SE413196B - Forfarande for elektrokemisk upparbetning av anvenda svavelsyrahaltiga betlosningar for betning av jern - Google Patents
Forfarande for elektrokemisk upparbetning av anvenda svavelsyrahaltiga betlosningar for betning av jernInfo
- Publication number
- SE413196B SE413196B SE7414719A SE7414719A SE413196B SE 413196 B SE413196 B SE 413196B SE 7414719 A SE7414719 A SE 7414719A SE 7414719 A SE7414719 A SE 7414719A SE 413196 B SE413196 B SE 413196B
- Authority
- SE
- Sweden
- Prior art keywords
- solution
- iron
- pickling
- cathode
- acid
- Prior art date
Links
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title claims description 126
- 229910052742 iron Inorganic materials 0.000 title claims description 57
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 title claims description 45
- 238000000034 method Methods 0.000 title claims description 34
- 238000002360 preparation method Methods 0.000 title description 2
- 238000005554 pickling Methods 0.000 claims description 58
- 239000002253 acid Substances 0.000 claims description 38
- 150000003839 salts Chemical class 0.000 claims description 18
- 230000008569 process Effects 0.000 claims description 15
- 238000005868 electrolysis reaction Methods 0.000 claims description 13
- 235000003891 ferrous sulphate Nutrition 0.000 claims description 13
- 239000011790 ferrous sulphate Substances 0.000 claims description 13
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 10
- 229910021653 sulphate ion Inorganic materials 0.000 claims description 10
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 9
- 238000000354 decomposition reaction Methods 0.000 claims description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 8
- -1 iron ions Chemical class 0.000 claims description 7
- 229910052936 alkali metal sulfate Inorganic materials 0.000 claims description 6
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims description 6
- 239000011777 magnesium Substances 0.000 claims description 5
- 230000001413 cellular effect Effects 0.000 claims description 2
- 239000003792 electrolyte Substances 0.000 claims description 2
- 238000009413 insulation Methods 0.000 claims description 2
- 239000000243 solution Substances 0.000 description 70
- 210000004027 cell Anatomy 0.000 description 37
- 238000000926 separation method Methods 0.000 description 11
- 239000000654 additive Substances 0.000 description 10
- 238000006243 chemical reaction Methods 0.000 description 9
- PMZURENOXWZQFD-UHFFFAOYSA-L sodium sulphate Substances [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 8
- 238000005342 ion exchange Methods 0.000 description 7
- 150000002500 ions Chemical class 0.000 description 7
- 230000008929 regeneration Effects 0.000 description 7
- 238000011069 regeneration method Methods 0.000 description 7
- 230000007246 mechanism Effects 0.000 description 6
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 6
- 229910052753 mercury Inorganic materials 0.000 description 6
- 230000032258 transport Effects 0.000 description 6
- 230000000996 additive effect Effects 0.000 description 5
- 229910052938 sodium sulfate Inorganic materials 0.000 description 5
- 235000011152 sodium sulphate Nutrition 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 4
- 235000011941 Tilia x europaea Nutrition 0.000 description 4
- 239000001166 ammonium sulphate Substances 0.000 description 4
- 235000011130 ammonium sulphate Nutrition 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
- 150000001768 cations Chemical class 0.000 description 4
- 150000004688 heptahydrates Chemical class 0.000 description 4
- 239000004571 lime Substances 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- 238000012958 reprocessing Methods 0.000 description 4
- 235000011149 sulphuric acid Nutrition 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 3
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 230000002349 favourable effect Effects 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 230000037427 ion transport Effects 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000012528 membrane Substances 0.000 description 3
- 238000006386 neutralization reaction Methods 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 229910000497 Amalgam Inorganic materials 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000003929 acidic solution Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000000498 cooling water Substances 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-M hydrogensulfate Chemical compound OS([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 description 2
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 2
- 229910052939 potassium sulfate Inorganic materials 0.000 description 2
- 239000001120 potassium sulphate Substances 0.000 description 2
- 235000011151 potassium sulphates Nutrition 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 238000010626 work up procedure Methods 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 206010057040 Temperature intolerance Diseases 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 210000002421 cell wall Anatomy 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000001427 coherent effect Effects 0.000 description 1
- 230000002301 combined effect Effects 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000000502 dialysis Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 238000003487 electrochemical reaction Methods 0.000 description 1
- 238000000909 electrodialysis Methods 0.000 description 1
- 239000012717 electrostatic precipitator Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000008543 heat sensitivity Effects 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 230000002101 lytic effect Effects 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 230000007257 malfunction Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 235000021110 pickles Nutrition 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 238000006748 scratching Methods 0.000 description 1
- 230000002393 scratching effect Effects 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/42—Electrodialysis; Electro-osmosis ; Electro-ultrafiltration; Membrane capacitive deionization
- B01D61/44—Ion-selective electrodialysis
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/36—Regeneration of waste pickling liquors
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
- C25C1/06—Electrolytic production, recovery or refining of metals by electrolysis of solutions or iron group metals, refractory metals or manganese
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Water Supply & Treatment (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Urology & Nephrology (AREA)
- Electrochemistry (AREA)
- Health & Medical Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Electrolytic Production Of Metals (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| HUKE000935 HU169344B (en) | 1973-11-27 | 1973-11-27 | Method for electrochemical cycle-processing pickle end-solutions containing sulfuric acid |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| SE7414719L SE7414719L (enrdf_load_stackoverflow) | 1975-05-28 |
| SE413196B true SE413196B (sv) | 1980-04-28 |
Family
ID=10997755
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SE7414719A SE413196B (sv) | 1973-11-27 | 1974-11-22 | Forfarande for elektrokemisk upparbetning av anvenda svavelsyrahaltiga betlosningar for betning av jern |
Country Status (13)
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3206538C2 (de) * | 1982-02-24 | 1984-04-12 | Keramchemie GmbH, 5433 Siershahn | Verfahren zur elektrolytischen Regenerierung von verbrauchter Schwefelsäure-Beizflüssigkeit |
| US4740281A (en) * | 1986-10-14 | 1988-04-26 | Allied Corporation | Recovery of acids from materials comprising acid and salt |
| DE19850525A1 (de) * | 1998-11-03 | 2000-05-04 | Eilenburger Elektrolyse & Umwelttechnik Gmbh | Verfahren zum elektrochemischen Regenerieren von Schwefelsäure-Eisen-III-sulfat-Beizlösungen für Edelstähle |
| DE19850524C2 (de) * | 1998-11-03 | 2002-04-04 | Eilenburger Elektrolyse & Umwelttechnik Gmbh | Nitratfreies Recycling-Beizverfahren für Edelstähle |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE481309A (enrdf_load_stackoverflow) * | 1947-03-25 |
-
1973
- 1973-11-27 HU HUKE000935 patent/HU169344B/hu unknown
-
1974
- 1974-11-18 LU LU71306A patent/LU71306A1/xx unknown
- 1974-11-22 SE SE7414719A patent/SE413196B/sv not_active IP Right Cessation
- 1974-11-25 DK DK612074A patent/DK145682C/da active
- 1974-11-25 YU YU314174A patent/YU39931B/xx unknown
- 1974-11-25 FR FR7438583A patent/FR2252422B1/fr not_active Expired
- 1974-11-26 NO NO744247A patent/NO136303C/no unknown
- 1974-11-26 IT IT7044474A patent/IT1024914B/it active
- 1974-11-26 NL NL7415391A patent/NL177424C/xx not_active IP Right Cessation
- 1974-11-26 CH CH1568674A patent/CH610014A5/xx not_active IP Right Cessation
- 1974-11-27 DE DE2456058A patent/DE2456058C2/de not_active Expired
- 1974-11-27 AT AT950174A patent/AT332192B/de not_active IP Right Cessation
- 1974-11-27 DE DE7439469U patent/DE7439469U/de not_active Expired
- 1974-11-27 BE BE150890A patent/BE822639A/xx not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| NL177424C (nl) | 1985-09-16 |
| ATA950174A (de) | 1975-12-15 |
| HU169344B (en) | 1976-11-27 |
| LU71306A1 (enrdf_load_stackoverflow) | 1975-05-28 |
| IT1024914B (it) | 1978-07-20 |
| DK145682B (da) | 1983-01-24 |
| CH610014A5 (en) | 1979-03-30 |
| NO136303C (no) | 1977-08-17 |
| NO136303B (enrdf_load_stackoverflow) | 1977-05-09 |
| NL7415391A (nl) | 1975-05-29 |
| DE2456058A1 (de) | 1975-05-28 |
| NO744247L (enrdf_load_stackoverflow) | 1975-06-23 |
| YU314174A (en) | 1982-10-31 |
| FR2252422A1 (enrdf_load_stackoverflow) | 1975-06-20 |
| DE7439469U (de) | 1976-04-29 |
| SE7414719L (enrdf_load_stackoverflow) | 1975-05-28 |
| DE2456058C2 (de) | 1984-09-27 |
| BE822639A (fr) | 1975-05-27 |
| FR2252422B1 (enrdf_load_stackoverflow) | 1980-08-01 |
| NL177424B (nl) | 1985-04-16 |
| AT332192B (de) | 1976-09-10 |
| YU39931B (en) | 1985-06-30 |
| DK145682C (da) | 1983-08-08 |
| DK612074A (enrdf_load_stackoverflow) | 1975-08-18 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| NUG | Patent has lapsed |
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