SA112330479B1 - عملية لزرع جسيمات معدنية بواسطة الطلاء بالكهرباء مع التثبيط في الموضع - Google Patents
عملية لزرع جسيمات معدنية بواسطة الطلاء بالكهرباء مع التثبيط في الموضع Download PDFInfo
- Publication number
- SA112330479B1 SA112330479B1 SA112330479A SA112330479A SA112330479B1 SA 112330479 B1 SA112330479 B1 SA 112330479B1 SA 112330479 A SA112330479 A SA 112330479A SA 112330479 A SA112330479 A SA 112330479A SA 112330479 B1 SA112330479 B1 SA 112330479B1
- Authority
- SA
- Saudi Arabia
- Prior art keywords
- electrode
- electrically conductive
- metal particles
- catalytic
- manufacturing
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 33
- 230000008569 process Effects 0.000 title claims abstract description 27
- 238000009713 electroplating Methods 0.000 title claims abstract description 26
- 239000002923 metal particle Substances 0.000 title claims abstract description 22
- 238000011065 in-situ storage Methods 0.000 title abstract description 5
- 230000005764 inhibitory process Effects 0.000 title abstract description 3
- 230000000903 blocking effect Effects 0.000 claims abstract description 25
- 229910052751 metal Inorganic materials 0.000 claims abstract description 24
- 239000002184 metal Substances 0.000 claims abstract description 24
- 239000013626 chemical specie Substances 0.000 claims abstract description 23
- 230000003647 oxidation Effects 0.000 claims abstract description 23
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 23
- 230000003197 catalytic effect Effects 0.000 claims abstract description 20
- 238000006722 reduction reaction Methods 0.000 claims abstract description 18
- 150000003839 salts Chemical class 0.000 claims abstract description 16
- 230000009467 reduction Effects 0.000 claims abstract description 14
- 238000004519 manufacturing process Methods 0.000 claims abstract description 12
- 238000003795 desorption Methods 0.000 claims abstract 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 76
- 229910052697 platinum Inorganic materials 0.000 claims description 35
- 238000000151 deposition Methods 0.000 claims description 18
- 230000008021 deposition Effects 0.000 claims description 17
- 238000001179 sorption measurement Methods 0.000 claims description 11
- 241000894007 species Species 0.000 claims description 11
- 239000000243 solution Substances 0.000 claims description 10
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 7
- 239000003112 inhibitor Substances 0.000 claims description 7
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 6
- 230000002401 inhibitory effect Effects 0.000 claims description 6
- 239000006229 carbon black Substances 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 4
- 239000013000 chemical inhibitor Substances 0.000 claims description 3
- 239000000470 constituent Substances 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 239000001294 propane Substances 0.000 claims description 3
- 239000003929 acidic solution Substances 0.000 claims description 2
- 238000005516 engineering process Methods 0.000 claims description 2
- 230000004224 protection Effects 0.000 claims 9
- VWEWCZSUWOEEFM-WDSKDSINSA-N Ala-Gly-Ala-Gly Chemical compound C[C@H](N)C(=O)NCC(=O)N[C@@H](C)C(=O)NCC(O)=O VWEWCZSUWOEEFM-WDSKDSINSA-N 0.000 claims 1
- 241000196324 Embryophyta Species 0.000 claims 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- 240000000233 Melia azedarach Species 0.000 claims 1
- 238000004140 cleaning Methods 0.000 claims 1
- 239000004922 lacquer Substances 0.000 claims 1
- 238000010521 absorption reaction Methods 0.000 abstract description 10
- 239000002245 particle Substances 0.000 description 23
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 19
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 10
- 238000009792 diffusion process Methods 0.000 description 10
- 239000000446 fuel Substances 0.000 description 9
- 239000007789 gas Substances 0.000 description 8
- 230000000694 effects Effects 0.000 description 6
- 238000001075 voltammogram Methods 0.000 description 6
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 5
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 5
- 238000004062 sedimentation Methods 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 230000002209 hydrophobic effect Effects 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- -1 oxygen hydrogen Chemical class 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000000356 contaminant Substances 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- 238000004832 voltammetry Methods 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- QKSKPIVNLNLAAV-UHFFFAOYSA-N bis(2-chloroethyl) sulfide Chemical compound ClCCSCCCl QKSKPIVNLNLAAV-UHFFFAOYSA-N 0.000 description 2
- 239000002981 blocking agent Substances 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 239000013528 metallic particle Substances 0.000 description 2
- 238000012544 monitoring process Methods 0.000 description 2
- 238000010951 particle size reduction Methods 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 230000004044 response Effects 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- QNRATNLHPGXHMA-XZHTYLCXSA-N (r)-(6-ethoxyquinolin-4-yl)-[(2s,4s,5r)-5-ethyl-1-azabicyclo[2.2.2]octan-2-yl]methanol;hydrochloride Chemical compound Cl.C([C@H]([C@H](C1)CC)C2)CN1[C@@H]2[C@H](O)C1=CC=NC2=CC=C(OCC)C=C21 QNRATNLHPGXHMA-XZHTYLCXSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229920000557 Nafion® Polymers 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000005137 deposition process Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000003487 electrochemical reaction Methods 0.000 description 1
- 238000004070 electrodeposition Methods 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 230000035784 germination Effects 0.000 description 1
- 239000003966 growth inhibitor Substances 0.000 description 1
- 230000005661 hydrophobic surface Effects 0.000 description 1
- 238000011534 incubation Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000012229 microporous material Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8825—Methods for deposition of the catalytic active composition
- H01M4/8853—Electrodeposition
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/50—Electroplating: Baths therefor from solutions of platinum group metals
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/50—Electroplating: Baths therefor from solutions of platinum group metals
- C25D3/52—Electroplating: Baths therefor from solutions of platinum group metals characterised by the organic bath constituents used
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8803—Supports for the deposition of the catalytic active composition
- H01M4/8807—Gas diffusion layers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/92—Metals of platinum group
- H01M4/921—Alloys or mixtures with metallic elements
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M2008/1095—Fuel cells with polymeric electrolytes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Metallurgy (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Inert Electrodes (AREA)
- Catalysts (AREA)
- Electroplating Methods And Accessories (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
- Electroplating And Plating Baths Therefor (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1153606A FR2974582A1 (fr) | 2011-04-27 | 2011-04-27 | Procede de croissance de particules metalliques par electrodeposition avec inhibition in situ |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SA112330479B1 true SA112330479B1 (ar) | 2015-12-20 |
Family
ID=45954687
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SA112330479A SA112330479B1 (ar) | 2011-04-27 | 2012-04-25 | عملية لزرع جسيمات معدنية بواسطة الطلاء بالكهرباء مع التثبيط في الموضع |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US9391331B2 (https=) |
| EP (1) | EP2702190B1 (https=) |
| JP (1) | JP6238889B2 (https=) |
| KR (1) | KR102040338B1 (https=) |
| FR (1) | FR2974582A1 (https=) |
| SA (1) | SA112330479B1 (https=) |
| WO (1) | WO2012146520A1 (https=) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6672210B2 (ja) | 2017-03-21 | 2020-03-25 | 株式会社東芝 | 電気化学反応装置と電気化学反応方法 |
| CN107188273A (zh) * | 2017-04-27 | 2017-09-22 | 华中科技大学 | 一种三维碳基金属氧化物电催化电极的制备方法 |
| CN113638017A (zh) * | 2021-08-12 | 2021-11-12 | 深圳先进技术研究院 | 一种在金属导电图形上电镀Pt的方法 |
Family Cites Families (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB381932A (en) * | 1931-07-11 | 1932-10-11 | Mond Nickel Co Ltd | Improvements relating to the electro-deposition of palladium |
| JPS5811000B2 (ja) * | 1977-03-31 | 1983-02-28 | 新日本製鐵株式会社 | 水溶液の電解に用いる不溶性陽極の製造方法 |
| CA1106797A (en) * | 1977-07-22 | 1981-08-11 | Electrolyser Corporation Ltd. (The) | Active cobalt electrode for the cathodic evolution of hydrogen |
| US4401527A (en) * | 1979-08-20 | 1983-08-30 | Occidental Chemical Corporation | Process for the electrodeposition of palladium |
| US4541905A (en) * | 1983-12-13 | 1985-09-17 | The Ohio State University Research Foundation | Electrodes for use in electrocatalytic processes |
| US4778574A (en) * | 1987-09-14 | 1988-10-18 | American Chemical & Refining Company, Inc. | Amine-containing bath for electroplating palladium |
| US5529680A (en) * | 1990-06-29 | 1996-06-25 | Electroplating Engineers Of Japan, Limited | Platinum electroforming and platinum electroplating |
| US5084144A (en) | 1990-07-31 | 1992-01-28 | Physical Sciences Inc. | High utilization supported catalytic metal-containing gas-diffusion electrode, process for making it, and cells utilizing it |
| EP0737760B1 (de) * | 1995-04-15 | 2000-04-19 | Degussa-Hüls Aktiengesellschaft | Galvanisches Platinbad |
| US6863795B2 (en) * | 2001-03-23 | 2005-03-08 | Interuniversitair Microelektronica Centrum (Imec) | Multi-step method for metal deposition |
| JP4894101B2 (ja) * | 2001-07-19 | 2012-03-14 | アイシン精機株式会社 | 色素増感型太陽電池の対極の製造方法、色素増感型太陽電池の製造方法 |
| US8449739B2 (en) * | 2002-12-31 | 2013-05-28 | Northern Illinois University | Metal-coated carbon surfaces for use in fuel cells |
| JP3949652B2 (ja) | 2003-02-17 | 2007-07-25 | Ｎｅｃエレクトロニクス株式会社 | 半導体装置の製造方法 |
| US8465858B2 (en) * | 2004-07-28 | 2013-06-18 | University Of South Carolina | Development of a novel method for preparation of PEMFC electrodes |
| US20100210453A1 (en) * | 2006-03-29 | 2010-08-19 | Max-Planck-Gesellschaft Zur Foerderung Der Wissenschaften E.V. | Preparation Of Nanostructured Metals And Metal Compounds And Their Uses |
| JP4932370B2 (ja) * | 2006-07-28 | 2012-05-16 | 日本マクダーミッド株式会社 | 電解めっき方法、プリント配線板及び半導体ウェハー |
| US7955488B2 (en) * | 2007-04-12 | 2011-06-07 | National Tsing Hua University | Process of electrodeposition platinum and platinum-based alloy nano-particles with addition of ethylene glycol |
| JP2009001846A (ja) * | 2007-06-20 | 2009-01-08 | Bridgestone Corp | 貴金属の電気メッキ方法、貴金属担持導電性材料、固体高分子型燃料電池用電極及び固体高分子型燃料電池 |
| WO2009076430A1 (en) * | 2007-12-11 | 2009-06-18 | Enthone Inc. | Electrolytic deposition of metal-based composite coatings comprising nano-particles |
| US9034165B2 (en) * | 2008-06-23 | 2015-05-19 | Brookhaven Science Associates, Llc | Underpotential deposition-mediated layer-by-layer growth of thin films |
| EP2261398B1 (en) * | 2009-06-10 | 2018-12-05 | Universität des Saarlandes | Metal foams |
| CN101928979B (zh) * | 2010-08-06 | 2012-07-04 | 厦门大学 | 金属纳米催化剂的表面结构调控和制备方法 |
| FR2998814B1 (fr) * | 2012-11-30 | 2015-05-08 | Eurecat Sa | Procede de preparation de catalyseurs metalliques supportes |
-
2011
- 2011-04-27 FR FR1153606A patent/FR2974582A1/fr not_active Withdrawn
-
2012
- 2012-04-18 JP JP2014506822A patent/JP6238889B2/ja active Active
- 2012-04-18 KR KR1020137028339A patent/KR102040338B1/ko active Active
- 2012-04-18 EP EP12714335.2A patent/EP2702190B1/fr active Active
- 2012-04-18 US US14/114,515 patent/US9391331B2/en active Active
- 2012-04-18 WO PCT/EP2012/057087 patent/WO2012146520A1/fr not_active Ceased
- 2012-04-25 SA SA112330479A patent/SA112330479B1/ar unknown
Also Published As
| Publication number | Publication date |
|---|---|
| US20140048419A1 (en) | 2014-02-20 |
| JP2014516389A (ja) | 2014-07-10 |
| KR102040338B1 (ko) | 2019-11-04 |
| EP2702190B1 (fr) | 2015-05-27 |
| JP6238889B2 (ja) | 2017-11-29 |
| WO2012146520A1 (fr) | 2012-11-01 |
| KR20140029418A (ko) | 2014-03-10 |
| US9391331B2 (en) | 2016-07-12 |
| EP2702190A1 (fr) | 2014-03-05 |
| FR2974582A1 (fr) | 2012-11-02 |
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