SG169326A1 - Organometallic ruthenium complexes and related methods for the preparation of tetra-substituted and other hindered olefins - Google Patents
Organometallic ruthenium complexes and related methods for the preparation of tetra-substituted and other hindered olefinsInfo
- Publication number
- SG169326A1 SG169326A1 SG201100293-8A SG2011002938A SG169326A1 SG 169326 A1 SG169326 A1 SG 169326A1 SG 2011002938 A SG2011002938 A SG 2011002938A SG 169326 A1 SG169326 A1 SG 169326A1
- Authority
- SG
- Singapore
- Prior art keywords
- substituted
- tetra
- preparation
- related methods
- ring
- Prior art date
Links
- -1 Organometallic ruthenium complexes Chemical class 0.000 title abstract 2
- 150000001336 alkenes Chemical class 0.000 title 1
- 125000002373 5 membered heterocyclic group Chemical group 0.000 abstract 2
- 229910052799 carbon Inorganic materials 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 229910052757 nitrogen Inorganic materials 0.000 abstract 2
- 125000004433 nitrogen atom Chemical group N* 0.000 abstract 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 2
- ADLVDYMTBOSDFE-UHFFFAOYSA-N 5-chloro-6-nitroisoindole-1,3-dione Chemical compound C1=C(Cl)C([N+](=O)[O-])=CC2=C1C(=O)NC2=O ADLVDYMTBOSDFE-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 238000005865 alkene metathesis reaction Methods 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 239000003446 ligand Substances 0.000 abstract 1
- 238000006798 ring closing metathesis reaction Methods 0.000 abstract 1
- 229910052707 ruthenium Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0046—Ruthenium compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2265—Carbenes or carbynes, i.e.(image)
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
- C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
- C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
- C08G61/08—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds of carbocyclic compounds containing one or more carbon-to-carbon double bonds in the ring
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
- B01J2231/54—Metathesis reactions, e.g. olefin metathesis
- B01J2231/543—Metathesis reactions, e.g. olefin metathesis alkene metathesis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/821—Ruthenium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US75122505P | 2005-12-16 | 2005-12-16 | |
| US80174206P | 2006-05-19 | 2006-05-19 | |
| US85371706P | 2006-10-19 | 2006-10-19 | |
| US85914806P | 2006-11-15 | 2006-11-15 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SG169326A1 true SG169326A1 (en) | 2011-03-30 |
Family
ID=37964546
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SG201100293-8A SG169326A1 (en) | 2005-12-16 | 2006-12-18 | Organometallic ruthenium complexes and related methods for the preparation of tetra-substituted and other hindered olefins |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US8008224B2 (https=) |
| EP (1) | EP1971616A1 (https=) |
| JP (1) | JP5522941B2 (https=) |
| KR (2) | KR20080103961A (https=) |
| CN (1) | CN101460513B (https=) |
| SG (1) | SG169326A1 (https=) |
| WO (1) | WO2007075427A1 (https=) |
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8877936B2 (en) * | 2008-04-09 | 2014-11-04 | California Institute Of Technology | Ruthenium olefin metathesis catalysts bearing N-heterocyclic carbene ligands with substituted backbone |
| FR2939331B1 (fr) | 2008-12-10 | 2012-08-10 | Inst Francais Du Petrole | Composition catalytique et procede de metathese de corps gras insature |
| AP2011006003A0 (en) | 2009-05-05 | 2011-12-31 | Stepan Co | Sulfonated internal olefin surfactant for enhancedoil recovery. |
| WO2011135029A1 (en) | 2010-04-28 | 2011-11-03 | Dsm Ip Assets B.V. | Metathesis crosslinkable coating compositions |
| JP5674059B2 (ja) * | 2011-01-24 | 2015-02-25 | 国立大学法人名古屋大学 | ルテニウム錯体を含む水素移動反応用触媒及び水素移動反応物の製造方法 |
| CN102145304B (zh) * | 2011-02-24 | 2012-08-08 | 华东师范大学 | 一种负载型格拉布斯催化剂的制备及其应用 |
| FR2983475B1 (fr) | 2011-12-02 | 2014-01-17 | IFP Energies Nouvelles | Procede de metathese d'olefines lineaires alpha utilisant un complexe du ruthenium comportant un carbene n-heterocyclique dissymetrique |
| JP6092379B2 (ja) | 2012-06-29 | 2017-03-08 | アペイロン シンセシス エス アー | 金属錯体、その適用、及びメタセシス反応の実施方法 |
| PL225024B1 (pl) | 2012-08-16 | 2017-02-28 | Univ Warszawski | Nowe kompleksy rutenu oraz ich zastosowanie |
| WO2017012379A1 (zh) * | 2015-07-20 | 2017-01-26 | 中国科学院上海有机化学研究所 | 草酸酰胺类配体及其在铜催化芳基卤代物偶联反应中的用途 |
| EP3376859B1 (en) | 2015-11-18 | 2021-01-06 | Provivi, Inc. | Microorganisms for the production of insect pheromones and related compounds |
| WO2017087710A2 (en) | 2015-11-18 | 2017-05-26 | Provivi, Inc. | Production of fatty olefin derivatives via olefin metathesis |
| KR20180116238A (ko) * | 2015-12-10 | 2018-10-24 | 우미코레 아게 운트 코 카게 | 올레핀 복분해 촉매 |
| WO2017214133A2 (en) | 2016-06-06 | 2017-12-14 | Provivi, Inc. | Semi-biosynthetic production of fatty alcohols and fatty aldehydes |
| HUE073559T2 (hu) | 2017-02-17 | 2026-01-28 | Provivi Inc | Feromonok és kapcsolódó anyagok szintézise olefin-metatézisen keresztül |
| MX382401B (es) | 2017-05-17 | 2025-03-13 | Provivi Inc | Microorganismos para la producción de feromonas de insectos y compuestos relacionados. |
| US10683388B2 (en) * | 2017-08-15 | 2020-06-16 | University Of Florida Research Foundation, Incorporated | High temperature metathesis chemistry |
| CN108299506A (zh) * | 2018-01-29 | 2018-07-20 | 中国科学院成都有机化学有限公司 | N-杂环卡宾钌络合物及其制备方法和用途 |
| CN109225334B (zh) * | 2018-07-20 | 2021-05-18 | 吉林化工学院 | 一种具有邻位空间位阻结构的钌烯烃复分解催化剂及其制备方法和应用 |
| CN109364998B (zh) * | 2018-10-15 | 2021-07-06 | 天津科技大学 | 一种用于烯烃复分解反应的催化剂及其制备和应用方法 |
| CN111250168B (zh) * | 2018-11-30 | 2021-06-01 | 中国科学院大连化学物理研究所 | 一种钌基催化剂及其制备方法、应用 |
| CN110041262B (zh) | 2019-01-02 | 2020-03-27 | 成都开美思商务信息咨询中心(有限合伙) | 氮杂环卡宾配体及其钌催化剂、制备方法和应用 |
| CN112547126B (zh) * | 2020-12-21 | 2023-03-21 | 上海中化科技有限公司 | 钌卡宾化合物、其组合物、制备方法及应用 |
| CN113000066B (zh) * | 2021-01-09 | 2022-04-12 | 河南大学 | 一种z-选择性钌卡宾烯烃复分解催化剂及其制备方法和应用 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19815275B4 (de) | 1998-04-06 | 2009-06-25 | Evonik Degussa Gmbh | Alkylidenkomplexe des Rutheniums mit N-heterozyklischen Carbenliganden und deren Verwendung als hochaktive, selektive Katalysatoren für die Olefin-Metathese |
| EP1180108B1 (en) | 1999-05-24 | 2003-08-27 | California Institute Of Technology | Imidazolidine-based metal carbene metathesis catalysts |
| JP3943015B2 (ja) * | 2000-08-10 | 2007-07-11 | トラスティーズ オブ ボストン カレッジ | リサイクル可能メタセシス触媒 |
| WO2002020535A1 (en) * | 2000-09-05 | 2002-03-14 | California Institute Of Technology | Highly active metathesis catalysts generated in situ from inexpensive and air stable precursors |
| US6759537B2 (en) * | 2001-03-23 | 2004-07-06 | California Institute Of Technology | Hexacoordinated ruthenium or osmium metal carbene metathesis catalysts |
| CA2442368C (en) * | 2001-03-30 | 2015-10-13 | California Institute Of Technology | Cross-metathesis reaction of functionalized and substituted olefins using group 8 transition metal carbene complexes as metathesis catalysts |
| US7683180B2 (en) * | 2001-04-16 | 2010-03-23 | California Institute Of Technology | Group 8 transition metal carbene complexes as enantionselective olefin metathesis catalysts |
| US6818586B2 (en) * | 2001-08-01 | 2004-11-16 | Cymetech, Llp | Hexacoordinated ruthenium or osmium metal carbene metathesis catalysts |
| EP2251360B1 (en) * | 2001-08-29 | 2013-07-31 | California Institute of Technology | Ring-opening metathesis polymerization of bridged bicyclic and polycyclic olefins containing two or more heteroatoms |
-
2006
- 2006-12-18 KR KR1020087017250A patent/KR20080103961A/ko not_active Ceased
- 2006-12-18 JP JP2008545845A patent/JP5522941B2/ja not_active Expired - Fee Related
- 2006-12-18 WO PCT/US2006/047934 patent/WO2007075427A1/en not_active Ceased
- 2006-12-18 US US11/640,400 patent/US8008224B2/en active Active
- 2006-12-18 SG SG201100293-8A patent/SG169326A1/en unknown
- 2006-12-18 EP EP06845551A patent/EP1971616A1/en not_active Withdrawn
- 2006-12-18 CN CN200680051426.3A patent/CN101460513B/zh not_active Expired - Fee Related
- 2006-12-18 KR KR1020147019358A patent/KR20140097571A/ko not_active Ceased
-
2011
- 2011-08-30 US US13/221,871 patent/US8361922B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| US20070282148A1 (en) | 2007-12-06 |
| US20120123133A1 (en) | 2012-05-17 |
| US8008224B2 (en) | 2011-08-30 |
| KR20140097571A (ko) | 2014-08-06 |
| CN101460513A (zh) | 2009-06-17 |
| CN101460513B (zh) | 2014-08-27 |
| JP2009519947A (ja) | 2009-05-21 |
| JP5522941B2 (ja) | 2014-06-18 |
| EP1971616A1 (en) | 2008-09-24 |
| WO2007075427A1 (en) | 2007-07-05 |
| US8361922B2 (en) | 2013-01-29 |
| KR20080103961A (ko) | 2008-11-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| SG169326A1 (en) | Organometallic ruthenium complexes and related methods for the preparation of tetra-substituted and other hindered olefins | |
| Cazin | N-Heterocyclic carbenes in transition metal catalysis and organocatalysis | |
| WO2007010453A3 (en) | Transition metal compounds having a cyclic phosphorus-containing ligand and a cyclic organic ligand for use in metathesis reactions | |
| Trnka et al. | Novel η3-vinylcarbene complexes derived from ruthenium-based olefin metathesis catalysts | |
| Bantreil et al. | Mixed N-heterocyclic carbene/phosphite ruthenium complexes: towards a new generation of olefin metathesis catalysts | |
| PL1826220T3 (pl) | Zastosowanie katalizatorów o zwiększonej aktywności do metatezy kauczuków nitrylowych | |
| Hong et al. | Double C H Activation of an N‐Heterocyclic Carbene Ligand in a Ruthenium Olefin Metathesis Catalyst | |
| WO2005094345A3 (en) | Latent, high-activity olefin metathesis catalysts containing an n-heterocyclic carbene ligand | |
| WO2002083742A3 (en) | Group 8 transition metal carbene complexes as enantioselective olefin metathesis catalysts | |
| Davies et al. | Ni (I) and Ni (II) ring-expanded N-heterocyclic carbene complexes: C–H activation, indole elimination and catalytic hydrodehalogenation | |
| Corberán et al. | Coinage metal complexes with N-heterocyclic carbene ligands as selective catalysts in diboration reaction | |
| DE60039166D1 (de) | Mit triazolydin-liganden koordinierte rutheniummetall-alkyliden-komplexe die hohe olefin-metathese-aktivität aufweisen | |
| WO2007130306A3 (en) | Ortho-metallated hafnium complexes of imidazole ligands | |
| EP1765839A4 (en) | TRANSITION METAL COLOR COMPLEXES CONTAINING CATIONIC SUBSTITUTES AS CATALYSTS OF OLEFIN METATHESE ACTIONS | |
| MY130628A (en) | Phosphorus containing ligands for metathesis catalysts | |
| Stoelzel et al. | N-heterocyclic silylene (NHSi) rhodium and iridium complexes: synthesis, structure, reactivity, and catalytic ability | |
| Veige | Carbon monoxide as a reagent: A report on the role of N-heterocyclic carbene (NHC) ligands in metal-catalyzed carbonylation reactions | |
| Shibata et al. | Rhodium-catalyzed regioselective addition of the ortho C–H bond in aromatic amides to the C–C double bond in α, β-unsaturated γ-lactones and dihydrofurans | |
| Grohmann et al. | Diruthenium (I, I) Catalysts for the Formation of β‐and γ‐Lactams via Carbenoid C H Insertion of α‐Diazoacetamides | |
| Bose et al. | C–H activation of arenes and heteroarenes by early transition metallaborane,[(Cp* Ta) 2 B 5 H 11](Cp*= η 5-C 5 Me 5) | |
| Álvarez-Rodríguez et al. | Ruthenium carbene complexes analogous to grubbs-I catalysts featuring germylenes as ancillary ligands | |
| Nascimento et al. | Challenging metathesis catalysts with nucleophiles and brønsted base: examining the stability of state-of-the-art ruthenium carbene catalysts to attack by amines | |
| Liu et al. | A half-sandwich 1, 2-azaborolyl ruthenium complex: synthesis, characterization, and evaluation of its catalytic activities | |
| Munslow et al. | Bidentate carbenoid ester coordination in ruthenium (ii) Schiff-base complexes leading to excellent levels of diastereo-and enantioselectivity in catalytic alkene cyclopropanationElectronic supplementary information (ESI) available: experimental and theoretical details, structures of [RuL1 (CH3CN) 2] and [RuL1 (η2-CHCO2Et)](. pdb). CCDC 167600. See http://www. rsc. org/suppdata/cc/b1/b104964j | |
| WO2005016524A3 (de) | Immobilisierte immidazole und ruthenium-katalysatoren |