SG172454A1 - New metallocene compounds, catalysts comprising them, process for producing an olefin polymer by use of the catalysts, and olefin homo- and copolymers - Google Patents

Info

Publication number

SG172454A1

SG172454A1 SG2011048345A SG2011048345A SG172454A1 SG 172454 A1 SG172454 A1 SG 172454A1 SG 2011048345 A SG2011048345 A SG 2011048345A SG 2011048345 A SG2011048345 A SG 2011048345A SG 172454 A1 SG172454 A1 SG 172454A1

Authority

SG

Singapore

Prior art keywords

group

carbon atoms

methyl

indenyl

zirconium dichloride

Prior art date

2008-12-31

Links

• Espacenet
• Global Dossier
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• 239000003054 catalyst Substances 0.000 title claims abstract description 269
• 150000001875 compounds Chemical class 0.000 title claims abstract description 58
• 238000000034 method Methods 0.000 title claims description 64
• 230000008569 process Effects 0.000 title claims description 52
• 150000001336 alkenes Chemical class 0.000 title claims description 37
• JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title claims description 17
• 229920001577 copolymer Polymers 0.000 title abstract description 32
• 229920000098 polyolefin Polymers 0.000 title description 7
• 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 435
• -1 polypropylene Polymers 0.000 claims abstract description 183
• 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 115
• 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 76
• 125000004435 hydrogen atom Chemical class [H]* 0.000 claims abstract description 66
• QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims abstract description 55
• 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims abstract description 49
• YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 claims abstract description 42
• 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 41
• 239000001257 hydrogen Substances 0.000 claims abstract description 39
• 238000006116 polymerization reaction Methods 0.000 claims abstract description 37
• 229910052799 carbon Inorganic materials 0.000 claims abstract description 36
• 229930195733 hydrocarbon Natural products 0.000 claims abstract description 22
• 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 20
• 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 claims abstract description 18
• 125000002950 monocyclic group Chemical group 0.000 claims abstract description 15
• 125000003118 aryl group Chemical group 0.000 claims description 139
• 125000000217 alkyl group Chemical group 0.000 claims description 126
• 125000004122 cyclic group Chemical group 0.000 claims description 86
• 229910052782 aluminium Inorganic materials 0.000 claims description 73
• 229910052757 nitrogen Inorganic materials 0.000 claims description 67
• 229910052710 silicon Inorganic materials 0.000 claims description 66
• 229910052796 boron Inorganic materials 0.000 claims description 62
• 239000000460 chlorine Substances 0.000 claims description 61
• 125000005842 heteroatom Chemical group 0.000 claims description 61
• 229910052760 oxygen Inorganic materials 0.000 claims description 60
• 229910052717 sulfur Inorganic materials 0.000 claims description 60
• 229910052801 chlorine Inorganic materials 0.000 claims description 59
• 229910052794 bromium Inorganic materials 0.000 claims description 54
• 229910052698 phosphorus Inorganic materials 0.000 claims description 54
• 229910052731 fluorine Inorganic materials 0.000 claims description 52
• 125000002877 alkyl aryl group Chemical group 0.000 claims description 51
• 125000005843 halogen group Chemical group 0.000 claims description 44
• 125000003342 alkenyl group Chemical group 0.000 claims description 41
• 125000005103 alkyl silyl group Chemical group 0.000 claims description 38
• 125000003710 aryl alkyl group Chemical group 0.000 claims description 38
• 125000005104 aryl silyl group Chemical group 0.000 claims description 38
• UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 35
• VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 33
• 239000005977 Ethylene Substances 0.000 claims description 30
• 125000003545 alkoxy group Chemical group 0.000 claims description 29
• 125000003808 silyl group Chemical group [H][Si]([H])([H])[*] 0.000 claims description 29
• 125000005018 aryl alkenyl group Chemical group 0.000 claims description 27
• 125000004104 aryloxy group Chemical group 0.000 claims description 27
• 229920006395 saturated elastomer Polymers 0.000 claims description 22
• 125000004429 atom Chemical group 0.000 claims description 15
• 230000000737 periodic effect Effects 0.000 claims description 15
• 229910052726 zirconium Inorganic materials 0.000 claims description 15
• 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 claims description 14
• 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 13
• OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 12
• 125000005741 alkyl alkenyl group Chemical group 0.000 claims description 11
• VPGLGRNSAYHXPY-UHFFFAOYSA-L zirconium(2+);dichloride Chemical compound Cl[Zr]Cl VPGLGRNSAYHXPY-UHFFFAOYSA-L 0.000 claims description 11
• PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 10
• 229910052732 germanium Inorganic materials 0.000 claims description 10
• LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 claims description 9
• 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 9
• KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 claims description 8
• WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 claims description 8
• KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 8
• 150000001721 carbon Chemical group 0.000 claims description 8
• 229910052751 metal Inorganic materials 0.000 claims description 8
• 239000002184 metal Substances 0.000 claims description 8
• YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 claims description 8
• XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 7
• 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 7
• 239000010703 silicon Substances 0.000 claims description 7
• ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 6
• 125000003709 fluoroalkyl group Chemical group 0.000 claims description 6
• GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims description 6
• 239000000126 substance Substances 0.000 claims description 6
• 229910052718 tin Inorganic materials 0.000 claims description 6
• BKWNZVQQIYSORG-UHFFFAOYSA-N 3-ethylbicyclo[2.2.1]hepta-1,3-diene Chemical compound C1CC2=CC(CC)=C1C2 BKWNZVQQIYSORG-UHFFFAOYSA-N 0.000 claims description 5
• ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 5
• QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical group [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 5
• 125000001624 naphthyl group Chemical group 0.000 claims description 5
• SJYNFBVQFBRSIB-UHFFFAOYSA-N norbornadiene Chemical compound C1=CC2C=CC1C2 SJYNFBVQFBRSIB-UHFFFAOYSA-N 0.000 claims description 5
• 229930195734 saturated hydrocarbon Natural products 0.000 claims description 5
• 229930195735 unsaturated hydrocarbon Natural products 0.000 claims description 5
• PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 claims description 4
• RMDKEBZUCHXUER-UHFFFAOYSA-N 4-methylbicyclo[2.2.1]hept-2-ene Chemical compound C1CC2C=CC1(C)C2 RMDKEBZUCHXUER-UHFFFAOYSA-N 0.000 claims description 4
• INYHZQLKOKTDAI-UHFFFAOYSA-N 5-ethenylbicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(C=C)CC1C=C2 INYHZQLKOKTDAI-UHFFFAOYSA-N 0.000 claims description 4
• 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 4
• 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 claims description 4
• 229910052735 hafnium Chemical group 0.000 claims description 4
• VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical group [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims description 4
• TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims description 4
• JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 claims description 4
• 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 4
• XBFJAVXCNXDMBH-UHFFFAOYSA-N tetracyclo[6.2.1.1(3,6).0(2,7)]dodec-4-ene Chemical compound C1C(C23)C=CC1C3C1CC2CC1 XBFJAVXCNXDMBH-UHFFFAOYSA-N 0.000 claims description 4
• SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims description 3
• 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
• 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 3
• 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 3
• ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 claims description 3
• 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 3
• 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
• 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 3
• 238000005304 joining Methods 0.000 claims description 3
• 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
• 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
• 125000001147 pentyl group Chemical group C(CCCC)* 0.000 claims description 3
• ISWSIDIOOBJBQZ-UHFFFAOYSA-M phenolate Chemical compound [O-]C1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-M 0.000 claims description 3
• 229940031826 phenolate Drugs 0.000 claims description 3
• 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
• HHBQPYYNWUAPBT-UHFFFAOYSA-J 2-(2-oxidophenyl)phenolate;zirconium(4+) Chemical class [Zr+4].[O-]C1=CC=CC=C1C1=CC=CC=C1[O-].[O-]C1=CC=CC=C1C1=CC=CC=C1[O-] HHBQPYYNWUAPBT-UHFFFAOYSA-J 0.000 claims description 2
• 125000004860 4-ethylphenyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)C([H])([H])C([H])([H])[H] 0.000 claims description 2
• 125000004861 4-isopropyl phenyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)C([H])(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 2
• 125000000590 4-methylphenyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)C([H])([H])[H] 0.000 claims description 2
• PQGGNDZXVKQIBS-UHFFFAOYSA-L [Cl-].[Cl-].C[Si](=[Zr+2](C1C(=CC2=C(C=CC=C12)C1=C(C=CC=C1)C(C)(C)C)CC1(CC=CCC1)C)C1C(=CC2=C(C=CC=C12)C1=C(C=CC=C1)C(C)(C)C)CC1(CC=CCC1)C)C Chemical compound [Cl-].[Cl-].C[Si](=[Zr+2](C1C(=CC2=C(C=CC=C12)C1=C(C=CC=C1)C(C)(C)C)CC1(CC=CCC1)C)C1C(=CC2=C(C=CC=C12)C1=C(C=CC=C1)C(C)(C)C)CC1(CC=CCC1)C)C PQGGNDZXVKQIBS-UHFFFAOYSA-L 0.000 claims description 2
• USQCEKQZAORTRY-UHFFFAOYSA-L [Cl-].[Cl-].C[Si](=[Zr+2](C1C(=CC2=C(C=CC=C12)C1=C(C=CC=C1)C(C)(C)C)CC1(CCCCCC1)CC)C1C(=CC2=C(C=CC=C12)C1=C(C=CC=C1)C(C)(C)C)CC1(CCCCCC1)CC)C Chemical compound [Cl-].[Cl-].C[Si](=[Zr+2](C1C(=CC2=C(C=CC=C12)C1=C(C=CC=C1)C(C)(C)C)CC1(CCCCCC1)CC)C1C(=CC2=C(C=CC=C12)C1=C(C=CC=C1)C(C)(C)C)CC1(CCCCCC1)CC)C USQCEKQZAORTRY-UHFFFAOYSA-L 0.000 claims description 2
• ZORHZVXAYOKBBA-UHFFFAOYSA-L [Cl-].[Cl-].C[Si](=[Zr+2](C1C(=CC2=C(C=CC=C12)C1=C(C=CC=C1)C(C)(C)C)CC1(CCCCCC1)CCC)C1C(=CC2=C(C=CC=C12)C1=C(C=CC=C1)C(C)(C)C)CC1(CCCCCC1)CCC)C Chemical compound [Cl-].[Cl-].C[Si](=[Zr+2](C1C(=CC2=C(C=CC=C12)C1=C(C=CC=C1)C(C)(C)C)CC1(CCCCCC1)CCC)C1C(=CC2=C(C=CC=C12)C1=C(C=CC=C1)C(C)(C)C)CC1(CCCCCC1)CCC)C ZORHZVXAYOKBBA-UHFFFAOYSA-L 0.000 claims description 2
• GJOCUAITAVZTSG-UHFFFAOYSA-L [Cl-].[Cl-].C[Si](=[Zr+2](C1C(=CC2=C(C=CC=C12)C1=C(C=CC=C1)C(C)(C)C)CC1(CCCCCCCC1)C)C1C(=CC2=C(C=CC=C12)C1=C(C=CC=C1)C(C)(C)C)CC1(CCCCCCCC1)C)C Chemical compound [Cl-].[Cl-].C[Si](=[Zr+2](C1C(=CC2=C(C=CC=C12)C1=C(C=CC=C1)C(C)(C)C)CC1(CCCCCCCC1)C)C1C(=CC2=C(C=CC=C12)C1=C(C=CC=C1)C(C)(C)C)CC1(CCCCCCCC1)C)C GJOCUAITAVZTSG-UHFFFAOYSA-L 0.000 claims description 2
• VCDQKVOUPGTFTH-UHFFFAOYSA-L [Cl-].[Cl-].C[Si](=[Zr+2](C1C(=CC2=C(C=CC=C12)C1=C(C=CC=C1)C(C)(C)C)CC1(CCCCCCCC1)CCC)C1C(=CC2=C(C=CC=C12)C1=C(C=CC=C1)C(C)(C)C)CC1(CCCCCCCC1)CCC)C Chemical compound [Cl-].[Cl-].C[Si](=[Zr+2](C1C(=CC2=C(C=CC=C12)C1=C(C=CC=C1)C(C)(C)C)CC1(CCCCCCCC1)CCC)C1C(=CC2=C(C=CC=C12)C1=C(C=CC=C1)C(C)(C)C)CC1(CCCCCCCC1)CCC)C VCDQKVOUPGTFTH-UHFFFAOYSA-L 0.000 claims description 2
• IIACNDOIAAYCNH-UHFFFAOYSA-L [Cl-].[Cl-].C[Si](=[Zr+2](C1C(=CC2=C(C=CC=C12)C1=C(C=CC=C1)C(C)(C)C)CC1(COC1)CC)C1C(=CC2=C(C=CC=C12)C1=C(C=CC=C1)C(C)(C)C)CC1(COC1)CC)C Chemical compound [Cl-].[Cl-].C[Si](=[Zr+2](C1C(=CC2=C(C=CC=C12)C1=C(C=CC=C1)C(C)(C)C)CC1(COC1)CC)C1C(=CC2=C(C=CC=C12)C1=C(C=CC=C1)C(C)(C)C)CC1(COC1)CC)C IIACNDOIAAYCNH-UHFFFAOYSA-L 0.000 claims description 2
• PWYUQSKYEKCICM-UHFFFAOYSA-L [Cl-].[Cl-].C[Si](=[Zr+2](C1C(=CC2=C(C=CC=C12)C1=CC(=CC(=C1)C)C)CC1(CC1)CCC)C1C(=CC2=C(C=CC=C12)C1=CC(=CC(=C1)C)C)CC1(CC1)CCC)C Chemical compound [Cl-].[Cl-].C[Si](=[Zr+2](C1C(=CC2=C(C=CC=C12)C1=CC(=CC(=C1)C)C)CC1(CC1)CCC)C1C(=CC2=C(C=CC=C12)C1=CC(=CC(=C1)C)C)CC1(CC1)CCC)C PWYUQSKYEKCICM-UHFFFAOYSA-L 0.000 claims description 2
• LYPJDIZHHRJNDA-UHFFFAOYSA-L [Cl-].[Cl-].C[Si](=[Zr+2](C1C(=CC2=C(C=CC=C12)C1=CC(=CC(=C1)C)C)CC1(CCCCCC1)CCC)C1C(=CC2=C(C=CC=C12)C1=CC(=CC(=C1)C)C)CC1(CCCCCC1)CCC)C Chemical compound [Cl-].[Cl-].C[Si](=[Zr+2](C1C(=CC2=C(C=CC=C12)C1=CC(=CC(=C1)C)C)CC1(CCCCCC1)CCC)C1C(=CC2=C(C=CC=C12)C1=CC(=CC(=C1)C)C)CC1(CCCCCC1)CCC)C LYPJDIZHHRJNDA-UHFFFAOYSA-L 0.000 claims description 2
• APDTXFNHJXROCF-UHFFFAOYSA-L [Cl-].[Cl-].C[Si](=[Zr+2](C1C(=CC2=C(C=CC=C12)C1=CC(=CC(=C1)C)C)CC1(CCCCCCCC1)C)C1C(=CC2=C(C=CC=C12)C1=CC(=CC(=C1)C)C)CC1(CCCCCCCC1)C)C Chemical compound [Cl-].[Cl-].C[Si](=[Zr+2](C1C(=CC2=C(C=CC=C12)C1=CC(=CC(=C1)C)C)CC1(CCCCCCCC1)C)C1C(=CC2=C(C=CC=C12)C1=CC(=CC(=C1)C)C)CC1(CCCCCCCC1)C)C APDTXFNHJXROCF-UHFFFAOYSA-L 0.000 claims description 2
• FDOVXQQPEJMMEW-UHFFFAOYSA-L [Cl-].[Cl-].C[Si](=[Zr+2](C1C(=CC2=C(C=CC=C12)C1=CC(=CC(=C1)C)C)CC1(CCCCCCCC1)CCC)C1C(=CC2=C(C=CC=C12)C1=CC(=CC(=C1)C)C)CC1(CCCCCCCC1)CCC)C Chemical compound [Cl-].[Cl-].C[Si](=[Zr+2](C1C(=CC2=C(C=CC=C12)C1=CC(=CC(=C1)C)C)CC1(CCCCCCCC1)CCC)C1C(=CC2=C(C=CC=C12)C1=CC(=CC(=C1)C)C)CC1(CCCCCCCC1)CCC)C FDOVXQQPEJMMEW-UHFFFAOYSA-L 0.000 claims description 2
• UPLONFCBOXXRBS-UHFFFAOYSA-L [Cl-].[Cl-].C[Si](=[Zr+2](C1C(=CC2=C(C=CC=C12)C1=CC2=CC=CC=C2C=C1)CC1(CC1)CCC)C1C(=CC2=C(C=CC=C12)C1=CC2=CC=CC=C2C=C1)CC1(CC1)CCC)C Chemical compound [Cl-].[Cl-].C[Si](=[Zr+2](C1C(=CC2=C(C=CC=C12)C1=CC2=CC=CC=C2C=C1)CC1(CC1)CCC)C1C(=CC2=C(C=CC=C12)C1=CC2=CC=CC=C2C=C1)CC1(CC1)CCC)C UPLONFCBOXXRBS-UHFFFAOYSA-L 0.000 claims description 2
• UBDOEOFLYUEFDI-UHFFFAOYSA-L [Cl-].[Cl-].C[Si](=[Zr+2](C1C(=CC2=C(C=CC=C12)C1=CC2=CC=CC=C2C=C1)CC1(CCCCC1)CC)C1C(=CC2=C(C=CC=C12)C1=CC2=CC=CC=C2C=C1)CC1(CCCCC1)CC)C Chemical compound [Cl-].[Cl-].C[Si](=[Zr+2](C1C(=CC2=C(C=CC=C12)C1=CC2=CC=CC=C2C=C1)CC1(CCCCC1)CC)C1C(=CC2=C(C=CC=C12)C1=CC2=CC=CC=C2C=C1)CC1(CCCCC1)CC)C UBDOEOFLYUEFDI-UHFFFAOYSA-L 0.000 claims description 2
• UMGBHIDPZAVBFX-UHFFFAOYSA-L [Cl-].[Cl-].C[Si](=[Zr+2](C1C(=CC2=C(C=CC=C12)C1=CC2=CC=CC=C2C=C1)CC1(CCCCCC1)CC)C1C(=CC2=C(C=CC=C12)C1=CC2=CC=CC=C2C=C1)CC1(CCCCCC1)CC)C Chemical compound [Cl-].[Cl-].C[Si](=[Zr+2](C1C(=CC2=C(C=CC=C12)C1=CC2=CC=CC=C2C=C1)CC1(CCCCCC1)CC)C1C(=CC2=C(C=CC=C12)C1=CC2=CC=CC=C2C=C1)CC1(CCCCCC1)CC)C UMGBHIDPZAVBFX-UHFFFAOYSA-L 0.000 claims description 2
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• HPKBFHDRGPIYAG-UHFFFAOYSA-N tris(2,4,6-trifluorophenyl)borane Chemical compound FC1=CC(F)=CC(F)=C1B(C=1C(=CC(F)=CC=1F)F)C1=C(F)C=C(F)C=C1F HPKBFHDRGPIYAG-UHFFFAOYSA-N 0.000 description 1
• YFDAMRSZJLWUSQ-UHFFFAOYSA-N tris(2-methylphenyl)borane Chemical compound CC1=CC=CC=C1B(C=1C(=CC=CC=1)C)C1=CC=CC=C1C YFDAMRSZJLWUSQ-UHFFFAOYSA-N 0.000 description 1
• LKNHGIFPRLUGEG-UHFFFAOYSA-N tris(3,4,5-trifluorophenyl)borane Chemical compound FC1=C(F)C(F)=CC(B(C=2C=C(F)C(F)=C(F)C=2)C=2C=C(F)C(F)=C(F)C=2)=C1 LKNHGIFPRLUGEG-UHFFFAOYSA-N 0.000 description 1
• OHSAEOPCBBOWPU-UHFFFAOYSA-N tris(3,5-dimethylphenyl)borane Chemical compound CC1=CC(C)=CC(B(C=2C=C(C)C=C(C)C=2)C=2C=C(C)C=C(C)C=2)=C1 OHSAEOPCBBOWPU-UHFFFAOYSA-N 0.000 description 1
• YPVVTWIAXFPZLS-UHFFFAOYSA-N tris(4-fluorophenyl)borane Chemical compound C1=CC(F)=CC=C1B(C=1C=CC(F)=CC=1)C1=CC=C(F)C=C1 YPVVTWIAXFPZLS-UHFFFAOYSA-N 0.000 description 1
• OSMBUUFIZBTSNO-UHFFFAOYSA-N tris[4-(fluoromethyl)phenyl]borane Chemical compound C1=CC(CF)=CC=C1B(C=1C=CC(CF)=CC=1)C1=CC=C(CF)C=C1 OSMBUUFIZBTSNO-UHFFFAOYSA-N 0.000 description 1
• OLFPYUPGPBITMH-UHFFFAOYSA-N tritylium Chemical compound C1=CC=CC=C1[C+](C=1C=CC=CC=1)C1=CC=CC=C1 OLFPYUPGPBITMH-UHFFFAOYSA-N 0.000 description 1
• 229940056345 tums Drugs 0.000 description 1
• 238000005303 weighing Methods 0.000 description 1
• 238000010626 work up procedure Methods 0.000 description 1
• 239000004711 α-olefin Substances 0.000 description 1