RU2650171C2 - Параллельное получение водорода, монооксида углерода и углеродсодержащего продукта - Google Patents
Параллельное получение водорода, монооксида углерода и углеродсодержащего продукта Download PDFInfo
- Publication number
- RU2650171C2 RU2650171C2 RU2015129604A RU2015129604A RU2650171C2 RU 2650171 C2 RU2650171 C2 RU 2650171C2 RU 2015129604 A RU2015129604 A RU 2015129604A RU 2015129604 A RU2015129604 A RU 2015129604A RU 2650171 C2 RU2650171 C2 RU 2650171C2
- Authority
- RU
- Russia
- Prior art keywords
- hydrogen
- containing gas
- gas mixture
- reaction
- carbon
- Prior art date
Links
- 239000001257 hydrogen Substances 0.000 title claims abstract description 149
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 149
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 title claims abstract description 47
- 229910002091 carbon monoxide Inorganic materials 0.000 title claims abstract description 45
- 238000002360 preparation method Methods 0.000 title abstract description 5
- CREMABGTGYGIQB-UHFFFAOYSA-N carbon carbon Chemical compound C.C CREMABGTGYGIQB-UHFFFAOYSA-N 0.000 title 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 title 1
- 238000006243 chemical reaction Methods 0.000 claims abstract description 147
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 136
- 239000007789 gas Substances 0.000 claims abstract description 134
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims abstract description 126
- 238000000034 method Methods 0.000 claims abstract description 68
- 239000000203 mixture Substances 0.000 claims abstract description 67
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 64
- 229910002092 carbon dioxide Inorganic materials 0.000 claims abstract description 63
- 239000001569 carbon dioxide Substances 0.000 claims abstract description 63
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 51
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 29
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 29
- 230000008569 process Effects 0.000 claims abstract description 27
- 150000002431 hydrogen Chemical class 0.000 claims abstract description 13
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 96
- 230000015572 biosynthetic process Effects 0.000 claims description 54
- 238000003786 synthesis reaction Methods 0.000 claims description 50
- 239000003054 catalyst Substances 0.000 claims description 26
- 230000006378 damage Effects 0.000 claims description 21
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 19
- 238000004519 manufacturing process Methods 0.000 claims description 19
- 239000001301 oxygen Substances 0.000 claims description 19
- 229910052760 oxygen Inorganic materials 0.000 claims description 19
- 238000006731 degradation reaction Methods 0.000 claims description 18
- 230000010354 integration Effects 0.000 claims description 16
- 230000015556 catabolic process Effects 0.000 claims description 10
- 238000004939 coking Methods 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 238000005979 thermal decomposition reaction Methods 0.000 claims description 7
- 230000002211 methanization Effects 0.000 claims description 6
- 238000007086 side reaction Methods 0.000 claims description 6
- 230000002441 reversible effect Effects 0.000 claims description 4
- 239000000126 substance Substances 0.000 abstract description 11
- 230000000694 effects Effects 0.000 abstract description 5
- 239000007787 solid Substances 0.000 abstract description 5
- 238000000354 decomposition reaction Methods 0.000 abstract 1
- 239000008187 granular material Substances 0.000 description 31
- 229910052751 metal Inorganic materials 0.000 description 25
- 239000002184 metal Substances 0.000 description 25
- 238000000197 pyrolysis Methods 0.000 description 24
- 239000000047 product Substances 0.000 description 23
- 238000002407 reforming Methods 0.000 description 15
- 239000000571 coke Substances 0.000 description 14
- 239000000463 material Substances 0.000 description 11
- 150000002739 metals Chemical class 0.000 description 11
- 238000000629 steam reforming Methods 0.000 description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 239000011343 solid material Substances 0.000 description 9
- 239000003345 natural gas Substances 0.000 description 8
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 8
- 239000004215 Carbon black (E152) Substances 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 238000001816 cooling Methods 0.000 description 6
- 238000012545 processing Methods 0.000 description 6
- 239000007858 starting material Substances 0.000 description 6
- 238000012546 transfer Methods 0.000 description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 5
- 238000000605 extraction Methods 0.000 description 5
- 230000002349 favourable effect Effects 0.000 description 5
- -1 for example Chemical class 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 229910052697 platinum Inorganic materials 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 230000003197 catalytic effect Effects 0.000 description 4
- 238000013461 design Methods 0.000 description 4
- 238000011084 recovery Methods 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 3
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 3
- 229910004298 SiO 2 Inorganic materials 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 3
- 239000003245 coal Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 3
- 229910003455 mixed metal oxide Inorganic materials 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 230000000737 periodic effect Effects 0.000 description 3
- 239000002574 poison Substances 0.000 description 3
- 231100000614 poison Toxicity 0.000 description 3
- 238000010791 quenching Methods 0.000 description 3
- 230000000171 quenching effect Effects 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 2
- 229910052580 B4C Inorganic materials 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 239000000443 aerosol Substances 0.000 description 2
- 150000001342 alkaline earth metals Chemical class 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- INAHAJYZKVIDIZ-UHFFFAOYSA-N boron carbide Chemical compound B12B3B4C32B41 INAHAJYZKVIDIZ-UHFFFAOYSA-N 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 229910052741 iridium Inorganic materials 0.000 description 2
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 2
- 229910052747 lanthanoid Inorganic materials 0.000 description 2
- 150000002602 lanthanoids Chemical class 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 239000010948 rhodium Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000007873 sieving Methods 0.000 description 2
- 239000002028 Biomass Substances 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 206010063493 Premature ageing Diseases 0.000 description 1
- 208000032038 Premature aging Diseases 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000005083 Zinc sulfide Substances 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 150000007824 aliphatic compounds Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- SNAAJJQQZSMGQD-UHFFFAOYSA-N aluminum magnesium Chemical compound [Mg].[Al] SNAAJJQQZSMGQD-UHFFFAOYSA-N 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 238000002453 autothermal reforming Methods 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 238000001193 catalytic steam reforming Methods 0.000 description 1
- 230000001413 cellular effect Effects 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 1
- RCFVMJKOEJFGTM-UHFFFAOYSA-N cerium zirconium Chemical compound [Zr].[Ce] RCFVMJKOEJFGTM-UHFFFAOYSA-N 0.000 description 1
- 238000012824 chemical production Methods 0.000 description 1
- 239000007809 chemical reaction catalyst Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- WHDPTDWLEKQKKX-UHFFFAOYSA-N cobalt molybdenum Chemical compound [Co].[Co].[Mo] WHDPTDWLEKQKKX-UHFFFAOYSA-N 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229910052878 cordierite Inorganic materials 0.000 description 1
- 238000005262 decarbonization Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 description 1
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000007323 disproportionation reaction Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000010982 kinetic investigation Methods 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- CNEOGBIICRAWOH-UHFFFAOYSA-N methane;molybdenum Chemical compound C.[Mo] CNEOGBIICRAWOH-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- DDTIGTPWGISMKL-UHFFFAOYSA-N molybdenum nickel Chemical compound [Ni].[Mo] DDTIGTPWGISMKL-UHFFFAOYSA-N 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229910052863 mullite Inorganic materials 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000010955 niobium Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 150000002898 organic sulfur compounds Chemical class 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical class [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000006057 reforming reaction Methods 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 229910052596 spinel Inorganic materials 0.000 description 1
- 239000011029 spinel Substances 0.000 description 1
- 229910052566 spinel group Inorganic materials 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 230000009897 systematic effect Effects 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- 229930192474 thiophene Natural products 0.000 description 1
- 150000003577 thiophenes Chemical class 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229910052984 zinc sulfide Inorganic materials 0.000 description 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
- 229910000859 α-Fe Inorganic materials 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
- C01B3/24—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/40—Carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/02—Fixed-bed gasification of lump fuel
- C10J3/06—Continuous processes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
- C10K3/02—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
- C10K3/026—Increasing the carbon monoxide content, e.g. reverse water-gas shift [RWGS]
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0238—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a carbon dioxide reforming step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0266—Processes for making hydrogen or synthesis gas containing a decomposition step
- C01B2203/0272—Processes for making hydrogen or synthesis gas containing a decomposition step containing a non-catalytic decomposition step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1235—Hydrocarbons
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Carbon And Carbon Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP12199043 | 2012-12-21 | ||
| EP12199043.6 | 2012-12-21 | ||
| PCT/IB2013/061032 WO2014097142A1 (de) | 2012-12-21 | 2013-12-17 | Parallele herstellung von wasserstoff, kohlenstoffmonoxid und einem kohlenstoffhaltigen produkt |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2015129604A RU2015129604A (ru) | 2017-01-27 |
| RU2650171C2 true RU2650171C2 (ru) | 2018-04-09 |
Family
ID=47471596
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2015129604A RU2650171C2 (ru) | 2012-12-21 | 2013-12-17 | Параллельное получение водорода, монооксида углерода и углеродсодержащего продукта |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US9834440B2 (esLanguage) |
| EP (1) | EP2935098B1 (esLanguage) |
| JP (1) | JP6479677B2 (esLanguage) |
| KR (1) | KR102189391B1 (esLanguage) |
| CN (1) | CN104918882B (esLanguage) |
| AR (1) | AR094247A1 (esLanguage) |
| AU (1) | AU2013365822A1 (esLanguage) |
| CA (1) | CA2895924C (esLanguage) |
| ES (1) | ES2666141T3 (esLanguage) |
| NO (1) | NO2935098T3 (esLanguage) |
| PL (1) | PL2935098T3 (esLanguage) |
| RU (1) | RU2650171C2 (esLanguage) |
| TW (1) | TWI633049B (esLanguage) |
| WO (1) | WO2014097142A1 (esLanguage) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2781139C1 (ru) * | 2018-12-20 | 2022-10-06 | Тиссенкрупп Индастриал Солюшнс Аг | Способ получения водорода, монооксида углерода и углеродосодержащего продукта |
| US12252405B2 (en) | 2018-12-20 | 2025-03-18 | Thyssenkrupp Uhde Gmbh | Process and device for producing hydrogen, carbon monoxide and a carbon-containing product |
Families Citing this family (48)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9475037B2 (en) | 2013-03-07 | 2016-10-25 | Basf Se | Nickel hexaaluminate-containing catalyst for reforming hydrocarbons in the presence of carbon dioxide |
| AR102047A1 (es) * | 2014-08-19 | 2017-02-01 | Linde Ag | Proceso para producir gas de síntesis |
| PL2987769T3 (pl) * | 2014-08-19 | 2020-06-29 | Basf Se | Sposób wytwarzania gazu syntezowego i energii elektrycznej |
| DE102015015531A1 (de) * | 2015-12-01 | 2017-06-01 | Basf Se | Verfahren zur Erzeugung von Synthesegas |
| DE102015015968A1 (de) | 2015-12-01 | 2017-06-01 | Basf Se | Verfahren zur Erzeugung von Synthesegas |
| WO2017186482A1 (de) * | 2016-04-28 | 2017-11-02 | CCP Technology GmbH | Verfahren und vorrichtung zur herstellung von synthesegas |
| RU2633354C1 (ru) * | 2016-12-20 | 2017-10-12 | Федеральное государственное автономное образовательное учреждение высшего образования "Национальный исследовательский Томский государственный университет" (ТГУ, НИ ТГУ) | Катализатор и способ раздельного получения водорода и монооксида углерода из метана |
| WO2018219986A1 (de) * | 2017-06-02 | 2018-12-06 | Basf Se | Verfahren zur kohlenstoffdioxid-hydrierung in gegenwart eines iridium- und/oder rhodiumhaltigen katalysators |
| EP3415466A1 (de) | 2017-06-12 | 2018-12-19 | SunFire GmbH | Russvermeidungs- und/oder russverminderungsverfahren sowie -anordnung und russbeseitigungsverfahren sowie -anordnung in abkühlstrecken sowie rekuperatoren |
| CN107416769A (zh) * | 2017-08-03 | 2017-12-01 | 山西潞安煤基合成油有限公司 | 一种甲烷二氧化碳重整制备合成气的方法 |
| DE102017120814A1 (de) * | 2017-09-08 | 2019-03-14 | Karlsruher Institut für Technologie | Konvertierungsreaktor und Verfahrensführung |
| UA127416C2 (uk) | 2017-12-08 | 2023-08-16 | Хальдор Топсьое А/С | Спосіб і система для виробництва синтез-газу |
| JP7365341B2 (ja) | 2017-12-08 | 2023-10-19 | トプソー・アクチエゼルスカベット | 合成ガスを生産するためのプラントと方法 |
| KR102678026B1 (ko) * | 2017-12-08 | 2024-06-26 | 토프쉐 에이/에스 | 탄화수소 가스를 개질하기 위한 방법 및 시스템 |
| KR102674399B1 (ko) * | 2017-12-08 | 2024-06-14 | 토프쉐 에이/에스 | 합성 가스의 제조를 위한 시스템 및 방법 |
| CN108302953B (zh) * | 2018-03-27 | 2024-04-30 | 中山大学 | 一种工业高温固体散料余热回收系统和方法 |
| CN113165883B (zh) | 2018-12-03 | 2023-08-22 | 国际壳牌研究有限公司 | 用于将二氧化碳转化为一氧化碳的方法及反应器 |
| DE102018132661B4 (de) | 2018-12-18 | 2020-10-01 | Thyssenkrupp Ag | Verfahren zur Kohlenwasserstoffpyrolyse mit räumlich getrennter Beheizungs- und Reaktionszone innerhalb des Reaktorraums |
| US12319576B2 (en) * | 2019-04-23 | 2025-06-03 | Haldor Topsøe A/S | High temperature reactor vessel, plant and method |
| HUE057982T2 (hu) * | 2019-05-27 | 2022-06-28 | Covestro Deutschland Ag | Eljárás poliuretán anyag hulladék újrafeldolgozására izocianátok és poliuretánok elõállításában alkalmazható vegyi nyersanyagok elõállításához |
| JP2023500816A (ja) * | 2019-10-25 | 2023-01-11 | ビーエーエスエフ ソシエタス・ヨーロピア | 炭化水素の熱分解と電気化学的分離工程とを組み合わせることによって高純度の水素を製造するための方法 |
| EP3819259A1 (de) * | 2019-11-06 | 2021-05-12 | Covestro Deutschland AG | Verfahren zur isocyanat- und polyurethan-herstellung mit verbesserter nachhaltigkeit |
| KR102841175B1 (ko) * | 2020-01-28 | 2025-07-30 | 아주대학교산학협력단 | 수소 생산용 탄화수소 열분해 반응기 |
| JP7779543B2 (ja) * | 2020-05-19 | 2025-12-03 | 国立大学法人静岡大学 | 反応システム、固体炭素を捕集する方法、水素を含むガスを製造する方法、触媒セット、及び固体炭素捕集用触媒 |
| AU2021284970B2 (en) * | 2020-06-01 | 2023-10-12 | Shell Internationale Research Maatschappij B.V. | A process and reactor for converting carbon dioxide into carbon monoxide, involving a catalyst |
| CN115697895B (zh) * | 2020-06-01 | 2024-03-01 | 国际壳牌研究有限公司 | 用于将二氧化碳、氢气和甲烷转化为合成气的灵活工艺 |
| CA3081971A1 (fr) * | 2020-06-04 | 2021-12-04 | Hydro-Quebec | Methode et reacteur pour la production de gaz de synthese a partir d'une source de carbone et d'hydrogene en presence d'une oxy-flamme |
| KR102421182B1 (ko) * | 2020-07-30 | 2022-07-13 | 부산대학교 산학협력단 | 탄소 연료를 이용한 수소 또는 수소 합성 가스의 생산방법 및 이의 생산장치 |
| DE102020211407A1 (de) | 2020-09-10 | 2022-03-10 | Caphenia Gmbh | Verfahren und Vorrichtung zur Herstellung von Synthesegas |
| GB202016417D0 (en) * | 2020-10-16 | 2020-12-02 | Johnson Matthey Davy Technologies Ltd | Process for producing a gas stream comprising carbon monoxide |
| JP2024512242A (ja) * | 2021-02-18 | 2024-03-19 | カーボン テクノロジー ホールディングス， エルエルシー | カーボンネガティブ冶金製品 |
| KR102506154B1 (ko) * | 2021-03-03 | 2023-03-07 | 한국에너지기술연구원 | 수소 및 탄소체 제조장치 및 제조방법 |
| CN113148952A (zh) * | 2021-04-09 | 2021-07-23 | 集美大学 | 沼气干重整制合成气及氢燃料系统 |
| KR102333666B1 (ko) * | 2021-05-11 | 2021-12-02 | 한국기계연구원 | 이산화탄소를 배출하지 않는 수소 생산 시스템 및 수소 생산 방법 |
| KR102592537B1 (ko) * | 2021-08-27 | 2023-10-25 | 한국에너지기술연구원 | 부생 가스를 이용한 고부가가치 화학물질의 제조방법 및 장치 |
| KR102419495B1 (ko) * | 2021-09-03 | 2022-07-11 | 주식회사 제로시스 | 수소 생산 장치 |
| CN114570423B (zh) * | 2021-12-27 | 2023-09-15 | 中国科学院山西煤炭化学研究所 | 一种合成气制乙醇、丙醇的催化剂及其制备方法和应用 |
| KR102520557B1 (ko) * | 2022-02-03 | 2023-04-13 | 주식회사 에이피그린 | 탄소 포집 방법 및 장치 |
| AU2023306968A1 (en) * | 2022-07-10 | 2025-01-30 | Czero, Inc. | Carbon formation chemical looping using oxygen |
| CA3264056A1 (en) * | 2022-08-18 | 2024-02-22 | Czero, Inc. | PROCESSES AND METHODS FOR THE PRODUCTION OF HYDROGEN AND CARBON FROM HYDROCARBONS |
| WO2024177743A1 (en) * | 2023-02-22 | 2024-08-29 | Chevron U.S.A. Inc. | Methods and systems utilizing methane pyrolysis integrated with carbon dioxide conversion for producing low-carbon intensity fuels |
| FR3146891B1 (fr) * | 2023-03-23 | 2025-10-10 | Ifp Energies Now | Procédé de conversion du gaz à l'eau inversée avec chauffe séparée des flux de charge |
| CN121152767A (zh) * | 2023-05-15 | 2025-12-16 | 莫尔顿工业股份有限公司 | 利用二氧化碳和热解衍生氢气通过逆水煤气变换反应生产合成气 |
| WO2024245851A1 (de) * | 2023-06-02 | 2024-12-05 | Teijin Carbon Europe Gmbh | Verfahren zur abgasbehandlung |
| US20250135424A1 (en) * | 2023-10-27 | 2025-05-01 | Molten Industries Inc. | Integrated thermal energy storage for hydrocarbon pyrolysis |
| FR3157370A1 (fr) * | 2023-12-21 | 2025-06-27 | IFP Energies Nouvelles | Dispositif de distribution d’unité de conversion du gaz à l'eau inversée |
| WO2025227073A1 (en) * | 2024-04-26 | 2025-10-30 | Czero, Inc. | Solid carbon products and methods of producing solid carbon |
| WO2025233156A1 (en) * | 2024-05-08 | 2025-11-13 | Basf Se | Method for controlling synthesis gas processing from carbonaceous feedstock |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0601956A2 (en) * | 1992-12-10 | 1994-06-15 | Haldor Topsoe A/S | Process for the preparation of carbon monoxide rich gas |
| CN101249949A (zh) * | 2008-03-27 | 2008-08-27 | 中国科学院过程工程研究所 | 一种由烃类气体制备氢气的工艺 |
| WO2010069549A1 (en) * | 2008-12-17 | 2010-06-24 | Saudi Basic Industries Corporation | Process for increasing the carbon monoxide content of a syngas mixture |
| RU2408529C1 (ru) * | 2009-06-04 | 2011-01-10 | Алексей Дмитриевич Романов | Способ получения синтез-газа и водорода |
| RU2441837C2 (ru) * | 2010-04-19 | 2012-02-10 | Федеральное государственное образовательное учреждение высшего профессионального образования "Чувашский государственный университет имени И.Н. Ульянова" | Способ производства монооксида углерода |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB365912A (en) * | 1930-04-30 | 1932-01-28 | Humphreys & Glasgow Ltd | Improvements in or relating to the manufacture of combustible gas rich in hydrogen |
| US3919114A (en) | 1969-11-21 | 1975-11-11 | Texaco Development Corp | Synthesis gas process |
| US4410504A (en) * | 1982-04-30 | 1983-10-18 | United Technologies Corporation | Method of producing high density carbon |
| GB2168718B (en) * | 1984-10-29 | 1988-06-29 | Humphreys & Glasgow Ltd | Process for the production of synthesis gas and its utilisation |
| AU654612B2 (en) | 1992-01-27 | 1994-11-10 | Shell Internationale Research Maatschappij B.V. | Process for producing a hydrogen-containing gas |
| US5767165A (en) | 1995-03-16 | 1998-06-16 | Steinberg; Meyer | Method for converting natural gas and carbon dioxide to methanol and reducing CO2 emissions |
| JP2000219508A (ja) * | 1999-02-01 | 2000-08-08 | Mitsui Eng & Shipbuild Co Ltd | 水素ｐｓａのオフガスからｃｏを製造する方法 |
| US6749829B2 (en) * | 2002-07-23 | 2004-06-15 | Bp Corporation North America Inc. | Hydrogen to steam reforming of natural gas to synthesis gas |
| US20070253886A1 (en) | 2004-04-06 | 2007-11-01 | Universite De Sherbrooke | Carbon sequestration and dry reforming process and catalysts to produce same |
| CN102076604B (zh) | 2008-07-04 | 2014-11-12 | 株式会社村田制作所 | 二氧化碳重整方法 |
| JP5402683B2 (ja) * | 2009-02-02 | 2014-01-29 | 株式会社村田製作所 | 逆シフト反応用触媒、その製造方法、および合成ガスの製造方法 |
| KR101570882B1 (ko) | 2009-08-04 | 2015-11-23 | 에스케이이노베이션 주식회사 | 메탄의 열분해 및 이산화탄소 전환 반응을 포함하는 탄소 함유 물질의 가스화 방법 |
| FR2955865B1 (fr) * | 2010-02-01 | 2012-03-16 | Cotaver | Procede de recyclage du dioxyde de carbone (co2) |
| DE102011106645A1 (de) | 2011-07-05 | 2013-01-10 | Linde Aktiengesellschaft | Verfahren zur Erzeugung von Koks |
| DE102011106642A1 (de) | 2011-07-05 | 2013-01-10 | Linde Ag | Verfahren zur Synthesegaserzeugung |
| EP2584023A1 (en) * | 2011-10-21 | 2013-04-24 | Neste Oil Oyj | Method of producing a syngas composition |
| DE102012010542A1 (de) * | 2011-12-20 | 2013-06-20 | CCP Technology GmbH | Verfahren und anlage zur erzeugung von synthesegas |
-
2013
- 2013-12-17 NO NO13865384A patent/NO2935098T3/no unknown
- 2013-12-17 AU AU2013365822A patent/AU2013365822A1/en not_active Abandoned
- 2013-12-17 JP JP2015548834A patent/JP6479677B2/ja active Active
- 2013-12-17 CN CN201380066238.8A patent/CN104918882B/zh active Active
- 2013-12-17 ES ES13865384.5T patent/ES2666141T3/es active Active
- 2013-12-17 RU RU2015129604A patent/RU2650171C2/ru active
- 2013-12-17 KR KR1020157019663A patent/KR102189391B1/ko active Active
- 2013-12-17 WO PCT/IB2013/061032 patent/WO2014097142A1/de not_active Ceased
- 2013-12-17 EP EP13865384.5A patent/EP2935098B1/de active Active
- 2013-12-17 CA CA2895924A patent/CA2895924C/en active Active
- 2013-12-17 US US14/652,346 patent/US9834440B2/en active Active
- 2013-12-17 PL PL13865384T patent/PL2935098T3/pl unknown
- 2013-12-19 TW TW102147076A patent/TWI633049B/zh not_active IP Right Cessation
- 2013-12-20 AR ARP130104985A patent/AR094247A1/es unknown
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0601956A2 (en) * | 1992-12-10 | 1994-06-15 | Haldor Topsoe A/S | Process for the preparation of carbon monoxide rich gas |
| CN101249949A (zh) * | 2008-03-27 | 2008-08-27 | 中国科学院过程工程研究所 | 一种由烃类气体制备氢气的工艺 |
| WO2010069549A1 (en) * | 2008-12-17 | 2010-06-24 | Saudi Basic Industries Corporation | Process for increasing the carbon monoxide content of a syngas mixture |
| RU2408529C1 (ru) * | 2009-06-04 | 2011-01-10 | Алексей Дмитриевич Романов | Способ получения синтез-газа и водорода |
| RU2441837C2 (ru) * | 2010-04-19 | 2012-02-10 | Федеральное государственное образовательное учреждение высшего профессионального образования "Чувашский государственный университет имени И.Н. Ульянова" | Способ производства монооксида углерода |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2781139C1 (ru) * | 2018-12-20 | 2022-10-06 | Тиссенкрупп Индастриал Солюшнс Аг | Способ получения водорода, монооксида углерода и углеродосодержащего продукта |
| US12252405B2 (en) | 2018-12-20 | 2025-03-18 | Thyssenkrupp Uhde Gmbh | Process and device for producing hydrogen, carbon monoxide and a carbon-containing product |
| RU2832837C1 (ru) * | 2020-05-27 | 2025-01-09 | Басф Се | Циклический углеродный способ |
Also Published As
| Publication number | Publication date |
|---|---|
| EP2935098B1 (de) | 2018-02-14 |
| TWI633049B (zh) | 2018-08-21 |
| NO2935098T3 (esLanguage) | 2018-07-14 |
| EP2935098A1 (de) | 2015-10-28 |
| EP2935098A4 (de) | 2016-10-26 |
| CA2895924A1 (en) | 2014-06-26 |
| PL2935098T3 (pl) | 2018-08-31 |
| AR094247A1 (es) | 2015-07-22 |
| US20150336795A1 (en) | 2015-11-26 |
| RU2015129604A (ru) | 2017-01-27 |
| KR20150100805A (ko) | 2015-09-02 |
| CN104918882A (zh) | 2015-09-16 |
| KR102189391B1 (ko) | 2020-12-11 |
| US9834440B2 (en) | 2017-12-05 |
| WO2014097142A1 (de) | 2014-06-26 |
| JP6479677B2 (ja) | 2019-03-06 |
| CN104918882B (zh) | 2019-03-01 |
| ES2666141T3 (es) | 2018-05-03 |
| CA2895924C (en) | 2021-03-16 |
| TW201438987A (zh) | 2014-10-16 |
| JP2016501823A (ja) | 2016-01-21 |
| AU2013365822A1 (en) | 2015-07-23 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| RU2650171C2 (ru) | Параллельное получение водорода, монооксида углерода и углеродсодержащего продукта | |
| JP7528243B2 (ja) | 炭化水素の製造 | |
| AU2004217993B2 (en) | Hydrogen manufacture using pressure swing reforming | |
| RU2652720C2 (ru) | Способ утилизации горючих отходящих газов, попутных газов и/или биогазов | |
| Chen et al. | Experimental studies of pure hydrogen production in a commercialized fluidized-bed membrane reactor with SMR and ATR catalysts | |
| US20040170559A1 (en) | Hydrogen manufacture using pressure swing reforming | |
| EP0112613A2 (en) | Process for producing hydrogen-rich gas from hydrocarbonaceous feeds | |
| JP2011212574A (ja) | タール含有ガスの改質用触媒及びその製造方法、並びにタール含有ガスの改質方法 | |
| WO2009065792A1 (en) | Process to prepare a mixture of hydrogen and carbon monoxide | |
| AU2021284970B2 (en) | A process and reactor for converting carbon dioxide into carbon monoxide, involving a catalyst | |
| RU2781139C1 (ru) | Способ получения водорода, монооксида углерода и углеродосодержащего продукта | |
| Ismagilov et al. | Hydrogen Production from Coalmine Methane | |
| KR910009208B1 (ko) | 수소 농축 가스의 생산 방법 |