SU416949A3 - Способ получения тетраалкиловых эфиров ортокремниевой кислоты - Google Patents
Способ получения тетраалкиловых эфиров ортокремниевой кислотыInfo
- Publication number
- SU416949A3 SU416949A3 SU1356342A SU1356342A SU416949A3 SU 416949 A3 SU416949 A3 SU 416949A3 SU 1356342 A SU1356342 A SU 1356342A SU 1356342 A SU1356342 A SU 1356342A SU 416949 A3 SU416949 A3 SU 416949A3
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- silicon
- ethers
- acid
- mixture
- orthocrystalline
- Prior art date
Links
- 238000000034 method Methods 0.000 title description 14
- 150000002170 ethers Chemical class 0.000 title description 4
- 239000002253 acid Substances 0.000 title 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 27
- 229910052710 silicon Inorganic materials 0.000 description 20
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 18
- 239000010703 silicon Substances 0.000 description 18
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 16
- 239000000203 mixture Substances 0.000 description 11
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 8
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical class O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 8
- 239000000725 suspension Substances 0.000 description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 7
- 229910052739 hydrogen Inorganic materials 0.000 description 7
- 239000001257 hydrogen Substances 0.000 description 7
- 239000003054 catalyst Substances 0.000 description 5
- 229910000519 Ferrosilicon Inorganic materials 0.000 description 4
- WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 150000001340 alkali metals Chemical class 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229910021332 silicide Inorganic materials 0.000 description 3
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 description 3
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000011067 equilibration Methods 0.000 description 1
- 125000004494 ethyl ester group Chemical group 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- -1 silicic acid ester Chemical class 0.000 description 1
- 150000003377 silicon compounds Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- QDRKDTQENPPHOJ-UHFFFAOYSA-N sodium ethoxide Chemical compound [Na+].CC[O-] QDRKDTQENPPHOJ-UHFFFAOYSA-N 0.000 description 1
- SYXYWTXQFUUWLP-UHFFFAOYSA-N sodium;butan-1-olate Chemical compound [Na+].CCCC[O-] SYXYWTXQFUUWLP-UHFFFAOYSA-N 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 125000003698 tetramethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- ZQZCOBSUOFHDEE-UHFFFAOYSA-N tetrapropyl silicate Chemical compound CCCO[Si](OCCC)(OCCC)OCCC ZQZCOBSUOFHDEE-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/04—Esters of silicic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Logic Circuits (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19681793222 DE1793222A1 (de) | 1968-08-17 | 1968-08-17 | Verfahren zur Herstellung von Orthokieselsaeuretetraalkylestern |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU416949A3 true SU416949A3 (ru) | 1974-02-25 |
Family
ID=5707619
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU1356342A SU416949A3 (ru) | 1968-08-17 | 1969-08-08 | Способ получения тетраалкиловых эфиров ортокремниевой кислоты |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US3627807A (enExample) |
| AT (1) | AT297034B (enExample) |
| BE (1) | BE737543A (enExample) |
| CH (1) | CH520710A (enExample) |
| DE (1) | DE1793222A1 (enExample) |
| DK (1) | DK144917C (enExample) |
| FI (1) | FI48743C (enExample) |
| FR (1) | FR2015846A1 (enExample) |
| GB (1) | GB1237159A (enExample) |
| LU (1) | LU59261A1 (enExample) |
| NL (1) | NL165464C (enExample) |
| NO (1) | NO126329B (enExample) |
| SE (1) | SE353726B (enExample) |
| SU (1) | SU416949A3 (enExample) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2354683C2 (de) * | 1973-11-02 | 1982-02-11 | Dynamit Nobel Ag, 5210 Troisdorf | Verfahren zur Herstellung von Orthokieselsäuretetraalkoxialkylestern |
| FR2318872A1 (fr) * | 1975-07-19 | 1977-02-18 | Dynamit Nobel Ag | Procede pou l'obtention d'esters alkyliques d'acide orthosilicique |
| US4185029A (en) * | 1975-07-19 | 1980-01-22 | Dynamit Nobel Aktiengesellschaft | Method of preparing orthosilicic acid alkyl esters |
| DE2557932A1 (de) * | 1975-12-22 | 1977-06-30 | Dynamit Nobel Ag | Verfahren zur herstellung von koernigem quarzglas |
| EP0004730B1 (en) * | 1978-03-23 | 1982-11-10 | Zirconal Processes Limited | Improvements in the manufacture of alkylsilicates and their conversion to alkylpolysilicates |
| DE2816386A1 (de) * | 1978-04-15 | 1979-10-25 | Dynamit Nobel Ag | Verfahren zur herstellung von orthokieselsaeuretetraalkylestern |
| US4211717A (en) * | 1979-03-23 | 1980-07-08 | Zirconal Processes Limited | Manufacture of alkyl silicates |
| US4288604A (en) * | 1980-05-19 | 1981-09-08 | Stauffer Chemical Company | Method for the production of tetraalkyl silicates |
| US4323690A (en) * | 1981-04-20 | 1982-04-06 | Carboline Company | Method of making silicate esters |
| GB2140814A (en) * | 1983-05-05 | 1984-12-05 | Lakseed Limited | Process for the manufacture of tetra-alkoxysilanes |
| US4487949A (en) * | 1983-11-22 | 1984-12-11 | Union Carbide Corporation | Process for the preparation of alkyl silicates |
| US4761492A (en) * | 1987-09-28 | 1988-08-02 | Union Carbide Corporation | Process for recovering trimethoxysilane from a trimethoxysilane and methanol mixture |
| US4762939A (en) * | 1987-09-30 | 1988-08-09 | Union Carbide Corporation | Process for trialkoxysilane/tetraalkoxysilane mixtures from silicon metal and alcohol |
| US5084590A (en) * | 1991-06-24 | 1992-01-28 | Union Carbide Chemicals & Plastics Technology Corporation | Trimethoxysilane preparation via the methanol-silicon reaction using a continuous process and multiple reactors |
| US6090965A (en) * | 1998-04-02 | 2000-07-18 | Osi Specialties, Inc. | Removal of dissolved silicates from alcohol-silicon direct synthesis solvents |
| US6166237A (en) * | 1999-08-13 | 2000-12-26 | Crompton Corporation | Removal of dissolved silicates from alcohol-silicon direct synthesis solvents |
| US6580000B1 (en) * | 2002-06-06 | 2003-06-17 | Ak Research Company | Process for the manufacture of alkoxysilanes and alkoxy orthosilicates |
| US8153566B2 (en) * | 2008-09-30 | 2012-04-10 | Cherron Oronite Company LLC | Lubricating oil compositions |
| US8901050B2 (en) | 2010-03-31 | 2014-12-02 | Chevron Oronite Company Llc | Method for improving copper corrosion performance |
| US8933001B2 (en) | 2010-03-31 | 2015-01-13 | Chevron Oronite Company Llc | Method for improving fluorocarbon elastomer seal compatibility |
| US10442899B2 (en) | 2014-11-17 | 2019-10-15 | Silbond Corporation | Stable ethylsilicate polymers and method of making the same |
| EP3954743A1 (de) | 2020-08-12 | 2022-02-16 | Evonik Operations GmbH | Verwendung von siliziumdioxid zur verbesserung der leitfähigkeit von beschichtungen |
| CN115677746A (zh) * | 2022-11-18 | 2023-02-03 | 南通索吉尔化工有限公司 | 一种提高硅粉利用率制备正硅酸乙酯的方法 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2927937A (en) * | 1955-04-26 | 1960-03-08 | Union Carbide Corp | Preparation of alkyl orthosilicates by attrition milling |
| US2909550A (en) * | 1955-06-02 | 1959-10-20 | Union Carbide Corp | Methods of preparing esters of orthosilicic acid |
| GB913346A (en) * | 1960-06-01 | 1962-12-19 | Hygrotherm Eng Ltd | A method for the production of aryl silicates |
-
1968
- 1968-08-17 DE DE19681793222 patent/DE1793222A1/de active Granted
-
1969
- 1969-08-08 SU SU1356342A patent/SU416949A3/ru active
- 1969-08-11 LU LU59261D patent/LU59261A1/xx unknown
- 1969-08-12 CH CH1217469A patent/CH520710A/de not_active IP Right Cessation
- 1969-08-13 FR FR6927898A patent/FR2015846A1/fr not_active Withdrawn
- 1969-08-14 BE BE737543D patent/BE737543A/xx unknown
- 1969-08-14 AT AT784269A patent/AT297034B/de not_active IP Right Cessation
- 1969-08-15 FI FI692388A patent/FI48743C/fi active
- 1969-08-15 SE SE11403/69A patent/SE353726B/xx unknown
- 1969-08-15 GB GB40897/69A patent/GB1237159A/en not_active Expired
- 1969-08-15 DK DK440169A patent/DK144917C/da active
- 1969-08-15 NL NL6912469.A patent/NL165464C/xx not_active IP Right Cessation
- 1969-08-16 NO NO03331/69A patent/NO126329B/no unknown
- 1969-08-18 US US851108A patent/US3627807A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| FR2015846A1 (enExample) | 1970-04-30 |
| LU59261A1 (enExample) | 1970-01-01 |
| NL165464B (nl) | 1980-11-17 |
| NL6912469A (enExample) | 1970-02-19 |
| DE1793222A1 (de) | 1971-04-15 |
| BE737543A (enExample) | 1970-01-16 |
| NL165464C (nl) | 1981-04-15 |
| US3627807A (en) | 1971-12-14 |
| FI48743C (fi) | 1974-12-10 |
| NO126329B (enExample) | 1973-01-22 |
| DK144917C (da) | 1982-11-22 |
| AT297034B (de) | 1972-03-10 |
| SE353726B (enExample) | 1973-02-12 |
| DK144917B (da) | 1982-07-05 |
| FI48743B (enExample) | 1974-09-02 |
| GB1237159A (en) | 1971-06-30 |
| CH520710A (de) | 1972-03-31 |
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