DE60039166D1 - Mit triazolydin-liganden koordinierte rutheniummetall-alkyliden-komplexe die hohe olefin-metathese-aktivität aufweisen - Google Patents
Mit triazolydin-liganden koordinierte rutheniummetall-alkyliden-komplexe die hohe olefin-metathese-aktivität aufweisenInfo
- Publication number
- DE60039166D1 DE60039166D1 DE60039166T DE60039166T DE60039166D1 DE 60039166 D1 DE60039166 D1 DE 60039166D1 DE 60039166 T DE60039166 T DE 60039166T DE 60039166 T DE60039166 T DE 60039166T DE 60039166 D1 DE60039166 D1 DE 60039166D1
- Authority
- DE
- Germany
- Prior art keywords
- complexes
- triazolydin
- metathese
- ligands
- activity
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003446 ligand Substances 0.000 title abstract 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 title 1
- 150000001336 alkenes Chemical class 0.000 title 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title 1
- 239000003054 catalyst Substances 0.000 abstract 2
- 229910052707 ruthenium Inorganic materials 0.000 abstract 2
- WLPUWLXVBWGYMZ-UHFFFAOYSA-N tricyclohexylphosphine Chemical compound C1CCCCC1P(C1CCCCC1)C1CCCCC1 WLPUWLXVBWGYMZ-UHFFFAOYSA-N 0.000 abstract 2
- 238000005865 alkene metathesis reaction Methods 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- -1 cyclic olefins Chemical class 0.000 abstract 1
- 150000001993 dienes Chemical class 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 238000006798 ring closing metathesis reaction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0046—Ruthenium compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
- Pyrane Compounds (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12746999P | 1999-03-31 | 1999-03-31 | |
PCT/US2000/008753 WO2000058322A1 (en) | 1999-03-31 | 2000-03-31 | Novel ruthenium metal alkylidene complexes coordinated with triazolylidene ligands that exhibit high olefin metathesis activity |
Publications (1)
Publication Number | Publication Date |
---|---|
DE60039166D1 true DE60039166D1 (de) | 2008-07-24 |
Family
ID=22430290
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE60039166T Expired - Lifetime DE60039166D1 (de) | 1999-03-31 | 2000-03-31 | Mit triazolydin-liganden koordinierte rutheniummetall-alkyliden-komplexe die hohe olefin-metathese-aktivität aufweisen |
Country Status (7)
Country | Link |
---|---|
US (2) | US6426419B1 (de) |
EP (1) | EP1180107B1 (de) |
JP (1) | JP2002540213A (de) |
AT (1) | ATE398133T1 (de) |
AU (1) | AU4189300A (de) |
DE (1) | DE60039166D1 (de) |
WO (1) | WO2000058322A1 (de) |
Families Citing this family (67)
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DE19815275B4 (de) * | 1998-04-06 | 2009-06-25 | Evonik Degussa Gmbh | Alkylidenkomplexe des Rutheniums mit N-heterozyklischen Carbenliganden und deren Verwendung als hochaktive, selektive Katalysatoren für die Olefin-Metathese |
US7285593B1 (en) | 1998-05-19 | 2007-10-23 | Advanced Polymer Technologies, Inc. | Polyolefin compositions optionally having variable toughness and/or hardness |
US6696597B2 (en) | 1998-09-01 | 2004-02-24 | Tilliechem, Inc. | Metathesis syntheses of pheromones or their components |
US7507854B2 (en) | 1998-09-01 | 2009-03-24 | Materia, Inc. | Impurity reduction in Olefin metathesis reactions |
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US20140088260A1 (en) | 1999-02-05 | 2014-03-27 | Materia, Inc. | Metathesis-active adhesion agents and methods for enhancing polymer adhesion to surfaces |
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US7329758B1 (en) | 1999-05-24 | 2008-02-12 | California Institute Of Technology | Imidazolidine-based metal carbene metathesis catalysts |
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WO2002020535A1 (en) * | 2000-09-05 | 2002-03-14 | California Institute Of Technology | Highly active metathesis catalysts generated in situ from inexpensive and air stable precursors |
US6838489B2 (en) * | 2001-03-23 | 2005-01-04 | Cymetech, Llc | High activity metal carbene metathesis catalysts generated using a thermally activated N-heterocyclic carbene precursor |
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EP1373170A4 (de) * | 2001-03-30 | 2007-03-21 | California Inst Of Techn | Kreuz-metathese von funktionalisierten und substituierten olefinen unter einsatz von gruppe 8 übergangsmetall-carben-komplexe als methatese-katalysatoren |
JP4271942B2 (ja) * | 2001-03-30 | 2009-06-03 | カリフォルニア インスティチュート オブ テクノロジー | シクロオレフィンの選択的開環クロス−メタセシス |
US7683180B2 (en) | 2001-04-16 | 2010-03-23 | California Institute Of Technology | Group 8 transition metal carbene complexes as enantionselective olefin metathesis catalysts |
CN1911942B (zh) * | 2001-08-01 | 2010-06-23 | 加州理工学院 | 六配位钌或锇金属卡宾易位催化剂 |
CN1265882C (zh) * | 2001-08-01 | 2006-07-26 | 加州理工学院 | 六配位钌或锇金属卡宾易位催化剂 |
JP4643091B2 (ja) * | 2001-08-24 | 2011-03-02 | カリフォルニア インスティテュート オブ テクノロジー | 6配位ルテニウムまたはオスミウム金属カルベンメタセシス触媒 |
JP4295096B2 (ja) * | 2001-08-29 | 2009-07-15 | カリフォルニア インスティチュート オブ テクノロジー | 2個以上のヘテロ原子を含有する架橋された二環式および多環式のオレフィンの開環メタセシス重合 |
RU2352549C2 (ru) | 2002-04-29 | 2009-04-20 | Дау Глобал Текнолоджиз Инк. | Интегрированные химические способы промышленного применения растительных масел из семян |
WO2004005223A1 (en) * | 2002-07-05 | 2004-01-15 | Sasol Technology (Uk) Ltd | Phosphorus containing ligands for metathesis catalysts |
WO2004062763A2 (en) * | 2003-01-13 | 2004-07-29 | Cargill, Incorporated | Method for making industrial chemicals |
US7094898B2 (en) * | 2003-05-29 | 2006-08-22 | University Of Ottawa | Ruthenium compounds, their production and use |
US7205424B2 (en) * | 2003-06-19 | 2007-04-17 | University Of New Orleans Research And Technology Foundation, Inc. | Preparation of ruthenium-based olefin metathesis catalysts |
WO2005048283A2 (en) * | 2003-07-18 | 2005-05-26 | Northwestern University | Surface and site-specific polymerization by direct-write lithography |
EP1648943B1 (de) * | 2003-07-28 | 2010-03-31 | Firestone Polymers, LLC | Entfernen von gelartigen ungesättigten elastomeren aus der polymerisationsapparatur, die mit deren herstellung verbunden ist. |
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ZA200700170B (en) | 2004-06-09 | 2008-05-28 | Uti Limited Partnership | Transition metal carbene complexes containing a cationi substituent as catalysts of olefin metathesis reactions |
US7960555B2 (en) * | 2004-10-20 | 2011-06-14 | University Of Massachusetts | Substituted pyridine ligands and related water-soluble catalysts |
WO2006045070A2 (en) * | 2004-10-20 | 2006-04-27 | University Of Massachusetts | Peg-substituted pyridine ligands and related water-soluble catalysts |
US8101697B2 (en) * | 2005-02-01 | 2012-01-24 | Bridgestone Corporation | Multi-functionalized high-trans elastomeric polymers |
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WO2006127483A1 (en) * | 2005-05-20 | 2006-11-30 | Bridgestone Corporation | Method for preparing low molecular weight polymers |
US7482925B2 (en) * | 2005-06-24 | 2009-01-27 | Visa U.S.A. | Apparatus and method to electromagnetically shield portable consumer devices |
WO2007081987A2 (en) * | 2006-01-10 | 2007-07-19 | Elevance Renewable Sciences, Inc. | Method of making hydrogenated metathesis products |
CN101563315B (zh) * | 2006-07-12 | 2013-08-14 | 埃莱文斯可更新科学公司 | 环烯烃与种子油等的开环交叉复分解反应 |
WO2008010961A2 (en) | 2006-07-13 | 2008-01-24 | Elevance Renewable Sciences, Inc. | Synthesis of terminal alkenes from internal alkenes and ethylene via olefin metathesis |
MX2009002042A (es) | 2006-08-25 | 2009-03-06 | Dow Global Technologies Inc | Produccion de compuestos telequelicos mediante despolimerizacion de metatesis. |
JP2010501719A (ja) * | 2006-08-25 | 2010-01-21 | ダウ グローバル テクノロジーズ インコーポレイティド | メタセシスによる非晶質ポリマーセグメント交換によるブロックコポリマーの製造 |
EP2061826B1 (de) * | 2006-08-25 | 2012-08-01 | Dow Global Technologies LLC | Herstellung von zufallsblockcopolymeren durch metathese von polymersegmenten mit hohem schmelzpunkt |
US8557921B2 (en) | 2006-08-25 | 2013-10-15 | Dow Global Technologies Llc | Production of meta-block copolymers by polymer segment interchange |
EP2076483A4 (de) | 2006-10-13 | 2013-12-04 | Elevance Renewable Sciences | Verfahren zur herstellung organischer verbindungen durch metathese und hydrocyanierung |
DK2121546T3 (en) * | 2006-10-13 | 2018-03-12 | Elevance Renewable Sciences | Process for preparing omega-dicarboxylic acid olefin derivative by metathesis |
WO2008046106A2 (en) * | 2006-10-13 | 2008-04-17 | Elevance Renewable Sciences, Inc. | Synthesis of terminal alkenes from internal alkenes via olefin metathesis |
US20080306230A1 (en) * | 2007-06-07 | 2008-12-11 | General Electric Company | Composition and Associated Method |
JP5547631B2 (ja) * | 2007-06-20 | 2014-07-16 | エージェンシー フォー サイエンス, テクノロジー アンド リサーチ | N−複素環式カルベンメタラサイクル触媒およびその方法 |
ES2569483T3 (es) * | 2007-06-21 | 2016-05-11 | Amgen Inc. | Métodos para sintetizar cinacalcet y sales del mismo |
US8241575B2 (en) | 2008-01-28 | 2012-08-14 | The Johns Hopkins University | Molecularly imprinted polymer sensor device |
RU2011108263A (ru) * | 2008-08-04 | 2012-09-10 | ФАЙРСТОУН ПОЛИМЕРС, ЭлЭлСи (US) | Аддукты полимеров, получаемых метатезисной полимеризацией, и их получение |
US8436110B2 (en) | 2008-10-31 | 2013-05-07 | Dow Global Technologies Llc | Olefin metathesis process employing bimetallic ruthenium complex with bridging hydrido ligands |
WO2010129051A1 (en) | 2009-05-05 | 2010-11-11 | Stepan Company | Sulfonated internal olefin surfactant for enhanced oil recovery |
US8895667B2 (en) | 2009-07-17 | 2014-11-25 | Tyco Electronics Corporation | Methods of making reversible crosslinked polymers and related methods |
WO2011139704A2 (en) * | 2010-04-27 | 2011-11-10 | The Regents Of The University Of California | Crystalline 1h-1,2,3-triazol-5-ylidenes |
ES2557463T3 (es) * | 2010-06-22 | 2016-01-26 | Firmenich Sa | Complejos a base de rutenio |
WO2013059724A1 (en) * | 2011-10-21 | 2013-04-25 | California Institute Of Technology | System and method for determining the isotopic anatomy of organic and volatile molecules |
US9234985B2 (en) | 2012-08-01 | 2016-01-12 | California Institute Of Technology | Birefringent polymer brush structures formed by surface initiated ring-opening metathesis polymerization |
WO2014022482A1 (en) | 2012-08-01 | 2014-02-06 | California Institute Of Technology | Solvent-free enyne metathesis polymerization |
EP2903996B1 (de) | 2012-10-05 | 2018-08-01 | California Institute of Technology | Metathesenpolymerisation photoinitiierter olefine |
PL221841B1 (pl) * | 2012-12-28 | 2016-06-30 | Inst Chemii Organicznej Pan | Nowe kompleksy rutenu, sposób ich wytwarzania oraz ich zastosowanie w metatezie olefin |
WO2014186631A1 (en) * | 2013-05-15 | 2014-11-20 | California Institute Of Technology | Highly z-selective and enantioselective ring opening/cross metathesis |
EP3063592B1 (de) | 2013-10-30 | 2021-04-07 | California Institute of Technology | Direkte fotostrukturierung von robusten und unterschiedlichen materialien |
WO2016022965A1 (en) | 2014-08-08 | 2016-02-11 | Massachusetts Institute Of Technology | Persistent carbene adducts and related methods |
KR102261420B1 (ko) * | 2017-10-31 | 2021-06-07 | 주식회사 엘지화학 | 세척액 조성물 및 이를 이용한 중합 장치 세척 방법 |
JP2022542784A (ja) * | 2019-07-17 | 2022-10-07 | カリフォルニア・インスティテュート・オブ・テクノロジー | Z選択的オレフィンメタセシス触媒の新合成 |
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US5194534A (en) * | 1991-09-24 | 1993-03-16 | Hercules Incorporated | Tungsten-imido catalysts for ring-opening metathesis polymerization of cycloolefins |
US5710298A (en) | 1992-04-03 | 1998-01-20 | California Institute Of Technology | Method of preparing ruthenium and osmium carbene complexes |
JP3067031B2 (ja) | 1992-04-03 | 2000-07-17 | カリフォルニア インスティチュート オブ テクノロジー | オレフィンメタセシス重合方法 |
US5312940A (en) | 1992-04-03 | 1994-05-17 | California Institute Of Technology | Ruthenium and osmium metal carbene complexes for olefin metathesis polymerization |
DE4447066A1 (de) | 1994-12-29 | 1996-07-04 | Hoechst Ag | Heterocyclische Carbene enthaltende Metallkomplexverbindungen |
US5831108A (en) | 1995-08-03 | 1998-11-03 | California Institute Of Technology | High metathesis activity ruthenium and osmium metal carbene complexes |
US5939504A (en) | 1995-12-07 | 1999-08-17 | Advanced Polymer Technologies | Method for extending the pot life of an olefin metathesis polymerization reaction |
US6020443A (en) | 1996-02-08 | 2000-02-01 | Advanced Polymer Technologies, Inc. | Polymerization of low grade DCPD monomers using an olefin metathesis catalyst |
DE19610908A1 (de) * | 1996-03-20 | 1997-09-25 | Hoechst Ag | Verfahren zur Herstellung heterocyclischer Carbene |
DE19629523A1 (de) | 1996-07-22 | 1998-01-29 | Basf Ag | Verfahren zur Herstellung von optisch aktiven Verbindungen durch enantioselektive intramolekulare Stetter-Reaktion |
DE19815275B4 (de) * | 1998-04-06 | 2009-06-25 | Evonik Degussa Gmbh | Alkylidenkomplexe des Rutheniums mit N-heterozyklischen Carbenliganden und deren Verwendung als hochaktive, selektive Katalysatoren für die Olefin-Metathese |
-
2000
- 2000-03-31 JP JP2000608022A patent/JP2002540213A/ja active Pending
- 2000-03-31 US US09/539,840 patent/US6426419B1/en not_active Expired - Fee Related
- 2000-03-31 AT AT00921600T patent/ATE398133T1/de not_active IP Right Cessation
- 2000-03-31 AU AU41893/00A patent/AU4189300A/en not_active Abandoned
- 2000-03-31 WO PCT/US2000/008753 patent/WO2000058322A1/en active Search and Examination
- 2000-03-31 DE DE60039166T patent/DE60039166D1/de not_active Expired - Lifetime
- 2000-03-31 EP EP00921600A patent/EP1180107B1/de not_active Revoked
-
2001
- 2001-01-25 US US09/770,993 patent/US6624265B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
EP1180107B1 (de) | 2008-06-11 |
JP2002540213A (ja) | 2002-11-26 |
EP1180107A4 (de) | 2005-01-12 |
AU4189300A (en) | 2000-10-16 |
US6624265B2 (en) | 2003-09-23 |
ATE398133T1 (de) | 2008-07-15 |
WO2000058322A1 (en) | 2000-10-05 |
US6426419B1 (en) | 2002-07-30 |
US20020013473A1 (en) | 2002-01-31 |
EP1180107A1 (de) | 2002-02-20 |
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