RU2662221C2 - Катализатор риформинга углеводородов в присутствии диоксида углерода, содержащий гексаалюминат никеля - Google Patents

Катализатор риформинга углеводородов в присутствии диоксида углерода, содержащий гексаалюминат никеля Download PDF

Info

Publication number
RU2662221C2
RU2662221C2 RU2015142397A RU2015142397A RU2662221C2 RU 2662221 C2 RU2662221 C2 RU 2662221C2 RU 2015142397 A RU2015142397 A RU 2015142397A RU 2015142397 A RU2015142397 A RU 2015142397A RU 2662221 C2 RU2662221 C2 RU 2662221C2
Authority
RU
Russia
Prior art keywords
catalyst
nickel
hexaaluminate
carbon dioxide
particles
Prior art date
Application number
RU2015142397A
Other languages
English (en)
Russian (ru)
Other versions
RU2015142397A (ru
Inventor
Штефан ШУНК
Эккехард Шваб
Андриан МИЛАНОВ
Гвидо ВАССЕРШАФФ
Томас РУССЬЕР
Original Assignee
Басф Се
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Басф Се filed Critical Басф Се
Publication of RU2015142397A publication Critical patent/RU2015142397A/ru
Application granted granted Critical
Publication of RU2662221C2 publication Critical patent/RU2662221C2/ru

Links

Images

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B01J35/45—Nanoparticles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/612—Surface area less than 10 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • B01J35/737—Hexaaluminate-type AB12O19
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0236—Drying, e.g. preparing a suspension, adding a soluble salt and drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/036—Precipitation; Co-precipitation to form a gel or a cogel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04—Mixing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B01J37/088—Decomposition of a metal salt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/40—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/30—Scanning electron microscopy; Transmission electron microscopy
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0072—Preparation of particles, e.g. dispersion of droplets in an oil bath
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0238—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a carbon dioxide reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1052—Nickel or cobalt catalysts
    • C01B2203/1058—Nickel catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1082—Composition of support materials
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1241—Natural gas or methane
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/32—Hydrogen storage
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/141—Feedstock
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Catalysts (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Crystallography & Structural Chemistry (AREA)
RU2015142397A 2013-03-07 2014-03-06 Катализатор риформинга углеводородов в присутствии диоксида углерода, содержащий гексаалюминат никеля RU2662221C2 (ru)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
EP13158074.8 2013-03-07
EP13158074 2013-03-07
EP13194345.8 2013-11-26
EP13194345 2013-11-26
PCT/EP2014/054362 WO2014135642A1 (de) 2013-03-07 2014-03-06 Nickelhexaaluminathaltiger katalysator zur reformierung von kohlenwasserstoffen in gegenwart von kohlendioxid

Publications (2)

Publication Number Publication Date
RU2015142397A RU2015142397A (ru) 2017-04-17
RU2662221C2 true RU2662221C2 (ru) 2018-07-25

Family

ID=50231185

Family Applications (1)

Application Number Title Priority Date Filing Date
RU2015142397A RU2662221C2 (ru) 2013-03-07 2014-03-06 Катализатор риформинга углеводородов в присутствии диоксида углерода, содержащий гексаалюминат никеля

Country Status (8)

Country Link
US (1) US9475037B2 (enExample)
EP (1) EP2964385A1 (enExample)
JP (1) JP2016510687A (enExample)
KR (1) KR20150129786A (enExample)
CN (1) CN105050714B (enExample)
DE (1) DE112014001125A5 (enExample)
RU (1) RU2662221C2 (enExample)
WO (1) WO2014135642A1 (enExample)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2886514A1 (de) * 2013-12-20 2015-06-24 Basf Se Verfahren zur Reformierung von Gemischen aus Kohlenwasserstoffen und Kohlendioxid
US9416087B2 (en) 2014-10-08 2016-08-16 Chevron Phillips Chemical Company Lp Methods for the production of α,β-unsaturated carboxylic acids and salts thereof
US9725393B2 (en) 2014-10-08 2017-08-08 Chevron Phillips Chemical Company Lp Methods for the production of α,β-unsaturated carboxylic acids and salts thereof
ES2781329T3 (es) 2015-07-22 2020-09-01 Basf Se Procedimiento para preparar ácido furan-2,5-dicarboxílico
CN108473455A (zh) 2015-11-04 2018-08-31 巴斯夫欧洲公司 用于制备包含5-(羟基甲基)糠醛和特定的hmf酯的混合物的方法
EP3371161A1 (en) 2015-11-04 2018-09-12 Basf Se A process for preparing furan-2,5-dicarboxylic acid
CN108368017B (zh) 2015-12-15 2021-07-09 切弗朗菲利浦化学公司 由金属内酯和阴离子聚电解质形成α,β-不饱和羧酸和其盐
US10544080B2 (en) 2017-06-14 2020-01-28 Chevron Phillips Chemical Company Lp Continuous process for the conversion of olefins and carbon dioxide to acrylates via solution phase reactor
US10550061B2 (en) 2017-06-14 2020-02-04 Chevron Phillips Chemical Company Lp Sulfur oxoacid-substituted and phosphorus oxoacid-substituted polyaromatic resins and salts thereof as promoters in acrylate production from coupling reactions of olefins and carbon dioxide
JP6959695B2 (ja) 2017-08-11 2021-11-05 アイディーエーシー ホールディングス インコーポレイテッド 複数のアクセスネットワークの間でのトラフィックステアリングおよび切り替え
CN107673383A (zh) * 2017-09-06 2018-02-09 新地能源工程技术有限公司 六铝酸盐、包含其的载体及其制备方法和高温甲烷化催化剂
CN107597199A (zh) * 2017-09-13 2018-01-19 武汉凯迪工程技术研究总院有限公司 循环流化床烃重整催化剂及其制备方法和应用
CN109012144B (zh) * 2018-07-19 2021-03-30 中国科学院大学 六铝酸盐复合氧化物材料在h2s催化分解反应中的应用
US11174213B2 (en) 2018-10-12 2021-11-16 Chevron Phillips Chemical Company, Lp Effects of catalyst concentration and solid activator on nickel-mediated olefin/carbon dioxide coupling to acrylates
CN113329815B (zh) * 2019-01-31 2024-06-11 巴斯夫欧洲公司 包含包含氧、镧、铝和钴的混合氧化物的模制品
US20230271844A1 (en) * 2020-07-14 2023-08-31 Basf Corporation Strontium-catalyzed boehmite formation
WO2024003354A1 (en) 2022-07-01 2024-01-04 Basf Se Cobalt-based catalyst for the conversion of hydrocarbons to synthesis gas
WO2024003347A1 (en) 2022-07-01 2024-01-04 Basf Se Cobalt- and strontium-based catalyst for the conversion of hydrocarbons to synthesis gas

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2366503C1 (ru) * 2008-04-14 2009-09-10 Институт Катализа Им. Г.К. Борескова Сибирского Отделения Российской Академии Наук Катализатор, способ его приготовления (варианты) и способ получения биотоплива
RU2388535C1 (ru) * 2009-04-15 2010-05-10 Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук (статус государственного учреждения) Катализатор, способ его приготовления и способ окисления метана

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2721837B1 (fr) * 1994-07-01 1996-08-30 Inst Francais Du Petrole Catalyseur d'oxydation resistant a des temperatures elevees, son procede de preparation et procede de combustion utilisant un tel catalyseur
WO2001025142A1 (en) * 1999-10-01 2001-04-12 Bp Amoco Corporation Preparing synthesis gas using hydrotalcite-derived nickel catalysts
GB0115850D0 (en) * 2001-06-28 2001-08-22 Isis Innovations Ltd Catalyst
US20040138317A1 (en) * 2002-11-11 2004-07-15 Conocophillips Company Supports for high surface area catalysts
US20050265920A1 (en) * 2002-11-11 2005-12-01 Conocophillips Company Supports and catalysts comprising rare earth aluminates, and their use in partial oxidation
JP4096096B2 (ja) * 2002-12-25 2008-06-04 独立行政法人産業技術総合研究所 ヘキサアルミネート多孔質セラミックス及びその製造方法
DE10322339A1 (de) * 2003-05-17 2004-12-02 Mtu Aero Engines Gmbh Einlaufbelag für Gasturbinen
US7309480B2 (en) 2004-04-16 2007-12-18 H2Gen Innovations, Inc. Catalyst for hydrogen generation through steam reforming of hydrocarbons
DE102004025798A1 (de) * 2004-05-26 2005-12-22 Mtu Aero Engines Gmbh Wärmedämmschichtsystem
JP4976656B2 (ja) * 2005-03-07 2012-07-18 電気化学工業株式会社 触媒担体及びその製造方法
US8142756B1 (en) * 2006-03-28 2012-03-27 The United States Of America As Represented By The U.S. Department Of Energy Methods of reforming hydrocarbon fuels using hexaaluminate catalysts
US7736536B2 (en) * 2006-07-11 2010-06-15 Intematix Corporation Compositions comprising a mixture of a BAM phosphor and at least one other hexaaluminate
CA2771808A1 (en) * 2009-08-21 2011-02-24 Universite De Sherbrooke Steam reforming of hydrocarbonaceous fuels over a ni-alumina spinel catalyst
CN102836718B (zh) * 2011-06-20 2014-06-04 中国科学院过程工程研究所 一种介孔六铝酸盐负载镍基的甲烷化催化剂及其制备方法
US8916491B2 (en) 2011-11-08 2014-12-23 Basf Se Process for producing a methanation catalyst and a process for the methanation of synthesis gas
US9259712B2 (en) 2011-11-08 2016-02-16 Basf Se Process for producing a reforming catalyst and the reforming of methane
US9566571B2 (en) * 2012-02-10 2017-02-14 Basf Se Hexaaluminate-comprising catalyst for the reforming of hydrocarbons and a reforming process
US20140001407A1 (en) 2012-06-29 2014-01-02 Basf Se High-pressure process for the carbon dioxide reforming of hydrocarbons in the presence of iridium-comprising active compositions
WO2014097142A1 (de) 2012-12-21 2014-06-26 Basf Se Parallele herstellung von wasserstoff, kohlenstoffmonoxid und einem kohlenstoffhaltigen produkt

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2366503C1 (ru) * 2008-04-14 2009-09-10 Институт Катализа Им. Г.К. Борескова Сибирского Отделения Российской Академии Наук Катализатор, способ его приготовления (варианты) и способ получения биотоплива
RU2388535C1 (ru) * 2009-04-15 2010-05-10 Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук (статус государственного учреждения) Катализатор, способ его приготовления и способ окисления метана

Non-Patent Citations (5)

* Cited by examiner, † Cited by third party
Title
MARINA V. BUKHTIYAROVA ET AL., Steam reforming of methane over Ni-substituted Sr hexaaluminates, Catalysis for sustainable energy, 2012, 11-21. *
MARINA V. BUKHTIYAROVA ET AL., Steam reforming of methane over Ni-substituted Sr hexaaluminates, Catalysis for sustainable energy, 2012, 11-21. TODD H. GARDNER ET ALL, Effect of nickel hexaaluminate mirror cation on structure-sensitive reactions during n-tetradecane partial oxidation, 2007, Applied Catalysis A: General, 2007, 323, 1-8. WENLING CHU ET AL., The partial oxidation of methane to syngas over the nickel-modified hexaaluminate catalysts BaNi y Al 12-y O 19-, Applied Catalysis A: General 235, 2002, 39-45. TODD H.GARDNER, Structural Characterization of Ni-Substituted Hexaaluminate Catalyst Using EXAFS, XANES, XPS, XRD, AND TPR, J. Phys. Chem. C. 2010, 114, 7888-7894. *
TODD H. GARDNER ET ALL, Effect of nickel hexaaluminate mirror cation on structure-sensitive reactions during n-tetradecane partial oxidation, 2007, Applied Catalysis A: General, 2007, 323, 1-8. *
TODD H.GARDNER, Structural Characterization of Ni-Substituted Hexaaluminate Catalyst Using EXAFS, XANES, XPS, XRD, AND TPR, J. Phys. Chem. C. 2010, 114, 7888-7894. *
WENLING CHU ET AL., The partial oxidation of methane to syngas over the nickel-modified hexaaluminate catalysts BaNi y Al 12-y O 19-, Applied Catalysis A: General 235, 2002, 39-45. *

Also Published As

Publication number Publication date
CN105050714A (zh) 2015-11-11
WO2014135642A1 (de) 2014-09-12
EP2964385A1 (de) 2016-01-13
KR20150129786A (ko) 2015-11-20
CN105050714B (zh) 2018-06-26
RU2015142397A (ru) 2017-04-17
US20160008791A1 (en) 2016-01-14
JP2016510687A (ja) 2016-04-11
DE112014001125A5 (de) 2015-11-19
US9475037B2 (en) 2016-10-25

Similar Documents

Publication Publication Date Title
RU2662221C2 (ru) Катализатор риформинга углеводородов в присутствии диоксида углерода, содержащий гексаалюминат никеля
RU2631497C2 (ru) Содержащий гексаалюминат катализатор риформинга углеводородов и способ риформинга
RU2340394C2 (ru) Способ получения носителя для катализатора с повышенной гидротермальной стабильностью (варианты), катализатор для синтеза углеводородов и способ синтеза углеводородов из синтез-газа
RU2680060C1 (ru) Способ риформинга смесей из углеводородов и диоксида углерода
Jia et al. Nickel catalysts supported on calcium titanate for enhanced CO methanation
US7276540B2 (en) Supports for high surface area catalysts
RU2638534C1 (ru) Катализатор конверсии природного или попутного газа в синтез-газ в процессе автотермического риформинга и способ его получения
JP5090367B2 (ja) 金属硝酸塩転化法
US10780425B2 (en) Steam reforming catalyst and method of making thereof
US9259713B2 (en) Process for the preparation of a catalyst using at least one rapid drying stage and at least one fluidised bed drying stage and use thereof for fischer-tropsch synthesis
CA2942587A1 (en) Yttrium-containing catalyst for high-temperature carbon dioxide hydration, combined high-temperature carbon dioxide hydration, and reforming and/or reforming, and a method for high-temperature carbon dioxide hydration, combined high-temperature carbon dioxide hydration and reforming an/or reforming
EA014964B1 (ru) Низкотемпературный катализатор конверсии водяного газа
US10987660B2 (en) Hexaaluminate-comprising catalyst for the reforming of hydrocarbons and a reforming process
EP3129142B1 (en) Shell impregnated catalyst and process for producing a shell impregnated catalyst body
JP5537960B2 (ja) 炭化水素改質触媒、該触媒の製造方法および該触媒を用いる改質方法
RU2650495C1 (ru) Катализатор для паровой конверсии углеводородов
TW201902827A (zh) 在含鎳尖晶石及鎂尖晶石的催化劑存在下進行二氧化碳氫化之方法
RU2629667C1 (ru) СПОСОБ ПОЛУЧЕНИЯ МЕЗОПОРИСТЫХ КСЕРОГЕЛЕЙ И НАНОПОРОШКОВ В СИСТЕМЕ ZrO2(Y2O3)-Al2O3 ДЛЯ НОСИТЕЛЕЙ КАТАЛИЗАТОРОВ ПРИ КОНВЕРСИИ МЕТАНА В СИНТЕЗ-ГАЗ
WO2022186319A1 (ja) 還元剤、ガスの製造方法および変換効率増加方法
EP2900368B1 (en) Steam reforming catalyst and method of making thereof
KR20250000060A (ko) 메탄 개질에 의한 합성가스 생산용 고안정성 니켈 촉매의 제조방법 및 이를 이용한 합성가스 생산방법
JP2022135912A (ja) 還元剤、ガスの製造方法および変換効率増加方法
Papavasiliou et al. Synthesis and characterization of composite ceramic nanomaterials by coprecipitation.

Legal Events

Date Code Title Description
MM4A The patent is invalid due to non-payment of fees

Effective date: 20190307