JP5522941B2 - 有機金属ルテニウム錯体および関連する四置換および別の嵩高いオレフィンの製造方法 - Google Patents

有機金属ルテニウム錯体および関連する四置換および別の嵩高いオレフィンの製造方法 Download PDF

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JP5522941B2
JP5522941B2 JP2008545845A JP2008545845A JP5522941B2 JP 5522941 B2 JP5522941 B2 JP 5522941B2 JP 2008545845 A JP2008545845 A JP 2008545845A JP 2008545845 A JP2008545845 A JP 2008545845A JP 5522941 B2 JP5522941 B2 JP 5522941B2
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substituted
olefin
unsubstituted
group
catalyst
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JP2009519947A5 (https=
JP2009519947A (ja
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ジェイコブ・バーリン
ロバート・エイチ・グラブス
ヤン・シュロディ
イアン・シー・スチュワート
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California Institute of Technology
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0046—Ruthenium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2265—Carbenes or carbynes, i.e.(image)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
    • C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
    • C08G61/08—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds of carbocyclic compounds containing one or more carbon-to-carbon double bonds in the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/54—Metathesis reactions, e.g. olefin metathesis
    • B01J2231/543—Metathesis reactions, e.g. olefin metathesis alkene metathesis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
JP2008545845A 2005-12-16 2006-12-18 有機金属ルテニウム錯体および関連する四置換および別の嵩高いオレフィンの製造方法 Expired - Fee Related JP5522941B2 (ja)

Applications Claiming Priority (9)

Application Number Priority Date Filing Date Title
US75122505P 2005-12-16 2005-12-16
US60/751,225 2005-12-16
US80174206P 2006-05-19 2006-05-19
US60/801,742 2006-05-19
US85371706P 2006-10-19 2006-10-19
US60/853,717 2006-10-19
US85914806P 2006-11-15 2006-11-15
US60/859,148 2006-11-15
PCT/US2006/047934 WO2007075427A1 (en) 2005-12-16 2006-12-18 Organometallic ruthenium complexes and related methods for the preparation of tetra-substituted and other hindered olefins

Publications (3)

Publication Number Publication Date
JP2009519947A JP2009519947A (ja) 2009-05-21
JP2009519947A5 JP2009519947A5 (https=) 2010-02-18
JP5522941B2 true JP5522941B2 (ja) 2014-06-18

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JP2008545845A Expired - Fee Related JP5522941B2 (ja) 2005-12-16 2006-12-18 有機金属ルテニウム錯体および関連する四置換および別の嵩高いオレフィンの製造方法

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Country Link
US (2) US8008224B2 (https=)
EP (1) EP1971616A1 (https=)
JP (1) JP5522941B2 (https=)
KR (2) KR20080103961A (https=)
CN (1) CN101460513B (https=)
SG (1) SG169326A1 (https=)
WO (1) WO2007075427A1 (https=)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8877936B2 (en) * 2008-04-09 2014-11-04 California Institute Of Technology Ruthenium olefin metathesis catalysts bearing N-heterocyclic carbene ligands with substituted backbone
FR2939331B1 (fr) 2008-12-10 2012-08-10 Inst Francais Du Petrole Composition catalytique et procede de metathese de corps gras insature
AP2011006003A0 (en) 2009-05-05 2011-12-31 Stepan Co Sulfonated internal olefin surfactant for enhancedoil recovery.
WO2011135029A1 (en) 2010-04-28 2011-11-03 Dsm Ip Assets B.V. Metathesis crosslinkable coating compositions
JP5674059B2 (ja) * 2011-01-24 2015-02-25 国立大学法人名古屋大学 ルテニウム錯体を含む水素移動反応用触媒及び水素移動反応物の製造方法
CN102145304B (zh) * 2011-02-24 2012-08-08 华东师范大学 一种负载型格拉布斯催化剂的制备及其应用
FR2983475B1 (fr) 2011-12-02 2014-01-17 IFP Energies Nouvelles Procede de metathese d'olefines lineaires alpha utilisant un complexe du ruthenium comportant un carbene n-heterocyclique dissymetrique
JP6092379B2 (ja) 2012-06-29 2017-03-08 アペイロン シンセシス エス アー 金属錯体、その適用、及びメタセシス反応の実施方法
PL225024B1 (pl) 2012-08-16 2017-02-28 Univ Warszawski Nowe kompleksy rutenu oraz ich zastosowanie
WO2017012379A1 (zh) * 2015-07-20 2017-01-26 中国科学院上海有机化学研究所 草酸酰胺类配体及其在铜催化芳基卤代物偶联反应中的用途
EP3376859B1 (en) 2015-11-18 2021-01-06 Provivi, Inc. Microorganisms for the production of insect pheromones and related compounds
WO2017087710A2 (en) 2015-11-18 2017-05-26 Provivi, Inc. Production of fatty olefin derivatives via olefin metathesis
KR20180116238A (ko) * 2015-12-10 2018-10-24 우미코레 아게 운트 코 카게 올레핀 복분해 촉매
WO2017214133A2 (en) 2016-06-06 2017-12-14 Provivi, Inc. Semi-biosynthetic production of fatty alcohols and fatty aldehydes
HUE073559T2 (hu) 2017-02-17 2026-01-28 Provivi Inc Feromonok és kapcsolódó anyagok szintézise olefin-metatézisen keresztül
MX382401B (es) 2017-05-17 2025-03-13 Provivi Inc Microorganismos para la producción de feromonas de insectos y compuestos relacionados.
US10683388B2 (en) * 2017-08-15 2020-06-16 University Of Florida Research Foundation, Incorporated High temperature metathesis chemistry
CN108299506A (zh) * 2018-01-29 2018-07-20 中国科学院成都有机化学有限公司 N-杂环卡宾钌络合物及其制备方法和用途
CN109225334B (zh) * 2018-07-20 2021-05-18 吉林化工学院 一种具有邻位空间位阻结构的钌烯烃复分解催化剂及其制备方法和应用
CN109364998B (zh) * 2018-10-15 2021-07-06 天津科技大学 一种用于烯烃复分解反应的催化剂及其制备和应用方法
CN111250168B (zh) * 2018-11-30 2021-06-01 中国科学院大连化学物理研究所 一种钌基催化剂及其制备方法、应用
CN110041262B (zh) 2019-01-02 2020-03-27 成都开美思商务信息咨询中心(有限合伙) 氮杂环卡宾配体及其钌催化剂、制备方法和应用
CN112547126B (zh) * 2020-12-21 2023-03-21 上海中化科技有限公司 钌卡宾化合物、其组合物、制备方法及应用
CN113000066B (zh) * 2021-01-09 2022-04-12 河南大学 一种z-选择性钌卡宾烯烃复分解催化剂及其制备方法和应用

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DE19815275B4 (de) 1998-04-06 2009-06-25 Evonik Degussa Gmbh Alkylidenkomplexe des Rutheniums mit N-heterozyklischen Carbenliganden und deren Verwendung als hochaktive, selektive Katalysatoren für die Olefin-Metathese
EP1180108B1 (en) 1999-05-24 2003-08-27 California Institute Of Technology Imidazolidine-based metal carbene metathesis catalysts
JP3943015B2 (ja) * 2000-08-10 2007-07-11 トラスティーズ オブ ボストン カレッジ リサイクル可能メタセシス触媒
WO2002020535A1 (en) * 2000-09-05 2002-03-14 California Institute Of Technology Highly active metathesis catalysts generated in situ from inexpensive and air stable precursors
US6759537B2 (en) * 2001-03-23 2004-07-06 California Institute Of Technology Hexacoordinated ruthenium or osmium metal carbene metathesis catalysts
CA2442368C (en) * 2001-03-30 2015-10-13 California Institute Of Technology Cross-metathesis reaction of functionalized and substituted olefins using group 8 transition metal carbene complexes as metathesis catalysts
US7683180B2 (en) * 2001-04-16 2010-03-23 California Institute Of Technology Group 8 transition metal carbene complexes as enantionselective olefin metathesis catalysts
US6818586B2 (en) * 2001-08-01 2004-11-16 Cymetech, Llp Hexacoordinated ruthenium or osmium metal carbene metathesis catalysts
EP2251360B1 (en) * 2001-08-29 2013-07-31 California Institute of Technology Ring-opening metathesis polymerization of bridged bicyclic and polycyclic olefins containing two or more heteroatoms

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Publication number Publication date
US20070282148A1 (en) 2007-12-06
US20120123133A1 (en) 2012-05-17
US8008224B2 (en) 2011-08-30
KR20140097571A (ko) 2014-08-06
CN101460513A (zh) 2009-06-17
CN101460513B (zh) 2014-08-27
JP2009519947A (ja) 2009-05-21
SG169326A1 (en) 2011-03-30
EP1971616A1 (en) 2008-09-24
WO2007075427A1 (en) 2007-07-05
US8361922B2 (en) 2013-01-29
KR20080103961A (ko) 2008-11-28

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