SK752000A3 - High activity polyethylene catalyst composition and method for producing a precursor of such catalyst composition - Google Patents
High activity polyethylene catalyst composition and method for producing a precursor of such catalyst composition Download PDFInfo
- Publication number
- SK752000A3 SK752000A3 SK75-2000A SK752000A SK752000A3 SK 752000 A3 SK752000 A3 SK 752000A3 SK 752000 A SK752000 A SK 752000A SK 752000 A3 SK752000 A3 SK 752000A3
- Authority
- SK
- Slovakia
- Prior art keywords
- silica
- mmol
- compound
- per gram
- composition according
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 63
- 239000003054 catalyst Substances 0.000 title claims abstract description 60
- 238000004519 manufacturing process Methods 0.000 title claims description 6
- 239000002243 precursor Substances 0.000 title claims description 5
- 230000000694 effects Effects 0.000 title abstract description 13
- -1 polyethylene Polymers 0.000 title description 13
- 239000004698 Polyethylene Substances 0.000 title description 8
- 229920000573 polyethylene Polymers 0.000 title description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 151
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 74
- 150000001875 compounds Chemical class 0.000 claims abstract description 29
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims abstract description 20
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 18
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 18
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000005977 Ethylene Substances 0.000 claims abstract description 16
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 16
- 150000003609 titanium compounds Chemical class 0.000 claims abstract description 16
- 239000012018 catalyst precursor Substances 0.000 claims abstract description 12
- 150000004796 dialkyl magnesium compounds Chemical class 0.000 claims abstract description 10
- 125000002370 organoaluminium group Chemical group 0.000 claims abstract description 8
- 239000004711 α-olefin Substances 0.000 claims abstract description 4
- 230000003197 catalytic effect Effects 0.000 claims description 17
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 15
- KJJBSBKRXUVBMX-UHFFFAOYSA-N magnesium;butane Chemical compound [Mg+2].CCC[CH2-].CCC[CH2-] KJJBSBKRXUVBMX-UHFFFAOYSA-N 0.000 claims description 14
- 238000006116 polymerization reaction Methods 0.000 claims description 13
- 239000011777 magnesium Substances 0.000 claims description 11
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 10
- 229910052749 magnesium Inorganic materials 0.000 claims description 10
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 claims description 8
- 229910003902 SiCl 4 Inorganic materials 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 7
- 150000002901 organomagnesium compounds Chemical class 0.000 claims description 5
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 5
- VXEGSRKPIUDPQT-UHFFFAOYSA-N 4-[4-(4-methoxyphenyl)piperazin-1-yl]aniline Chemical compound C1=CC(OC)=CC=C1N1CCN(C=2C=CC(N)=CC=2)CC1 VXEGSRKPIUDPQT-UHFFFAOYSA-N 0.000 claims description 4
- 239000005049 silicon tetrachloride Substances 0.000 claims description 4
- JGHYBJVUQGTEEB-UHFFFAOYSA-M dimethylalumanylium;chloride Chemical group C[Al](C)Cl JGHYBJVUQGTEEB-UHFFFAOYSA-M 0.000 claims description 2
- YHNWUQFTJNJVNU-UHFFFAOYSA-N magnesium;butane;ethane Chemical compound [Mg+2].[CH2-]C.CCC[CH2-] YHNWUQFTJNJVNU-UHFFFAOYSA-N 0.000 claims description 2
- KXDANLFHGCWFRQ-UHFFFAOYSA-N magnesium;butane;octane Chemical compound [Mg+2].CCC[CH2-].CCCCCCC[CH2-] KXDANLFHGCWFRQ-UHFFFAOYSA-N 0.000 claims description 2
- 239000005055 methyl trichlorosilane Substances 0.000 claims description 2
- JLUFWMXJHAVVNN-UHFFFAOYSA-N methyltrichlorosilane Chemical compound C[Si](Cl)(Cl)Cl JLUFWMXJHAVVNN-UHFFFAOYSA-N 0.000 claims description 2
- UQMOLLPKNHFRAC-UHFFFAOYSA-N tetrabutyl silicate Chemical compound CCCCO[Si](OCCCC)(OCCCC)OCCCC UQMOLLPKNHFRAC-UHFFFAOYSA-N 0.000 claims description 2
- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical group CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 claims description 2
- ZUEKXCXHTXJYAR-UHFFFAOYSA-N tetrapropan-2-yl silicate Chemical compound CC(C)O[Si](OC(C)C)(OC(C)C)OC(C)C ZUEKXCXHTXJYAR-UHFFFAOYSA-N 0.000 claims description 2
- ZQZCOBSUOFHDEE-UHFFFAOYSA-N tetrapropyl silicate Chemical compound CCCO[Si](OCCC)(OCCC)OCCC ZQZCOBSUOFHDEE-UHFFFAOYSA-N 0.000 claims description 2
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 claims description 2
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 2
- 125000004429 atom Chemical group 0.000 claims 1
- 239000012876 carrier material Substances 0.000 abstract description 7
- 229910052739 hydrogen Inorganic materials 0.000 abstract description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract description 6
- 239000001257 hydrogen Substances 0.000 abstract description 6
- 239000000725 suspension Substances 0.000 description 24
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 19
- 229920000642 polymer Polymers 0.000 description 16
- 229920000092 linear low density polyethylene Polymers 0.000 description 14
- 239000004707 linear low-density polyethylene Substances 0.000 description 14
- 125000002734 organomagnesium group Chemical group 0.000 description 13
- 239000004700 high-density polyethylene Substances 0.000 description 12
- 229920001903 high density polyethylene Polymers 0.000 description 11
- 239000002904 solvent Substances 0.000 description 9
- 239000012454 non-polar solvent Substances 0.000 description 8
- 239000010936 titanium Substances 0.000 description 8
- 239000007789 gas Substances 0.000 description 7
- 150000003623 transition metal compounds Chemical class 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 239000012190 activator Substances 0.000 description 6
- 238000004458 analytical method Methods 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 238000001035 drying Methods 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 238000003786 synthesis reaction Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 229910001868 water Inorganic materials 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 3
- 239000000969 carrier Substances 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 229910052723 transition metal Inorganic materials 0.000 description 3
- 150000003624 transition metals Chemical class 0.000 description 3
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
- 229910008051 Si-OH Inorganic materials 0.000 description 2
- 229910006358 Si—OH Inorganic materials 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 238000012685 gas phase polymerization Methods 0.000 description 2
- 150000002681 magnesium compounds Chemical class 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- BKIMMITUMNQMOS-UHFFFAOYSA-N nonane Chemical compound CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 229920010126 Linear Low Density Polyethylene (LLDPE) Polymers 0.000 description 1
- 239000004594 Masterbatch (MB) Substances 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- UBAZGMLMVVQSCD-UHFFFAOYSA-N carbon dioxide;molecular oxygen Chemical compound O=O.O=C=O UBAZGMLMVVQSCD-UHFFFAOYSA-N 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001924 cycloalkanes Chemical class 0.000 description 1
- DIOQZVSQGTUSAI-NJFSPNSNSA-N decane Chemical compound CCCCCCCCC[14CH3] DIOQZVSQGTUSAI-NJFSPNSNSA-N 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 210000004602 germ cell Anatomy 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- GXNDYZPMZKJDSS-UHFFFAOYSA-N hex-1-ene Chemical compound CCCCC=C.CCCCC=C GXNDYZPMZKJDSS-UHFFFAOYSA-N 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229920004889 linear high-density polyethylene Polymers 0.000 description 1
- 238000004949 mass spectrometry Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- DIOQZVSQGTUSAI-UHFFFAOYSA-N n-butylhexane Natural products CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 238000005325 percolation Methods 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 125000005372 silanol group Chemical group 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000004260 weight control Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/652—Pretreating with metals or metal-containing compounds
- C08F4/656—Pretreating with metals or metal-containing compounds with silicon or compounds thereof
- C08F4/6565—Pretreating with metals or metal-containing compounds with silicon or compounds thereof and magnesium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP97430020 | 1997-07-25 | ||
| PCT/GB1998/002181 WO1999005187A1 (en) | 1997-07-25 | 1998-07-22 | High activity polyethylene catalysts |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SK752000A3 true SK752000A3 (en) | 2000-07-11 |
Family
ID=8229966
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SK75-2000A SK752000A3 (en) | 1997-07-25 | 1998-07-22 | High activity polyethylene catalyst composition and method for producing a precursor of such catalyst composition |
Country Status (24)
| Country | Link |
|---|---|
| US (1) | US6136745A (tr) |
| EP (1) | EP0998503B1 (tr) |
| JP (1) | JP2001510865A (tr) |
| KR (1) | KR20010022116A (tr) |
| CN (1) | CN1264393A (tr) |
| AT (1) | ATE223444T1 (tr) |
| AU (1) | AU737956B2 (tr) |
| BR (1) | BR9810814A (tr) |
| CA (1) | CA2295498A1 (tr) |
| DE (1) | DE69807703T2 (tr) |
| DZ (1) | DZ2573A1 (tr) |
| EA (1) | EA001786B1 (tr) |
| EG (1) | EG21253A (tr) |
| ES (1) | ES2183393T3 (tr) |
| HU (1) | HU220591B1 (tr) |
| ID (1) | ID24621A (tr) |
| NO (1) | NO20000359L (tr) |
| NZ (1) | NZ502349A (tr) |
| PL (1) | PL337997A1 (tr) |
| SK (1) | SK752000A3 (tr) |
| TR (1) | TR200000182T2 (tr) |
| TW (1) | TW418217B (tr) |
| WO (1) | WO1999005187A1 (tr) |
| ZA (1) | ZA986590B (tr) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU7431300A (en) * | 1999-09-17 | 2001-04-24 | Bp Chemicals Limited | Catalyst for polyethylene giving an improved short chain branching distribution |
| US6962889B2 (en) * | 2004-01-28 | 2005-11-08 | Engelhard Corporation | Spherical catalyst for olefin polymerization |
| KR20050095133A (ko) * | 2004-03-25 | 2005-09-29 | 차이나 페트로리움 앤드 케미컬 코포레이션 | 에틸렌 중합용 촉매, 및 그의 제조방법과 용도 |
| US7153803B2 (en) * | 2004-06-28 | 2006-12-26 | Engelhard Corporation | High activity and good hydrogen response Ziegler-Natta polyethylene catalyst |
| RU2320410C1 (ru) * | 2006-11-16 | 2008-03-27 | Институт Катализа Имени Г.К. Борескова Сибирского Отделения Российской Академии Наук | Способ приготовления катализатора и процесс полимеризации этилена с использованием этого катализатора |
| EP2133367A1 (en) | 2008-06-09 | 2009-12-16 | INEOS Manufacturing Belgium NV | Novel Copolymers |
| EP2172490A1 (en) | 2008-10-03 | 2010-04-07 | Ineos Europe Limited | Controlled polymerisation process |
| EP2357035A1 (en) | 2010-01-13 | 2011-08-17 | Ineos Europe Limited | Polymer powder storage and/or transport and/or degassing vessels |
| EP2383298A1 (en) | 2010-04-30 | 2011-11-02 | Ineos Europe Limited | Polymerization process |
| EP2383301A1 (en) | 2010-04-30 | 2011-11-02 | Ineos Europe Limited | Polymerization process |
| JP5981441B2 (ja) | 2010-11-26 | 2016-08-31 | サウディ ベーシック インダストリーズ コーポレイション | エチレンの重合および共重合のための固体触媒成分を製造するプロセス |
| US9394381B2 (en) | 2010-11-29 | 2016-07-19 | Ineos Sales (Uk) Limited | Polymerisation control process |
| KR101715259B1 (ko) * | 2010-12-15 | 2017-03-13 | 에스케이이노베이션 주식회사 | 신규한 메탈로센 담지촉매 조성물 및 이를 이용한 폴리올레핀의 제조방법 |
| US8383740B1 (en) | 2011-08-12 | 2013-02-26 | Ineos Usa Llc | Horizontal agitator |
| WO2013056979A1 (en) | 2011-10-17 | 2013-04-25 | Ineos Europe Ag | Polymer degassing process control |
| WO2013156491A1 (en) | 2012-04-19 | 2013-10-24 | Ineos Europe Ag | Catalyst for the polymerisation of olefins, process for its production and use |
| KR101721194B1 (ko) | 2013-11-28 | 2017-03-29 | 주식회사 엘지화학 | 담지 메탈로센 촉매의 제조방법 |
| WO2015080523A1 (ko) * | 2013-11-28 | 2015-06-04 | 주식회사 엘지화학 | 담지 메탈로센 촉매의 제조방법 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH072776B2 (ja) * | 1985-01-28 | 1995-01-18 | 東燃株式会社 | オレフイン重合用触媒成分 |
| US5063188A (en) * | 1990-04-06 | 1991-11-05 | Texas Alkyls, Inc. | Catalyst component for ethylene polyermization and copolymerization |
| IT1250706B (it) * | 1991-07-25 | 1995-04-21 | Enichem Polimeri | Catalizzatore per la polimerizzazione di olefine |
| US5514634A (en) * | 1991-11-06 | 1996-05-07 | Mobil Oil Corporation | High activity polyethylene catalysts |
| US5939348A (en) * | 1991-11-06 | 1999-08-17 | Mobil Oil Corporation | Catalyst for the manufacture of polythylene with a narrow molecular weight distribution |
| US5470812A (en) * | 1991-11-06 | 1995-11-28 | Mobil Oil Corporation | High activity polyethylene catalysts prepared with alkoxysilane reagents |
| WO1994020546A1 (en) * | 1993-03-03 | 1994-09-15 | Akzo Nobel N.V. | Supported catalyst component for ethylene (co)polymerization |
| CA2233659C (en) * | 1995-10-06 | 2007-12-04 | Mobil Oil Corporation | Catalyst for the manufacture of polyethylene with a narrow molecular weight distribution |
-
1998
- 1998-07-22 ES ES98935186T patent/ES2183393T3/es not_active Expired - Lifetime
- 1998-07-22 NZ NZ502349A patent/NZ502349A/en unknown
- 1998-07-22 CA CA002295498A patent/CA2295498A1/en not_active Abandoned
- 1998-07-22 BR BR9810814-0A patent/BR9810814A/pt unknown
- 1998-07-22 CN CN98807366A patent/CN1264393A/zh active Pending
- 1998-07-22 US US09/120,113 patent/US6136745A/en not_active Expired - Lifetime
- 1998-07-22 KR KR1020007000686A patent/KR20010022116A/ko not_active Application Discontinuation
- 1998-07-22 AU AU84536/98A patent/AU737956B2/en not_active Ceased
- 1998-07-22 TR TR2000/00182T patent/TR200000182T2/tr unknown
- 1998-07-22 HU HU0002642A patent/HU220591B1/hu not_active IP Right Cessation
- 1998-07-22 WO PCT/GB1998/002181 patent/WO1999005187A1/en not_active Application Discontinuation
- 1998-07-22 JP JP2000504177A patent/JP2001510865A/ja active Pending
- 1998-07-22 ID IDW20000152A patent/ID24621A/id unknown
- 1998-07-22 SK SK75-2000A patent/SK752000A3/sk unknown
- 1998-07-22 EA EA200000088A patent/EA001786B1/ru not_active IP Right Cessation
- 1998-07-22 AT AT98935186T patent/ATE223444T1/de active
- 1998-07-22 EP EP98935186A patent/EP0998503B1/en not_active Expired - Lifetime
- 1998-07-22 DE DE69807703T patent/DE69807703T2/de not_active Expired - Lifetime
- 1998-07-22 PL PL98337997A patent/PL337997A1/xx unknown
- 1998-07-23 ZA ZA9806590A patent/ZA986590B/xx unknown
- 1998-07-24 TW TW087112158A patent/TW418217B/zh not_active IP Right Cessation
- 1998-07-25 DZ DZ980183A patent/DZ2573A1/xx active
- 1998-07-25 EG EG87298A patent/EG21253A/xx active
-
2000
- 2000-01-24 NO NO20000359A patent/NO20000359L/no not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| NZ502349A (en) | 2001-06-29 |
| JP2001510865A (ja) | 2001-08-07 |
| EA200000088A1 (ru) | 2000-10-30 |
| ZA986590B (en) | 2000-01-24 |
| CN1264393A (zh) | 2000-08-23 |
| ES2183393T3 (es) | 2003-03-16 |
| AU737956B2 (en) | 2001-09-06 |
| DE69807703D1 (de) | 2002-10-10 |
| BR9810814A (pt) | 2000-09-12 |
| ID24621A (id) | 2000-07-27 |
| KR20010022116A (ko) | 2001-03-15 |
| CA2295498A1 (en) | 1999-02-04 |
| HUP0002642A2 (hu) | 2000-12-28 |
| NO20000359D0 (no) | 2000-01-24 |
| WO1999005187A1 (en) | 1999-02-04 |
| US6136745A (en) | 2000-10-24 |
| TR200000182T2 (tr) | 2000-09-21 |
| EP0998503A1 (en) | 2000-05-10 |
| EA001786B1 (ru) | 2001-08-27 |
| TW418217B (en) | 2001-01-11 |
| DZ2573A1 (fr) | 2003-02-22 |
| PL337997A1 (en) | 2000-09-25 |
| HU220591B1 (hu) | 2002-03-28 |
| EG21253A (en) | 2001-04-01 |
| HUP0002642A3 (en) | 2001-04-28 |
| DE69807703T2 (de) | 2003-01-30 |
| EP0998503B1 (en) | 2002-09-04 |
| AU8453698A (en) | 1999-02-16 |
| NO20000359L (no) | 2000-03-27 |
| ATE223444T1 (de) | 2002-09-15 |
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