231B/sh unknown
- 1998-12-20 SA SA98190906A patent/SA98190906B1/ar unknown
-
1999
- 1999-07-12 US US09/351,720 patent/US6057260A/en not_active Expired - Lifetime
-
2000
- 2000-06-09 NO NO20002961A patent/NO323902B1/no not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
ID24889A (id) | 2000-08-31 |
SA98190906B1 (ar) | 2006-05-20 |
US6057260A (en) | 2000-05-02 |
NZ505647A (en) | 2003-01-31 |
KR20010033066A (ko) | 2001-04-25 |
CN1104281C (zh) | 2003-04-02 |
JP2002508240A (ja) | 2002-03-19 |
AU736524B2 (en) | 2001-07-26 |
MY116306A (en) | 2003-12-31 |
HUP0004462A2 (hu) | 2001-04-28 |
CA2312351A1 (en) | 1999-06-24 |
UA60349C2 (uk) | 2003-10-15 |
NO20002961L (no) | 2000-06-09 |
BR9813466A (pt) | 2000-10-10 |
WO1999030818A1 (en) | 1999-06-24 |
PE65199A1 (es) | 1999-06-26 |
JP4287999B2 (ja) | 2009-07-01 |
NO20002961D0 (no) | 2000-06-09 |
CZ20002174A3 (cs) | 2001-03-14 |
CZ295487B6 (cs) | 2005-08-17 |
AU1620799A (en) | 1999-07-05 |
EP1037706A1 (en) | 2000-09-27 |
CA2312351C (en) | 2006-05-30 |
AR017429A1 (es) | 2001-09-05 |
CN1281386A (zh) | 2001-01-24 |
HUP0004462A3 (en) | 2003-07-28 |
ZA9811383B (en) | 2000-06-12 |
PL340765A1 (en) | 2001-02-26 |
RU2202411C2 (ru) | 2003-04-20 |
TW516975B (en) | 2003-01-11 |
YU57298A (sh) | 2000-03-21 |
YU49231B (sh) | 2004-11-25 |
US6072078A (en) | 2000-06-06 |
NO323902B1 (no) | 2007-07-16 |
MXPA00005760A (es) | 2002-04-24 |
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