SE451634B - Vetejonsensor med membranholje av syrejonledande keramik och anvendning av vetejonsensor for bestemning av koncentrationen av vetejoner i ett vetskeformigt medium - Google Patents
Vetejonsensor med membranholje av syrejonledande keramik och anvendning av vetejonsensor for bestemning av koncentrationen av vetejoner i ett vetskeformigt mediumInfo
- Publication number
- SE451634B SE451634B SE8007134A SE8007134A SE451634B SE 451634 B SE451634 B SE 451634B SE 8007134 A SE8007134 A SE 8007134A SE 8007134 A SE8007134 A SE 8007134A SE 451634 B SE451634 B SE 451634B
- Authority
- SE
- Sweden
- Prior art keywords
- oxide
- hydrogen ion
- ion sensor
- electrode
- oxygen
- Prior art date
Links
- 239000012528 membrane Substances 0.000 title claims description 33
- 239000000919 ceramic Substances 0.000 title claims description 29
- 239000007788 liquid Substances 0.000 title claims description 5
- 239000001301 oxygen Substances 0.000 title description 50
- 229910052760 oxygen Inorganic materials 0.000 title description 50
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title description 27
- 241000209140 Triticum Species 0.000 title 2
- 235000021307 Triticum Nutrition 0.000 title 2
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 claims description 45
- -1 silver-silver halide Chemical class 0.000 claims description 45
- 229910010293 ceramic material Inorganic materials 0.000 claims description 23
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 22
- 239000000203 mixture Substances 0.000 claims description 16
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 10
- 239000001257 hydrogen Substances 0.000 claims description 10
- 229910052739 hydrogen Inorganic materials 0.000 claims description 10
- 229910052751 metal Inorganic materials 0.000 claims description 10
- 239000002184 metal Substances 0.000 claims description 10
- 229910002076 stabilized zirconia Inorganic materials 0.000 claims description 10
- 150000004820 halides Chemical class 0.000 claims description 8
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 7
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 claims description 7
- 229910052709 silver Inorganic materials 0.000 claims description 7
- 239000004332 silver Substances 0.000 claims description 7
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 claims description 6
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 5
- 239000000292 calcium oxide Substances 0.000 claims description 5
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 5
- 229910052802 copper Inorganic materials 0.000 claims description 5
- 239000010949 copper Substances 0.000 claims description 5
- 239000003381 stabilizer Substances 0.000 claims description 5
- ZCUFMDLYAMJYST-UHFFFAOYSA-N thorium dioxide Chemical compound O=[Th]=O ZCUFMDLYAMJYST-UHFFFAOYSA-N 0.000 claims description 5
- 229910003452 thorium oxide Inorganic materials 0.000 claims description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 4
- BERDEBHAJNAUOM-UHFFFAOYSA-N copper(i) oxide Chemical compound [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 claims description 4
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims description 4
- 229910052753 mercury Inorganic materials 0.000 claims description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
- 239000007789 gas Substances 0.000 claims description 3
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 claims description 3
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 2
- 229910000420 cerium oxide Inorganic materials 0.000 claims description 2
- 238000011049 filling Methods 0.000 claims description 2
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000006193 liquid solution Substances 0.000 claims description 2
- 239000000395 magnesium oxide Substances 0.000 claims description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims description 2
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 claims description 2
- HYXGAEYDKFCVMU-UHFFFAOYSA-N scandium oxide Chemical compound O=[Sc]O[Sc]=O HYXGAEYDKFCVMU-UHFFFAOYSA-N 0.000 claims description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 1
- 239000000460 chlorine Substances 0.000 claims 1
- 229910052801 chlorine Inorganic materials 0.000 claims 1
- 150000002431 hydrogen Chemical class 0.000 claims 1
- 229910052742 iron Inorganic materials 0.000 claims 1
- 239000000243 solution Substances 0.000 description 48
- 230000004044 response Effects 0.000 description 27
- 239000011521 glass Substances 0.000 description 19
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- 238000005259 measurement Methods 0.000 description 11
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 11
- 238000012360 testing method Methods 0.000 description 9
- 239000003792 electrolyte Substances 0.000 description 8
- 238000002474 experimental method Methods 0.000 description 8
- 229910044991 metal oxide Inorganic materials 0.000 description 8
- 238000007254 oxidation reaction Methods 0.000 description 8
- 239000012071 phase Substances 0.000 description 8
- 239000007787 solid Substances 0.000 description 8
- 230000000694 effects Effects 0.000 description 5
- 150000002500 ions Chemical class 0.000 description 5
- 150000004706 metal oxides Chemical class 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 239000008346 aqueous phase Substances 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000012546 transfer Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000004809 Teflon Substances 0.000 description 3
- 229920006362 Teflon® Polymers 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000013461 design Methods 0.000 description 3
- 238000010494 dissociation reaction Methods 0.000 description 3
- 230000005593 dissociations Effects 0.000 description 3
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 description 3
- 238000001139 pH measurement Methods 0.000 description 3
- 229910052697 platinum Inorganic materials 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 238000004544 sputter deposition Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 238000013494 PH determination Methods 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 238000007743 anodising Methods 0.000 description 2
- 239000000872 buffer Substances 0.000 description 2
- 239000002775 capsule Substances 0.000 description 2
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 2
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 229940037395 electrolytes Drugs 0.000 description 2
- 229910001938 gadolinium oxide Inorganic materials 0.000 description 2
- 229940075613 gadolinium oxide Drugs 0.000 description 2
- CMIHHWBVHJVIGI-UHFFFAOYSA-N gadolinium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[Gd+3].[Gd+3] CMIHHWBVHJVIGI-UHFFFAOYSA-N 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 239000012212 insulator Substances 0.000 description 2
- 238000000462 isostatic pressing Methods 0.000 description 2
- 229910000474 mercury oxide Inorganic materials 0.000 description 2
- UKWHYYKOEPRTIC-UHFFFAOYSA-N mercury(ii) oxide Chemical compound [Hg]=O UKWHYYKOEPRTIC-UHFFFAOYSA-N 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 239000012488 sample solution Substances 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 239000007784 solid electrolyte Substances 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- IATRAKWUXMZMIY-UHFFFAOYSA-N strontium oxide Chemical compound [O-2].[Sr+2] IATRAKWUXMZMIY-UHFFFAOYSA-N 0.000 description 2
- 150000003568 thioethers Chemical class 0.000 description 2
- RUDFQVOCFDJEEF-UHFFFAOYSA-N yttrium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Y+3].[Y+3] RUDFQVOCFDJEEF-UHFFFAOYSA-N 0.000 description 2
- 241001009766 Argyrodendron trifoliolatum Species 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 1
- 239000005751 Copper oxide Substances 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 238000009529 body temperature measurement Methods 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 239000007975 buffered saline Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- GTKRFUAGOKINCA-UHFFFAOYSA-M chlorosilver;silver Chemical compound [Ag].[Ag]Cl GTKRFUAGOKINCA-UHFFFAOYSA-M 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910000431 copper oxide Inorganic materials 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 239000002019 doping agent Substances 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052595 hematite Inorganic materials 0.000 description 1
- 239000011019 hematite Substances 0.000 description 1
- 230000005525 hole transport Effects 0.000 description 1
- 150000004678 hydrides Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000010416 ion conductor Substances 0.000 description 1
- LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 210000004779 membrane envelope Anatomy 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 210000000056 organ Anatomy 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000008363 phosphate buffer Substances 0.000 description 1
- 238000007750 plasma spraying Methods 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000012255 powdered metal Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 229910001404 rare earth metal oxide Inorganic materials 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- 238000007582 slurry-cast process Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/28—Electrolytic cell components
- G01N27/30—Electrodes, e.g. test electrodes; Half-cells
- G01N27/333—Ion-selective electrodes or membranes
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Molecular Biology (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Measuring Oxygen Concentration In Cells (AREA)
- Investigating Or Analyzing Materials By The Use Of Fluid Adsorption Or Reactions (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/084,510 US4264424A (en) | 1979-10-12 | 1979-10-12 | Hydrogen ion sensor having a membrane sheath of an oxygen ion conducting ceramic |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| SE8007134L SE8007134L (sv) | 1981-04-13 |
| SE451634B true SE451634B (sv) | 1987-10-19 |
Family
ID=22185397
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SE8007134A SE451634B (sv) | 1979-10-12 | 1980-10-10 | Vetejonsensor med membranholje av syrejonledande keramik och anvendning av vetejonsensor for bestemning av koncentrationen av vetejoner i ett vetskeformigt medium |
Country Status (8)
Families Citing this family (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4328082A (en) * | 1980-06-26 | 1982-05-04 | Beckman Instruments, Inc. | Solid state ion-sensitive electrode and method of making said electrode |
| JPS5857747U (ja) * | 1981-10-06 | 1983-04-19 | 三菱重工業株式会社 | Ｐｈ電極 |
| US4575410A (en) * | 1982-03-11 | 1986-03-11 | Beckman Industrial Corporation | Solid state electrode system for measuring pH |
| EP0124565A1 (en) * | 1982-10-29 | 1984-11-14 | Den Kongelige Porcelainsfabrik A/S | Ceramic material |
| US4500413A (en) * | 1982-12-20 | 1985-02-19 | General Electric Company | Sintered ceramic article with porous region |
| US4576667A (en) * | 1982-12-20 | 1986-03-18 | General Electric Company | Process for preparing a sintered ceramic article with porous region |
| JPS59154351A (ja) * | 1983-02-23 | 1984-09-03 | Ngk Insulators Ltd | 水素イオン濃度測定装置 |
| JPS6021963U (ja) * | 1983-07-21 | 1985-02-15 | 日本特殊陶業株式会社 | ガスセンサ |
| JPH076941B2 (ja) * | 1989-01-10 | 1995-01-30 | 日本ピラー工業株式会社 | Ｐｈセンサー |
| US5043053A (en) * | 1989-05-01 | 1991-08-27 | General Electric Company | Reference electrode probe for use in aqueous environments of high temperature and high radiation |
| JPH0588771U (ja) * | 1991-07-25 | 1993-12-03 | 日本電気ホームエレクトロニクス株式会社 | 電気半田こて |
| US5441610A (en) * | 1992-02-28 | 1995-08-15 | Renlund; Gary M. | Oxygen supply and removal method and apparatus |
| US5302258A (en) * | 1992-02-28 | 1994-04-12 | Triox Technologies, Inc. | Method and apparatus for separating oxygen from a gaseous mixture |
| FR2688680A1 (fr) * | 1992-03-19 | 1993-09-24 | Centre Nat Rech Scient | Electrode de prise de potentiel sur la peau. |
| US5238553A (en) * | 1992-05-11 | 1993-08-24 | Electric Power Research Institute | Reference electrode assembly and process for constructing |
| AU2155200A (en) * | 1998-11-25 | 2000-06-13 | Penn State Research Foundation, The | Yttria-stabilized zirconia membrane electrode |
| US6773678B2 (en) | 2000-03-20 | 2004-08-10 | Endress + Hauser Conducta Gesellschaft Fur Mess Und Regeltechnik Mbh + Co. | Mounting system and retractable sensor holder for analytical sensors |
| US6551478B1 (en) | 2001-04-09 | 2003-04-22 | The United States Of America As Represented By The Department Of Energy | Flexible high-temperature pH probe |
| DE10233901B4 (de) * | 2002-07-25 | 2005-06-23 | Testo Gmbh & Co | Messvorrichtung mit Einstechelektrode |
| FR2924362B1 (fr) * | 2007-11-30 | 2012-07-13 | Centre Nat Rech Scient | Reacteur chimique avec superstructure nanometrique |
| US8833146B2 (en) * | 2010-04-26 | 2014-09-16 | Southwest Research Institute | Corrosion sensor |
| US9134266B2 (en) * | 2011-12-15 | 2015-09-15 | Mettler-Toledo Ag | Reference electrode |
| JP6004477B2 (ja) * | 2012-06-14 | 2016-10-12 | 一般財団法人電力中央研究所 | 一体型参照電極の製造方法 |
| US20160362805A1 (en) * | 2013-11-01 | 2016-12-15 | Adam Clayton Powell, IV | Methods and apparatuses for increasing energy efficiency and improving membrane robustness in primary metal production |
| DE102015101191A1 (de) * | 2015-01-28 | 2016-07-28 | Endress + Hauser Conducta Gesellschaft für Mess- und Regeltechnik mbH + Co. KG | Potentiometrischer Sensor |
| US9863243B1 (en) | 2015-04-28 | 2018-01-09 | National Technology & Engineering Solutions Of Sandia, Llc | Ruggedized downhole tool for real-time measurements and uses thereof |
| JP2018522253A (ja) * | 2015-05-18 | 2018-08-09 | ネクセリス，エルエルシー | 核反応炉用ガス監視システムおよびガス監視方法 |
| CN113311046B (zh) * | 2021-05-14 | 2023-05-23 | 武汉大学 | 一种测量熔盐氧负离子浓度的电化学装置及电化学方法 |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3402078A (en) * | 1968-09-17 | Gen Electric | Solid stabilized zirconia or thoria having a layer of tantalum pentoxide and titanium oxide thereon | |
| US3404040A (en) * | 1965-06-29 | 1968-10-01 | Gen Electric | Article comprising stabilized zirconia and a current collector embedded therein |
| US3436269A (en) * | 1965-06-10 | 1969-04-01 | Gen Electric | Electrical device comprising metal oxide-containing solid electrolyte and electrode |
| US3429962A (en) * | 1965-12-01 | 1969-02-25 | Gen Electric | Method of forming a metallic oxide article |
| US3481855A (en) * | 1966-07-15 | 1969-12-02 | United Nuclear Corp | Continuous oxygen monitor for liquid metals |
| US3481780A (en) * | 1966-12-01 | 1969-12-02 | Gen Electric | Process for the densification of zirconia |
| US3816269A (en) * | 1970-04-14 | 1974-06-11 | Kennecott Copper Corp | Method for determining the concentration of a metal in an alloy melt |
| US3791954A (en) * | 1970-08-06 | 1974-02-12 | Ngk Insulators Ltd | Device for measuring oxygen concentration of molten metal |
| US3709810A (en) * | 1970-09-30 | 1973-01-09 | Gen Electric | Hydrogen ion selective sensor and electrode therefor |
| US3671414A (en) * | 1971-03-10 | 1972-06-20 | Gen Electric | Hydrogen ion-selective sensor |
| US3673069A (en) * | 1971-05-03 | 1972-06-27 | Gen Electric | Carbon dioxide sensor |
| US3740326A (en) * | 1971-06-18 | 1973-06-19 | Gen Electric | Chloride selective electrode |
| US3871981A (en) * | 1971-09-01 | 1975-03-18 | Bailey Meter Co | In-situ oxygen detector |
| US3883408A (en) * | 1972-05-03 | 1975-05-13 | Inland Steel Co | Furnace atmosphere oxygen analysis apparatus |
| US3776831A (en) * | 1972-11-15 | 1973-12-04 | Atomic Energy Commission | Device for measuring oxygen activity in liquid sodium |
| US3911901A (en) * | 1974-07-24 | 1975-10-14 | Gen Electric | In vivo hydrogen ion sensor |
| JPS5327092A (en) * | 1976-08-25 | 1978-03-13 | Toyota Motor Co Ltd | Oxygen concentration detector for exhaust gas* preparating and measuring method thereof |
| JPS5346475A (en) * | 1976-10-09 | 1978-04-26 | Sumitomo Spec Metals | Apparatus for deodorizing nasty gases from shellmold facilities |
| JPS5354086A (en) * | 1976-10-26 | 1978-05-17 | Toyota Motor Co Ltd | Oxygen sensor |
| US4179491A (en) * | 1976-11-15 | 1979-12-18 | National Research Development Corporation | Electrical device with separator as conductor for hydrogen cations |
| JPS53107394A (en) * | 1977-03-01 | 1978-09-19 | Toyota Motor Co Ltd | Confining method for oxygen sensor solid cell |
| DE2714558A1 (de) * | 1977-04-01 | 1978-10-12 | Bosch Gmbh Robert | Sinteraktive, hochfeste zirkonoxidkeramik |
-
1979
- 1979-10-12 US US06/084,510 patent/US4264424A/en not_active Expired - Lifetime
-
1980
- 1980-09-25 CA CA000361431A patent/CA1155495A/en not_active Expired
- 1980-10-09 IT IT25235/80A patent/IT1133847B/it active
- 1980-10-09 DE DE3038104A patent/DE3038104C2/de not_active Expired
- 1980-10-10 ES ES495855A patent/ES495855A0/es active Granted
- 1980-10-10 SE SE8007134A patent/SE451634B/sv not_active IP Right Cessation
- 1980-10-10 MX MX184305A patent/MX148956A/es unknown
- 1980-10-13 JP JP14213480A patent/JPS5677751A/ja active Granted
-
1981
- 1981-08-12 ES ES504720A patent/ES8205315A1/es not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| SE8007134L (sv) | 1981-04-13 |
| US4264424A (en) | 1981-04-28 |
| ES504720A0 (es) | 1982-06-01 |
| CA1155495A (en) | 1983-10-18 |
| IT1133847B (it) | 1986-07-24 |
| JPS5677751A (en) | 1981-06-26 |
| MX148956A (es) | 1983-07-27 |
| ES8205315A1 (es) | 1982-06-01 |
| DE3038104C2 (de) | 1984-01-19 |
| IT8025235A0 (it) | 1980-10-09 |
| DE3038104A1 (de) | 1981-04-23 |
| ES8200769A1 (es) | 1981-11-16 |
| ES495855A0 (es) | 1981-11-16 |
| JPS6122260B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1986-05-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| SE451634B (sv) | Vetejonsensor med membranholje av syrejonledande keramik och anvendning av vetejonsensor for bestemning av koncentrationen av vetejoner i ett vetskeformigt medium | |
| Ghali | Corrosion resistance of aluminum and magnesium alloys: understanding, performance, and testing | |
| Sato | Electrochemical measurements and control of oxygen fugacity and other gaseous fugacities with solid electrolyte sensors | |
| TWI649549B (zh) | 在高溫之熔融鹽中腐蝕之電化學偵測及金屬之腐蝕速率 | |
| Zou et al. | Ionic liquid reference electrodes with a well‐controlled Co (II)/Co (III) redox buffer as solid contact | |
| JPH0262954A (ja) | 電流滴定の方法 | |
| Spitzer et al. | Reference electrodes for aqueous solutions | |
| JP3398221B2 (ja) | イオン性溶融物における酸素分圧の電気化学的な測定用の照合電極 | |
| Atkinson et al. | An investigation of the performance characteristics and operational lifetimes of multi-element thick film sensor arrays used in the determination of water quality parameters | |
| Chen et al. | Solid-state ion-selective pH sensor | |
| US4818366A (en) | Long life reference electrode | |
| US7632384B1 (en) | Multi-functional sensor system for molten salt technologies | |
| Swaddle et al. | Electrode reactions of metal complexes in solution at high pressures | |
| JPS62502064A (ja) | 電気化学的センサ−、その電気化学的センサ−を製造及び使用する方法 | |
| SE460623B (sv) | Jonselektiv potentiometrisk maetanordning | |
| Danielson et al. | Recent Developments with High Temperature Stabilized‐Zirconia pH Sensors | |
| Souto et al. | Progress in scanning electrochemical microscopy by coupling potentiometric and amperometric measurement modes | |
| US3825482A (en) | Ion-selective electrodes using tungsten bronzes as active element | |
| Ponomareva et al. | Hydrogen sensor based on antimonium pentoxide-phosphoric acid solid electrolyte | |
| KR840001154Y1 (ko) | 산소이온 통과세라믹 막 외장 함유 수소이온 센서 | |
| Yosypchuk et al. | Reference electrodes based on solid amalgams | |
| Tan et al. | Sensing behavior of an amperometric hydrogen sensor: theoretical modeling and experimental verification | |
| Kahlert | Potentiometry | |
| Light et al. | Evaluation of the zirconia pH sensor at 95° C | |
| US20240295520A1 (en) | Palladium-hydrogen ph electrode |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| NAL | Patent in force |
Ref document number: 8007134-3 Format of ref document f/p: F |
|
| NUG | Patent has lapsed |
Ref document number: 8007134-3 Format of ref document f/p: F |