SE459497B - Foerfarande foer foerestring av harts med aatminstone en ekvivalent maengd pentaerytritol och produkt framstaelld genom foerfarandet - Google Patents
Foerfarande foer foerestring av harts med aatminstone en ekvivalent maengd pentaerytritol och produkt framstaelld genom foerfarandetInfo
- Publication number
- SE459497B SE459497B SE8502204A SE8502204A SE459497B SE 459497 B SE459497 B SE 459497B SE 8502204 A SE8502204 A SE 8502204A SE 8502204 A SE8502204 A SE 8502204A SE 459497 B SE459497 B SE 459497B
- Authority
- SE
- Sweden
- Prior art keywords
- resin
- pentaerythritol
- phosphinic acid
- reaction
- color
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 25
- 239000011347 resin Substances 0.000 claims description 79
- 229920005989 resin Polymers 0.000 claims description 79
- ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical compound O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 claims description 30
- 238000006243 chemical reaction Methods 0.000 claims description 28
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 27
- 238000005886 esterification reaction Methods 0.000 claims description 26
- 230000032050 esterification Effects 0.000 claims description 25
- 239000003784 tall oil Substances 0.000 claims description 25
- 239000002253 acid Substances 0.000 claims description 20
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 15
- 239000000047 product Substances 0.000 claims description 14
- 239000002023 wood Substances 0.000 claims description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 7
- 239000003377 acid catalyst Substances 0.000 claims description 6
- 239000011261 inert gas Substances 0.000 claims description 6
- 239000010665 pine oil Substances 0.000 claims description 5
- 239000005060 rubber Substances 0.000 claims description 5
- 229910001873 dinitrogen Inorganic materials 0.000 claims description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 1
- 239000007795 chemical reaction product Substances 0.000 claims 1
- 229910052698 phosphorus Inorganic materials 0.000 claims 1
- 239000011574 phosphorus Substances 0.000 claims 1
- 239000003054 catalyst Substances 0.000 description 17
- 150000002148 esters Chemical class 0.000 description 15
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- 230000035484 reaction time Effects 0.000 description 7
- 239000000463 material Substances 0.000 description 6
- 238000011282 treatment Methods 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 230000008901 benefit Effects 0.000 description 4
- -1 pentaerythritol ester Chemical class 0.000 description 4
- 150000007513 acids Chemical class 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 238000004821 distillation Methods 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 241000779819 Syncarpia glomulifera Species 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 238000007323 disproportionation reaction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000002314 glycerols Chemical class 0.000 description 2
- 230000000977 initiatory effect Effects 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000001739 pinus spp. Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 150000005846 sugar alcohols Polymers 0.000 description 2
- 229910021653 sulphate ion Inorganic materials 0.000 description 2
- 229940036248 turpentine Drugs 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229930040373 Paraformaldehyde Natural products 0.000 description 1
- 235000005205 Pinus Nutrition 0.000 description 1
- 241000218602 Pinus <genus> Species 0.000 description 1
- 241000669326 Selenaspidus articulatus Species 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 238000005273 aeration Methods 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 150000001733 carboxylic acid esters Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000006114 decarboxylation reaction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000004508 fractional distillation Methods 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- TVZISJTYELEYPI-UHFFFAOYSA-N hypodiphosphoric acid Chemical compound OP(O)(=O)P(O)(O)=O TVZISJTYELEYPI-UHFFFAOYSA-N 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 238000006011 modification reaction Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 229920002866 paraformaldehyde Polymers 0.000 description 1
- 150000008301 phosphite esters Chemical class 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09F—NATURAL RESINS; FRENCH POLISH; DRYING-OILS; OIL DRYING AGENTS, i.e. SICCATIVES; TURPENTINE
- C09F1/00—Obtaining purification, or chemical modification of natural resins, e.g. oleo-resins
- C09F1/04—Chemical modification, e.g. esterification
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US61013184A | 1984-05-14 | 1984-05-14 | |
US06/679,985 US4548746A (en) | 1984-05-14 | 1984-12-10 | Rosin pentaerythritol ester preparation improvement |
Publications (3)
Publication Number | Publication Date |
---|---|
SE8502204D0 SE8502204D0 (sv) | 1985-05-06 |
SE8502204L SE8502204L (sv) | 1985-11-15 |
SE459497B true SE459497B (sv) | 1989-07-10 |
Family
ID=27086198
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
SE8502204A SE459497B (sv) | 1984-05-14 | 1985-05-06 | Foerfarande foer foerestring av harts med aatminstone en ekvivalent maengd pentaerytritol och produkt framstaelld genom foerfarandet |
Country Status (8)
Country | Link |
---|---|
US (1) | US4548746A (fr) |
BE (1) | BE902415A (fr) |
DE (1) | DE3516776A1 (fr) |
FI (1) | FI79341C (fr) |
FR (1) | FR2564101B1 (fr) |
GB (1) | GB2158835B (fr) |
NL (1) | NL186643C (fr) |
SE (1) | SE459497B (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1991014748A1 (fr) * | 1990-03-21 | 1991-10-03 | Bergvik Kemi Ab | Procede de purification |
Families Citing this family (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4650607A (en) * | 1985-05-09 | 1987-03-17 | Westvaco Corporation | Method for rosin esterification |
US4643848A (en) * | 1986-02-21 | 1987-02-17 | Westvaco Corporation | Modified rosin ester preparation |
US4657706A (en) * | 1986-06-10 | 1987-04-14 | Hercules Incorporated | Method of improving the color of tall oil rosin esters |
US4657703A (en) * | 1986-06-30 | 1987-04-14 | Hercules Incorporated | Method of improving the color of tall oil rosin esters |
US4690783A (en) * | 1986-08-29 | 1987-09-01 | Union Camp Corporation | Method of preparing rosin ester from polyol with phosphorous acid catalyst |
US4693847A (en) * | 1986-11-14 | 1987-09-15 | Union Camp Corporation | Method of preparing hot-melt stable rosin ester with organic ester of hypophosphorous acid catalyst |
US4788009A (en) * | 1986-11-14 | 1988-11-29 | Union Camp Corporation | Method of preparing rosin esters of improved thermal stability with inorganic salt of phosphorous or hypophosphorous acid |
US4758379A (en) * | 1986-11-14 | 1988-07-19 | Union Camp Corporation | Process of preparing polyol esters of rosin with excess rosin |
US4725384A (en) * | 1986-11-17 | 1988-02-16 | Westvaco Corporation | Method for rosin esterification in the presence of phosphinic acid and phenol sulfide and subsequent neutralization with a magnesium salt |
US5177133A (en) * | 1990-10-10 | 1993-01-05 | Georgia-Pacific Resins, Inc. | Hot melt adhesive composition |
US5504152A (en) * | 1995-01-10 | 1996-04-02 | Arizona Chemical Company | Esterification of rosin |
US5830992A (en) * | 1996-12-12 | 1998-11-03 | Union Camp Corporation | Light color, color stable rosin esters and methods for preparing same |
FI112247B (fi) * | 1997-04-18 | 2003-11-14 | Arizona Chemical Oy | Alhaisen hajutason omaavan mäntyöljyhartsiesterin valmistaminen |
CN1056400C (zh) * | 1997-07-11 | 2000-09-13 | 北京工商大学 | 一种松香酸聚乙二醇酯的制备方法 |
DE10321107A1 (de) * | 2003-05-09 | 2004-11-25 | Cognis Deutschland Gmbh & Co. Kg | Verfahren zur Herstellung eines Benzoesäureesters |
US7651559B2 (en) | 2005-11-04 | 2010-01-26 | Franklin Industrial Minerals | Mineral composition |
US20110213120A1 (en) * | 2010-03-01 | 2011-09-01 | Arizona Chemical Company | Rosin esters for non-woven applications, methods of making and using and products therefrom |
US20160237313A1 (en) | 2013-09-27 | 2016-08-18 | Arizona Chemical Company, Llc | Methods of Making Rosin Esters |
US9940852B2 (en) | 2013-09-27 | 2018-04-10 | Kranton Chemical, LLC | Rosin esters and compositions thereof |
WO2015048402A1 (fr) | 2013-09-27 | 2015-04-02 | Arizona Chemical Company, Llc | Compositions contenant des polymères d'éthylène |
JP6789812B2 (ja) | 2013-09-27 | 2020-11-25 | アリゾナ・ケミカル・カンパニー・エルエルシー | ロジンエステル及びその組成物 |
CN104774560A (zh) * | 2014-01-09 | 2015-07-15 | 江西麻山化工有限公司 | 一种松香甘油酯的制备方法 |
CN104087178A (zh) * | 2014-07-29 | 2014-10-08 | 广西众昌树脂有限公司 | 丙烯酸改性松香甘油酯的制备方法 |
JP6821647B2 (ja) | 2015-03-26 | 2021-01-27 | アリゾナ ケミカル カンパニー エルエルシーArizona Chemical Company, Llc | ロジンエステルおよびエチレンポリマーを含有する組成物 |
US10435586B2 (en) | 2015-12-31 | 2019-10-08 | Kraton Chemical, Llc | Oligoesters and compositions thereof |
US9920192B2 (en) * | 2016-05-19 | 2018-03-20 | Eastman Chemical Company | Polymeric compositions with improved noise suppression |
EP3504267B8 (fr) | 2016-09-23 | 2024-10-16 | Kraton Chemical, LLC | Compositions d'oligoesters et procédés de fabrication et d'utilisation associés |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2369125A (en) * | 1941-06-28 | 1945-02-13 | Hercules Powder Co Ltd | Rosin esters and method of producing |
US2509910A (en) * | 1943-04-16 | 1950-05-30 | Us Navy | Time-delay circuit |
US2441197A (en) * | 1945-06-09 | 1948-05-11 | Anna Kalman | Treatment of tall oil |
US2572086A (en) * | 1947-05-08 | 1951-10-23 | Gen Mills Inc | Rosin acid esters |
US2590910A (en) * | 1947-05-08 | 1952-04-01 | Gen Mills Inc | Rosin acid esters |
US2729660A (en) * | 1953-01-21 | 1956-01-03 | Gen Mills Inc | Phosphite esters as esterification catalysts |
US3232968A (en) * | 1959-12-01 | 1966-02-01 | Gen Aniline & Film Corp | Process for preparing n-acyl taurates using hypophosphorous acid as catalyst |
US3071604A (en) * | 1960-06-30 | 1963-01-01 | Nopco Chem Co | Preparation of light colored fatty acid esters |
GB979673A (en) * | 1961-11-28 | 1965-01-06 | Ici Ltd | Preparation of ester of polyoxyalkylene compounds |
US3780012A (en) * | 1972-12-18 | 1973-12-18 | Arizona Chem | Production of tall oil rosin pentaerythritol esters having improved color |
US3780013A (en) * | 1972-12-18 | 1973-12-18 | Arizona Chem | Preparation of color improved tall oil rosin pentaerythritol esters |
US4172070A (en) * | 1978-03-27 | 1979-10-23 | Arizona Chemical Company | Oxygen-stable rosin-primary polyhydric aliphatic alcohol esters and a method for preparing the same utilizing arylsulfonic acid catalysis |
-
1984
- 1984-12-10 US US06/679,985 patent/US4548746A/en not_active Expired - Lifetime
-
1985
- 1985-05-06 SE SE8502204A patent/SE459497B/sv not_active IP Right Cessation
- 1985-05-09 DE DE19853516776 patent/DE3516776A1/de active Granted
- 1985-05-09 NL NLAANVRAGE8501335,A patent/NL186643C/xx not_active IP Right Cessation
- 1985-05-13 BE BE0/215009A patent/BE902415A/fr not_active IP Right Cessation
- 1985-05-14 FI FI851913A patent/FI79341C/fi not_active IP Right Cessation
- 1985-05-14 FR FR8507311A patent/FR2564101B1/fr not_active Expired
- 1985-05-14 GB GB08512178A patent/GB2158835B/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1991014748A1 (fr) * | 1990-03-21 | 1991-10-03 | Bergvik Kemi Ab | Procede de purification |
Also Published As
Publication number | Publication date |
---|---|
FR2564101A1 (fr) | 1985-11-15 |
FI79341C (fi) | 1989-12-11 |
GB2158835B (en) | 1987-05-13 |
DE3516776A1 (de) | 1985-11-14 |
SE8502204L (sv) | 1985-11-15 |
SE8502204D0 (sv) | 1985-05-06 |
FI851913A0 (fi) | 1985-05-14 |
NL186643C (nl) | 1991-01-16 |
FI79341B (fi) | 1989-08-31 |
US4548746A (en) | 1985-10-22 |
FR2564101B1 (fr) | 1987-08-07 |
DE3516776C2 (fr) | 1988-06-16 |
GB8512178D0 (en) | 1985-06-19 |
GB2158835A (en) | 1985-11-20 |
FI851913L (fi) | 1985-11-15 |
NL186643B (nl) | 1990-08-16 |
BE902415A (fr) | 1985-09-02 |
NL8501335A (nl) | 1985-12-02 |
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